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ACIDS AND BASES
GenChem2
•What comes in your mind when you hear the word
acid or a base?
•Some associate an acid and a base to a substance that
taste sour and bitter, respectively.
•What is
really an
acid and
base?
Different
theories
about acids
and bases
•Arrhenius theory
•Bronsted-Lowry theory
•Lewis or electron-pair theory
•are the three theories that
point out a specific
characteristic which defines
an acid and a base.
Arrhenius theory
• Svante Arrhenius formulated a
theory that defines an acid
and a base as substances that
when ionize in water produce
hydrogen ions (H+) and
hydroxide ions (OH-).
• However, Arrhenius theory
could not explain why salt
having no H+ or OH- still
exhibit the property of an acid
or a base upon dissolving in
water.
In this lesson, we will
define an acid and a base
according to the Bronsted-
Lowry theory.
Bronsted-
Lowry’s theory
acids on and
bases
•Johannes Nicolaus
Bronsted, a Danish
chemist, and Thomas
Martin Lowry, an
English chemist,
introduced the
Bronsted-Lowry
theory of acids and
bases
•They defined an acid
as a substance that
is capable of
transferring protons,
the positively charge
ion(H+), and a base
as substance
capable of accepting
protons.
•Substances that behave based on
the given definition, are classified
as Bronsted acids and Bronsted
bases.
•When an acid reacts with a base, a
proton (H+) will transfer from acid
towards the base.
•The product that will be formed
after an acid loses H+ is called the
conjugate base while the product
that will be formed after a base
accepts H+ is called the conjugate
acid.
• In the reaction of HCl and NH3, as shown in Figure 1, HCl donates hydrogen
ion (H+) towards ammonia (NH3) forming ammonium ion (NH4+), the
conjugate acid, and chloride ion (Cl-), the conjugate base.
Acid-Base Property of
Water
•A compound like water, H2O,
that contains both a hydrogen
atom and a lone pair of
electrons can act as an acid or a
base, depending on the specific
reaction. Compound exhibiting
such property is called
amphoteric.
H2O acts as an acid -When water acts as an acid, it
will donate proton to the base.
H2O acts as a base- When water acts as a
base, it will accept proton.
•Water can also
undergo self-
ionization or auto-
ionization, the
process occurs
when water
molecules react
with another
molecule to form
H3O+ and OH-.
Self-ionization
•The reaction in which a water
molecule donates one of its
protons to a neighboring water
molecule (both base and acid/
amphoteric)
Autoionization
•In autoionization of water,
a proton is transferred
from one water molecule
to another to produce
hydronium ion (𝐻3𝑂+
)and
a hydroxide ion (𝑂𝐻−
)
Practice Exercise 1. Label each reactant as A1 for Bronsted-Lowry acid or B1 for
Bronsted-Lowry base and each product as CA, for conjugate acid or CB for conjugate
base. Then, write the conjugate acid-base pair.

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ACIDS AND BASES general chemistry senior high school.pptx

  • 2. •What comes in your mind when you hear the word acid or a base? •Some associate an acid and a base to a substance that taste sour and bitter, respectively.
  • 3.
  • 5. Different theories about acids and bases •Arrhenius theory •Bronsted-Lowry theory •Lewis or electron-pair theory •are the three theories that point out a specific characteristic which defines an acid and a base.
  • 6. Arrhenius theory • Svante Arrhenius formulated a theory that defines an acid and a base as substances that when ionize in water produce hydrogen ions (H+) and hydroxide ions (OH-). • However, Arrhenius theory could not explain why salt having no H+ or OH- still exhibit the property of an acid or a base upon dissolving in water.
  • 7. In this lesson, we will define an acid and a base according to the Bronsted- Lowry theory.
  • 8. Bronsted- Lowry’s theory acids on and bases •Johannes Nicolaus Bronsted, a Danish chemist, and Thomas Martin Lowry, an English chemist, introduced the Bronsted-Lowry theory of acids and bases
  • 9. •They defined an acid as a substance that is capable of transferring protons, the positively charge ion(H+), and a base as substance capable of accepting protons.
  • 10. •Substances that behave based on the given definition, are classified as Bronsted acids and Bronsted bases. •When an acid reacts with a base, a proton (H+) will transfer from acid towards the base.
  • 11. •The product that will be formed after an acid loses H+ is called the conjugate base while the product that will be formed after a base accepts H+ is called the conjugate acid.
  • 12. • In the reaction of HCl and NH3, as shown in Figure 1, HCl donates hydrogen ion (H+) towards ammonia (NH3) forming ammonium ion (NH4+), the conjugate acid, and chloride ion (Cl-), the conjugate base.
  • 13. Acid-Base Property of Water •A compound like water, H2O, that contains both a hydrogen atom and a lone pair of electrons can act as an acid or a base, depending on the specific reaction. Compound exhibiting such property is called amphoteric.
  • 14. H2O acts as an acid -When water acts as an acid, it will donate proton to the base.
  • 15. H2O acts as a base- When water acts as a base, it will accept proton.
  • 16. •Water can also undergo self- ionization or auto- ionization, the process occurs when water molecules react with another molecule to form H3O+ and OH-.
  • 17. Self-ionization •The reaction in which a water molecule donates one of its protons to a neighboring water molecule (both base and acid/ amphoteric)
  • 18. Autoionization •In autoionization of water, a proton is transferred from one water molecule to another to produce hydronium ion (𝐻3𝑂+ )and a hydroxide ion (𝑂𝐻− )
  • 19. Practice Exercise 1. Label each reactant as A1 for Bronsted-Lowry acid or B1 for Bronsted-Lowry base and each product as CA, for conjugate acid or CB for conjugate base. Then, write the conjugate acid-base pair.