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University of Khartoum
Faculty of Engineering
Department of Petroleum and Natural gas Engineering
Show about :
Combined Low Salinity Water Injection and
Foam Flooding in Sandstone Reservoir Rock:
A New Hybrid EOR
29 April 2020 1
Authors :
• Abdolmohsen Shabib-AsL, University of Calgary
• Mohammed Abdallah Ayoub , University of Technology
PETRONAS
• Khaled Abdallah Elraies, University of Technology PETRONAS
29 April 2020 2
Presentation Outlines:
1- Introduction
2- Material and Procedures
3- Methodology
4- Results and discussion
5 - Conclusion
29 April 2020 3
Introduction :
• To date, several methods have been implemented either
individually or as combination to increase oil recovery.
• The combined methods also called hybrid Enhanced Oil Recovery
(EOR) pose great challenges in the oil and gas industry.
• This presentation investigates the potential of a new hybrid EOR
method termed Low Salinity Water Assisted Foam flooding
(LSWAF).
29 April 2020 4
Introduction :
• Foam flooding process has been in use for improving the oil
recovery.
• Most experiments of foam flooding have been conducted in water-
wet medium conditions without the presence of oil due to its
interaction with foam.
• However, interactions of crude oil with foam leads to destabilize
the foam (Nell 2015).
29 April 2020 5
Introduction :
• One of the methods can be used to minimize this negative
interaction is combination method with the other techniques such
as Low Salinity Water (LSW).
• LSW is responsible to change wettability of the rock from oil wet
to water wet.
• Foam with high stability is responsible to increase gas sweep
efficiency.
29 April 2020 6
Material and Procedures :
The rock :
• The reservoir rock was obtained from the KOCUREK Company
(USA). With properties as shown in Table (1):
• X-Ray diffractometer (XRD) and basic routine core analysis using
Poroperm Machine were used to confirm the properties above and has
given almost same data .
29 April 2020 7
Material and Procedures :
Crude oil :
Two samples of crude oil designated as crude oil A and B were used.
Tables 2 and 3 exhibit the properties of crude samples:
Table 2 - Crude oil (A) properties
29 April 2020 8
Material and Procedures :
Table 3 - Crude oil (B) properties
29 April 2020 9
Material and Procedures :
The brine :
• The brines for LSW were prepared by mixing controlled amounts of K⁺,
Na⁺, Ca²⁺, Mg²⁺, and Cl⁻ with distilled water.
• 30 brines were prepared with different salt concentrations. See Table 4
• Two types of formation water, namely FW1 and FW2 were produced
for establishing initial and connate water saturations.
29 April 2020 10
Material and Procedures :
Table 4 -brines and two FW salt Concentrations :
29 April 2020 11
Material and Procedures :
The surfactant :
Alpha Olefin Sulphonate (AOS) with the chemical formula CnH2n-1
SO₃Na (n=14–16) was received from Stepan Company.
 Injection gas :
Carbon dioxide (CO₂) with a purity of 99.95% was used.
29 April 2020 12
Methodology :
• Fig. 1 shows a schematic of the experimental design of this study.
29 April 2020 13
Methodology :
Formation water selection :
They have two types of Formation water and they should select only
one for experimental work. Fig. 2 shows procedures of FW selection :
29 April 2020 14
Methodology :
LSW Selection :
Fig. 3. shows a schematic drawing of the experimental procedures
29 April 2020 15
Methodology :
 Chemical Screening :
• three tests including interfacial tension (IFT), Aqueous stability test
(AST), and foam stability test (FST) were conducted.
• The main objective of this step was to formulate a chemical solution
that will ultimately reduce interfacial tension (IFT) by forming a stable
foam when in contact with oil.
29 April 2020 16
Methodology :
Core flooding :
• The optimum formulations selected from previous steps were used for
conducting core flooding experiments, to find optimum oil recovery
factor under various conditions.
• Fig. 4 shows Schematic diagram of the Core flooding experiments.
29 April 2020 17
Methodology :
29 April 2020 18
Results and discussion :
 Formation water selection result :
• The desired formation water would be the one that could change the
wettability into oil-wet state as a basis.
• The experimental results revealed that FW1 turned the wettability into
more oil wet rather than FW2 that remained the wettability state.
• Therefore, the FW1 is the one used for all the experimental tests.
results presented in Fig 5.
29 April 2020 19
Results and discussion :
Formation water selection result :
29 April 2020 20
Results and discussion :
• The greatest changes of wettability were observed for the KCl at
500ppm ,NaCl, then MgCl₂, CaCl₂ , Mix composition, and finally FW.
• Fig. 6 shows the plot of contact angle changes versus time.
29 April 2020 21
Results and discussion :
29 April 2020 22
Results and discussion :
29 April 2020 23
Results and discussion :
• Surfactant Aqueous Solution (SAS) with formulation of Mix
composition of LSW + 1.5 wt.% AOS composition has a good trend
• But due to the cost of surfactant and availability we have reduced the
concentration of surfactant to the 1 wt.% AOS since the same trend
has been observed.
29 April 2020 24
Results and discussion :
Core flooding result :
See Fig 7 and 8 :
29 April 2020 25
Results and discussion :
Fig 7 – Cumulative oil of crude A
29 April 2020 26
Results and discussion :
Fig 8 – Cumulative oil of crude B
29 April 2020 27
Conclusion :
• Fw1 was selected.
• 1.0 wt.% AOS of SAS
• The highest oil recovery was achieved during LSW-19 or KCl
injection pattern (87.45% of OOIP).
29 April 2020 28
References :
1- Combined Low Salinity Water Injection and Foam Flooding in
Sandstone Reservoir Rock: A New Hybrid EOR
Abdolmohsen Shabib-AsL, University of Calgary; Mohammed Abdallah Ayoub and Khaled Abdalla Elraies, Universiti
Teknologi PETRONAS
29 April 2020 29
29 April 2020 30
29 April 2020 31

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(spe-194975-ms):(Combined Low Salinity Water Injection and Foam Flooding in Sandstone Reservoir Rock: A New Hybrid EOR )

  • 1. University of Khartoum Faculty of Engineering Department of Petroleum and Natural gas Engineering Show about : Combined Low Salinity Water Injection and Foam Flooding in Sandstone Reservoir Rock: A New Hybrid EOR 29 April 2020 1
  • 2. Authors : • Abdolmohsen Shabib-AsL, University of Calgary • Mohammed Abdallah Ayoub , University of Technology PETRONAS • Khaled Abdallah Elraies, University of Technology PETRONAS 29 April 2020 2
  • 3. Presentation Outlines: 1- Introduction 2- Material and Procedures 3- Methodology 4- Results and discussion 5 - Conclusion 29 April 2020 3
  • 4. Introduction : • To date, several methods have been implemented either individually or as combination to increase oil recovery. • The combined methods also called hybrid Enhanced Oil Recovery (EOR) pose great challenges in the oil and gas industry. • This presentation investigates the potential of a new hybrid EOR method termed Low Salinity Water Assisted Foam flooding (LSWAF). 29 April 2020 4
  • 5. Introduction : • Foam flooding process has been in use for improving the oil recovery. • Most experiments of foam flooding have been conducted in water- wet medium conditions without the presence of oil due to its interaction with foam. • However, interactions of crude oil with foam leads to destabilize the foam (Nell 2015). 29 April 2020 5
  • 6. Introduction : • One of the methods can be used to minimize this negative interaction is combination method with the other techniques such as Low Salinity Water (LSW). • LSW is responsible to change wettability of the rock from oil wet to water wet. • Foam with high stability is responsible to increase gas sweep efficiency. 29 April 2020 6
  • 7. Material and Procedures : The rock : • The reservoir rock was obtained from the KOCUREK Company (USA). With properties as shown in Table (1): • X-Ray diffractometer (XRD) and basic routine core analysis using Poroperm Machine were used to confirm the properties above and has given almost same data . 29 April 2020 7
  • 8. Material and Procedures : Crude oil : Two samples of crude oil designated as crude oil A and B were used. Tables 2 and 3 exhibit the properties of crude samples: Table 2 - Crude oil (A) properties 29 April 2020 8
  • 9. Material and Procedures : Table 3 - Crude oil (B) properties 29 April 2020 9
  • 10. Material and Procedures : The brine : • The brines for LSW were prepared by mixing controlled amounts of K⁺, Na⁺, Ca²⁺, Mg²⁺, and Cl⁻ with distilled water. • 30 brines were prepared with different salt concentrations. See Table 4 • Two types of formation water, namely FW1 and FW2 were produced for establishing initial and connate water saturations. 29 April 2020 10
  • 11. Material and Procedures : Table 4 -brines and two FW salt Concentrations : 29 April 2020 11
  • 12. Material and Procedures : The surfactant : Alpha Olefin Sulphonate (AOS) with the chemical formula CnH2n-1 SO₃Na (n=14–16) was received from Stepan Company.  Injection gas : Carbon dioxide (CO₂) with a purity of 99.95% was used. 29 April 2020 12
  • 13. Methodology : • Fig. 1 shows a schematic of the experimental design of this study. 29 April 2020 13
  • 14. Methodology : Formation water selection : They have two types of Formation water and they should select only one for experimental work. Fig. 2 shows procedures of FW selection : 29 April 2020 14
  • 15. Methodology : LSW Selection : Fig. 3. shows a schematic drawing of the experimental procedures 29 April 2020 15
  • 16. Methodology :  Chemical Screening : • three tests including interfacial tension (IFT), Aqueous stability test (AST), and foam stability test (FST) were conducted. • The main objective of this step was to formulate a chemical solution that will ultimately reduce interfacial tension (IFT) by forming a stable foam when in contact with oil. 29 April 2020 16
  • 17. Methodology : Core flooding : • The optimum formulations selected from previous steps were used for conducting core flooding experiments, to find optimum oil recovery factor under various conditions. • Fig. 4 shows Schematic diagram of the Core flooding experiments. 29 April 2020 17
  • 19. Results and discussion :  Formation water selection result : • The desired formation water would be the one that could change the wettability into oil-wet state as a basis. • The experimental results revealed that FW1 turned the wettability into more oil wet rather than FW2 that remained the wettability state. • Therefore, the FW1 is the one used for all the experimental tests. results presented in Fig 5. 29 April 2020 19
  • 20. Results and discussion : Formation water selection result : 29 April 2020 20
  • 21. Results and discussion : • The greatest changes of wettability were observed for the KCl at 500ppm ,NaCl, then MgCl₂, CaCl₂ , Mix composition, and finally FW. • Fig. 6 shows the plot of contact angle changes versus time. 29 April 2020 21
  • 22. Results and discussion : 29 April 2020 22
  • 23. Results and discussion : 29 April 2020 23
  • 24. Results and discussion : • Surfactant Aqueous Solution (SAS) with formulation of Mix composition of LSW + 1.5 wt.% AOS composition has a good trend • But due to the cost of surfactant and availability we have reduced the concentration of surfactant to the 1 wt.% AOS since the same trend has been observed. 29 April 2020 24
  • 25. Results and discussion : Core flooding result : See Fig 7 and 8 : 29 April 2020 25
  • 26. Results and discussion : Fig 7 – Cumulative oil of crude A 29 April 2020 26
  • 27. Results and discussion : Fig 8 – Cumulative oil of crude B 29 April 2020 27
  • 28. Conclusion : • Fw1 was selected. • 1.0 wt.% AOS of SAS • The highest oil recovery was achieved during LSW-19 or KCl injection pattern (87.45% of OOIP). 29 April 2020 28
  • 29. References : 1- Combined Low Salinity Water Injection and Foam Flooding in Sandstone Reservoir Rock: A New Hybrid EOR Abdolmohsen Shabib-AsL, University of Calgary; Mohammed Abdallah Ayoub and Khaled Abdalla Elraies, Universiti Teknologi PETRONAS 29 April 2020 29