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K. Ramesh et al Int. Journal of Engineering Research and Applications
ISSN : 2248-9622, Vol. 4, Issue 1( Version 3), January 2014, pp.346-354

RESEARCH ARTICLE

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OPEN ACCESS

Impact of Groundwater Quality from Industrial East Coastal
Town, Southern India
K. Ramesh*, L. Elango**
* (Centre for Water Resources, Department of Civil Engineering, Anna University, Chennai-600 025, INDIA)
** (Department of Geology, Anna University, Chennai -600 025, INDIA)

ABSTRACT
Contamination of drinking water by human and industrial activities is a serious concern now-a-day.
Indiscriminate use of groundwater deteriorates the quality and quantity of water. The study was carried out to
assess the impacts of industrial activities on the groundwater quality in and around Cuddalore coast town during
September 2012 and February 2013. The quality was assessed in terms of physio-chemical parameters and
compared with BIS. The groundwater samples are classified into Ca2+-HCO32- type, Ca2+-Mg2+-Cl- type based on
its hydrogeochemical characteristics. . The groundwater at many locations in the study area is not suitable for
drinking because of its high salinity, hardness and chloride, which is mainly caused by industries discharge,
agricultural activities and seawater intrusion. The WQI reflected that most of the samples are of poor water to
very poor water. The Wilcox diagram, USSL diagrams and PI shows that most of the samples are suitable for
irrigation. It was found that the groundwater was contaminated at few sample locations. The consequence of
industrialization and urbanization leads to degradation of water quality. Hence the local government needs to
initiate remedial measures.
Keywords - Physiochemical characteristics, seawater intrusion, suitability drinking and irrigation, coastal town.

I.

INTRODUCTION

Water is a precious and most commonly
used resource. Water is one of the most abundant
chemical substances on earth, as it covers two third
of the earth surface. Of the total amount of global
water, only 2.4% is distributed on the main land, of
which only a small portion can be utilized as fresh
water. The available fresh water to man is hardly 0.30.5% of the total water available on the earth and
therefore, its judicious use is imperative [1].
Groundwater plays significant role in the living
organisms that existing in this world. Groundwater
has become a necessary resource over the past
decades due to the increase in its usage for drinking,
irrigation, industrial use etc. In the last few decades,
there has been a tremendous increase in demand for
fresh water due to rapid growth of population and the
accelerated pace of industrialization. Human health is
threatened by most of the agricultural development
activities particularly in relation to excessive
application of fertilizers and unsanitary conditions.
Rapid urbanization, especially in developing
countries like India, has affected the availability and
quality of groundwater due to its overexploitation and
improper disposal in urban areas. Many of the
groundwater in the coastal aquifer is suffering from
seawater intrusion both by natural process and
anthropogenic activities [2].
According to [3], 80% of all disease in
human being is water-borne. Once the groundwater is
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polluted; its quality cannot be restored by stopping
the pollutants from the source. Also most of the
industries operating in the area discharge their
effluent directly into the sea or creek without
considering the effects of these wastes on the coastal
shallow aquifers and aquatic lives. In the coastal
regions the availability of fresh water is always
threatened by over extraction or by seawater intrusion
and in some cases the risk is from the agricultural and
industrial activities. The objective of the present
work is to discuss the suitability of groundwater for
human consumption and irrigation quality.

II.

II.STUDY AREA

The present study was carried out in east
coastal region of Cuddalore that lies 125 kilometers
south of Chennai on the coast of the Bay of Bengal
(Figure 1). The study area forms a part of Cuddalore
district which lies in between north Latitudes of
11˚44’04” and 11˚68’01”and east longitudes
79˚70’09” and 79˚77’05” with a total extent of 46
sq.km. The area form a part of the Survey of India
topo-sheet no 58 M/10. The area has a tropical
climate with an annual average precipitation of 1160
mm and most of the rainfall occurs during northeast
monsoon (October to January). The temperature
ranges from 21ºC to 39ºC with an average of 28ºC.
The humidity of the region varies from 67% to 85%.
The area falls under seismic zone-II with a plain
terrain. Agricultural activities, especially paddy,
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K. Ramesh et al Int. Journal of Engineering Research and Applications
ISSN : 2248-9622, Vol. 4, Issue 1( Version 3), January 2014, pp.346-354
sugarcane, groundnut cultivation are most common.
The area is entirely underlain by

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this pollution impact the health status of the
surrounding area of industrial region.

Figure.1 Location Map of Study Area
Sedimentary formations, which include calcareous
sandstone, coastal alluvium, and laterite soil of
tertiary and quaternary age. The most common
outcrops in the area are limestone, sandstone and
clays. The soil types are red sandy loam, loamy sand,
lateritic, clay loam and clayey soil. The general
phreatic aquifers with moderate to shallow water
table conditions exist in this area. The depth of bore
wells ranges from 40 to 170 m below groundwater
level and deeper bores ranges from 400 to 500 m.
Groundwater has been used for various purposes,
such as domestic, agricultural and industrial needs.
Groundwater in this area is overexploited for
industrial and agricultural purposes are predominant
land use in this area. The industrial pollution and
seawater intrusion are the main reasons for
deterioration of water quality. An industrial estate
SIPCOT (Small Industries Promotion Corporation of
Tamil Nadu) with groups of industries near the coast,
which generate chemicals and raw materials are
distributed along the coastal area. Most of industries
are wet process industries and hence consume large
quantity of water. The entire water requirement of
these SPICOT industries is met by ground water. The
groundwater availability and quality of the area is
adversely affected by the industrialization and
urbanization of the town. The villagers particularly
children have skin problem and constant itching and
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III.
METHODOLOGY
Groundwater samples were collected from
22 locations in and around Cuddalore coastal town
during pre-monsoon period (Sep 2012) and postmonsoon (Feb 2013) and the parameters EC were
measured on the spot at the time of sample collection
using potable kit. The collected groundwater samples
were transferred into plastic container for analysis of
chemical characters and the water samples collected
in the field were analyzed for electrical conductivity
(EC), pH, total dissolved solids (TDS), major cations
like calcium(Ca2+), magnesium(Mg2+), sodium(Na+),
potassium(K+) and anions like bicarbonate(HCO3-),
carbonate(CO32-), chloride(Cl-) and sulphate (SO42-),
in the laboratory using the standard methods given by
the American Public Health Association [4]. Analysis
of heavy metals is tested in the Atomic Absorption
Spectrometry such as Nitrate (NO3-), Iron (Fe-),
Phosphate (PO4-) and fluoride (F-) is to identify the
heavy metals concentration in the groundwater. The
heavy metal concentrations are generally leads to
anthropogenic activities.

IV.

RESULT AND DISCUSSION

Groundwater Chemistry
World health organization [5] has reported that about
80% of the health hazards occur in world due to the
poor quality of water used for consumption. The pH
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K. Ramesh et al Int. Journal of Engineering Research and Applications
ISSN : 2248-9622, Vol. 4, Issue 1( Version 3), January 2014, pp.346-354
indicates the acidic or alkaline material present in the
water. The pH of groundwater samples in this area
ranges from 4.0-8 .0 and 6-7.8 during pre and postmonsoon respectively, seasonal variation shows the
pH values fluctuating at all locations. The higher pH
is present in the eastern part of the study area in both

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is caused primarily by the presence of cations such as
calcium and magnesium and anions such as
carbonate, bicarbonate, chloride and sulphate in
water. Water with hardness greater than 300 mg/.l
may raise the risk of calcification of arteries, urinary
concretions, diseases of kidney or bladder or stomach

Figure.2 Spatial Variation of Electrical Conductivity
monsoon seasons and is slightly acidic due to the
industrial effluent and domestic sewage. Most of the
area shows the permissible limit of pH in drinking
water is within 6.5- 8.5 according to Bureau of Indian
Standards [6]. Electrical Conductivity (EC) value of
the study area varied from 320-7210μѕ/cm and 3516495 μѕ/cm during pre and postmonsoon seasons
(Figure 2). EC is a measure of water’s capacity to
conduct electric current since most of the salts in the
water are present in the ionic form. In general,
groundwater tends to have high electrical
conductivity due to the presence of high amount of
dissolved salts. EC is decisive parameters in
determining suitability of water for a particular
purpose. Drinking water quality is also affected by
the presence of soluble salts. The total dissolved
solids (TDS) upto 500 to 1500 mg/l is permitted for
drinking as well as other domestic purposes as per the
standards. Water with high TDS indicates more ionic
concentration, which is inferior and can cause
physiological disorders to its users [7]. TDS observed
from this area is between 204-4614 mg/l and 2243904 mg/l in pre and post-monsoon. Most of the
groundwater samples are within the maximum
permissible limit for drinking water as per the BIS,
except four samples. In this region, the total hardness
varies between 202-960 mg/l and 100-800 mg/l
during pre and post-monsoon were quite high with
their prescribed standards of 300 mg/l. Hardness in
water is due to the natural accumulation of salts from
contact with soil and geological formation or it may
direct pollution by industrial effluent. Total hardness
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disorders [8]. The calcium concentration in water
samples collected from the study area ranged from
800-500 mg/l and 100-420 mg/l in pre and postmonsoon seasons. So, most of the samples exceed the
permissible limit due to rapid industrialization and
urbanization and their wastes are known to account
for such anthropogenic sources of calcium in water
[9]. Calcium is a major constituent of various types
of rocks and aquifers. Calcium is an essential cause
for hardness in water, incrustation in boilers and
essential constituent of human beings. In
groundwater the calcium content generally exceeds
the magnesium content [10]. In this present study the
magnesium level in the water samples ranged from
30-495 mg/l and 25-440 mg/l in pre and postmonsoon seasons. In most of the locations
magnesium exceeds the permissible limit which may
result in intestinal irritation of human system
particularly near the industrial area.
The
concentration of sodium in the area varies from 50640 mg/l in pre-monsoon and in post-monsoon the
value range from 80-650 mg/l. Groundwater in most
of the areas comes under the non-safe zone for
drinking with reference to the concentration of
sodium, which is more than 200 mg/l. The higher
concentration of sodium may pose a risk to persons
suffering from cardiac, rental and circulatory diseases
[11]. Person afflicted with certain diseases require
low sodium concentration In present investigation
potassium concentration was ranged from 15-137
mg/l and 35-130 mg/l during pre and post-monsoon.
The permissible limit of potassium is 10 mg/l and in
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K. Ramesh et al Int. Journal of Engineering Research and Applications
ISSN : 2248-9622, Vol. 4, Issue 1( Version 3), January 2014, pp.346-354

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Concentration (mg/l)

NO3 (mg/l)
100
90
80
70
60
50
40
30
20
10
0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22
Sampling Wells

Figure. 3 Nitrate variations
Iron (Fe-) concentration in natural water is
very low. The concentration in the groundwater of
the area varied from 0.1-3.5 mg/l in post-monsoon
season (Figure 4), and most of the samples have low
iron concentration and very few samples exceeds the
permissible limit. The desirable limit of Fe for
drinking water was 0.3 mg/l and maximum
permissible limit was 1.0 mg/l as per Indian
standards. Iron is biologically an important element
which is essential to all organisms and present in
hemoglobin system [16]. Iron in drinking water is
due to geological, industrial wastes and domestic
discharge.
Fe (mg/l)

P(mg/l)

F(mg/l)

3.5

Concentration (mg/l)

the study area nearly 50% of the samples exceed the
permissible limit. K is an essential nutrient but if
ingested in excess may behave as a laxative.
Bicarbonate (HCO3-) was observed higher of 1481000 mg/l during post-monsoon season than premonsoon 183-976 mg/l. The source of high
concentration of bicarbonate may be due to
dissolution of CO3 of the soil and percolation due to
rain water as well as irrigation [12]. The most
important source of chlorides in the water is the
discharge of industries effluents or sewage, fertilizers
and septic tanks. The chloride concentration varied
from 20-487 mg/l and 26-520 mg/l during pre and
post-monsoon. The chloride ion is higher than 200
mg/l may pose risk to human health and may cause
unpleasant taste of water. Its high consumption may
be crucial for development of essential hypertension,
risk for stroke, osteoporosis, renal stones and asthma
[13]. High concentration of chlorides is considered to
be the indicators of pollution due to high organic
wastes of industrial or animal origin, presence of
sodium chloride from rocks and saline water
intrusion. High chloride content may harm metallic
pipes as well as growing plants. In this study area few
areas have higher concentration, which could be
dangerous from health point of view. The high
chloride may be attribute industrial, domestic wastes,
leaching, from upper soil layers in dry climates and
natural geochemical activities in this area [14]. In
present investigation sulphate concentration was
ranged from 33-489 mg/l and 15-450 mg/l during pre
and post-monsoon. The major physiological effects
resulting from the ingestion of large quantities of
sulphate
are
catharsis,
dehydration
and
gastrointestinal irritation. In the study area the 32%
of sulphate ions exceed the permissible limit of 250
mg/l. The higher sulphate content is present due to
bio-chemical, anthropogenic sources and industrial
process etc and a higher concentration were seen near
the industrial areas in both seasons.
The nitrate concentration in groundwater collected
from the study area ranged between 40 to 96 mg/l
and 45 to 92 mg/l in pre and post-monsoon (Figure
3). The permissible limit of nitrate is 45 mg/l
prescribed as per standards. Increased level of nitrate
at various locations may be attributed due to the
surface disposal of sewage and agricultural wastes.
The permissible limit of nitrate is 45 mg/l. The
influence of nitrate is seen in western part of the
study area where the agricultural practices. The
origin of nitrate is derived may be from agricultural
areas due to leaching process from plant nutrient,
nitrate fertilizers, industrial effluents and poor
sanitary conditions [15]. The high concentration of
nitrate in drinking water causes methenoglobinemia
in infants, a disease characterized by blood changes.

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3
2.5
2
1.5
1
0.5
0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22
Sampling Wells

Figure .4 Iron, Phosporus and Fluoride
variations in Post-monsoon season
Phosphorus is an important constituent of
the lithosphere. The result indicates the presence of
phosphate in the groundwater ranges from 0.55 to 3.6
mg/l during postmonsoon season as shown in figure
4.The higher phosphorus in groundwater is an
indication of contamination by industrial pollutant
and sewage [17]. Some samples show the beyond the
limits recommended for domestic purposes. The
water-soluble phosphate in the widely used
fertilizers, surface water runoff, agricultural runoff
and man activity could also contribute to the
groundwater [18-19].
One of the main trace elements in
groundwater is fluoride which generally occurs as
natural constituents. Fluoride ion in drinking water is
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K. Ramesh et al Int. Journal of Engineering Research and Applications
ISSN : 2248-9622, Vol. 4, Issue 1( Version 3), January 2014, pp.346-354
known for both beneficial and detrimental effects on
health. Excess of fluoride in water causes serious
damage to the teeth and bones of the human body,
which shows the symptoms of disintegration and
decay, diseases called dental fluorosis, muscular
fluorosis and skeletal fluorosis. The fluoride
concentration range in the study area was found to be
1 to 1.8 mg/l in post monsoon season (Figure 4). The
BIS described the drinking water quality 1.5 mg/l
nearly 22% of samples exceeds the permissible limit.
According to UNESCO specifications, water
containing more than 1.5 mg/l of fluoride cause
mottled tooth enamel in children and not suitable for
drinking purpose. Recently it has been identified that
water containing fluoride 1.4 to 5.5 mg/l causes
dissolution of aluminum from utensils, causing
Dementia-a disease leading to loss of memory and
mental impairment [20].
Hydrochemical facies
Piper diagram is used to determine hydrochemical
facies of water Major ions are plotted as cations and
anions percentage in meq/l in two base triangles with
total ions set to equal 100 percentages (Figure 5). The
data points in the two triangles are then projected to
central diamond which allows comparison of a large
number of samples. The chemical data is plotted on
the piper trilinear diagram [21]. Major cations and
anions such as Ca, Mg, Na, K, HCO3, SO4 and Cl in
meq/l were plotted in piper trilinear diagram as the
percent of the major constituents. Grouping of waters
on the piper diagram suggests a common composition
and origin. It can be used to classify and identify
mixing of waters that most of groundwater samples
fall in the field Ca-HCO3 and Mixed Ca-Mg-Cl and
few samples fall in Ca-Cl in both the seasons.

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Water Quality Index (WQI)
The WQI has been calculated to evaluate the
suitability of groundwater quality for drinking
purposes [22]. WQI is defined as a technique of
rating that provides the composite influence of
individual water quality parameters on the overall
quality of water for human consumption [23]. The
world health organization [24] standards for drinking
purposes have been considered for the calculation of
WQI. For the calculation of WQI 10 parameters such

Figure.6 Spatial variations of Water Quality
Index
Table 1: Water quality classification based on WQI
WQI
Value

Feb
(%)

Excellent

9.09

13.63

Good Water

22.72

13.63

100-200

Poor Water

27.27

45.45

200-300

Very Poor Water

36.36

27.27

>300

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Sept
(% )

Less
than 50
50-100

Figure. 5 Piper diagram depicting hydrochemical
facies

Water Quality

Unsuitable for
drinking

4.54

-

as pH, Na+, K+, Ca2+, Mg2+, Cl-, HCO3-, SO42- and
TDS have been considered. WQI varied from 33 to
312 during pre-monsoon season and from 46 to 291
during post-monsoon season (Figure 6) and therefore
can be categorized into four types excellent to very
poor water for drinking. Table 1 shows the
percentage of water samples that falls under different
much with season. Some samples were changed into
good to excellent and unsuitable to poor water quality
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K. Ramesh et al Int. Journal of Engineering Research and Applications
ISSN : 2248-9622, Vol. 4, Issue 1( Version 3), January 2014, pp.346-354
due to dilution processes taken place in the pre to
post-monsoon. Hence, it can be seen that water
quality of different locations in the industrial region
quality in September 2012 and February 2013. The
monsoonal dilution does not serve much towards the
quality improvement in the industrially contaminated
area and so the WQI of these regions does not change
deteriorates in both the seasons and low value is
observed in the southern part of the study area. This
area is generally free from industries and sea water
intrusion because it is away from the Cuddalore
coastal zone. Majority of samples falls poor to very
poor water in both the seasons. The higher WQI
values in the samples can be attributed to the
continuous discharge of industrial effluent and a little
amount of sewage in the study area. The analysis
reveals that the groundwater of the area needs to be
treated before consumption and it also needs to be
protected from the perils of contamination.

[26]. A few hydrogeochemical parameters that are
suggested as criteria for sea water contamination are
Ca2+/Mg2+, Cl-/(CO32- + HCO32-), Na+/Cl- ratios
(Figure 7) etc. In the study area the ratios are ranging
by following values.
Cl-/(CO32-+HCO32-) ratio used as a criterion
to evaluate the salt water intrusion. Chloride is most
dominant in ocean water and normally occurs in
small amount in groundwater, while HCO 32- is
usually the most abundant negative ion in
groundwater but it occurs in minor amounts in the sea
water. The degree of concentration is as follows.
Table 3: Criteria for Reorganization of
Saltwater Intrusion
From the above limit values, majority of the area
Range of Cl/(CO32- + HCO3-)
Ratio
<0.05

Stuyfzand Classification
Stuyfzand [25] has proposed a method of
classification of groundwater and identified 8 main
types on the basis of Chlorinity (Cl-) shown in Table
2. It is used for identification of freshwater flow zone
from the zone of salt-water intrusion. In both the
monsoon periods the Oligohaline water types occur

0.05-1.30

only in Stuyfzand Classification ofgroundwater
Table 2: Loc.19.fresh water occurs in location
11,14,15,16,17,18,21 and 22. Fresh-Brackish water

>200

-

Main Type

Cl- (mg/l)

Main Type

Cl
(mg/l)

Very
Oligohaline

<5

Brackish

300-103

Oligohaline

5-30

BrackishSalt

103-104

Fresh

30-150

Salt

1042x104

FreshBrackish

150-300

Hyperhaline

>2x104

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1.30-2.80
2.80-6.60
6.60-15.50

Description
Normally fresh groundwater
Slightly contaminated
groundwater
Moderately contaminated
groundwater
Injuriously contaminated
groundwater
Highly contaminated
groundwater
Sea water

From the above limit values, majority of the area
shows slightly contaminated groundwater with the
values of 0.05-1.30 and 5 samples is seems to be
moderately contaminated groundwater. There is no
fresh groundwater and whatever water available is
injuriously polluted and highly contaminated
according to the ratio as shown in Table 3.
Na/Cl ratios of saltwater intrusion are
usually lower than the marine values (i.e., <0.86,
molar ratio). On the other hand, high (more than 1)
Na+/Cl- ratios, typically characterize anthropogenic
sources. The low Na+/Cl- ratios combined with other
geological parameters, can foretell the arrival of
saltwater intrusion. According to Na+/Cl- ratio, 50%
of the study area is contaminated with marine source
of contamination. Remaining area is contaminated
due to anthropogenic sources like domestic and
industrial effluents.

only in Loc.19.fresh water occurs in location
11,14,15,16,17,18,21 and 22. Fresh-Brackish water
found in sampling locations 1, 2,10,12,13 and 20. All
the remaining sampling locations 3, 4, 5, 6, 7, 8 and 9
the brackish water type exists.
Criteria for Reorganization of Saltwater Intrusion
In order to identify brackish or saline waters
hydro geochemical parameters are normally used
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K. Ramesh et al Int. Journal of Engineering Research and Applications
ISSN : 2248-9622, Vol. 4, Issue 1( Version 3), January 2014, pp.346-354

Figure.7 Source of Contamination based on
ratios
Irrigation Water Quality
Irrigation water is one of the important
concerns to the plant growth. The Groundwater is
valuable only when its quality is suitable for a variety
of purposes. Water for irrigation should satisfy the
needs of basic requirements of plant growth. EC and
Na+ play a vital role in the suitability of water for
irrigation. The high salt content in irrigation water
causes an increase in soil solution osmotic pressure.
A high salt content in water leads to formation of
saline soil. The salts, besides affecting the growth of
plants directly, also affect soil structure, permeability
and aeration, which indirectly affect plant growth
[27]. The suitability of water for irrigation can be
estimated by means of many determinants, though,
Sodium Adsorption Ratio (SAR), Percent Sodium
(Na+%), Permeability Index (PI), and Residual
Sodium Carbonate (RSC) .

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Sodium concentration is important in classifying
irrigation water because sodium reacts with soil to
reduce its permeability, texture makes the soil hard to
plough and unsuitable for seeding emergence [29].
Sodium with chloride or sulphate as the predominant
anion is saline soil and carbonate as the predominant
anion is termed alkaline soils. Wilcox diagram
(Wilcox 1955) is adopted for the classification of
groundwater for irrigation, wherein the EC is plotted
in x axis and % Na+ in Y axis. Depending on the
distribution of Na+% water are classified into four
classes [30] such as Excellent to Good, Good to
Permissible, Doubtful to Unsuitable and Unsuitable.
During both the seasons most of samples fall in
categories of excellent to good and good to
permissible excepting four samples which are
unsuitable for irrigation purpose.
Sodium adsorption ratio and salinity hazard
The sodium/alkali hazard is typically
expressed as the sodium adsorption ratio (SAR). The
index quantifies the proportion of sodium (Na+) to
calcium (Ca2+) and magnesium (Mg2+) ions in a
sample. All the values are expressed in meq/l. The
diagram is a simple plot of salinity hazard (EC) on
the X- axis and sodium hazard on the Y-axis USSL
classification diagram of groundwater for irrigation
purpose (Figure 9).Sodium concentration is important
in classifying the water for irrigation purposes
because sodium concentrations can reduce the soil
permeability and soil structure [31]. The analytical
data plotted on the US salinity diagram illustrates that
most of the groundwater samples fall in the field of
good water to permissible (fair) water, which can be
used for irrigation on

Wilcox Diagram
Wilcox [28] used percent sodium and
specific conductance used evaluating irrigation water.
In the Wilcox diagram Na% is plotted against
specific conductance. An appraisal of the Wilcox
diagram (Figure 8) shows that most of the samples
from the study area fall under good to permissible

Figure.9 USSL classification

Figure.8 Wilcox Classification
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almost all types of soil with little danger of
exchangeable sodium. The five samples fall in poor
quality water due to the high electrical conductivity
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K. Ramesh et al Int. Journal of Engineering Research and Applications
ISSN : 2248-9622, Vol. 4, Issue 1( Version 3), January 2014, pp.346-354
will cause salinization [32]. Irrigation water with
high Na+% may cause sodium accumulation and
calcium deficiency in the soil leading to a breakdown
of its physical properties [29]. Therefore, good
drainage, high leaching and use of organic matter are
required for its management in this area.
Permeability Index (PI)

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brackish and brackish water types. Regarding salt
water intrusion, Cl-/ (CO32-+HCO32-) ratio, and the
groundwater is found slightly too moderately
contaminated. According to Na+/Cl- ratio, the
contamination may be due to marine source of origin,
anthropogenic and geogenic sources.
The
groundwater samples from the Cuddalore Old Town
and Port is highly polluted and unfit for drinking
purpose. Though the suitability of water for irrigation
is determined based on Wilcox and USSL
classification diagram and Permeability Index, it is
only an empirical conclusion. However looking at the
results it may be concluded that majority of samples
is suitable for irrigation purposes except few samples
are unsuitable for irrigation purposes. The present
study also indicates that quality is gradually getting
deteriorated and it may continue with time. The
reasons may be contamination of groundwater due to
the industrial activities, urbanization, agricultural
activities and increased human interventions in the
groundwater. The influence of sea water in the fresh
water aquifer in this coastal area needs special
attention in terms of monitoring and sustainable
management of groundwater. Hence the local
government needs to initiate remedial measures.

REFERENCES
[1]
Figure.10 Permeability index.
[2]
The soil permeability is affected by the
long-term use of irrigation water and the influencing
constituents are the total dissolved solids, sodium
bicarbonate and soil types. In the present study, the
permeability index values range between 14 to 85
and 6 to 30 mg/l in pre and postmonsoon . The above
results therefore suggests that water samples fall
within Class I and Class II (Figure 10)and can be
categorized as good irrigation water [30]. The
increased percentage of groundwater samples under
class I and II is due to dilution subsequent lower
values of permeability index.

[3]
[4]

[5]
[6]

[7]

V.

CONCLUSION

Groundwater is a precious natural resource
and it is an important component of the hydrologic
cycle. The type of water that predominates in the area
is Ca2+-HCO32- and Mixed Ca2+-Mg2+-Cl- type based
on the hydrochemical facies. In general groundwater
quality of Cuddalore coast is not harmful to human
beings except few sampling location has high
salinity, hardness, chloride, Nitrate were crossed
prescribed limits of drinking water. The reasons due
to industrial effluent discharge, urbanization and
other anthropogenic activities. According to
Stuyfzand classification, the area is found to be freshwww.ijera.com

[8]

[9]

K. Ganesh, Hedge, and Y.S. Kale, Quality
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  • 1. K. Ramesh et al Int. Journal of Engineering Research and Applications ISSN : 2248-9622, Vol. 4, Issue 1( Version 3), January 2014, pp.346-354 RESEARCH ARTICLE www.ijera.com OPEN ACCESS Impact of Groundwater Quality from Industrial East Coastal Town, Southern India K. Ramesh*, L. Elango** * (Centre for Water Resources, Department of Civil Engineering, Anna University, Chennai-600 025, INDIA) ** (Department of Geology, Anna University, Chennai -600 025, INDIA) ABSTRACT Contamination of drinking water by human and industrial activities is a serious concern now-a-day. Indiscriminate use of groundwater deteriorates the quality and quantity of water. The study was carried out to assess the impacts of industrial activities on the groundwater quality in and around Cuddalore coast town during September 2012 and February 2013. The quality was assessed in terms of physio-chemical parameters and compared with BIS. The groundwater samples are classified into Ca2+-HCO32- type, Ca2+-Mg2+-Cl- type based on its hydrogeochemical characteristics. . The groundwater at many locations in the study area is not suitable for drinking because of its high salinity, hardness and chloride, which is mainly caused by industries discharge, agricultural activities and seawater intrusion. The WQI reflected that most of the samples are of poor water to very poor water. The Wilcox diagram, USSL diagrams and PI shows that most of the samples are suitable for irrigation. It was found that the groundwater was contaminated at few sample locations. The consequence of industrialization and urbanization leads to degradation of water quality. Hence the local government needs to initiate remedial measures. Keywords - Physiochemical characteristics, seawater intrusion, suitability drinking and irrigation, coastal town. I. INTRODUCTION Water is a precious and most commonly used resource. Water is one of the most abundant chemical substances on earth, as it covers two third of the earth surface. Of the total amount of global water, only 2.4% is distributed on the main land, of which only a small portion can be utilized as fresh water. The available fresh water to man is hardly 0.30.5% of the total water available on the earth and therefore, its judicious use is imperative [1]. Groundwater plays significant role in the living organisms that existing in this world. Groundwater has become a necessary resource over the past decades due to the increase in its usage for drinking, irrigation, industrial use etc. In the last few decades, there has been a tremendous increase in demand for fresh water due to rapid growth of population and the accelerated pace of industrialization. Human health is threatened by most of the agricultural development activities particularly in relation to excessive application of fertilizers and unsanitary conditions. Rapid urbanization, especially in developing countries like India, has affected the availability and quality of groundwater due to its overexploitation and improper disposal in urban areas. Many of the groundwater in the coastal aquifer is suffering from seawater intrusion both by natural process and anthropogenic activities [2]. According to [3], 80% of all disease in human being is water-borne. Once the groundwater is www.ijera.com polluted; its quality cannot be restored by stopping the pollutants from the source. Also most of the industries operating in the area discharge their effluent directly into the sea or creek without considering the effects of these wastes on the coastal shallow aquifers and aquatic lives. In the coastal regions the availability of fresh water is always threatened by over extraction or by seawater intrusion and in some cases the risk is from the agricultural and industrial activities. The objective of the present work is to discuss the suitability of groundwater for human consumption and irrigation quality. II. II.STUDY AREA The present study was carried out in east coastal region of Cuddalore that lies 125 kilometers south of Chennai on the coast of the Bay of Bengal (Figure 1). The study area forms a part of Cuddalore district which lies in between north Latitudes of 11˚44’04” and 11˚68’01”and east longitudes 79˚70’09” and 79˚77’05” with a total extent of 46 sq.km. The area form a part of the Survey of India topo-sheet no 58 M/10. The area has a tropical climate with an annual average precipitation of 1160 mm and most of the rainfall occurs during northeast monsoon (October to January). The temperature ranges from 21ºC to 39ºC with an average of 28ºC. The humidity of the region varies from 67% to 85%. The area falls under seismic zone-II with a plain terrain. Agricultural activities, especially paddy, 346 | P a g e
  • 2. K. Ramesh et al Int. Journal of Engineering Research and Applications ISSN : 2248-9622, Vol. 4, Issue 1( Version 3), January 2014, pp.346-354 sugarcane, groundnut cultivation are most common. The area is entirely underlain by www.ijera.com this pollution impact the health status of the surrounding area of industrial region. Figure.1 Location Map of Study Area Sedimentary formations, which include calcareous sandstone, coastal alluvium, and laterite soil of tertiary and quaternary age. The most common outcrops in the area are limestone, sandstone and clays. The soil types are red sandy loam, loamy sand, lateritic, clay loam and clayey soil. The general phreatic aquifers with moderate to shallow water table conditions exist in this area. The depth of bore wells ranges from 40 to 170 m below groundwater level and deeper bores ranges from 400 to 500 m. Groundwater has been used for various purposes, such as domestic, agricultural and industrial needs. Groundwater in this area is overexploited for industrial and agricultural purposes are predominant land use in this area. The industrial pollution and seawater intrusion are the main reasons for deterioration of water quality. An industrial estate SIPCOT (Small Industries Promotion Corporation of Tamil Nadu) with groups of industries near the coast, which generate chemicals and raw materials are distributed along the coastal area. Most of industries are wet process industries and hence consume large quantity of water. The entire water requirement of these SPICOT industries is met by ground water. The groundwater availability and quality of the area is adversely affected by the industrialization and urbanization of the town. The villagers particularly children have skin problem and constant itching and www.ijera.com III. METHODOLOGY Groundwater samples were collected from 22 locations in and around Cuddalore coastal town during pre-monsoon period (Sep 2012) and postmonsoon (Feb 2013) and the parameters EC were measured on the spot at the time of sample collection using potable kit. The collected groundwater samples were transferred into plastic container for analysis of chemical characters and the water samples collected in the field were analyzed for electrical conductivity (EC), pH, total dissolved solids (TDS), major cations like calcium(Ca2+), magnesium(Mg2+), sodium(Na+), potassium(K+) and anions like bicarbonate(HCO3-), carbonate(CO32-), chloride(Cl-) and sulphate (SO42-), in the laboratory using the standard methods given by the American Public Health Association [4]. Analysis of heavy metals is tested in the Atomic Absorption Spectrometry such as Nitrate (NO3-), Iron (Fe-), Phosphate (PO4-) and fluoride (F-) is to identify the heavy metals concentration in the groundwater. The heavy metal concentrations are generally leads to anthropogenic activities. IV. RESULT AND DISCUSSION Groundwater Chemistry World health organization [5] has reported that about 80% of the health hazards occur in world due to the poor quality of water used for consumption. The pH 347 | P a g e
  • 3. K. Ramesh et al Int. Journal of Engineering Research and Applications ISSN : 2248-9622, Vol. 4, Issue 1( Version 3), January 2014, pp.346-354 indicates the acidic or alkaline material present in the water. The pH of groundwater samples in this area ranges from 4.0-8 .0 and 6-7.8 during pre and postmonsoon respectively, seasonal variation shows the pH values fluctuating at all locations. The higher pH is present in the eastern part of the study area in both www.ijera.com is caused primarily by the presence of cations such as calcium and magnesium and anions such as carbonate, bicarbonate, chloride and sulphate in water. Water with hardness greater than 300 mg/.l may raise the risk of calcification of arteries, urinary concretions, diseases of kidney or bladder or stomach Figure.2 Spatial Variation of Electrical Conductivity monsoon seasons and is slightly acidic due to the industrial effluent and domestic sewage. Most of the area shows the permissible limit of pH in drinking water is within 6.5- 8.5 according to Bureau of Indian Standards [6]. Electrical Conductivity (EC) value of the study area varied from 320-7210μѕ/cm and 3516495 μѕ/cm during pre and postmonsoon seasons (Figure 2). EC is a measure of water’s capacity to conduct electric current since most of the salts in the water are present in the ionic form. In general, groundwater tends to have high electrical conductivity due to the presence of high amount of dissolved salts. EC is decisive parameters in determining suitability of water for a particular purpose. Drinking water quality is also affected by the presence of soluble salts. The total dissolved solids (TDS) upto 500 to 1500 mg/l is permitted for drinking as well as other domestic purposes as per the standards. Water with high TDS indicates more ionic concentration, which is inferior and can cause physiological disorders to its users [7]. TDS observed from this area is between 204-4614 mg/l and 2243904 mg/l in pre and post-monsoon. Most of the groundwater samples are within the maximum permissible limit for drinking water as per the BIS, except four samples. In this region, the total hardness varies between 202-960 mg/l and 100-800 mg/l during pre and post-monsoon were quite high with their prescribed standards of 300 mg/l. Hardness in water is due to the natural accumulation of salts from contact with soil and geological formation or it may direct pollution by industrial effluent. Total hardness www.ijera.com disorders [8]. The calcium concentration in water samples collected from the study area ranged from 800-500 mg/l and 100-420 mg/l in pre and postmonsoon seasons. So, most of the samples exceed the permissible limit due to rapid industrialization and urbanization and their wastes are known to account for such anthropogenic sources of calcium in water [9]. Calcium is a major constituent of various types of rocks and aquifers. Calcium is an essential cause for hardness in water, incrustation in boilers and essential constituent of human beings. In groundwater the calcium content generally exceeds the magnesium content [10]. In this present study the magnesium level in the water samples ranged from 30-495 mg/l and 25-440 mg/l in pre and postmonsoon seasons. In most of the locations magnesium exceeds the permissible limit which may result in intestinal irritation of human system particularly near the industrial area. The concentration of sodium in the area varies from 50640 mg/l in pre-monsoon and in post-monsoon the value range from 80-650 mg/l. Groundwater in most of the areas comes under the non-safe zone for drinking with reference to the concentration of sodium, which is more than 200 mg/l. The higher concentration of sodium may pose a risk to persons suffering from cardiac, rental and circulatory diseases [11]. Person afflicted with certain diseases require low sodium concentration In present investigation potassium concentration was ranged from 15-137 mg/l and 35-130 mg/l during pre and post-monsoon. The permissible limit of potassium is 10 mg/l and in 348 | P a g e
  • 4. K. Ramesh et al Int. Journal of Engineering Research and Applications ISSN : 2248-9622, Vol. 4, Issue 1( Version 3), January 2014, pp.346-354 www.ijera.com Concentration (mg/l) NO3 (mg/l) 100 90 80 70 60 50 40 30 20 10 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 Sampling Wells Figure. 3 Nitrate variations Iron (Fe-) concentration in natural water is very low. The concentration in the groundwater of the area varied from 0.1-3.5 mg/l in post-monsoon season (Figure 4), and most of the samples have low iron concentration and very few samples exceeds the permissible limit. The desirable limit of Fe for drinking water was 0.3 mg/l and maximum permissible limit was 1.0 mg/l as per Indian standards. Iron is biologically an important element which is essential to all organisms and present in hemoglobin system [16]. Iron in drinking water is due to geological, industrial wastes and domestic discharge. Fe (mg/l) P(mg/l) F(mg/l) 3.5 Concentration (mg/l) the study area nearly 50% of the samples exceed the permissible limit. K is an essential nutrient but if ingested in excess may behave as a laxative. Bicarbonate (HCO3-) was observed higher of 1481000 mg/l during post-monsoon season than premonsoon 183-976 mg/l. The source of high concentration of bicarbonate may be due to dissolution of CO3 of the soil and percolation due to rain water as well as irrigation [12]. The most important source of chlorides in the water is the discharge of industries effluents or sewage, fertilizers and septic tanks. The chloride concentration varied from 20-487 mg/l and 26-520 mg/l during pre and post-monsoon. The chloride ion is higher than 200 mg/l may pose risk to human health and may cause unpleasant taste of water. Its high consumption may be crucial for development of essential hypertension, risk for stroke, osteoporosis, renal stones and asthma [13]. High concentration of chlorides is considered to be the indicators of pollution due to high organic wastes of industrial or animal origin, presence of sodium chloride from rocks and saline water intrusion. High chloride content may harm metallic pipes as well as growing plants. In this study area few areas have higher concentration, which could be dangerous from health point of view. The high chloride may be attribute industrial, domestic wastes, leaching, from upper soil layers in dry climates and natural geochemical activities in this area [14]. In present investigation sulphate concentration was ranged from 33-489 mg/l and 15-450 mg/l during pre and post-monsoon. The major physiological effects resulting from the ingestion of large quantities of sulphate are catharsis, dehydration and gastrointestinal irritation. In the study area the 32% of sulphate ions exceed the permissible limit of 250 mg/l. The higher sulphate content is present due to bio-chemical, anthropogenic sources and industrial process etc and a higher concentration were seen near the industrial areas in both seasons. The nitrate concentration in groundwater collected from the study area ranged between 40 to 96 mg/l and 45 to 92 mg/l in pre and post-monsoon (Figure 3). The permissible limit of nitrate is 45 mg/l prescribed as per standards. Increased level of nitrate at various locations may be attributed due to the surface disposal of sewage and agricultural wastes. The permissible limit of nitrate is 45 mg/l. The influence of nitrate is seen in western part of the study area where the agricultural practices. The origin of nitrate is derived may be from agricultural areas due to leaching process from plant nutrient, nitrate fertilizers, industrial effluents and poor sanitary conditions [15]. The high concentration of nitrate in drinking water causes methenoglobinemia in infants, a disease characterized by blood changes. www.ijera.com 3 2.5 2 1.5 1 0.5 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 Sampling Wells Figure .4 Iron, Phosporus and Fluoride variations in Post-monsoon season Phosphorus is an important constituent of the lithosphere. The result indicates the presence of phosphate in the groundwater ranges from 0.55 to 3.6 mg/l during postmonsoon season as shown in figure 4.The higher phosphorus in groundwater is an indication of contamination by industrial pollutant and sewage [17]. Some samples show the beyond the limits recommended for domestic purposes. The water-soluble phosphate in the widely used fertilizers, surface water runoff, agricultural runoff and man activity could also contribute to the groundwater [18-19]. One of the main trace elements in groundwater is fluoride which generally occurs as natural constituents. Fluoride ion in drinking water is 349 | P a g e
  • 5. K. Ramesh et al Int. Journal of Engineering Research and Applications ISSN : 2248-9622, Vol. 4, Issue 1( Version 3), January 2014, pp.346-354 known for both beneficial and detrimental effects on health. Excess of fluoride in water causes serious damage to the teeth and bones of the human body, which shows the symptoms of disintegration and decay, diseases called dental fluorosis, muscular fluorosis and skeletal fluorosis. The fluoride concentration range in the study area was found to be 1 to 1.8 mg/l in post monsoon season (Figure 4). The BIS described the drinking water quality 1.5 mg/l nearly 22% of samples exceeds the permissible limit. According to UNESCO specifications, water containing more than 1.5 mg/l of fluoride cause mottled tooth enamel in children and not suitable for drinking purpose. Recently it has been identified that water containing fluoride 1.4 to 5.5 mg/l causes dissolution of aluminum from utensils, causing Dementia-a disease leading to loss of memory and mental impairment [20]. Hydrochemical facies Piper diagram is used to determine hydrochemical facies of water Major ions are plotted as cations and anions percentage in meq/l in two base triangles with total ions set to equal 100 percentages (Figure 5). The data points in the two triangles are then projected to central diamond which allows comparison of a large number of samples. The chemical data is plotted on the piper trilinear diagram [21]. Major cations and anions such as Ca, Mg, Na, K, HCO3, SO4 and Cl in meq/l were plotted in piper trilinear diagram as the percent of the major constituents. Grouping of waters on the piper diagram suggests a common composition and origin. It can be used to classify and identify mixing of waters that most of groundwater samples fall in the field Ca-HCO3 and Mixed Ca-Mg-Cl and few samples fall in Ca-Cl in both the seasons. www.ijera.com Water Quality Index (WQI) The WQI has been calculated to evaluate the suitability of groundwater quality for drinking purposes [22]. WQI is defined as a technique of rating that provides the composite influence of individual water quality parameters on the overall quality of water for human consumption [23]. The world health organization [24] standards for drinking purposes have been considered for the calculation of WQI. For the calculation of WQI 10 parameters such Figure.6 Spatial variations of Water Quality Index Table 1: Water quality classification based on WQI WQI Value Feb (%) Excellent 9.09 13.63 Good Water 22.72 13.63 100-200 Poor Water 27.27 45.45 200-300 Very Poor Water 36.36 27.27 >300 www.ijera.com Sept (% ) Less than 50 50-100 Figure. 5 Piper diagram depicting hydrochemical facies Water Quality Unsuitable for drinking 4.54 - as pH, Na+, K+, Ca2+, Mg2+, Cl-, HCO3-, SO42- and TDS have been considered. WQI varied from 33 to 312 during pre-monsoon season and from 46 to 291 during post-monsoon season (Figure 6) and therefore can be categorized into four types excellent to very poor water for drinking. Table 1 shows the percentage of water samples that falls under different much with season. Some samples were changed into good to excellent and unsuitable to poor water quality 350 | P a g e
  • 6. K. Ramesh et al Int. Journal of Engineering Research and Applications ISSN : 2248-9622, Vol. 4, Issue 1( Version 3), January 2014, pp.346-354 due to dilution processes taken place in the pre to post-monsoon. Hence, it can be seen that water quality of different locations in the industrial region quality in September 2012 and February 2013. The monsoonal dilution does not serve much towards the quality improvement in the industrially contaminated area and so the WQI of these regions does not change deteriorates in both the seasons and low value is observed in the southern part of the study area. This area is generally free from industries and sea water intrusion because it is away from the Cuddalore coastal zone. Majority of samples falls poor to very poor water in both the seasons. The higher WQI values in the samples can be attributed to the continuous discharge of industrial effluent and a little amount of sewage in the study area. The analysis reveals that the groundwater of the area needs to be treated before consumption and it also needs to be protected from the perils of contamination. [26]. A few hydrogeochemical parameters that are suggested as criteria for sea water contamination are Ca2+/Mg2+, Cl-/(CO32- + HCO32-), Na+/Cl- ratios (Figure 7) etc. In the study area the ratios are ranging by following values. Cl-/(CO32-+HCO32-) ratio used as a criterion to evaluate the salt water intrusion. Chloride is most dominant in ocean water and normally occurs in small amount in groundwater, while HCO 32- is usually the most abundant negative ion in groundwater but it occurs in minor amounts in the sea water. The degree of concentration is as follows. Table 3: Criteria for Reorganization of Saltwater Intrusion From the above limit values, majority of the area Range of Cl/(CO32- + HCO3-) Ratio <0.05 Stuyfzand Classification Stuyfzand [25] has proposed a method of classification of groundwater and identified 8 main types on the basis of Chlorinity (Cl-) shown in Table 2. It is used for identification of freshwater flow zone from the zone of salt-water intrusion. In both the monsoon periods the Oligohaline water types occur 0.05-1.30 only in Stuyfzand Classification ofgroundwater Table 2: Loc.19.fresh water occurs in location 11,14,15,16,17,18,21 and 22. Fresh-Brackish water >200 - Main Type Cl- (mg/l) Main Type Cl (mg/l) Very Oligohaline <5 Brackish 300-103 Oligohaline 5-30 BrackishSalt 103-104 Fresh 30-150 Salt 1042x104 FreshBrackish 150-300 Hyperhaline >2x104 www.ijera.com 1.30-2.80 2.80-6.60 6.60-15.50 Description Normally fresh groundwater Slightly contaminated groundwater Moderately contaminated groundwater Injuriously contaminated groundwater Highly contaminated groundwater Sea water From the above limit values, majority of the area shows slightly contaminated groundwater with the values of 0.05-1.30 and 5 samples is seems to be moderately contaminated groundwater. There is no fresh groundwater and whatever water available is injuriously polluted and highly contaminated according to the ratio as shown in Table 3. Na/Cl ratios of saltwater intrusion are usually lower than the marine values (i.e., <0.86, molar ratio). On the other hand, high (more than 1) Na+/Cl- ratios, typically characterize anthropogenic sources. The low Na+/Cl- ratios combined with other geological parameters, can foretell the arrival of saltwater intrusion. According to Na+/Cl- ratio, 50% of the study area is contaminated with marine source of contamination. Remaining area is contaminated due to anthropogenic sources like domestic and industrial effluents. only in Loc.19.fresh water occurs in location 11,14,15,16,17,18,21 and 22. Fresh-Brackish water found in sampling locations 1, 2,10,12,13 and 20. All the remaining sampling locations 3, 4, 5, 6, 7, 8 and 9 the brackish water type exists. Criteria for Reorganization of Saltwater Intrusion In order to identify brackish or saline waters hydro geochemical parameters are normally used www.ijera.com 351 | P a g e
  • 7. K. Ramesh et al Int. Journal of Engineering Research and Applications ISSN : 2248-9622, Vol. 4, Issue 1( Version 3), January 2014, pp.346-354 Figure.7 Source of Contamination based on ratios Irrigation Water Quality Irrigation water is one of the important concerns to the plant growth. The Groundwater is valuable only when its quality is suitable for a variety of purposes. Water for irrigation should satisfy the needs of basic requirements of plant growth. EC and Na+ play a vital role in the suitability of water for irrigation. The high salt content in irrigation water causes an increase in soil solution osmotic pressure. A high salt content in water leads to formation of saline soil. The salts, besides affecting the growth of plants directly, also affect soil structure, permeability and aeration, which indirectly affect plant growth [27]. The suitability of water for irrigation can be estimated by means of many determinants, though, Sodium Adsorption Ratio (SAR), Percent Sodium (Na+%), Permeability Index (PI), and Residual Sodium Carbonate (RSC) . www.ijera.com Sodium concentration is important in classifying irrigation water because sodium reacts with soil to reduce its permeability, texture makes the soil hard to plough and unsuitable for seeding emergence [29]. Sodium with chloride or sulphate as the predominant anion is saline soil and carbonate as the predominant anion is termed alkaline soils. Wilcox diagram (Wilcox 1955) is adopted for the classification of groundwater for irrigation, wherein the EC is plotted in x axis and % Na+ in Y axis. Depending on the distribution of Na+% water are classified into four classes [30] such as Excellent to Good, Good to Permissible, Doubtful to Unsuitable and Unsuitable. During both the seasons most of samples fall in categories of excellent to good and good to permissible excepting four samples which are unsuitable for irrigation purpose. Sodium adsorption ratio and salinity hazard The sodium/alkali hazard is typically expressed as the sodium adsorption ratio (SAR). The index quantifies the proportion of sodium (Na+) to calcium (Ca2+) and magnesium (Mg2+) ions in a sample. All the values are expressed in meq/l. The diagram is a simple plot of salinity hazard (EC) on the X- axis and sodium hazard on the Y-axis USSL classification diagram of groundwater for irrigation purpose (Figure 9).Sodium concentration is important in classifying the water for irrigation purposes because sodium concentrations can reduce the soil permeability and soil structure [31]. The analytical data plotted on the US salinity diagram illustrates that most of the groundwater samples fall in the field of good water to permissible (fair) water, which can be used for irrigation on Wilcox Diagram Wilcox [28] used percent sodium and specific conductance used evaluating irrigation water. In the Wilcox diagram Na% is plotted against specific conductance. An appraisal of the Wilcox diagram (Figure 8) shows that most of the samples from the study area fall under good to permissible Figure.9 USSL classification Figure.8 Wilcox Classification www.ijera.com almost all types of soil with little danger of exchangeable sodium. The five samples fall in poor quality water due to the high electrical conductivity 352 | P a g e
  • 8. K. Ramesh et al Int. Journal of Engineering Research and Applications ISSN : 2248-9622, Vol. 4, Issue 1( Version 3), January 2014, pp.346-354 will cause salinization [32]. Irrigation water with high Na+% may cause sodium accumulation and calcium deficiency in the soil leading to a breakdown of its physical properties [29]. Therefore, good drainage, high leaching and use of organic matter are required for its management in this area. Permeability Index (PI) www.ijera.com brackish and brackish water types. Regarding salt water intrusion, Cl-/ (CO32-+HCO32-) ratio, and the groundwater is found slightly too moderately contaminated. According to Na+/Cl- ratio, the contamination may be due to marine source of origin, anthropogenic and geogenic sources. The groundwater samples from the Cuddalore Old Town and Port is highly polluted and unfit for drinking purpose. Though the suitability of water for irrigation is determined based on Wilcox and USSL classification diagram and Permeability Index, it is only an empirical conclusion. However looking at the results it may be concluded that majority of samples is suitable for irrigation purposes except few samples are unsuitable for irrigation purposes. The present study also indicates that quality is gradually getting deteriorated and it may continue with time. The reasons may be contamination of groundwater due to the industrial activities, urbanization, agricultural activities and increased human interventions in the groundwater. The influence of sea water in the fresh water aquifer in this coastal area needs special attention in terms of monitoring and sustainable management of groundwater. Hence the local government needs to initiate remedial measures. REFERENCES [1] Figure.10 Permeability index. [2] The soil permeability is affected by the long-term use of irrigation water and the influencing constituents are the total dissolved solids, sodium bicarbonate and soil types. In the present study, the permeability index values range between 14 to 85 and 6 to 30 mg/l in pre and postmonsoon . The above results therefore suggests that water samples fall within Class I and Class II (Figure 10)and can be categorized as good irrigation water [30]. The increased percentage of groundwater samples under class I and II is due to dilution subsequent lower values of permeability index. [3] [4] [5] [6] [7] V. CONCLUSION Groundwater is a precious natural resource and it is an important component of the hydrologic cycle. The type of water that predominates in the area is Ca2+-HCO32- and Mixed Ca2+-Mg2+-Cl- type based on the hydrochemical facies. In general groundwater quality of Cuddalore coast is not harmful to human beings except few sampling location has high salinity, hardness, chloride, Nitrate were crossed prescribed limits of drinking water. The reasons due to industrial effluent discharge, urbanization and other anthropogenic activities. According to Stuyfzand classification, the area is found to be freshwww.ijera.com [8] [9] K. Ganesh, Hedge, and Y.S. Kale, Quality of lenetic waters of Dharwad district in north Karnataka. Journal of Environmental Health, 37(1), 1995, 52-56. H.M. Ozler, Hydrochemistry and Saltwater Intrusion in the Van aquifer, East Turkey, Environmental Geology, 43, 2003, 759-775. WHO, International Standards for Drinking Water 3rd Edition, Geneva, 2003, 346-385. APHA, Standard methods for the examination of water and waste water, 17th ed (Washington DC. USA, 1995). WHO, International standards for drinking water, Geneva, 1984. BIS, Specification for drinking water (Bureau of Indian Standards, New Delhi, 15:10500, 1991). N. Subba Rao, J. Prakasa Rao, D. John Devadass, K.V. Srinivasa Rao, C. Krishna, and B. Nagameeleswara Rao, Hydrogeochemistry and Groundwater Quality in a developing Urban Environment of a semi-arid region, Guntur, Andhra Pradesh, Journal of the Geological Society of India, 59, 2002, 159-166. H.C. Hopps, and G.L. Feder, Chemical qualities of water that contribute to human health in a positive way, Science of Total Environment, 54, 1986, 207-216. K. Subrahmanyam, and P. Yadaiah, Assessment of the Impact of Industrial 353 | P a g e
  • 9. K. Ramesh et al Int. Journal of Engineering Research and Applications ISSN : 2248-9622, Vol. 4, Issue 1( Version 3), January 2014, pp.346-354 effluents on water quality in Patancheru and Environments, Medak district, Andhra Pradesh, India, Hydrogeology Journal, 9(3), 2001, 297-312. [10] CGWB, Groundwater Year book of Andhra Pradesh (Central Groundwater Board, Ministry of Water Resources, Govt of India, 2005). [11] S. Mor, K. Ravindra, A. Vischher, R. P.Dahiya, and A. Chandra, Municipal Solid Waste Characterization and its assessment for potential methane generation at Gazipur landfill site, Delhi: A case study, Journal of Science of the Total Environment, 371(1), 2006, 1-10. [12] S.K. Tyagi, P.S. Data, and N.K. Pruthi, Hydrochemical appraisal of groundwater and its suitability in the intensive agricultural area of Muzaffarnagar disict, Uttar Pradesh, India, Environmental Geology, 56, 2009, 901-912. [13] H.C.Hopps and G.L.Feder, Chemical qualities of water that contributes to human health in positive way, Science of the Total Environment, 54, 1986, 207-216. [14] K. Srinivasamoorthy, S. Chidambaram, and M. Vasanthavigar, Geochemistry of fluoride in groundwater: Salem district, Tamil Nadu, Journal of Environmental Hydrology, 1, 2008, 16-25. [15] R.J.Madison, and J.O. Brunett, Overview of the occurrence of nitrate in groundwater of the United States ( National Water Summary 1984, US Geological Survey, Water Supply Paper, 1984, 22-75). [16] C.G. Fraga, and P.I.Oteiza, iron toxicity and antioxidant nutrients, Toxicology, 180, 2002, 23-32. [17] G.A.Nair, J.A.Bohjuari, M.A. Al-Mariami, F.A. Attia and F.F.El-Toumi, Groundwater quality of north-east Libya, Journal of Environmental Biology, 27, 2006, 695-700. [18] O. Oenema, L.Van Liere, and O. Schoumans, Effects of lowering nitrogen and phosphorus surpluses in agriculture on the quality of groundwater and surface water in the Netherlands, Journal of Hydrology, 304(1-4), 2005, 289-301. [19] P.J.A. Withers and P.M. Haygarth, Agriculture, Phosphorus and Eutrophication: a European perspective, Soil Use Manage, 23, 2007, 1-4. www.ijera.com [20] [21] [22] [23] [24] [25] [26] [27] [28] [29] [30] [31] [32] [33] www.ijera.com T.N. Sondi, N. Nigam, R. Prakash, P. Mehrotra, and K. Singh, Distribution of fluoride in groundwater in a part of the Kanpur, UP- News, 1998. A. M. Piper, A graphic procedure in the geochemical interpretation water analysis, Transactions of the American Geophysical Union, 25, 1944, 914-923. T.N. Tiwari, and M. Mishra, A preliminary assignment of water quality index of major Indian rivers, Indian Journal of Environmental Protection, 5(4), 1985, 276279. B. K. Mitra, Spatial and temporal variation of groundwater quality in sand dune area of Aomori prefecture in Japan, paper number 062023, 2006 ASAE annual meeting. WHO, Guidelines for drinking water, 3 rd edition, Geneva, 2004. P. J. Stuyfzand, Non point sources of trace elements in potable groundwater in the Netherlands, Proceedings 18th TWSA Water Workings, Testing and Research Institute, KIWA, 1989. S. Venkateswara Rao, and N. Subba Rao, Criteria for reorganization of salt water in coastal aquifers, Journal of groundwater news, 8(9), 1988, 9-12. A. K. Trivedi, and P.K. Yadav, Chemical and biological methods for water pollution studies, Environmental Publications, Karad, India, 1986. L.V. Wilcox, Classification and use of irrigation water (US Department of Agriculture, Circ 696, Washington DC, 1955). K.R. Karanth, Hydrogeology (McGraw-Hill, New Delhi, 1987). L. A. Richards, Diagnosis and improvement of saline and alkaline soils (Agriculture handbook 60, Washington DC, USDA, 1954, 160). D.K. Todd, Groundwater Hydrology (John Wiley and Sons, New York, 1980, 535). A. Ghafoor, F. Ullah, and M. Abdullah, Use of high Mg brackish water for reclamation of saline sodic soil, Soil improvement, Pakistan Journal of Agricultural Sciences, 27, 1990, 294-298. L. D. Dioneen, Water quality for agriculture (Department of Irrigation, University of California, Davis, 1967, 48). 354 | P a g e