The extensive use of pulverized coal injections in blast furnace worldwide, calls for higher coke quality. On the other hand, as coking coals become more expensive, with volatile price and relative availability, coke producers look for the introduction of cheaper coals in the blend. One of the answers to either of these drivers is stamped charging, initially oriented to the use of high volatile poorly coking coals.
Briefly, the technique of charge preparation consists in preparing a cake with the coal blend in a metallic box, then charging it in the coke oven. The higher charge density implies better coke quality when compared with conventional charging. So, depending on the situation, either better coke quality may be obtained, or poorer coking coals may be included in the blend.
The process has been around since the early XX century. As an example, Coed Ely coke plant, in South Wales, UK, operated two batteries of 30 ovens each, built by Coppe Company in 1914, 34’ long, 8’ 6” high and 50’ width, with a stamping station located in the space between the two batteries. Straw was used as an aid to cake strength. Straw was used as a binder and a specially designed charger car/ram built to load the charge into the oven from the back. Coke made by the stamp charging process was of a denser and larger variety than that made in other ways, making its use ideal for ironmaking in foundries where strength is an important factor. Another advantage noted was that a much larger range of coals could be coked with the limits of (high) volatility and coking properties much increased [1]. Also, other plants in West and East Europe adopted the technique: Germany, France, Poland, and Ukraine.
Modern process development took place in Fuerstenhausen Coke Plant, Völklingen, Germany, focused in the use of high volatile Sarre basin coal. In 1978, after intensive research and development the first 6 meters high cake was produced, overcoming a bottleneck for the economical implantation of this technology. The first plant of this dimension was started-up in 1984, at what is called today ZKS Zentralkokerei Saar, Völklingen, Germany [2].
Then, stamped charging was adopted by Tata Steel in 1989 [3] and other plants in the same country. During this century, an impressive capacity was built in China, with more than 100 M tpy [4]. The first modern stamp charging plant in the Americas was built in 2010 in ThyssenKrupp Steel CSA, Santa Cruz, Brazil [5].
3. Introduction
Drivers for this review
Start-up of a pilot coke oven
with stamped charging facility at
a steel plant in Peru, with
unexpected results
Dramatic expansion of stamped
charging capacity in China:
more than 100 Mtpa of installed
capacity (Dr. Q. Meng, ICSTI
2012)
孟庆波
4. Introduction
PCI calls for higher coke quality
Coking coal price volatility calls for use of
poorly coking coals
One of the answers has been stamped
charging
Introducing the coal blend previously ground
within a steel box, as successive layers that are
rammed mechanically
The higher the density, the higher the coke
quality (mostly for high volatile blends)
6. Introduction
1978 First 6 m high cake,
after long R&D effort
(Feuerfesten Coke Plant,
Germany)
1984 First 6 m high coke
stamp charged batteries
(ZKS, Völklingen) by Didier
and Saarberg Interplan
1989 Battery #7 in Tata Steel
1995-2013 Expansion in
China and India
7. Introduction
Some coke plants with stamped charging
Company Location Country Mta Year Builder Oven type
ZKS Völklingen Germany 1.3 2010 (#3)
2012 (#1)
Paul Wurth-Saarberg Conventional
ISD Alchevsk Coking Plant Alchevsk Ukraine 2.0 1993/2006 Azovintex-VeCon Conventional
Shanxi Changzhi Changzhi China 1.5 MEPC Conventional
Shanxi Zhonghua Dali Village China 1.2 SPDCI Heat-recovery
Zhongmei Jingda Hui’an China SPDCI Heat-recovery
Jincheng Qinhe Qinhe China SPDCI Heat-recovery
Shanxi Sanjia Jiexiu City China SPDCI Heat-recovery
Shanxi Luxin Energy Group Shanxi Prov. China SPDCI Heat-recovery
Xinjiang International Urumqi China SPDCI Heat-recovery
Jiangsu Zhuxi Activated C. Liyang City China 0.75 SPCDI Heat-recovery
Shanxi Fenyang Longquan Fenyang C. China 0.4 SPCDI Heat-recovery
Hunan Loudi Xinxing Loudi China 0.6 SPCDI Heat-recovery
Qingdao Steel Qingdao China 0.6 1995 Saarberg Conventional
Taiyuan Gangyuan Donggaobai China 0.4 SPCDI Heat-recovery
Xinggao Coking Group Gaoping China 1.0 2000
2008
SPCDI
FLSmidth Koch
Heat-recovery
Conventional
Tata Steel Jamshedpur India 2.0 1989/2000 Conventional
Sesa Goa Amona India 0.28 Sesa Goa Non-recovery
Bla Coke Arambhada India 0.25 Bla-VeCon Non-recovery
JSW Steel Bellary India 1.2 Sesa Goa-VeCon Heat-recovery
JSW Steel Bellary India 1.5 2008 Sinosteel Conventional
JSL India 0.42 Sinosteel Heat-recovery
JSPL Raigahr India 0.8 2008-2013 Sinosteel Heat-recovery
SISCOL Tamil Nadu India 0.4 2007 Sinosteel Heat-recovery
Lanco Ind. Ltd. Rachagunneri India 012 2005 Dasgupta-MEPC Heat-recovery
Hoogly Met Coke & Power Haldia India 1.6 MEPC Heat-recovery
TK-CSA Santa Cruz Brazil 2.0 2010 Sinosteel Heat-recovery
8. Equipment & Operation
Stamping equipment
Location
Stationary (i.e. in a building below the coal tower)
In a stamping/charging/pushing machine
Densification
Ramming (several layers)
Vibration (as a complement, for horizontal ovens)
Cake properties
Densification
Mechanical properties
18. Equipment & Operation
Wall pressure issues
ZKS
Didier batteries 1 & 2
started up in 1984,
6.25 m high
Battery 3 built by Paul
Wurth in 2010
Battery 1 demolished
and rebuilt in 2012
Battery 2 said to be
shut down in 2012
So, battery live was
28 years
19. Equipment & Operation
Wall pressure issues
Tata Steel
Jamshedpur
Oldest stamp charged
battery #7, built in
1989
Failures started in
2005
After long continuous
improvement work, all
ovens came back by
2010
20. Equipment & Operation
These examples suggests that with the
technology used for 6 m high stamp charged
batteries in the mid 80s, working life should
be around 30 years
This is less than what is expected for top
charged batteries (40-50 years)
But it is the same that for non-recovery/heat
recovery ovens, with or without stamped
charging
25. Blend Design & Coke Quality
China
Committee of Coke and
Coal Resources of the
China Coke Industry
Association: by using
stamp charge, coking coal
and fat coal can be
decreased by 14%
So, there is emphasis on
full utilization of stamp
charging installed
capacity
28. Blend Design & Coke Quality
Summary
Main blend component: high volatile local coal
Use of soft/semisoft coals
Use of low volatile inerts like anthracite and
petroleum coke, in some plants
For such blends, MICUM 10 and CSR improve in
comparison with top charging (less porosity)
29. Recent Research
Technical University of Berlin, Germany
Stampability, modeling of stamping operation
Tata Steel R&D, India
Tar pitch/molasses to improve cake strength
Fluid pet coke/anthracite to decrease cost
RDTE, China
Influence of coke structure on high temperature
behavior
30. Conclusions
With more than 100 Mtpa capacity installed,
stamped charging became one of the most
applied technologies to decrease blend cost
and/or to improve coke quality
Adoption by China and to a less extent by
India, suggests that further increase in
capacity may take place in the future
Some Universities, Institutes and Steel
Companies are supporting this technology
with R&D efforts