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A Publication of ATTRA - National Sustainable Agriculture Information Service • 1-800-346-9140 • www.attra.ncat.org
ATTRA—National Sustainable
Agriculture Information Ser-
vice is managed by the National
Center for Appropriate Technol-
ogy (NCAT) and is funded under
a grant from the United States
Department of Agriculture’s
Rural Business-Cooperative
Service. Visit the NCAT Web site
(www.ncat.org/agri.
html) for more informa-
tion on our sustainable
agriculture projects.
Funding for the development
of this publication was provided
by the USDA Risk Management
Agency.
Contents
Biodiesel Use, Handling,
and Fuel Quality
By Andrew Pressman
and Mike Morris
NCAT Energy
Specialists
September 2007
© 2007 NCAT
This publication addresses questions that farmers and ranchers may have about using biodiesel in diesel
engines. Biodiesel can be substituted for petroleum-based diesel fuel in virtually any standard unmodi-
fied diesel engine. However, biodiesel has chemical properties that require somewhat different use and
handling. While most biodiesel users experience few if any problems, consumers can take precautions
to avoid potential problems associated with poor quality fuel.
Introduction
Biodiesel is becoming widely available in
most parts of the U.S. and can be substi-
tuted for petroleum-based diesel fuel (“pet-
rodiesel”) in virtually any standard unmod-
ified diesel engine. Biodiesel offers many
advantages over petroleum-based diesel:
It is made from domestically
produced and renewable agricul-
tural products, mainly vegetable oil
or animal fat.
It is essentially non-toxic and bio-
degradable.
It has a high flash point (over 300ºF)
and is difficult to light on fire with
a match.
It reduces emissions of many toxic
air pollutants.
•
•
•
•
It functions as an excellent fuel
lubricant and performs similarly
to low-sulfur diesel with regards to
power, torque, and fuel consumption.
It can greatly reduce carbon emissions.
For discussion of the environmental advan-
tages of biodiesel, see the ATTRA publica-
tion Biodiesel: the Sustainability Dimensions.
To find retail biodiesel distributors in your
area, use NCAT’s Farm Energy Search Tool,
www.attra.ncat.org/farmenergysearchtool.
Most biodiesel users pour it in the tank and
experience few if any problems. Nonethe-
less, biodiesel has chemical properties that
can cause difficulties. For example:
Biodiesel’s detergent or solvent
properties can clog your fuel filter
as it cleans carbon deposits from
your engine.
•
•
•
Introduction .................... 1
Biodiesel, Ethanol,
Vegetable Oil: What’s
the Difference? ............... 2
Blending and
Storage .............................. 3
Issues and Concerns ..... 4
ASTM Standards ............. 6
The BQ-9000
Program............................. 7
Warranty Issues .............. 8
Fuel Quality Testing ..... 9
Conclusion ....................... 9
References ......................10
Photos:VernGrubinger
Page 2 ATTRA Biodiesel Use, Handling, and Fuel Quality
Compared to petrodiesel, biodie-
sel has somewhat worse cold-flow
properties.
Biodiesel degrades rubber and cer-
tain other materials, making it incom-
patible with some fuel lines, rubber
gaskets, and other engine parts.
This article offers suggestions to help farm-
ers and other consumers get the benefits of
biodiesel while avoiding performance and
equipment problems.
Biodiesel, Ethanol, Vegetable
Oil: What’s the Difference?
Biodiesel is a very different substance from
ethanol. Ethanol (or grain alcohol), the
familiar alcohol found in alcoholic bever-
ages, is commonly blended with gasoline
(not diesel fuel) and is made by fermenting
grains or other plants that contain sugar.
Fermentation is a biological process accom-
plished by yeasts and bacteria.
Biodiesel is essentially permanently thinned
plant or animal-based oil, with a viscosity
approximating that of standard #2 diesel
fuel. Biodiesel can be made from virtually
•
•
any plant oil or animal fat. Making biodie-
sel is a chemical process. During this chem-
ical reaction, a thick gooey substance, glyc-
erin, is released from the oil molecules and
replaced with a comparatively thin and light
alcohol, usually methanol. For an expla-
nation of how to make biodiesel, see the
ATTRA publication Biodiesel: a Primer.
Biodiesel is also very different from raw or
“straight” vegetable oil (SVO). Almost any
vegetable oil will combust, to one degree or
another, in a diesel engine. So it’s possible
to run most diesel engines on SVO. But this
is a somewhat risky process, mainly since
raw vegetable oil is too thick and viscous to
run well in diesel engines.
Biodiesel will perform well in almost any
standard diesel engine without modifica-
tions. On the other hand, to use SVO you
will need to modify your engine. Conver-
sion kits are readily available for $300 to
$1,500.(1) Generally, conversion means
installing a separate fuel tank, heater, and
fuel line, along with various switches and
controls. The idea is to thin the oil by heat-
ing it, while taking precautions to keep cold,
gooey vegetable oil out of your engine. You
start and run the engine on standard diesel
fuel or biodiesel. Once the engine is warm
and you’ve pre-heated the vegetable oil—
stored in a separate tank—you can switch to
SVO. Several minutes before turning off the
engine, you switch back to standard diesel
fuel or biodiesel, clearing all the SVO out of
your engine and fuel lines.
The U.S. Department of Energy, among
many other organizations, cautions that
SVO can reduce engine life and should not
be considered a fuel for long-term use.(2)
The use of SVO has been shown to cause
piston ring sticking, injector and combus-
tion chamber deposits, fuel system deposits,
reduced power, reduced fuel economy, and
increased exhaust emissions. Any of these
conditions can reduce engine life, increase
maintenance costs, or cause engine failure.
Modern diesel engines are also equipped
with catalytic converters, or filter traps, that
are not designed to handle SVO.
Photo:www.biodieselcommunity.orgPhoto:VernGrubinger
Caution: If you are making your own fuel,
using and storing large quantities of biodiesel,
or selling fuel commercially, you will need to
take many safety, legal, and quality-related
precautions beyond the ones described here.
Page 3ATTRAwww.attra.ncat.org
Performance problems don’t necessarily
happen quickly. Certain engines seem to
tolerate SVO better than others, and some
vehicles run trouble-free for years. On the
other hand, many SVO users succeed ini-
tially, and are lulled into a false sense of
security, only to run into serious problems
later.(3)
Despite the very real risk of engine dam-
age, SVO has certain advantages that may
make it worth considering for some farm-
ing situations and equipment, especially in
older engines. Using SVO is in some ways
simpler than making your own biodiesel.
Making biodiesel generally requires you
to use methanol, a toxic chemical, and to
dispose of glycerin, a waste product. By
contrast, SVO is generally only filtered
before use, and there are few if any waste
products to deal with.
Biodiesel Blends and
Blending
Biodiesel in its pure (100 percent) form is
known as neat biodiesel or B100. It can be
readily blended with petroleum diesel in
any proportion. A B20 blend, for example,
is 20 percent by volume biodiesel and 80
percent petrodiesel.
Different blends serve different purposes.
Small amounts of biodiesel (B1-B2) add
lubrication to low-sulfur fuels. Blends in the
B20 to B50 range provide significant envi-
ronmental benefits with a low increase in
cost to consumers. Blending also reduces
the likelihood of the solvency, material
incompatibility, or cold weather problems
discussed below.
The simplest method is splash blending.
Biodiesel should always be poured on top
of petroleum diesel, since it is slightly
heavier. The two fuels will mix fairly well
as the biodiesel gradually sinks through
the lighter petrodiesel. Some form of agi-
tation is needed, though, to achieve highly
uniform fuel. Random samples of splash-
blended fuel being marketed as B20 have
been found to contain actual biodiesel
content ranging from B2 to B90.(4)
You should avoid adding biodiesel to cold
petrodiesel, since this may cause crystals
to form. To prevent this from happening,
you can blend biodiesel with kerosene (also
called #1 diesel fuel) in a 50/50 mix before
adding it to cold diesel fuel.(5) If crystals
have already formed, the fuel will have to
be heated until they dissolve.
Biodiesel Storage
Biodiesel can be stored in standard petroleum
diesel storage tanks with some precautions:
Tanks that have previously been
used to store diesel fuel should be
cleaned before use. As noted below,
biodiesel is an excellent solvent and
will loosen deposits left by standard
diesel fuel. Tanks should also be
free of water, since this encourages
bacterial growth.
Tanks may be made of aluminum,
steel, Teflon, or fluorinated poly-
ethylene or polypropylene. Fiber-
glass is sometimes used, but should
be approached with caution since
some resins are not compatible with
biodiesel.(4)
•
•
Photos:VernGrubinger
Page 4 ATTRA Biodiesel Use, Handling, and Fuel Quality
Both petrodiesel and biodiesel can
cause metal parts to oxidize, so you
should replace any parts made of
brass, bronze, copper, lead, tin, or
zinc with aluminum or steel.
If biodiesel or blended fuels are
stored beyond around six months,
fuel stabilizers should be added.(6)
Old fuel will become acidic and
form sediments and varnish.
Biodiesel and biodiesel blends
should be stored at temperatures
at least 15 degrees above the pour
point of the fuels.(7) The pour point
is the temperature below which a
fuel will not pour.
Outdoor tanks should be located in
cool shaded areas if possible.
Issue #1: Solvent Effects
and Filter Clogging
According to researchers at the University
of Idaho, filter plugging is the most common
problem experienced by biodiesel users.(4)
Biodiesel has excellent solvent properties
and can be used as a cleaning agent and
paint remover. (It can remove the paint on
the side of your car or tractor, if you splash
it around while filling the tank.) In fact, it
can even dissolve concrete.(4)
Petroleum diesel often leaves a deposit in
the bottom of fuel lines, tanks, and deliv-
ery systems. Biodiesel can loosen and dis-
solve these sediments, as well as rust and
other materials. This causes fuel filters to
become clogged—sometimes in a matter of
hours after switching to B100. Symptoms of
filter clogging include a sudden power loss
or engine shuddering.
Older vehicles have more accumulated
deposits, and are especially prone to filter
clogging. Ideally, you should clean an old
•
•
•
•
fuel tank before converting to biodiesel. An
alternative is to switch to finer filters. Any-
one using B100 should know how to change
the fuel filter and should carry a spare fuel
filter or two. Expect to change your fuel fil-
ter two or three times before all the deposits
are cleaned out of your engine. If you are
using a modest blend (B20 or lower), you
are less likely to notice filter clogging.
Issue #2: Reduced Power
On average, B100 has about eight per-
cent less energy content (BTU per gallon)
than #2 petrodiesel, while B20 has one to
two percent less energy content.(8) If you
switch from standard diesel fuel to B100,
you may notice a slight decrease in horse-
power, torque, or fuel economy. At B20 or
less, you probably won’t be able to tell the
difference.
A cetane number is an indicator of diesel fuel
quality, measuring the readiness of fuel to
ignite when injected into the engine. Biodie-
sel’s cetane number is higher than that of
standard diesel fuel, and this advantage may
partly compensate for its lower BTU content.
Because biodiesel ignites more readily in
diesel engines than petrodiesel, some author-
ities recommend setting the injection timing
back by two to three degrees from top-dead
center. This will sometimes cause the engine
to run quieter, although it may also slightly
reduce your power.(9)
Issue #3: Cold Weather
Performance
All diesel fuel, including petroleum-based
fuel, begins to gel at cold temperatures.
The temperature at which a cloud of wax
crystals forms in the fuel is known as the
cloud point. The cold filter plugging point
is the lowest temperature at which fuel can
be drawn through a metal screen filter.(10)
The pour point is the temperature below
which a fuel will not pour.
In general, biodiesel gels at somewhat higher
temperatures than conventional #2 diesel.
When wax crystals begin to form in biodie-
sel, the entire fuel tends to cloud at the same
time. In contrast, petroleum diesel is made
A
nyone using
B100 should
know how
to change the fuel
filter and should
carry a spare fuel
filter or two.
Caution: If you are storing large amounts of
fuel, or selling it commercially, you will need
to take many additional precautions and meet
local laws and code requirements.
Page 5ATTRAwww.attra.ncat.org
up of many different compounds that gel at
different temperatures. When some of these
begin to crystallize, others remain liquid to a
much lower temperature.
The cloud point for standard #2 diesel fuel
is around 5ºF. The cloud point for biodiesel
depends on the feedstock and the amount
of free fatty acids in the fuel. The cloud
point for soy diesel is around 32ºF (4),
compared to cloud points around 20ºF for
canola and 12ºF for rapeseed.(11) Biodie-
sel made from used cooking grease or ani-
mal fats will tend to cloud at higher tem-
peratures than biodiesel made from virgin
oils. Biodiesel from the most highly satu-
rated feedstocks may gel at temperatures as
high as 50-55ºF.
Low-percentage biodiesel blends generally
have cold weather properties similar to pet-
rodiesel. The cloud point of B20 may be
3º-10ºF higher than #2 petrodiesel.(8)
Simple cold weather precautions include
using engine block or fuel filter heaters
and parking vehicles in or near a build-
ing. Fuel additives can also inhibit crystal
growth and gelling in standard diesel fuel.
Anecdotal reports suggest that few if any
of these products work well on B100. They
may be effective on blended fuel, however,
since they will work on the petroleum-based
portion of the fuel.
Issue #4: Softening Fuel Lines
Using a high-percentage biodiesel blend or
B100 can cause certain types of elastomers
and natural rubber compounds to bubble,
bleed, soften, and degrade over time. Virtu-
ally all diesel vehicles made since the early
1990s use components that are compatible
with B100.(4) But some older fuel hoses will
need to be replaced.
Equipment changes are rarely if ever
necessary with blends of B20 or lower.(8)
Besides rubber, other vulnerable materials
identified by the National Biodiesel Board
include polypropylene, polyvinyl, and Tygon.
Although there have been a few reports of
degraded injection pump seals, by far the most
common problem you are likely to encounter
is with rubber fuel lines. If you have an older
vehicle, you should inspect your fuel lines
frequently after you begin using biodiesel.
The good news is that these problems are
likely to appear gradually, if they appear
at all. Hoses will begin to soften and (even-
tually) weep. You are unlikely to experience
a catastrophic failure.
Case Study:
Phil Foster Ranches
Phil Foster began using biodiesel on his
organic vegetable farm near San Juan
Bautista, California in 2004. He saw the
use of non-petroleum fuels as consis-
tent with his philosophy as an organic
vegetable farmer. He liked the idea that
any fuel spills would be biodegradable
and far less toxic than standard diesel.
He was attracted by the air quality
and health advantages for his family
and his workers. And he liked the idea
of purchasing fuel made from agricul-
tural products, preferably ones grown
locally or regionally.
Phil didn’t have the time or inclination
to make his own fuel, so he began pur-
chasing biodiesel from a local retailer.
Initially, he tried B100 in some of his
vehicles, gradually expanding his usage
as he became comfortable with the
fuel’s performance. He also asked his
supplier lots of questions about test-
ing, standards, and feedstocks.
By 2006, biodiesel made up 81 percent
of the roughly 20,000 gallons of diesel
fuel consumed annually by the farm’s
tractors, pickups, and delivery trucks.
Most of the farm’s diesel vehicles are
now running B100, although with some
of his older equipment Phil has been
reluctant to go above B30.
Overall, Phil comments that “After four
years of using biodiesel, we’ve had
very good results.” He did experience
some filter plugging when switching
to biodiesel, and he now changes his
filters at every service. He also went
through a period recently where it
seemed as if he needed to change fil-
ters more often than normal. “Maybe
the fuel was a tad off ... We’ll probably
never know for sure.”
Fuel economy may have decreased
slightly, in the range of three to five
percent. There have also been a few
cold mornings (18º
- 20º
F) when the
vehicles running on B100 would not
start. Switching temporarily to B30 dur-
ing cold weather has solved this prob-
lem, and all vehicles have started fine
on B30.
Phil recently bought a new truck, which
he plans to run on B30 for the first six to
twelve months - enough time for any
problems to show up. Once he’s confi-
dent in the vehicle’s performance, he’ll
switch it over to B100.
Page 6 ATTRA Biodiesel Use, Handling, and Fuel Quality
Issue #5: Engine Oil Dilution
and Fuel Oxidation
In blends higher than B20, unburned
biodiesel can make its way past the piston
rings and into the oil pan.(8) This happens
because biodiesel has a slightly higher vis-
cosity and density than standard diesel.
Eventually, this fuel in the engine oil can
polymerize, causing oil sludge that coats
metal surfaces and causes moving parts to
stick.(4) If you are using biodiesel blends
higher than B20, you may need to change
your engine oil more frequently.
Issue #6: Microbial Growth
Water can sometimes drip through vents
and collect at the bottom of fuel tanks.
Certain varieties of algae, yeast, and fungi
can grow at the interface of the fuel and
water.(4) In order to prevent microbial
growth, you should drain any water from
the bottom of your fuel tank on a regular
basis. Certain biocides can also be added
to control microbial growth, but the dead
microbes may plug filters.
ASTM Standards
The American Society for Testing and
Materials (ASTM) is the industry organiza-
tion that defines legal fuel standards: mini-
mum values that a fuel must meet to operate
safely in a compression ignition engine.
All diesel engines sold in the U.S. are man-
ufactured to meet ASTM D975, the legal
standard for petrodiesel. In 2001, ASTM
In September 2005, Minnesota passed a
law requiring all diesel fuel to contain two
percent biodiesel. Soon after the mandate
went into effect, Minnesota truckers began
to experience sporadic problems, includ-
ing trucks breaking down on the road, hefty
repair bills, and lost road time. The culprit
was clogged fuel filters and it soon became
apparent that biodiesel was to blame.
Cold weather gelling was found to be the
main problem. In December 2005, the Min-
nesota Department of Commerce confirmed
that some biodiesel producers had shipped
biodiesel that did not meet ASTM D6751
specification for free and total glycerin.(12)
“There’s no room for poor-quality biodie-
sel in the marketplace,” said Steve Howell,
technical director with the National Biodiesel
Board. “Although investigations have indi-
cated that other factors unrelated to biodie-
sel may have led to at least some of the fil-
ter-plugging reports in Minnesota, there’s
no question that off-specification biodiesel
can have a severe reaction in cold weather,
even in low blends.”(13)
All Minnesota biodiesel producers subse-
quently had to prove that their fuel met
ASTM specifications.(12) After imple-
menting additional quality measures,
the Department of Commerce reaffirmed
the ruling that diesel fuel was required to
contain two percent biodiesel meeting
ASTM D6751 specifications.
Minnesota’s experience showed that even
a low-percentage of off-spec biodiesel—
as low as two percent!—can cause perfor-
mance problems .
Case Study:
The Minnesota Biodiesel Mandate
I
n 2001, ASTM
approved a
standard specif-
ically for biodiesel,
ASTM D6751.
Biodiesel-Compatible Fuel Lines
The following fuel lines are claimed by their manufacturers to be
B100-compatible (14):
• Goodyear part numbers 65148 thru 65153 & 65161 thru 65163 meet
SAE specification J30R9.
• Gates part number 4241G and 4241M for marine use.
• Kuriyama part number A4143.
• NAPA fuel injection hose part H205.
• McMaster-Carr Viton rubber tubing part number 5119K51
(among many others).
• Thomas Register listing of other Viton tubing suppliers.
approved a standard specifically for biodie-
sel, ASTM D6751. This standard covers all
biodiesel fuels, regardless of feedstock or
processing method.
These legal requirements only apply to fuel
that is sold. Home brewers, cooperatives,
and farms making fuel for their own use are
not required to meet ASTM D6751.
ASTM testing must be done by qualified
laboratories and requires expensive equip-
ment. The standards are listed in the table
on the following page.
Page 7ATTRAwww.attra.ncat.org
The BQ-9000 Program
The National Biodiesel Board has insti-
tuted a cooperative and voluntary quality
assurance program called BQ-9000. The
program was developed to ensure a more
consistent quality for biodiesel being pro-
duced, marketed, and used. While ASTM
standards only cover fuel quality, BQ-9000
encompasses storage, sampling, testing,
blending, shipping, distribution, and fuel
management practices.
Any biodiesel producer, marketer or
distributor of biodiesel or biodiesel blends
in the U.S. or Canada is eligible for pro-
gram accreditation. Accredited manufactur-
ers and certified marketers under this pro-
gram are listed on the BQ-9000 website,
www.bq-9000.com.
Property ASTM Method Limits Units
Calcium & Magnesium,
combined
EN 14538 5 max ppm (ug/g)
Flash Point (closed cup) D 93 93 min Degrees C
Alcohol Control
1. Methanol Content
2. Flash Point
EN 14110
D 93
0.2 max
130 min
% volume
Degrees C
Water & Sediment D 2709 0.05 max % volume
Kinematic Viscosity, 40 C D 445 1.9 – 6.0 mm2
/sec
Sulfated Ash D 874 0.02 max % mass
Sulfur
S 15 Grade
S 500 Grade
D 5453
D 5453
0.0015 max (15)
0.05 max (500)
% mass (ppm)
% mass (ppm)
Copper Strip Corrosion D 130 No. 3 max
Cetane D 613 47 min
Cloud Point D 2500 Report Degrees C
Carbon Residue 100% Sample D 4530 0.05 max % mass
Acid Number D 664 0.50 max mg KOH/g
Free Glycerin D 6584 0.020 max % mass
Total Glycerin D 6584 0.240 max % mass
Phosphorus Content D 4951 0.001 max % mass
Distillation, T90 AET D 1160 360 max Degrees C
Sodium/Potassium, combined EN 14538 5 max ppm
Oxidation Stability EN14112 3 min hours
Table 1: ASTM Standards
Adapted from The National Biodiesel Board, Specification For Biodiesel (B100) – ASTM D6751-07a.(15)
Page 8 ATTRA Biodiesel Use, Handling, and Fuel Quality
Will Biodiesel Void My
Warranty?
Many farms and ranches are discouraged
from using biodiesel, especially in newer
vehicles, because of fears that they will
“void their warranties.”
It’s a good idea to check with your vehicle
manufacturer to see if they have an official
policy on the use of biodiesel. Most major
engine companies have formally stated that
biodiesel blends below 20 percent that meet
ASTM D6751 will not void their engine
warranties.
The National Biodiesel Board has posted on
its website several statements from engine
companies (www.biodiesel.org). John Deere,
Caterpillar, and New Holland are among
the many companies that have adopted pol-
icies supportive of biodiesel. Other compa-
nies are in the process of developing guide-
lines for biodiesel.
A number of authorities state flatly that
the use of biodiesel does not, in itself, void
engine warranties. [See, for example, (1)
and (2)] Engine warranties typically cover
the “materials and workmanship” of the
engine, and say little or nothing about fuel.
It’s certainly true that bad quality biodie-
sel can cause performance problems that
are not the fault of the engine maker and
so are not covered by the warranty. These
situations are no different from ones where
a problem has been caused by bad quality
petroleum diesel or gasoline.
Engine manufacturers would generally refer
any customer with fuel-related problems to
the fuel supplier. According to the National
Biodiesel Board, any reputable fuel supplier
(petrodiesel, biodiesel, or blend) should
stand behind its product and cover any fuel
quality problems that occur.(16)
Biodiesel sold in the U.S. is subject to qual-
ity requirements that are just as strict as
those for standard diesel fuel. You are on
strong legal ground in using ASTM-compli-
ant biodiesel fuel—just as you would be in
using ASTM-compliant petroleum diesel.
Unfortunately, though, your strong legal
position does not guarantee that you will be
free from warranty-related hassles. Some
equipment dealers are still poorly informed
and will caution customers against using
biodiesel, since they (mistakenly) regard it
as unregulated or unreliable.
Are You Sure Your Fuel Is Meeting ASTM Standards?
A study released in November 2006 suggests that inconsistent fuel
quality continues to be a real issue for the US biodiesel industry—
despite the legal requirement that commercial fuel must meet ASTM
standards.
Co-funded by the National Biodiesel Board (NBB) and the National
Renewable Energy Laboratory (NREL), the study randomly collected
biodiesel samples from 32 fuel distributors around the country between
November 2005 and July 2006.
Half of the samples failed to meet at least one of the ASTM D6751
specifications, and some samples failed multiple standards. Thirty
percent of the samples failed to meet the flash point standard, and
one-third of the samples failed to meet the total glycerin standard.(18)
Caterpillar -
Biodiesel Use Statement
“Caterpillar neither approves nor prohibits use
of biodiesel fuels. Caterpillar is not in a position
to evaluate the many variations of biodiesel and
the long term effects on performance, durabil-
ity, or compliance to emissions standards for
Caterpillar products. The use of biodiesel fuel
does not affect Caterpillar’s materials and work-
manship. Failures that result from the use of any
fuel are not Caterpillar factory defects. There-
fore, the cost or repair would NOT be covered
by a Caterpillar’s warranty.”(17)
Caterpillar Commercial Diesel Engine Fluids
Recommendations
SEBU6251-08 March 2004
Page 9ATTRAwww.attra.ncat.org
How Can I Be Sure I’m
Getting Good Fuel?
It’s important to keep the issue of poor qual-
ity, off-spec fuel in perspective: The vast
majority of biodiesel consumers experience
no fuel-related problems whatsoever. There
is also (unfortunately) off-spec gasoline and
diesel fuel in the marketplace too.
To reduce your chances of buying off-spec
biodiesel, get to know your dealer and ask
questions. How long have they been in busi-
ness? What feedstocks are used? What are
the cold weather characteristics of the fuel?
How frequently is the fuel tested for ASTM
compliance? Are your manufacturer and
marketer BQ-9000 accredited?
Don’t assume that bigger companies are
necessarily better. Many small producers
take pride in making excellent fuel, and
some large producers have been known to
make bad batches.
Do-It-Yourself Fuel
Quality Testing
You can mail a sample of fuel to a labora-
tory for comprehensive ASTM testing, but
the price tag is likely to be a hefty $800
to $1,000 or more. Fortunately, there are
some inexpensive alternatives for consum-
ers and fuel makers.
Dr. Randall von Wedel has developed a sim-
ple testing kit called the pHLip (pronounced
“flip”) Test. You fill a vial with B100 to
the indicated level, then flip the sample 10
times and wait 10 minutes for the fuel to
float to the top. Through visual inspection
you can identify a variety of fuel quality
problems, including old, poorly washed, or
oxidized fuel. The kits are NOT a substitute
for ASTM testing and standards, but cost
only around $5 per test and allow quick in-
the-field testing. For more information, visit
www.phliptest.com.
Several simple fuel quality tests are also
described on the Journey to Forever site, at
http://journeytoforever.org/biodiesel_vehicle.
html. These include the “wash test,” “repro-
cessing test,” “methanol test,” and others.
While most of these are mainly of interest
to biodiesel fuel makers, some are within
the capability of technically minded fuel
consumers, too.
Conclusion
Biodiesel users should take some basic pre-
cautions to avoid performance problems:
Perform regular maintenance, check
fuel filters frequently, and change
them as necessary.
Understand biodiesel’s cold weather
properties and take appropriate
precautions.
Be aware of biodiesel’s incompat-
ibility with certain materials and
replace any incompatible parts,
especially rubber fuel lines.
Regularly drain water from the
bottom of fuel tanks, to prevent
microbial growth.
Use stored biodiesel within about
six months.
Make sure that fuel meets ASTM
D6751.
Incorporate biodiesel into farming
operations gradually. Start slowly
and expand your use of the fuel as
you gain confidence.
Make sure your biodiesel comes
from a reputable source. Get to
know your fuel provider and ask
questions about feedstocks and
quality testing.
•
•
•
•
•
•
•
•
pHLip test results, showing fuel quality problems.
Photo:www.biodieselcommunity.org
Page 10 ATTRA Biodiesel Use, Handling, and Fuel Quality
References
1. Pahl, Greg. 2005. Biodiesel: Growing a New
Energy Economy. White River Junction, VT:
Chelsea Green Publishing Company.
2. Clean Cities. 2006. “Straight Vegetable Oil as a
Diesel Fuel?” Washington, DC: U.S. Depart-
ment of Energy. Retrieved May 9, 2007.
www.eere.energy.gov/cleancities
3. Engine Manufacturers Association. 2006.
“Use of Raw Vegetable Oil or Animal Fats
in Diesel Engines.” Chicago, IL: Engine
Manufacturers Association.
4. Van Gerpen, Jon. “Biodiesel Use and Consumption.”
Montana Oilseed and Biodiesel Workshop.
Great Falls, MT: Montana Farmers Union and
Montana Grain Growers Association,
February 15, 2007.
5. Ryan, David. 2004. “Biodiesel—A Primer.”
Butte, MT: National Center for Appropriate
Technology.
6. Anon. 2006. Fuel Quality and Performance Guide.
National Biodiesel Board. Retrieved May 11,
2007. www.biodiesel.org/pdf _files/Fuel
QualityandPerformanceGuide.pdf
7. Tyson, K. Shaine. 2001. Biodiesel Handling and
Use Guidelines. Golden, CO: National Renew-
able Energy Laboratory.
8. Anon. 2005. “Use of Biodiesel Blends above
20% Biodiesel.” National Biodiesel Board.
Retrieved May 14, 2007. www.biodiesel.org/
pdf _files/Biodiesel_Blends_Above%20_20_
Final.pdf
9. Pelly, Mike. 2003. “Mike Pelly’s Biodiesel Method.”
Journey to Forever. Retrieved June 5, 2007.
www.journeytoforever.org/biodiesel_mike.html
10. Anon. No Date. Background. National Biodiesel
Board. Retrieved May 10, 2007. www.biodie-
sel.org/pdf _files/fuelfactsheets/Cold%20Flow.pdf
11. Brown, Jack and Jim Davis. January 31, 2007.
“Agronomics of Oil Seed Crops in the Pacific
Northwest.” Biodiesel in the Pacific Northwest
Biodiesel Workshop Course. National Biodiesel
Program, University of Idaho.
12. Zeman, Nicholas. 2006. “Remember December.”
Biodiesel Magazine, October. Retrieved May
11, 2007. www.biodieselmagazine.com/
article-print.jsp?article_id=1180
13. Barrett, Rick. 2006. “Minnesota Aims to Get
Biodiesel Back In Gear.” Milwaukee Journal
Sentinel, February 1. Retrieved May 11, 2007.
http://findarticles.com/p/articles/mi_qn4196/is_
20060201/ai_n16036216/print
14. Anon. No date. “Solvency Effects.” Piedmont Bio-
fuels. Retrieved May 14, 2007. http://biofuels.
coop/general-information/solvency-effects
15. Anon. 2007. Specification For Biodiesel (B100).
ASTM D6751-07a. National Biodiesel Board.
Retrieved June 9, 2007. www.biodiesel.org/
pdf-files/fuelfactsheets/BDSpec.pdf
16. Anon. No Date. “Biodiesel Standards and Warran-
ties.” National Biodiesel Board. Retrieved May
14, 2007. www.biodiesel.org/resources/
fuelfactsheets/standards-and-warranties.shtm
17. Freckmann, Chad. 2006. “Biodiesel: A Renew-
able, Premium Fuel to Meet Today’s and
Tomorrow’s Energy Needs in a Clean and
Sustainable Manner.” Kilarnock, VA: Hampton
Clean Cities Coalition. Retrieved May 9, 2007.
www.hrccc.org/presentations/BlueRidge
CleanFuels-Biodieseloverview.pdf
18. Anon. January 2007. “Biodiesel tests reveal off-spec
fuel in U.S. market.” Biodiesel Magazine. www.
biodieselmagazine.com/article.jsp?article_id=1345
Page 11ATTRAwww.attra.ncat.org
Notes
Page 12 ATTRA
Biodiesel Use, Handling, and Fuel Quality
By Andrew Pressman and Mike Morris
NCAT Energy Specialists
© 2007 NCAT
This publication is available on the Web at:
www.attra.ncat.org/attra-pub/biodiesel_use.html
or
www.attra.ncat.org/attra-pub/PDF/biodiesel_use.pdf
IP315
Slot 314
Version 102407

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Biodiesel Use, Handling, and Fuel Quality

  • 1. A Publication of ATTRA - National Sustainable Agriculture Information Service • 1-800-346-9140 • www.attra.ncat.org ATTRA—National Sustainable Agriculture Information Ser- vice is managed by the National Center for Appropriate Technol- ogy (NCAT) and is funded under a grant from the United States Department of Agriculture’s Rural Business-Cooperative Service. Visit the NCAT Web site (www.ncat.org/agri. html) for more informa- tion on our sustainable agriculture projects. Funding for the development of this publication was provided by the USDA Risk Management Agency. Contents Biodiesel Use, Handling, and Fuel Quality By Andrew Pressman and Mike Morris NCAT Energy Specialists September 2007 © 2007 NCAT This publication addresses questions that farmers and ranchers may have about using biodiesel in diesel engines. Biodiesel can be substituted for petroleum-based diesel fuel in virtually any standard unmodi- fied diesel engine. However, biodiesel has chemical properties that require somewhat different use and handling. While most biodiesel users experience few if any problems, consumers can take precautions to avoid potential problems associated with poor quality fuel. Introduction Biodiesel is becoming widely available in most parts of the U.S. and can be substi- tuted for petroleum-based diesel fuel (“pet- rodiesel”) in virtually any standard unmod- ified diesel engine. Biodiesel offers many advantages over petroleum-based diesel: It is made from domestically produced and renewable agricul- tural products, mainly vegetable oil or animal fat. It is essentially non-toxic and bio- degradable. It has a high flash point (over 300ºF) and is difficult to light on fire with a match. It reduces emissions of many toxic air pollutants. • • • • It functions as an excellent fuel lubricant and performs similarly to low-sulfur diesel with regards to power, torque, and fuel consumption. It can greatly reduce carbon emissions. For discussion of the environmental advan- tages of biodiesel, see the ATTRA publica- tion Biodiesel: the Sustainability Dimensions. To find retail biodiesel distributors in your area, use NCAT’s Farm Energy Search Tool, www.attra.ncat.org/farmenergysearchtool. Most biodiesel users pour it in the tank and experience few if any problems. Nonethe- less, biodiesel has chemical properties that can cause difficulties. For example: Biodiesel’s detergent or solvent properties can clog your fuel filter as it cleans carbon deposits from your engine. • • • Introduction .................... 1 Biodiesel, Ethanol, Vegetable Oil: What’s the Difference? ............... 2 Blending and Storage .............................. 3 Issues and Concerns ..... 4 ASTM Standards ............. 6 The BQ-9000 Program............................. 7 Warranty Issues .............. 8 Fuel Quality Testing ..... 9 Conclusion ....................... 9 References ......................10 Photos:VernGrubinger
  • 2. Page 2 ATTRA Biodiesel Use, Handling, and Fuel Quality Compared to petrodiesel, biodie- sel has somewhat worse cold-flow properties. Biodiesel degrades rubber and cer- tain other materials, making it incom- patible with some fuel lines, rubber gaskets, and other engine parts. This article offers suggestions to help farm- ers and other consumers get the benefits of biodiesel while avoiding performance and equipment problems. Biodiesel, Ethanol, Vegetable Oil: What’s the Difference? Biodiesel is a very different substance from ethanol. Ethanol (or grain alcohol), the familiar alcohol found in alcoholic bever- ages, is commonly blended with gasoline (not diesel fuel) and is made by fermenting grains or other plants that contain sugar. Fermentation is a biological process accom- plished by yeasts and bacteria. Biodiesel is essentially permanently thinned plant or animal-based oil, with a viscosity approximating that of standard #2 diesel fuel. Biodiesel can be made from virtually • • any plant oil or animal fat. Making biodie- sel is a chemical process. During this chem- ical reaction, a thick gooey substance, glyc- erin, is released from the oil molecules and replaced with a comparatively thin and light alcohol, usually methanol. For an expla- nation of how to make biodiesel, see the ATTRA publication Biodiesel: a Primer. Biodiesel is also very different from raw or “straight” vegetable oil (SVO). Almost any vegetable oil will combust, to one degree or another, in a diesel engine. So it’s possible to run most diesel engines on SVO. But this is a somewhat risky process, mainly since raw vegetable oil is too thick and viscous to run well in diesel engines. Biodiesel will perform well in almost any standard diesel engine without modifica- tions. On the other hand, to use SVO you will need to modify your engine. Conver- sion kits are readily available for $300 to $1,500.(1) Generally, conversion means installing a separate fuel tank, heater, and fuel line, along with various switches and controls. The idea is to thin the oil by heat- ing it, while taking precautions to keep cold, gooey vegetable oil out of your engine. You start and run the engine on standard diesel fuel or biodiesel. Once the engine is warm and you’ve pre-heated the vegetable oil— stored in a separate tank—you can switch to SVO. Several minutes before turning off the engine, you switch back to standard diesel fuel or biodiesel, clearing all the SVO out of your engine and fuel lines. The U.S. Department of Energy, among many other organizations, cautions that SVO can reduce engine life and should not be considered a fuel for long-term use.(2) The use of SVO has been shown to cause piston ring sticking, injector and combus- tion chamber deposits, fuel system deposits, reduced power, reduced fuel economy, and increased exhaust emissions. Any of these conditions can reduce engine life, increase maintenance costs, or cause engine failure. Modern diesel engines are also equipped with catalytic converters, or filter traps, that are not designed to handle SVO. Photo:www.biodieselcommunity.orgPhoto:VernGrubinger Caution: If you are making your own fuel, using and storing large quantities of biodiesel, or selling fuel commercially, you will need to take many safety, legal, and quality-related precautions beyond the ones described here.
  • 3. Page 3ATTRAwww.attra.ncat.org Performance problems don’t necessarily happen quickly. Certain engines seem to tolerate SVO better than others, and some vehicles run trouble-free for years. On the other hand, many SVO users succeed ini- tially, and are lulled into a false sense of security, only to run into serious problems later.(3) Despite the very real risk of engine dam- age, SVO has certain advantages that may make it worth considering for some farm- ing situations and equipment, especially in older engines. Using SVO is in some ways simpler than making your own biodiesel. Making biodiesel generally requires you to use methanol, a toxic chemical, and to dispose of glycerin, a waste product. By contrast, SVO is generally only filtered before use, and there are few if any waste products to deal with. Biodiesel Blends and Blending Biodiesel in its pure (100 percent) form is known as neat biodiesel or B100. It can be readily blended with petroleum diesel in any proportion. A B20 blend, for example, is 20 percent by volume biodiesel and 80 percent petrodiesel. Different blends serve different purposes. Small amounts of biodiesel (B1-B2) add lubrication to low-sulfur fuels. Blends in the B20 to B50 range provide significant envi- ronmental benefits with a low increase in cost to consumers. Blending also reduces the likelihood of the solvency, material incompatibility, or cold weather problems discussed below. The simplest method is splash blending. Biodiesel should always be poured on top of petroleum diesel, since it is slightly heavier. The two fuels will mix fairly well as the biodiesel gradually sinks through the lighter petrodiesel. Some form of agi- tation is needed, though, to achieve highly uniform fuel. Random samples of splash- blended fuel being marketed as B20 have been found to contain actual biodiesel content ranging from B2 to B90.(4) You should avoid adding biodiesel to cold petrodiesel, since this may cause crystals to form. To prevent this from happening, you can blend biodiesel with kerosene (also called #1 diesel fuel) in a 50/50 mix before adding it to cold diesel fuel.(5) If crystals have already formed, the fuel will have to be heated until they dissolve. Biodiesel Storage Biodiesel can be stored in standard petroleum diesel storage tanks with some precautions: Tanks that have previously been used to store diesel fuel should be cleaned before use. As noted below, biodiesel is an excellent solvent and will loosen deposits left by standard diesel fuel. Tanks should also be free of water, since this encourages bacterial growth. Tanks may be made of aluminum, steel, Teflon, or fluorinated poly- ethylene or polypropylene. Fiber- glass is sometimes used, but should be approached with caution since some resins are not compatible with biodiesel.(4) • • Photos:VernGrubinger
  • 4. Page 4 ATTRA Biodiesel Use, Handling, and Fuel Quality Both petrodiesel and biodiesel can cause metal parts to oxidize, so you should replace any parts made of brass, bronze, copper, lead, tin, or zinc with aluminum or steel. If biodiesel or blended fuels are stored beyond around six months, fuel stabilizers should be added.(6) Old fuel will become acidic and form sediments and varnish. Biodiesel and biodiesel blends should be stored at temperatures at least 15 degrees above the pour point of the fuels.(7) The pour point is the temperature below which a fuel will not pour. Outdoor tanks should be located in cool shaded areas if possible. Issue #1: Solvent Effects and Filter Clogging According to researchers at the University of Idaho, filter plugging is the most common problem experienced by biodiesel users.(4) Biodiesel has excellent solvent properties and can be used as a cleaning agent and paint remover. (It can remove the paint on the side of your car or tractor, if you splash it around while filling the tank.) In fact, it can even dissolve concrete.(4) Petroleum diesel often leaves a deposit in the bottom of fuel lines, tanks, and deliv- ery systems. Biodiesel can loosen and dis- solve these sediments, as well as rust and other materials. This causes fuel filters to become clogged—sometimes in a matter of hours after switching to B100. Symptoms of filter clogging include a sudden power loss or engine shuddering. Older vehicles have more accumulated deposits, and are especially prone to filter clogging. Ideally, you should clean an old • • • • fuel tank before converting to biodiesel. An alternative is to switch to finer filters. Any- one using B100 should know how to change the fuel filter and should carry a spare fuel filter or two. Expect to change your fuel fil- ter two or three times before all the deposits are cleaned out of your engine. If you are using a modest blend (B20 or lower), you are less likely to notice filter clogging. Issue #2: Reduced Power On average, B100 has about eight per- cent less energy content (BTU per gallon) than #2 petrodiesel, while B20 has one to two percent less energy content.(8) If you switch from standard diesel fuel to B100, you may notice a slight decrease in horse- power, torque, or fuel economy. At B20 or less, you probably won’t be able to tell the difference. A cetane number is an indicator of diesel fuel quality, measuring the readiness of fuel to ignite when injected into the engine. Biodie- sel’s cetane number is higher than that of standard diesel fuel, and this advantage may partly compensate for its lower BTU content. Because biodiesel ignites more readily in diesel engines than petrodiesel, some author- ities recommend setting the injection timing back by two to three degrees from top-dead center. This will sometimes cause the engine to run quieter, although it may also slightly reduce your power.(9) Issue #3: Cold Weather Performance All diesel fuel, including petroleum-based fuel, begins to gel at cold temperatures. The temperature at which a cloud of wax crystals forms in the fuel is known as the cloud point. The cold filter plugging point is the lowest temperature at which fuel can be drawn through a metal screen filter.(10) The pour point is the temperature below which a fuel will not pour. In general, biodiesel gels at somewhat higher temperatures than conventional #2 diesel. When wax crystals begin to form in biodie- sel, the entire fuel tends to cloud at the same time. In contrast, petroleum diesel is made A nyone using B100 should know how to change the fuel filter and should carry a spare fuel filter or two. Caution: If you are storing large amounts of fuel, or selling it commercially, you will need to take many additional precautions and meet local laws and code requirements.
  • 5. Page 5ATTRAwww.attra.ncat.org up of many different compounds that gel at different temperatures. When some of these begin to crystallize, others remain liquid to a much lower temperature. The cloud point for standard #2 diesel fuel is around 5ºF. The cloud point for biodiesel depends on the feedstock and the amount of free fatty acids in the fuel. The cloud point for soy diesel is around 32ºF (4), compared to cloud points around 20ºF for canola and 12ºF for rapeseed.(11) Biodie- sel made from used cooking grease or ani- mal fats will tend to cloud at higher tem- peratures than biodiesel made from virgin oils. Biodiesel from the most highly satu- rated feedstocks may gel at temperatures as high as 50-55ºF. Low-percentage biodiesel blends generally have cold weather properties similar to pet- rodiesel. The cloud point of B20 may be 3º-10ºF higher than #2 petrodiesel.(8) Simple cold weather precautions include using engine block or fuel filter heaters and parking vehicles in or near a build- ing. Fuel additives can also inhibit crystal growth and gelling in standard diesel fuel. Anecdotal reports suggest that few if any of these products work well on B100. They may be effective on blended fuel, however, since they will work on the petroleum-based portion of the fuel. Issue #4: Softening Fuel Lines Using a high-percentage biodiesel blend or B100 can cause certain types of elastomers and natural rubber compounds to bubble, bleed, soften, and degrade over time. Virtu- ally all diesel vehicles made since the early 1990s use components that are compatible with B100.(4) But some older fuel hoses will need to be replaced. Equipment changes are rarely if ever necessary with blends of B20 or lower.(8) Besides rubber, other vulnerable materials identified by the National Biodiesel Board include polypropylene, polyvinyl, and Tygon. Although there have been a few reports of degraded injection pump seals, by far the most common problem you are likely to encounter is with rubber fuel lines. If you have an older vehicle, you should inspect your fuel lines frequently after you begin using biodiesel. The good news is that these problems are likely to appear gradually, if they appear at all. Hoses will begin to soften and (even- tually) weep. You are unlikely to experience a catastrophic failure. Case Study: Phil Foster Ranches Phil Foster began using biodiesel on his organic vegetable farm near San Juan Bautista, California in 2004. He saw the use of non-petroleum fuels as consis- tent with his philosophy as an organic vegetable farmer. He liked the idea that any fuel spills would be biodegradable and far less toxic than standard diesel. He was attracted by the air quality and health advantages for his family and his workers. And he liked the idea of purchasing fuel made from agricul- tural products, preferably ones grown locally or regionally. Phil didn’t have the time or inclination to make his own fuel, so he began pur- chasing biodiesel from a local retailer. Initially, he tried B100 in some of his vehicles, gradually expanding his usage as he became comfortable with the fuel’s performance. He also asked his supplier lots of questions about test- ing, standards, and feedstocks. By 2006, biodiesel made up 81 percent of the roughly 20,000 gallons of diesel fuel consumed annually by the farm’s tractors, pickups, and delivery trucks. Most of the farm’s diesel vehicles are now running B100, although with some of his older equipment Phil has been reluctant to go above B30. Overall, Phil comments that “After four years of using biodiesel, we’ve had very good results.” He did experience some filter plugging when switching to biodiesel, and he now changes his filters at every service. He also went through a period recently where it seemed as if he needed to change fil- ters more often than normal. “Maybe the fuel was a tad off ... We’ll probably never know for sure.” Fuel economy may have decreased slightly, in the range of three to five percent. There have also been a few cold mornings (18º - 20º F) when the vehicles running on B100 would not start. Switching temporarily to B30 dur- ing cold weather has solved this prob- lem, and all vehicles have started fine on B30. Phil recently bought a new truck, which he plans to run on B30 for the first six to twelve months - enough time for any problems to show up. Once he’s confi- dent in the vehicle’s performance, he’ll switch it over to B100.
  • 6. Page 6 ATTRA Biodiesel Use, Handling, and Fuel Quality Issue #5: Engine Oil Dilution and Fuel Oxidation In blends higher than B20, unburned biodiesel can make its way past the piston rings and into the oil pan.(8) This happens because biodiesel has a slightly higher vis- cosity and density than standard diesel. Eventually, this fuel in the engine oil can polymerize, causing oil sludge that coats metal surfaces and causes moving parts to stick.(4) If you are using biodiesel blends higher than B20, you may need to change your engine oil more frequently. Issue #6: Microbial Growth Water can sometimes drip through vents and collect at the bottom of fuel tanks. Certain varieties of algae, yeast, and fungi can grow at the interface of the fuel and water.(4) In order to prevent microbial growth, you should drain any water from the bottom of your fuel tank on a regular basis. Certain biocides can also be added to control microbial growth, but the dead microbes may plug filters. ASTM Standards The American Society for Testing and Materials (ASTM) is the industry organiza- tion that defines legal fuel standards: mini- mum values that a fuel must meet to operate safely in a compression ignition engine. All diesel engines sold in the U.S. are man- ufactured to meet ASTM D975, the legal standard for petrodiesel. In 2001, ASTM In September 2005, Minnesota passed a law requiring all diesel fuel to contain two percent biodiesel. Soon after the mandate went into effect, Minnesota truckers began to experience sporadic problems, includ- ing trucks breaking down on the road, hefty repair bills, and lost road time. The culprit was clogged fuel filters and it soon became apparent that biodiesel was to blame. Cold weather gelling was found to be the main problem. In December 2005, the Min- nesota Department of Commerce confirmed that some biodiesel producers had shipped biodiesel that did not meet ASTM D6751 specification for free and total glycerin.(12) “There’s no room for poor-quality biodie- sel in the marketplace,” said Steve Howell, technical director with the National Biodiesel Board. “Although investigations have indi- cated that other factors unrelated to biodie- sel may have led to at least some of the fil- ter-plugging reports in Minnesota, there’s no question that off-specification biodiesel can have a severe reaction in cold weather, even in low blends.”(13) All Minnesota biodiesel producers subse- quently had to prove that their fuel met ASTM specifications.(12) After imple- menting additional quality measures, the Department of Commerce reaffirmed the ruling that diesel fuel was required to contain two percent biodiesel meeting ASTM D6751 specifications. Minnesota’s experience showed that even a low-percentage of off-spec biodiesel— as low as two percent!—can cause perfor- mance problems . Case Study: The Minnesota Biodiesel Mandate I n 2001, ASTM approved a standard specif- ically for biodiesel, ASTM D6751. Biodiesel-Compatible Fuel Lines The following fuel lines are claimed by their manufacturers to be B100-compatible (14): • Goodyear part numbers 65148 thru 65153 & 65161 thru 65163 meet SAE specification J30R9. • Gates part number 4241G and 4241M for marine use. • Kuriyama part number A4143. • NAPA fuel injection hose part H205. • McMaster-Carr Viton rubber tubing part number 5119K51 (among many others). • Thomas Register listing of other Viton tubing suppliers. approved a standard specifically for biodie- sel, ASTM D6751. This standard covers all biodiesel fuels, regardless of feedstock or processing method. These legal requirements only apply to fuel that is sold. Home brewers, cooperatives, and farms making fuel for their own use are not required to meet ASTM D6751. ASTM testing must be done by qualified laboratories and requires expensive equip- ment. The standards are listed in the table on the following page.
  • 7. Page 7ATTRAwww.attra.ncat.org The BQ-9000 Program The National Biodiesel Board has insti- tuted a cooperative and voluntary quality assurance program called BQ-9000. The program was developed to ensure a more consistent quality for biodiesel being pro- duced, marketed, and used. While ASTM standards only cover fuel quality, BQ-9000 encompasses storage, sampling, testing, blending, shipping, distribution, and fuel management practices. Any biodiesel producer, marketer or distributor of biodiesel or biodiesel blends in the U.S. or Canada is eligible for pro- gram accreditation. Accredited manufactur- ers and certified marketers under this pro- gram are listed on the BQ-9000 website, www.bq-9000.com. Property ASTM Method Limits Units Calcium & Magnesium, combined EN 14538 5 max ppm (ug/g) Flash Point (closed cup) D 93 93 min Degrees C Alcohol Control 1. Methanol Content 2. Flash Point EN 14110 D 93 0.2 max 130 min % volume Degrees C Water & Sediment D 2709 0.05 max % volume Kinematic Viscosity, 40 C D 445 1.9 – 6.0 mm2 /sec Sulfated Ash D 874 0.02 max % mass Sulfur S 15 Grade S 500 Grade D 5453 D 5453 0.0015 max (15) 0.05 max (500) % mass (ppm) % mass (ppm) Copper Strip Corrosion D 130 No. 3 max Cetane D 613 47 min Cloud Point D 2500 Report Degrees C Carbon Residue 100% Sample D 4530 0.05 max % mass Acid Number D 664 0.50 max mg KOH/g Free Glycerin D 6584 0.020 max % mass Total Glycerin D 6584 0.240 max % mass Phosphorus Content D 4951 0.001 max % mass Distillation, T90 AET D 1160 360 max Degrees C Sodium/Potassium, combined EN 14538 5 max ppm Oxidation Stability EN14112 3 min hours Table 1: ASTM Standards Adapted from The National Biodiesel Board, Specification For Biodiesel (B100) – ASTM D6751-07a.(15)
  • 8. Page 8 ATTRA Biodiesel Use, Handling, and Fuel Quality Will Biodiesel Void My Warranty? Many farms and ranches are discouraged from using biodiesel, especially in newer vehicles, because of fears that they will “void their warranties.” It’s a good idea to check with your vehicle manufacturer to see if they have an official policy on the use of biodiesel. Most major engine companies have formally stated that biodiesel blends below 20 percent that meet ASTM D6751 will not void their engine warranties. The National Biodiesel Board has posted on its website several statements from engine companies (www.biodiesel.org). John Deere, Caterpillar, and New Holland are among the many companies that have adopted pol- icies supportive of biodiesel. Other compa- nies are in the process of developing guide- lines for biodiesel. A number of authorities state flatly that the use of biodiesel does not, in itself, void engine warranties. [See, for example, (1) and (2)] Engine warranties typically cover the “materials and workmanship” of the engine, and say little or nothing about fuel. It’s certainly true that bad quality biodie- sel can cause performance problems that are not the fault of the engine maker and so are not covered by the warranty. These situations are no different from ones where a problem has been caused by bad quality petroleum diesel or gasoline. Engine manufacturers would generally refer any customer with fuel-related problems to the fuel supplier. According to the National Biodiesel Board, any reputable fuel supplier (petrodiesel, biodiesel, or blend) should stand behind its product and cover any fuel quality problems that occur.(16) Biodiesel sold in the U.S. is subject to qual- ity requirements that are just as strict as those for standard diesel fuel. You are on strong legal ground in using ASTM-compli- ant biodiesel fuel—just as you would be in using ASTM-compliant petroleum diesel. Unfortunately, though, your strong legal position does not guarantee that you will be free from warranty-related hassles. Some equipment dealers are still poorly informed and will caution customers against using biodiesel, since they (mistakenly) regard it as unregulated or unreliable. Are You Sure Your Fuel Is Meeting ASTM Standards? A study released in November 2006 suggests that inconsistent fuel quality continues to be a real issue for the US biodiesel industry— despite the legal requirement that commercial fuel must meet ASTM standards. Co-funded by the National Biodiesel Board (NBB) and the National Renewable Energy Laboratory (NREL), the study randomly collected biodiesel samples from 32 fuel distributors around the country between November 2005 and July 2006. Half of the samples failed to meet at least one of the ASTM D6751 specifications, and some samples failed multiple standards. Thirty percent of the samples failed to meet the flash point standard, and one-third of the samples failed to meet the total glycerin standard.(18) Caterpillar - Biodiesel Use Statement “Caterpillar neither approves nor prohibits use of biodiesel fuels. Caterpillar is not in a position to evaluate the many variations of biodiesel and the long term effects on performance, durabil- ity, or compliance to emissions standards for Caterpillar products. The use of biodiesel fuel does not affect Caterpillar’s materials and work- manship. Failures that result from the use of any fuel are not Caterpillar factory defects. There- fore, the cost or repair would NOT be covered by a Caterpillar’s warranty.”(17) Caterpillar Commercial Diesel Engine Fluids Recommendations SEBU6251-08 March 2004
  • 9. Page 9ATTRAwww.attra.ncat.org How Can I Be Sure I’m Getting Good Fuel? It’s important to keep the issue of poor qual- ity, off-spec fuel in perspective: The vast majority of biodiesel consumers experience no fuel-related problems whatsoever. There is also (unfortunately) off-spec gasoline and diesel fuel in the marketplace too. To reduce your chances of buying off-spec biodiesel, get to know your dealer and ask questions. How long have they been in busi- ness? What feedstocks are used? What are the cold weather characteristics of the fuel? How frequently is the fuel tested for ASTM compliance? Are your manufacturer and marketer BQ-9000 accredited? Don’t assume that bigger companies are necessarily better. Many small producers take pride in making excellent fuel, and some large producers have been known to make bad batches. Do-It-Yourself Fuel Quality Testing You can mail a sample of fuel to a labora- tory for comprehensive ASTM testing, but the price tag is likely to be a hefty $800 to $1,000 or more. Fortunately, there are some inexpensive alternatives for consum- ers and fuel makers. Dr. Randall von Wedel has developed a sim- ple testing kit called the pHLip (pronounced “flip”) Test. You fill a vial with B100 to the indicated level, then flip the sample 10 times and wait 10 minutes for the fuel to float to the top. Through visual inspection you can identify a variety of fuel quality problems, including old, poorly washed, or oxidized fuel. The kits are NOT a substitute for ASTM testing and standards, but cost only around $5 per test and allow quick in- the-field testing. For more information, visit www.phliptest.com. Several simple fuel quality tests are also described on the Journey to Forever site, at http://journeytoforever.org/biodiesel_vehicle. html. These include the “wash test,” “repro- cessing test,” “methanol test,” and others. While most of these are mainly of interest to biodiesel fuel makers, some are within the capability of technically minded fuel consumers, too. Conclusion Biodiesel users should take some basic pre- cautions to avoid performance problems: Perform regular maintenance, check fuel filters frequently, and change them as necessary. Understand biodiesel’s cold weather properties and take appropriate precautions. Be aware of biodiesel’s incompat- ibility with certain materials and replace any incompatible parts, especially rubber fuel lines. Regularly drain water from the bottom of fuel tanks, to prevent microbial growth. Use stored biodiesel within about six months. Make sure that fuel meets ASTM D6751. Incorporate biodiesel into farming operations gradually. Start slowly and expand your use of the fuel as you gain confidence. Make sure your biodiesel comes from a reputable source. Get to know your fuel provider and ask questions about feedstocks and quality testing. • • • • • • • • pHLip test results, showing fuel quality problems. Photo:www.biodieselcommunity.org
  • 10. Page 10 ATTRA Biodiesel Use, Handling, and Fuel Quality References 1. Pahl, Greg. 2005. Biodiesel: Growing a New Energy Economy. White River Junction, VT: Chelsea Green Publishing Company. 2. Clean Cities. 2006. “Straight Vegetable Oil as a Diesel Fuel?” Washington, DC: U.S. Depart- ment of Energy. Retrieved May 9, 2007. www.eere.energy.gov/cleancities 3. Engine Manufacturers Association. 2006. “Use of Raw Vegetable Oil or Animal Fats in Diesel Engines.” Chicago, IL: Engine Manufacturers Association. 4. Van Gerpen, Jon. “Biodiesel Use and Consumption.” Montana Oilseed and Biodiesel Workshop. Great Falls, MT: Montana Farmers Union and Montana Grain Growers Association, February 15, 2007. 5. Ryan, David. 2004. “Biodiesel—A Primer.” Butte, MT: National Center for Appropriate Technology. 6. Anon. 2006. Fuel Quality and Performance Guide. National Biodiesel Board. Retrieved May 11, 2007. www.biodiesel.org/pdf _files/Fuel QualityandPerformanceGuide.pdf 7. Tyson, K. Shaine. 2001. Biodiesel Handling and Use Guidelines. Golden, CO: National Renew- able Energy Laboratory. 8. Anon. 2005. “Use of Biodiesel Blends above 20% Biodiesel.” National Biodiesel Board. Retrieved May 14, 2007. www.biodiesel.org/ pdf _files/Biodiesel_Blends_Above%20_20_ Final.pdf 9. Pelly, Mike. 2003. “Mike Pelly’s Biodiesel Method.” Journey to Forever. Retrieved June 5, 2007. www.journeytoforever.org/biodiesel_mike.html 10. Anon. No Date. Background. National Biodiesel Board. Retrieved May 10, 2007. www.biodie- sel.org/pdf _files/fuelfactsheets/Cold%20Flow.pdf 11. Brown, Jack and Jim Davis. January 31, 2007. “Agronomics of Oil Seed Crops in the Pacific Northwest.” Biodiesel in the Pacific Northwest Biodiesel Workshop Course. National Biodiesel Program, University of Idaho. 12. Zeman, Nicholas. 2006. “Remember December.” Biodiesel Magazine, October. Retrieved May 11, 2007. www.biodieselmagazine.com/ article-print.jsp?article_id=1180 13. Barrett, Rick. 2006. “Minnesota Aims to Get Biodiesel Back In Gear.” Milwaukee Journal Sentinel, February 1. Retrieved May 11, 2007. http://findarticles.com/p/articles/mi_qn4196/is_ 20060201/ai_n16036216/print 14. Anon. No date. “Solvency Effects.” Piedmont Bio- fuels. Retrieved May 14, 2007. http://biofuels. coop/general-information/solvency-effects 15. Anon. 2007. Specification For Biodiesel (B100). ASTM D6751-07a. National Biodiesel Board. Retrieved June 9, 2007. www.biodiesel.org/ pdf-files/fuelfactsheets/BDSpec.pdf 16. Anon. No Date. “Biodiesel Standards and Warran- ties.” National Biodiesel Board. Retrieved May 14, 2007. www.biodiesel.org/resources/ fuelfactsheets/standards-and-warranties.shtm 17. Freckmann, Chad. 2006. “Biodiesel: A Renew- able, Premium Fuel to Meet Today’s and Tomorrow’s Energy Needs in a Clean and Sustainable Manner.” Kilarnock, VA: Hampton Clean Cities Coalition. Retrieved May 9, 2007. www.hrccc.org/presentations/BlueRidge CleanFuels-Biodieseloverview.pdf 18. Anon. January 2007. “Biodiesel tests reveal off-spec fuel in U.S. market.” Biodiesel Magazine. www. biodieselmagazine.com/article.jsp?article_id=1345
  • 12. Page 12 ATTRA Biodiesel Use, Handling, and Fuel Quality By Andrew Pressman and Mike Morris NCAT Energy Specialists © 2007 NCAT This publication is available on the Web at: www.attra.ncat.org/attra-pub/biodiesel_use.html or www.attra.ncat.org/attra-pub/PDF/biodiesel_use.pdf IP315 Slot 314 Version 102407