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M.Sc. Part-II (Sem-III) Analytical Chemistry
Paper No. -IX, ACH 3.1: ADVANCED ANALYTCAL TECHNIQUES
College : Yashwantrao Chavan College of Science karad
Time: 1 hour MARKS :50
Instruction :
1. Answer in one sentence ( Two mark for each question )
2. Solve any 50 out of 30 question
3. Choose the correct alternatives from following and Tick mark √ the correct answer
=============================================================
1. SEM stands for
a.Scanning Electron microscopy
b.Scanning Electric microscopy
c.standard Electron microscopy
d.All of these
2. Electron Microscope has the magnification of ----------------- and resolving power up to 0.5nm.
a. 10,00,000X
b. 10000 X
c. 10010 x
d. all of these
3. Only dead and the dried specimen can be seen by
a. scanning electron microscopy
b. Transmission electron Microscopy
c. Both a and b
d. none of these
4. Which type of electron source used in SEM and TEM Microscopy
a. Candle Light
b. Sun light
c. Tungsten Filament
d. All of these
5. TEM cannot be used to examine live specimen.
a. True
b. False
6. Electron Microscope was invented by physicist
a. Zacharius Jansen
b. Ernst Ruska and German engineer Max Knoll
c. both a and b
7. Electrons are produced at the source by thermionic heating
a. True
b.False
8.These electrons are accelerated to a voltage between 1-40 kV
a. 1-40 kV
b.10-50 kV
c. 30-50 Kv
d. All of these
9. The main sequence of Components in Mass Spectrometry is
a. Sample Inlet - Analyzer-Detector -Ionization Chamber- Mass.
b. Sample Inlet Mass Analyzer -Ionization Chamber- -Detector.
c. Sample Inlet -Ionization Chamber- Mass Analyzer-Detector.
d. Ionization Chamber- Mass Analyzer-Detector -Sample Inlet
10. In mass spectrometry, MALDI stands for
a. Matrix Assisted Laser Desorption Ionization
b. Matrix Assosted Laser Deabsorption Ionization
c. Matrix Assisted light Desorption Ionization
d. Matrix Assosted light Deabsorption Ionization
11. In chemical ionization, which type of reagent gases is commonly used?
a.Isobutane
b.. Methane
c. Ammonia
d.Isopropane
12. Which type of carbon allotrope shows -------------3D nanomaterial
a. Carbon nanotube
b.Graphite
c.C60
d.all of these
13.Scanning Tunneling Microscope was patented by
a.Sir Walter Wingfield
b.Sir Heinrich Rohrer
c.Sir Walter Brattain
d.Sir T.J Blachut
14. Which of the following is not a component of an STM (scanning tunneling microscope)?
a. Cantilever
b. Tip sensor
c. Piezoelectric scanner
d. Feedback control
15. The electron changes from a higher to a lower orbit, it releases energy. Is known as -------
spectroscopy
a.x ray
b.Auger
c. gamma
d. all of these
16. X-ray Photoelecctron Spectroscopy (XPS) is also known as
a. ESCA
b.MSCA
c.LSCA
c. all of these
17. XPS techniques is based on Einstein’s idea about the photoelectric effect developed around -
---
a. 1906
b.1905
c.1909
c. 1907
18. X-ray Photoelectron spectroscopy, based on the -----
a. photoelectric effect
b.Auger effect
c. ion effect
d. All of these
19. XPS requires irradiating a solid in - ---------------with monoenergetic soft X-rays and
analyzing the energies of the emitted electrons.
a.Vaccum chamber
b. Ultra-high Vacuum (UHV) chamber
c. both a and b
20. ----------- source used as monochromatic radiation in ESR
a. mercury light
b. Klystron tube
c.Argon gas
d.all of these
21. The phenomenon of electron spin resonance (ESR) is based on
a. proton charged particle
b. electron charged particle
c. both a and b
d. none of these
22. ESR or EPR spectroscopy is used ----------------------- in electromagnetic spectrum
a. Radiowaves
b. Microwaves
c.IR waves
d. all of these
23. The alignment can either be along the direction (parellel) to the magnetic filed which
corresponds to the lower energy state
a.ms = - ½
b.ms= + ½
c. both a and b
d. none of these
24. In ESR spectroscopy , Opposite (antiparallel) to the direction of the applied magnetic field
a.ms = - ½
b.ms= + ½
c. both a and b
d. none of these
25. Wave guide or wave meter is usually used as calibrated as frequency in units
a. wavelength
b. megahertz
c. wavenumber
d. All of these
26. in ESR spectroscopy , which type of detector is used?
a. silicon crystal
b. phosphorus crystal
c. both a and b
d. none of these
27. EPR spectroscopy based on --------- electrons
a. donor paired
b.lone paired
c. unpaired
d. all of these
28.Which is reference standared in ESR ?
a.KBr
b.NaCl
c.DPPH
d.Cu
29. EDAX stands for
a.Electron dispersive X-ray Analysis
b. Energy dispersive X-ray Analysis
c.both a and b
d.none of these
30.Klyston is produce frequency
a.95000 MHz
b.900 MHz
c.9500 MHz
d.500 MHz

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Advanced Analytical techniques (Question paper)

  • 1. M.Sc. Part-II (Sem-III) Analytical Chemistry Paper No. -IX, ACH 3.1: ADVANCED ANALYTCAL TECHNIQUES College : Yashwantrao Chavan College of Science karad Time: 1 hour MARKS :50 Instruction : 1. Answer in one sentence ( Two mark for each question ) 2. Solve any 50 out of 30 question 3. Choose the correct alternatives from following and Tick mark √ the correct answer ============================================================= 1. SEM stands for a.Scanning Electron microscopy b.Scanning Electric microscopy c.standard Electron microscopy d.All of these 2. Electron Microscope has the magnification of ----------------- and resolving power up to 0.5nm. a. 10,00,000X b. 10000 X c. 10010 x d. all of these 3. Only dead and the dried specimen can be seen by a. scanning electron microscopy b. Transmission electron Microscopy c. Both a and b d. none of these 4. Which type of electron source used in SEM and TEM Microscopy a. Candle Light
  • 2. b. Sun light c. Tungsten Filament d. All of these 5. TEM cannot be used to examine live specimen. a. True b. False 6. Electron Microscope was invented by physicist a. Zacharius Jansen b. Ernst Ruska and German engineer Max Knoll c. both a and b 7. Electrons are produced at the source by thermionic heating a. True b.False 8.These electrons are accelerated to a voltage between 1-40 kV a. 1-40 kV b.10-50 kV c. 30-50 Kv d. All of these 9. The main sequence of Components in Mass Spectrometry is a. Sample Inlet - Analyzer-Detector -Ionization Chamber- Mass. b. Sample Inlet Mass Analyzer -Ionization Chamber- -Detector. c. Sample Inlet -Ionization Chamber- Mass Analyzer-Detector. d. Ionization Chamber- Mass Analyzer-Detector -Sample Inlet 10. In mass spectrometry, MALDI stands for a. Matrix Assisted Laser Desorption Ionization b. Matrix Assosted Laser Deabsorption Ionization c. Matrix Assisted light Desorption Ionization d. Matrix Assosted light Deabsorption Ionization
  • 3. 11. In chemical ionization, which type of reagent gases is commonly used? a.Isobutane b.. Methane c. Ammonia d.Isopropane 12. Which type of carbon allotrope shows -------------3D nanomaterial a. Carbon nanotube b.Graphite c.C60 d.all of these 13.Scanning Tunneling Microscope was patented by a.Sir Walter Wingfield b.Sir Heinrich Rohrer c.Sir Walter Brattain d.Sir T.J Blachut 14. Which of the following is not a component of an STM (scanning tunneling microscope)? a. Cantilever b. Tip sensor c. Piezoelectric scanner d. Feedback control 15. The electron changes from a higher to a lower orbit, it releases energy. Is known as ------- spectroscopy a.x ray b.Auger c. gamma d. all of these 16. X-ray Photoelecctron Spectroscopy (XPS) is also known as
  • 4. a. ESCA b.MSCA c.LSCA c. all of these 17. XPS techniques is based on Einstein’s idea about the photoelectric effect developed around - --- a. 1906 b.1905 c.1909 c. 1907 18. X-ray Photoelectron spectroscopy, based on the ----- a. photoelectric effect b.Auger effect c. ion effect d. All of these 19. XPS requires irradiating a solid in - ---------------with monoenergetic soft X-rays and analyzing the energies of the emitted electrons. a.Vaccum chamber b. Ultra-high Vacuum (UHV) chamber c. both a and b 20. ----------- source used as monochromatic radiation in ESR a. mercury light b. Klystron tube c.Argon gas d.all of these
  • 5. 21. The phenomenon of electron spin resonance (ESR) is based on a. proton charged particle b. electron charged particle c. both a and b d. none of these 22. ESR or EPR spectroscopy is used ----------------------- in electromagnetic spectrum a. Radiowaves b. Microwaves c.IR waves d. all of these 23. The alignment can either be along the direction (parellel) to the magnetic filed which corresponds to the lower energy state a.ms = - ½ b.ms= + ½ c. both a and b d. none of these 24. In ESR spectroscopy , Opposite (antiparallel) to the direction of the applied magnetic field a.ms = - ½ b.ms= + ½ c. both a and b d. none of these 25. Wave guide or wave meter is usually used as calibrated as frequency in units a. wavelength b. megahertz c. wavenumber d. All of these 26. in ESR spectroscopy , which type of detector is used?
  • 6. a. silicon crystal b. phosphorus crystal c. both a and b d. none of these 27. EPR spectroscopy based on --------- electrons a. donor paired b.lone paired c. unpaired d. all of these 28.Which is reference standared in ESR ? a.KBr b.NaCl c.DPPH d.Cu 29. EDAX stands for a.Electron dispersive X-ray Analysis b. Energy dispersive X-ray Analysis c.both a and b d.none of these 30.Klyston is produce frequency a.95000 MHz b.900 MHz c.9500 MHz d.500 MHz