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BATTERY is an electrochemical device which
converts chemical energy into electrical energy,
or in other words it stores electrical energy in
the form of chemical energy
WHAT IS A BATTERY?
CELL COMPONENTS IN A
BATTERY SYSTEM
Anode
Cathode
Electrolyte
Separator
CELL CONSTRUCTION
CONTAINER
CATHODE
ELECTROLYTE
SEPARATOR
ANODE REACTION is an oxidation reaction which
releases electrons.
CELL REACTIONS IN A BATTERY
SYSTEM
CATHODE REACTION is a reduction reaction
which consumes electrons.
ELECTROLYTE is an ion-conducting medium which
conducts the ions between the electrodes so that
the above reactions can take place.
V
A
e-
_
+
WORKING PRINCIPLE
1. PRIMARY BATTERY
LECLANCHE CELLS (Zn/C)
Popular and low-cost system
Applications: Torch light, portable radios, toys,
novelties, etc.
Mg/MnO2 CELLS
High capacity primary battery
Applications: Military communication equipment,
voting machines, etc.
* Non-rechargeable (cell reactions are
irreversible)
* Self-discharges whether used or not
CLASSIFICATION OF BATTERIES
- RESERVE BATTERY
Mg/Cu2Cl2, Mg/AgCl (sea water activated
battery)
Applications: Torpedoes, Sea beacons (Mainly
in Meteorology and Defence fields)
Li/FeS2 (Thermally activated battery)
Applications: Missile application
- One of the cell components, usually the
electrolyte, is kept isolated from the rest and is
added at the time of use
2. SECONDARY BATTERY
Lead-Acid Battery
Nickel-Cadmium Battery
Nickel-Iron Battery
Nickel-Metal hydride Battery
Lithium Secondary Battery
Lithium-Ion battery
Rechargeable (cell reactions are reversible)
LEAD-ACID BATTERY
ANODE : Pb
CATHODE : PbO2
ELECTROLYTE : H2SO4
CELL VOLTAGE : 2.0 V
APPLICATIONS:
AUTOMOTIVE STARTING--LIGHTING--IGNITION
(SLI), ELECTRIC VEHICLES, EMERGENCY POWER
UTILITIES, PORTABLE TOOLS, INDUSTRIAL
TRUCKS, ETC.
ANODE : Cd
CATHODE : NiOOH
ELECTROLYTE : KOH
CELL VOLTAGE : 1.2 V
APPLICATIONS:
AIRCRAFT BATTERIES, COMMUNICATION
EQUIPMENT, MEMORY BACKUP, PHOTOGRAPHY
EQUIPMENT, ETC.
NICKEL-CADMIUM BATTERY
NICKEL-METALHYDRIDE BATTERY
ANODE : MH
CATHODE : NiOOH
ELECTROLYTE : KOH
CELL VOLTAGE : 1.2 V
APPLICATIONS:
CONSUMER ELECTRONICS, PORTABLE DEVICES,
ETC.
NICKEL-IRON BATTERY
ANODE : Fe
CATHODE : NiOOH
ELECTROLYTE : KOH
CELL VOLTAGE : 1.2 V
APPLICATIONS:
RAILWAY SIGNALING, STATIONARY POWER
SUPPLY, ETC.
LITHIUM SECONDARY BATTERY
ANODE : Li METAL
CATHODE : LiCoO2
ELECTROLYTE : LiPF6 in EC:PC
CELL VOLTAGE : 4 V
APPLICATIONS:
ELECTRIC VEHICLES, PORTABLE
ELECTRONIC DEVICES, ETC.
12
During electroplating …
(Electrochemistry involved)
At the anode…
1. Metal dissolution
(soluble anode)
2. Oxygen evolution
(insoluble anode)
At the cathode …
1. Metal deposition &
2. hydrogen evolution
MLx
(x-z)  Mz+ + xL-
Mz+ + ze  M
Phenomena
Metal ion discharge
Electrocyrstallization
13
Metal distribution relationships in
electrodeposition
System
components
• Tank
• Electrodes
• Solution
composition
• Process
conditions
• current
Factors influencing
metal distribution
• Geometric
• Electrochemical
• incidental
Electrodeposit
 Metal distribution
 Composition
 Structure
 Properties
14
Interdisciplinary nature of
electrodeposition
Discipline
• Electrochemistry
• Electrochemical
Engineering
• Surface science
• Solid state physics
• Metallurgy and
materials science
• Electronics
Involvement
• Electrode processes
• Transport phenomena
• Analytical tools
• Use of quantum mechanical
solid state concepts to study
electrode processes
• Properties of deposits
• Modern instrumentation
15
Important criteria when selecting
coatings
Coating
Substrate Hydrogen
embrittlement
Diffusion
Adhesion
Stress
Porosity
Additives
Structure
Properties
Wear
Corrosion

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Battery.PPT

  • 1. BATTERY is an electrochemical device which converts chemical energy into electrical energy, or in other words it stores electrical energy in the form of chemical energy WHAT IS A BATTERY? CELL COMPONENTS IN A BATTERY SYSTEM Anode Cathode Electrolyte Separator
  • 3. ANODE REACTION is an oxidation reaction which releases electrons. CELL REACTIONS IN A BATTERY SYSTEM CATHODE REACTION is a reduction reaction which consumes electrons. ELECTROLYTE is an ion-conducting medium which conducts the ions between the electrodes so that the above reactions can take place.
  • 5. 1. PRIMARY BATTERY LECLANCHE CELLS (Zn/C) Popular and low-cost system Applications: Torch light, portable radios, toys, novelties, etc. Mg/MnO2 CELLS High capacity primary battery Applications: Military communication equipment, voting machines, etc. * Non-rechargeable (cell reactions are irreversible) * Self-discharges whether used or not CLASSIFICATION OF BATTERIES
  • 6. - RESERVE BATTERY Mg/Cu2Cl2, Mg/AgCl (sea water activated battery) Applications: Torpedoes, Sea beacons (Mainly in Meteorology and Defence fields) Li/FeS2 (Thermally activated battery) Applications: Missile application - One of the cell components, usually the electrolyte, is kept isolated from the rest and is added at the time of use
  • 7. 2. SECONDARY BATTERY Lead-Acid Battery Nickel-Cadmium Battery Nickel-Iron Battery Nickel-Metal hydride Battery Lithium Secondary Battery Lithium-Ion battery Rechargeable (cell reactions are reversible)
  • 8. LEAD-ACID BATTERY ANODE : Pb CATHODE : PbO2 ELECTROLYTE : H2SO4 CELL VOLTAGE : 2.0 V APPLICATIONS: AUTOMOTIVE STARTING--LIGHTING--IGNITION (SLI), ELECTRIC VEHICLES, EMERGENCY POWER UTILITIES, PORTABLE TOOLS, INDUSTRIAL TRUCKS, ETC.
  • 9. ANODE : Cd CATHODE : NiOOH ELECTROLYTE : KOH CELL VOLTAGE : 1.2 V APPLICATIONS: AIRCRAFT BATTERIES, COMMUNICATION EQUIPMENT, MEMORY BACKUP, PHOTOGRAPHY EQUIPMENT, ETC. NICKEL-CADMIUM BATTERY
  • 10. NICKEL-METALHYDRIDE BATTERY ANODE : MH CATHODE : NiOOH ELECTROLYTE : KOH CELL VOLTAGE : 1.2 V APPLICATIONS: CONSUMER ELECTRONICS, PORTABLE DEVICES, ETC. NICKEL-IRON BATTERY ANODE : Fe CATHODE : NiOOH ELECTROLYTE : KOH CELL VOLTAGE : 1.2 V APPLICATIONS: RAILWAY SIGNALING, STATIONARY POWER SUPPLY, ETC.
  • 11. LITHIUM SECONDARY BATTERY ANODE : Li METAL CATHODE : LiCoO2 ELECTROLYTE : LiPF6 in EC:PC CELL VOLTAGE : 4 V APPLICATIONS: ELECTRIC VEHICLES, PORTABLE ELECTRONIC DEVICES, ETC.
  • 12. 12 During electroplating … (Electrochemistry involved) At the anode… 1. Metal dissolution (soluble anode) 2. Oxygen evolution (insoluble anode) At the cathode … 1. Metal deposition & 2. hydrogen evolution MLx (x-z)  Mz+ + xL- Mz+ + ze  M Phenomena Metal ion discharge Electrocyrstallization
  • 13. 13 Metal distribution relationships in electrodeposition System components • Tank • Electrodes • Solution composition • Process conditions • current Factors influencing metal distribution • Geometric • Electrochemical • incidental Electrodeposit  Metal distribution  Composition  Structure  Properties
  • 14. 14 Interdisciplinary nature of electrodeposition Discipline • Electrochemistry • Electrochemical Engineering • Surface science • Solid state physics • Metallurgy and materials science • Electronics Involvement • Electrode processes • Transport phenomena • Analytical tools • Use of quantum mechanical solid state concepts to study electrode processes • Properties of deposits • Modern instrumentation
  • 15. 15 Important criteria when selecting coatings Coating Substrate Hydrogen embrittlement Diffusion Adhesion Stress Porosity Additives Structure Properties Wear Corrosion