Boron (B), atomic number 5, is the first chemical element of Group 13 or Group IIIA in the periodic table has the smallest size and highest electronegativity, the compounds are essential to plant growth and wide industrial application of ancient civilization.
The topic is important for UG students. it covers almost all concepts of metallurgy. The important method of separation of ores, Ellingham diagram and its application.
The topic is important for UG students. it covers almost all concepts of metallurgy. The important method of separation of ores, Ellingham diagram and its application.
It contains introduction about dodecaborate anion , chemical properties like reaction with nitrogen, sulphur, phosphorus, arsenic, oxygen, carbon, selenium and metals. It's applications and the structural explanations are also includes.
This is an effort to make ppt of p block elements , a topic in XII, chemistry(cbse) , whom as a tutor i have often felt students are horrified due to its large text size, long descriptipns, several information to be remembered and several reasonings to keep in mind.
Hope this ppt would solve thier problem of a thorough preparation of topic with all important aspects covered in the ppt.
Founder Dr Mona Srivastava
Masterchemclasses
Improving the optical efficiency of white light-emitting diodes based on phos...journalBEEI
While the remote phosphor structure is not an appropriate solution for WLED color uniformity, it is more advantageous for the luminous output of WLED than the conformal phosphor or in-cup phosphor structure. Acknowledging the ability of the remote phosphor structure, many studies have been carried out to surmount the color quality disadvantage of this structure. A dual-layer remote phosphor configuration is proposed in this research paper to acquire better color quality for WLEDs through heightening the color rendering index (CRI) and the color quality scale (CQS). The color temperature of the WLED packages this study is 8500 K. By inserting a layer of green CaSO4:Ce3+,Mn2+ or red LiLaO2:Eu3+ phosphor on the yellow YAG:Ce3+ phosphor layer, the phosphor structure configuration can be constructed. Then, to get the best color quality, the concentration of added phosphor LiLaO2:Eu3+ would be changed. The findings showed the rise of CRI and CQS along with the LiLaO2:Eu3+, which implies the influence of LiLaO2:Eu3+ to the growth of red light components within WLEDs packages. The greater the concentration of LiLaO2:Eu3+ is, the more the CRI and CQS increase. Meanwhile, the luminous flux gains from the green phosphor CaSO4:Ce3+,Mn2+. Nevertheless, the luminous flux and color quality would decrease if the concentrations of both red LiLaO2:Eu3+ and green CaSO4:Ce3+,Mn2+ phosphors reach a certain corresponding level. Centered on the Mie-scattering theory and the law of Lambert-Beer, this result is illustrated. The findings in this research are vital references for manufacturing WLEDs with higher white light performance.
SOIL BORON, effect on plant growth and its managment in agriculture9416SaiSumanthHugar
This presentation consists of basics of boron element and its properties and their application in day to day life. it also presents the application of boron in agriculture and its managment.
It contains introduction about dodecaborate anion , chemical properties like reaction with nitrogen, sulphur, phosphorus, arsenic, oxygen, carbon, selenium and metals. It's applications and the structural explanations are also includes.
This is an effort to make ppt of p block elements , a topic in XII, chemistry(cbse) , whom as a tutor i have often felt students are horrified due to its large text size, long descriptipns, several information to be remembered and several reasonings to keep in mind.
Hope this ppt would solve thier problem of a thorough preparation of topic with all important aspects covered in the ppt.
Founder Dr Mona Srivastava
Masterchemclasses
Improving the optical efficiency of white light-emitting diodes based on phos...journalBEEI
While the remote phosphor structure is not an appropriate solution for WLED color uniformity, it is more advantageous for the luminous output of WLED than the conformal phosphor or in-cup phosphor structure. Acknowledging the ability of the remote phosphor structure, many studies have been carried out to surmount the color quality disadvantage of this structure. A dual-layer remote phosphor configuration is proposed in this research paper to acquire better color quality for WLEDs through heightening the color rendering index (CRI) and the color quality scale (CQS). The color temperature of the WLED packages this study is 8500 K. By inserting a layer of green CaSO4:Ce3+,Mn2+ or red LiLaO2:Eu3+ phosphor on the yellow YAG:Ce3+ phosphor layer, the phosphor structure configuration can be constructed. Then, to get the best color quality, the concentration of added phosphor LiLaO2:Eu3+ would be changed. The findings showed the rise of CRI and CQS along with the LiLaO2:Eu3+, which implies the influence of LiLaO2:Eu3+ to the growth of red light components within WLEDs packages. The greater the concentration of LiLaO2:Eu3+ is, the more the CRI and CQS increase. Meanwhile, the luminous flux gains from the green phosphor CaSO4:Ce3+,Mn2+. Nevertheless, the luminous flux and color quality would decrease if the concentrations of both red LiLaO2:Eu3+ and green CaSO4:Ce3+,Mn2+ phosphors reach a certain corresponding level. Centered on the Mie-scattering theory and the law of Lambert-Beer, this result is illustrated. The findings in this research are vital references for manufacturing WLEDs with higher white light performance.
SOIL BORON, effect on plant growth and its managment in agriculture9416SaiSumanthHugar
This presentation consists of basics of boron element and its properties and their application in day to day life. it also presents the application of boron in agriculture and its managment.
A Survey Paper On: The Chemistry of Vitamin B12 and Related Inorganic Model S...paperpublications3
Abstract: Cobaloxime complexes of the type [CoCl(DMGH)2(L)], where DMGH = dimethylglyoxime monoanion, L =tri-ethanol amine and 1,10 phenanthroline, were synthesized. The compounds were formulated on the basis of cobalt and chloride contents, IR and UV-visible spectral analyses and magnetic moment measurement. Cyclic voltammetric technique was also employed to investigate the interaction between Co(II)and the ligands under study.
Metals having chemical and electrochemical reactions with their surroundings can go bad and become unusable. It’s called corrosion. Many metals , especially iron , undergo corrosion when exposed to air and water. 1/10 of all metallic materials produced every year becomes unusable and it’s not possible to recycle them. Loss caused by corrosion costs billion of dollars every year. This study presents the results of corrosion resistance of ground blast furnace slag (GBFC) , chrome slag (CS)and corn stem ash. (CSA) In this study GBFC , CS and CSA , produced as a result of some procedures , are mixed with pitch in different portions. The reason for mixing with pitch is to gain the adherence. Then the iron plates were coated with this mixture. Coated and uncoated plates were undergone corrosion in Na Cl solution (35g/L Na Cl ). Having kept in the solution for one mount , the coated and uncoated plates were taken out and dried. The plates were put into Na Cl solution with the help of electrodes and the potential differences were measured. Our aim to do so was to reduce the potential difference. If the potential difference reduces , the electric currency reduces , so the corrosion is reduced too. The potential difference of the uncoated iron plates was 0.501 volts. Of coated with pitch 0.301 and mixed up with our experiment materials was 0. So the corrosion was reduced totally. This means: Billions of dollars loss is prevented A profitable use of GBFC , which is environmentally harmful , can be made and the nature can be protected. An economical use of CS , which is thrown away can be gained Some profit can be gained from corn stems that are left to be rotten in the fields. If the substance we’ve produced is used all the fields that iron is used , such as buildings , ships , water pipes etc , billions of dollars can be saved.
NON METALS AND THEIR COMPOUNDS-2
CARBON
Carbon is the non- metal with electronic configuration C= 2: 4, found in the group four and second level. Carbon is insoluble. Carbon can be found on the rocks e.g. chalk – CaCO3 and common in the organic food substance e.g. Glucose – C6H12O6.
Properties of carbon 1. Carbon monoxide 2. Carbon monoxide (CO)
The simplified electron and muon model, Oscillating Spacetime: The Foundation...RitikBhardwaj56
Discover the Simplified Electron and Muon Model: A New Wave-Based Approach to Understanding Particles delves into a groundbreaking theory that presents electrons and muons as rotating soliton waves within oscillating spacetime. Geared towards students, researchers, and science buffs, this book breaks down complex ideas into simple explanations. It covers topics such as electron waves, temporal dynamics, and the implications of this model on particle physics. With clear illustrations and easy-to-follow explanations, readers will gain a new outlook on the universe's fundamental nature.
Macroeconomics- Movie Location
This will be used as part of your Personal Professional Portfolio once graded.
Objective:
Prepare a presentation or a paper using research, basic comparative analysis, data organization and application of economic information. You will make an informed assessment of an economic climate outside of the United States to accomplish an entertainment industry objective.
2024.06.01 Introducing a competency framework for languag learning materials ...Sandy Millin
http://sandymillin.wordpress.com/iateflwebinar2024
Published classroom materials form the basis of syllabuses, drive teacher professional development, and have a potentially huge influence on learners, teachers and education systems. All teachers also create their own materials, whether a few sentences on a blackboard, a highly-structured fully-realised online course, or anything in between. Despite this, the knowledge and skills needed to create effective language learning materials are rarely part of teacher training, and are mostly learnt by trial and error.
Knowledge and skills frameworks, generally called competency frameworks, for ELT teachers, trainers and managers have existed for a few years now. However, until I created one for my MA dissertation, there wasn’t one drawing together what we need to know and do to be able to effectively produce language learning materials.
This webinar will introduce you to my framework, highlighting the key competencies I identified from my research. It will also show how anybody involved in language teaching (any language, not just English!), teacher training, managing schools or developing language learning materials can benefit from using the framework.
Acetabularia Information For Class 9 .docxvaibhavrinwa19
Acetabularia acetabulum is a single-celled green alga that in its vegetative state is morphologically differentiated into a basal rhizoid and an axially elongated stalk, which bears whorls of branching hairs. The single diploid nucleus resides in the rhizoid.
A workshop hosted by the South African Journal of Science aimed at postgraduate students and early career researchers with little or no experience in writing and publishing journal articles.
This presentation includes basic of PCOS their pathology and treatment and also Ayurveda correlation of PCOS and Ayurvedic line of treatment mentioned in classics.
Unit 8 - Information and Communication Technology (Paper I).pdfThiyagu K
This slides describes the basic concepts of ICT, basics of Email, Emerging Technology and Digital Initiatives in Education. This presentations aligns with the UGC Paper I syllabus.
Executive Directors Chat Leveraging AI for Diversity, Equity, and InclusionTechSoup
Let’s explore the intersection of technology and equity in the final session of our DEI series. Discover how AI tools, like ChatGPT, can be used to support and enhance your nonprofit's DEI initiatives. Participants will gain insights into practical AI applications and get tips for leveraging technology to advance their DEI goals.
Read| The latest issue of The Challenger is here! We are thrilled to announce that our school paper has qualified for the NATIONAL SCHOOLS PRESS CONFERENCE (NSPC) 2024. Thank you for your unwavering support and trust. Dive into the stories that made us stand out!
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Boron
Boron in Periodic Table
Boron (B), atomic number 5, is the first chemical element of Group 13 or Group IIIA
in the periodic table has the smallest size and highest electronegativity, the
compounds are essential to plant growth and wide industrial application of ancient
civilization. The small size, high ionization energy, and moderate electronegativity
(close to carbon and hydrogen) explain the formation of many exciting and unusual
covalent bond or compound of boron in chemistry. The natural boron contains two
isotopes like B or B-10 (19.6 percent) and B or B-11 (80.4 percent). Boron in the
Group 13 of the periodic table member occurs in a small amount due to its nucleus
being disintegrated by natural bombardment reactions but aluminum is very
abundant, occupies the third position after oxygen and silicon.
Properties and Occurrence
10 11
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Pure boron is a high melting solid diamagnetic substance (melting point = 2180 °C)
which be either crystalline (black) or amorphous (brown), uses as a semiconductor
conducts electricity at high temperature like a metal. Crystalline boron exists in
several allotropic forms which are structurally very complex, build up by B
icosahedra. Different types of packing on icosahedra in-unit crystal lattice form
different types of the structural formula of boron, the simplest form is α-
rhombohedral.
12
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The abundance of boron in crustal rocks (9 ppm) of our earth universe is very low
which is less than that of lithium (18 ppm) or lead (13.1 ppm). The vast deposits of
boron minerals like borate or borosilicates are occurred in the regions of California,
Turkey, Russia, and Argentina by former volcanic activities and water from hot
springs. The principal minerals of boron are colemanite, Ca [B O (OH) ] , 2H O;
kernite Na [B O (OH) ], 2H O; and borax, Na [B O (OH) ], 8H O. In India, Tibet,
and Sri Lanka, borax occurs as a precipitate from hot springs.
History, Isolation, and Uses
In history, the different civilizations of the world, the compound of boron borax uses
as a flux, or prepared glazes and hard glass. The element itself was isolated in the
nineteenth century by Davy, Gay Lussac, and Thenard by electrolysis of moist boric
acid. Moissan in 1892 prepared a rather pure specimen of boron (95 percent) by
heating B O with magnesium metal and the name proposed by Devay to illustrate its
source and similarities to carbon. The crystalline form of high purity element is now
obtained by reduction of volatile boron compounds (BCl or better BBr ) with
2 3 4 3 2 2
2 4 5 4 2 2 4 5 4 2
2 3
3 3
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hydrogen on heated titanium wire. However, the process can operate to form the
element on a kilogram scale. Below 1000 °C, amorphous boron is obtained, between
1000 to 1200 °C α and β-rhombohedral form is obtained and above 1200 °C
tetragonal crystal is formed.
In large quantities, the amorphous boron is obtained by reduction of B O with
magnesium (Mg) or other electropositive metals at high temperatures (B O + 3Mg
→ 2B + 3MgO). The reaction is exothermic with the free energy at 298K = -515 kJ.
The unreacted substances and MgO can be removed by washing the substance with
dilute hydrochloric acid (HCl) and sodium hydroxide (NaOH) solutions. The 95
percent pure boron powdered is cheaply obtained by electrolytic reduction of KBF in
molten KCl or KF at 800 °C.
Boron and its compounds are extensively used in filaments and fiber composites used
in reinforcement materials (space shuttles and aircraft). Boron carbides are used as
abrasive for polishing or grinding, the carbides and metal borides are extensively used
in neutron shielding and control rods for nuclear power plants. The isotope of boron
( B) has a high absorption cross-section for high energy neutrons (10 to 10 eV) is a
more beneficial substance in B-10 neutron capture therapy of brain tumors. Metal
borides (TiB , ZrB ) have found much technical application. Due to the physical and
chemical properties like high melting point, hard nature, and chemically inertness of
metal borides (compound of boron), metal borides are used as a coating on turbine
blades, rocket nozzles, and high-temperature reaction vessels. Boric acid, B O , and
borax are used in medicine, in making borosilicate glass, enamels, and fire retardant.
Chemical Reactivity of Boron
The crystalline elemental form of boron is chemically very inert and not affected by
acids or oxidizing agents but fused sodium hydroxide (NaOH) at 500 °C attacks to
form NaBO and hydrogen gas. The amorphous form is more reactive than the
crystalline form. Therefore, the amorphous elements of Group 13 (B, Al, Ga, In) burns
2 3
2 3
4
10 4 6
2 2
2 3
2
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in the air to form trioxides and nitrides. It dissolves in oxidizing acid-like nitric acid
(HNO ) or sulfuric acid (H SO ) but unreacted with hydrochloric acid (HCl). Only
boron and aluminum combine directly with nitrogen when heated to form BN and
AlN but GaN and InN may be obtained indirectly by heating the metals with
ammonia.
Boron Compounds
The electron configuration of boron is 1s 2s 2p , with the two electrons in s-orbitals
and one electron in p-orbital suggest the monovalent state but it never exhibits +1
oxidation number, only shows +3 state of the chemical element. The chemistry of the
first member of the boron family is naturally influenced by the small size and high
ionization energy and the compounds will be essentially covalent chemical bonding
with the oxidation state III. The formation of B ion appears unlikely for two main
reasons, the ionization energy for the formation of B ion would be very large, and
small ion has highly polarizing properties. Due to the presence of three bond pairs,
the compounds of boron function as a Lewis acid by accepting electron pairs from the
Lewis base.
The electron deficiency defines the unique characteristics of boron to form Pi-bonds
with elements like chlorine, fluorine, etc. In BH , BCl or BF , the element attains
noble gas configuration through dimerization of the molecule. Due to its small size,
the boron atom can readily form a stable lattice with metal atoms (interstitial alloy),
chain species, and three-dimension networks. Depending upon the individual
structure and chemical reactivity, the principal boron compounds may be classified
into, hydrides and their derivatives (carboranes and polyhedral borane metal
complexes), halides, oxygen compounds including polyborates, borosilicates, metal
borides, nitrogen, and organoboron compounds in learning chemistry.
3 2 4
2 2 1
+3
+3
3 3, 3