Agro inputs and Soil pollution -
its impacts
Dr. Thomas George, Pradeep Kumar .G.T and Visal Kumar.S
All India Network Project on Pesticide Residues
College of Agriculture, Vellayani
Soil and its Importance
Soil is the mixture of minerals,
organic matter, gases, liquids, and
the countless organisms that together
support life on Earth.
• Importance
–Source of nutrients
–Store and purification of water
(hydrologic cycle)
–recycle nutrients and gases
–Help recycle people’s waste
–Earth Resource
• O-horizon: freshly-fallen & partially-
decomposed leaves, twigs, animal waste,
fungi & organic materials. Colour: brown
or black.
• A-horizon: humus/partially decomposed
organic matter & some inorganic mineral
particles. darker & looser than the deeper
layers.
• O & A-horizon: contain a large amount of
bacteria, fungi, earthworms, small insects,
forms complex food web in soil, recycles
soil nutrients, & contribute to soil fertility.
• B-horizon /(subsoil): less organic material
& fewer organisms than A- horizon.
• C-horizon: consists of broken-up bedrock,
does not contain any organic materials.
Chemical composition helps to determine
pH of soil & also influences soil’s rate of
water absorption & retention.
• R-horizon: The unweathered rock
(bedrock) layer that is beneath all the
other layers
Top soil formation
• Duration : > 500 years to form an
inch
• Ways :
•Physical weathering
•Chemical weathering
•Biological weathering
Importance of soil in Indian scenario
• Agriculture – 43% of geographical area
• GDP – Agriculture accounts for 13.9%
(2013-14)
• Employment – 54.6% of population
• Export – 8.56% contributed from
agriculture
Soil pollution
• Industrial Activity
• Agricultural Activity
• Waste Disposal
• Accidental Oil Spills
• Acid Rain
• Nuclear waste
Soil pollution is when humans introduce harmful
objects, chemicals or substances, directly or
indirectly into the soil in a way that causes harm
to other living things or destroys soil.
Soil Pollution
Sources
Agrochemical Urban Industrial Atmospheric Incidental
• Manures
• Fertilizers
• Pesticides
Fuel
spillage
Electric
power
stations
(Ash,
fallout)
Mining
and
Smelting
heavy
metals
Wind- blown
pollutants
Warfare
explosives,
Poisonous
gases
Gas works
Tars
Heavy
metals
Transport
Fuel
combustion
Acid deposits
Nuclear Waste
disposal
Metallurgical
industries
Chemical
and
electronic
industries
Acid
deposits
Industrial
accidents
Pollution due to agricultural inputs
• Manures
• Fertilizers
• Pesticides
• Other chemicals
Fuel spillage from Agri. Machines.
Farm wastes, manure, slurry, debris, soil
erosion containing mostly inorganic
chemicals are reported to cause soil
pollution
Manure
• Manure is organic matter, mostly derived from
animal feces except in the case of green
manure, which can be used as organic green
fertilizer in agriculture. Manures contribute to
the fertility of the soil by adding organic
matter and nutrients, such as nitrogen, that
are trapped by bacteria in the soil.
Manure and soil pollution
• Decomposition of manure –reduce O2
availability in soil.
• Poultry manure – High concentration of heavy
metals.
• Odor and pathogens
Fertilizers
• Material of natural or synthetic origin that is
applied to soils or to plant tissues (usually
leaves) to supply one or more plant
nutrient essential to the growth of plants.
(phosphorous, nitrogen, potassium, etc)
Fertilizers and soil pollution
• These inputs of nutrients to the agricultural
system are either stored or transferred.
Storage capacity is limited by the nutrient-
holding ability of the soil and the amount of
plant and animal matter (biomass). Losses to
the environment occur when the input is
greater than the rate of harvesting (use), so
the storage capacity of the system fills up and
‘overflows’ - Pollution
Fertilizers and soil pollution
• Deterioration of the balance in the
composition of soil
• Decrease/increase in soil pH
• Soil structure deterioration
• Accumulation of minerals
• Limit the activities of nitrifying bacteria
• Eutrophication of dams and waterways
• Accumulation in the soil, and uptake by plants,
of heavy metals, particularly cadmium
Fertilizer pollution - Impacts
• Dangerously elevated levels of nitrogen in
drinking water. (blue baby disease or
Methemoglobinemia of young babies and cancer
due to nitrate ingestion in food and water)
• Destroy critical soil microbes.
• Eutrophication (enrichment with nutrients) of
dams and waterways, leading to the
development of blue-green algal blooms, which
reduce water holding capacity Reducing depth of
water body and reduce dissolved oxygen,
critically affect aquatic life.
Fertilizer pollution - Impacts
• Greenhouse Gases (CO2, CH4, N2O from
agriculture and fertilisers)
• Do not replace soil organic matter.
• Greater fertiliser – Increased N2 in leaves –
attracts grazers –
• Increased population
of Weeds
Pesticides
• Pesticides are substances meant for attracting,
seducing, and then destroying, or mitigating any
pest.
Insecticide class Representative structure Common pesticides
Organo chlorines DDT, Endosulfan, BHC,
Aldrin, Endrin etc
Organo
phosphates
Malathion, Chlorpyriphos,
Quinalphos, Triazophos,
Profenophos, etc
Synthetic
Pyrethroids
Fenvalerate,
Cypermethrin,
Deltamethrin, Cyfluthrin,
etc
Carbamates Carbaryl, Carbosulfan,
Carbofuran, Carbendazim,
etc
Neonicotenoids Acetamiprid, Imidacloprid,
Thiacloprid,
Thiamethoxam,
Dinotefuran, etc
Scientificbeekeeping.com
December 2013
22
Usage of different pesticides in India
PESTICIDE CYCLE
25
Processes –Pesticide Cycle
Accumulation
of Pesticide
Movement of
Pesticide
Degradation
of Pesticide
26
Processes-Pesticide Cycle
Accumulation of Pesticides
Adsorption
Movement of the pesticides
Diffusion
Volatalization
Leaching
Erosion & runoff
Uptake by plants & microbes
27
Factors Influencing Adsorption
Pesticidal
Characters
Soil
Characters
Environmental
Characters
28
Degradation
Degradation
Biological
degradation
Chemical
degradation
Photo
degradation
29
Photodegradation
• Breakdown of pesticide by
sunlight
• May be reduced by soil
incorporation
Pesticides and soil pollution
•Drain off
• Leaching
• Spillage
•Over dosage
Pesticidal Characters
Persistent pesticides may be long lasting in the root
zone .
With strong adsorption the leaching potential of the
pesticide will be reduced.
Highly volatile pesticides especially fumigants are
readily present in the soil & so their leaching is high.
Higher the solubility greater will be the leaching.
(Buttler et al.,1998). 32
Soil Characters
Permeability
Texture &
Structure
Organic
Matter
Moisture
33
Persistence
Half life period
Non persistent < 30days
Moderately persistent 30-100days
Persistent pesticides->100 days
( Kerle, 2007)
34
Pesticide pollution - Impact
• Bio amplification – DDT act as cumulative
poison.
• Broad spectrum Characteristics – Kill large
verity of insects including natural predators.
• Decreases the general biodiversity in the soil.
• Resistance.
• Carcinogenic to mammals.
Xenoestrogens or Endocrine disruptors
• Pesticides especially OC pesticides may act as
false messengers and
• By mimicking or antagonising natural hormones
in the body cause human health effects such as
immune suppression, hormone disruption,
diminished intelligence, reproductive
abnormalities,
• Affect oncogenes, specifically in relation to breast
cancer
37
Epizootic Ulcerative Syndrome
In 1991 a devastating fish disease
wiped out a large number of fish in
Kuttanad
Pesticide pollution was found to be the
predisposing factor for the disease
Free Residues Vs Bound Residues
38
Free Residues
39
Extracion is possible.
Bioavailable.
Bound Residues
• Can’t be extracted,
• Not bioavailble
40
Critical Level of Pesticides in Soil
Type of Pesticide Limit of Quantity(ppm)
Organochlorine 0.010
Organophosphate 0.025
Carbamates, Synthetic
pyrethroid
0.050
41
(Pesticide research journal, June 2014)
Heavy metal addition
• Metals like cadmium, cobalt, copper, and zinc
can be found in relatively high level as
impurities in pesticide preparations and in
fertilizers.
Sources of heavy metals in the environment
Most persistent pollutant present
in water
Difficult to degrade
Bioaccumulation
Pollution due to heavy metals
44
Human ?
HUMAN HEALTH HAZARDS
Neurobehavioural disorders - depression, insomnia,
Birth defects and Abortions
Foetal Brain damage
Cancer
Kidney damage
Reduced intelligence, loss of short-term memory
Cardiovascular problems
Asthmatic and related allergic problems
Skeletal diseases
Life style diseases : diabetes, obesity, hair loss
45
Itai -itai
• first documented occurrence of
mass cadmium poisoning
 osteomalacia (softening of the bones) &
osteoporosis (loss of bone mass and
weakness)
 Poisons liver and kidneys
 carcinogen
Heavy metal content in sediments of estuaries of Kerala
Metals Akkulam Beypore Ashtamudi Vembanad
Cr 39-118 - 80-155 85-120
Pb 88-243 43-172 29-98 30-165
Zn 71-109 79-187 57-208 35-780
Cu 20-39 3-9 20-42 27-49
Cd - - 4-27 5-8.5
Hg 0.09-0.27 0.05-2.0 0.22-0.85 0.12-11.5
Average heavy metal content in Meenachil river, Kottayam
indicates concentration above perrmissible limit
Indu et al., 2011
7
Heavy metal
(mg/l )
Cu Fe Mn Pb Zn Cd
Pre-monsoon 0.18 0.70 0.42 0.10 ND 0.11
Post-monsoon 0.06 1.80 0.15 0.76 0.16 0.06
Pollution and climate change – Global
scenario
• CO2 level – increases by 1.9ppm/year
• CH4 level – 1774ppb
• N2O level – 319ppb (from 270ppb)
• Temperature - 0.760C (last 100years)
• Sea level rise : 0.09 – 0.88m
• Alarm : Surface temperature : 0.6 – 2.5 0C by 2050
Pollution and climate change – Kerala
scenario
• CO2 emission – Burning of fuels, deforestation,
land degradation.
– 93 % from burning of fossil fuel and fire wood
– (80% from fossil fuel)
Case study
• Bhopal tragedy
Carbaryl production, MIC, 22,000 people died
• Ganga pollution (National river of India)
• 1300million Ltrs of sewage and 250 million Ltrs of chemical
waste (Industry) per day
• Release of dead bodies of animals and human beings
• Yamuna pollution
52
Thank You !!!

01 soil pollution tg

  • 1.
    Agro inputs andSoil pollution - its impacts Dr. Thomas George, Pradeep Kumar .G.T and Visal Kumar.S All India Network Project on Pesticide Residues College of Agriculture, Vellayani
  • 2.
    Soil and itsImportance Soil is the mixture of minerals, organic matter, gases, liquids, and the countless organisms that together support life on Earth.
  • 3.
    • Importance –Source ofnutrients –Store and purification of water (hydrologic cycle) –recycle nutrients and gases –Help recycle people’s waste –Earth Resource
  • 4.
    • O-horizon: freshly-fallen& partially- decomposed leaves, twigs, animal waste, fungi & organic materials. Colour: brown or black. • A-horizon: humus/partially decomposed organic matter & some inorganic mineral particles. darker & looser than the deeper layers. • O & A-horizon: contain a large amount of bacteria, fungi, earthworms, small insects, forms complex food web in soil, recycles soil nutrients, & contribute to soil fertility. • B-horizon /(subsoil): less organic material & fewer organisms than A- horizon. • C-horizon: consists of broken-up bedrock, does not contain any organic materials. Chemical composition helps to determine pH of soil & also influences soil’s rate of water absorption & retention. • R-horizon: The unweathered rock (bedrock) layer that is beneath all the other layers
  • 5.
    Top soil formation •Duration : > 500 years to form an inch • Ways : •Physical weathering •Chemical weathering •Biological weathering
  • 6.
    Importance of soilin Indian scenario • Agriculture – 43% of geographical area • GDP – Agriculture accounts for 13.9% (2013-14) • Employment – 54.6% of population • Export – 8.56% contributed from agriculture
  • 7.
    Soil pollution • IndustrialActivity • Agricultural Activity • Waste Disposal • Accidental Oil Spills • Acid Rain • Nuclear waste Soil pollution is when humans introduce harmful objects, chemicals or substances, directly or indirectly into the soil in a way that causes harm to other living things or destroys soil.
  • 8.
    Soil Pollution Sources Agrochemical UrbanIndustrial Atmospheric Incidental • Manures • Fertilizers • Pesticides Fuel spillage Electric power stations (Ash, fallout) Mining and Smelting heavy metals Wind- blown pollutants Warfare explosives, Poisonous gases Gas works Tars Heavy metals Transport Fuel combustion Acid deposits Nuclear Waste disposal Metallurgical industries Chemical and electronic industries Acid deposits Industrial accidents
  • 9.
    Pollution due toagricultural inputs • Manures • Fertilizers • Pesticides • Other chemicals Fuel spillage from Agri. Machines. Farm wastes, manure, slurry, debris, soil erosion containing mostly inorganic chemicals are reported to cause soil pollution
  • 10.
    Manure • Manure isorganic matter, mostly derived from animal feces except in the case of green manure, which can be used as organic green fertilizer in agriculture. Manures contribute to the fertility of the soil by adding organic matter and nutrients, such as nitrogen, that are trapped by bacteria in the soil.
  • 11.
    Manure and soilpollution • Decomposition of manure –reduce O2 availability in soil. • Poultry manure – High concentration of heavy metals. • Odor and pathogens
  • 12.
    Fertilizers • Material ofnatural or synthetic origin that is applied to soils or to plant tissues (usually leaves) to supply one or more plant nutrient essential to the growth of plants. (phosphorous, nitrogen, potassium, etc)
  • 13.
    Fertilizers and soilpollution • These inputs of nutrients to the agricultural system are either stored or transferred. Storage capacity is limited by the nutrient- holding ability of the soil and the amount of plant and animal matter (biomass). Losses to the environment occur when the input is greater than the rate of harvesting (use), so the storage capacity of the system fills up and ‘overflows’ - Pollution
  • 14.
    Fertilizers and soilpollution • Deterioration of the balance in the composition of soil • Decrease/increase in soil pH • Soil structure deterioration • Accumulation of minerals • Limit the activities of nitrifying bacteria • Eutrophication of dams and waterways • Accumulation in the soil, and uptake by plants, of heavy metals, particularly cadmium
  • 15.
    Fertilizer pollution -Impacts • Dangerously elevated levels of nitrogen in drinking water. (blue baby disease or Methemoglobinemia of young babies and cancer due to nitrate ingestion in food and water) • Destroy critical soil microbes. • Eutrophication (enrichment with nutrients) of dams and waterways, leading to the development of blue-green algal blooms, which reduce water holding capacity Reducing depth of water body and reduce dissolved oxygen, critically affect aquatic life.
  • 16.
    Fertilizer pollution -Impacts • Greenhouse Gases (CO2, CH4, N2O from agriculture and fertilisers) • Do not replace soil organic matter. • Greater fertiliser – Increased N2 in leaves – attracts grazers – • Increased population of Weeds
  • 17.
    Pesticides • Pesticides aresubstances meant for attracting, seducing, and then destroying, or mitigating any pest.
  • 20.
    Insecticide class Representativestructure Common pesticides Organo chlorines DDT, Endosulfan, BHC, Aldrin, Endrin etc Organo phosphates Malathion, Chlorpyriphos, Quinalphos, Triazophos, Profenophos, etc Synthetic Pyrethroids Fenvalerate, Cypermethrin, Deltamethrin, Cyfluthrin, etc Carbamates Carbaryl, Carbosulfan, Carbofuran, Carbendazim, etc Neonicotenoids Acetamiprid, Imidacloprid, Thiacloprid, Thiamethoxam, Dinotefuran, etc
  • 22.
  • 24.
    Usage of differentpesticides in India
  • 25.
  • 26.
    Processes –Pesticide Cycle Accumulation ofPesticide Movement of Pesticide Degradation of Pesticide 26
  • 27.
    Processes-Pesticide Cycle Accumulation ofPesticides Adsorption Movement of the pesticides Diffusion Volatalization Leaching Erosion & runoff Uptake by plants & microbes 27
  • 28.
  • 29.
  • 30.
    Photodegradation • Breakdown ofpesticide by sunlight • May be reduced by soil incorporation
  • 31.
    Pesticides and soilpollution •Drain off • Leaching • Spillage •Over dosage
  • 32.
    Pesticidal Characters Persistent pesticidesmay be long lasting in the root zone . With strong adsorption the leaching potential of the pesticide will be reduced. Highly volatile pesticides especially fumigants are readily present in the soil & so their leaching is high. Higher the solubility greater will be the leaching. (Buttler et al.,1998). 32
  • 33.
  • 34.
    Persistence Half life period Nonpersistent < 30days Moderately persistent 30-100days Persistent pesticides->100 days ( Kerle, 2007) 34
  • 35.
    Pesticide pollution -Impact • Bio amplification – DDT act as cumulative poison. • Broad spectrum Characteristics – Kill large verity of insects including natural predators. • Decreases the general biodiversity in the soil. • Resistance. • Carcinogenic to mammals.
  • 36.
    Xenoestrogens or Endocrinedisruptors • Pesticides especially OC pesticides may act as false messengers and • By mimicking or antagonising natural hormones in the body cause human health effects such as immune suppression, hormone disruption, diminished intelligence, reproductive abnormalities, • Affect oncogenes, specifically in relation to breast cancer
  • 37.
    37 Epizootic Ulcerative Syndrome In1991 a devastating fish disease wiped out a large number of fish in Kuttanad Pesticide pollution was found to be the predisposing factor for the disease
  • 38.
    Free Residues VsBound Residues 38
  • 39.
    Free Residues 39 Extracion ispossible. Bioavailable.
  • 40.
    Bound Residues • Can’tbe extracted, • Not bioavailble 40
  • 41.
    Critical Level ofPesticides in Soil Type of Pesticide Limit of Quantity(ppm) Organochlorine 0.010 Organophosphate 0.025 Carbamates, Synthetic pyrethroid 0.050 41 (Pesticide research journal, June 2014)
  • 42.
    Heavy metal addition •Metals like cadmium, cobalt, copper, and zinc can be found in relatively high level as impurities in pesticide preparations and in fertilizers.
  • 43.
    Sources of heavymetals in the environment
  • 44.
    Most persistent pollutantpresent in water Difficult to degrade Bioaccumulation Pollution due to heavy metals 44 Human ?
  • 45.
    HUMAN HEALTH HAZARDS Neurobehaviouraldisorders - depression, insomnia, Birth defects and Abortions Foetal Brain damage Cancer Kidney damage Reduced intelligence, loss of short-term memory Cardiovascular problems Asthmatic and related allergic problems Skeletal diseases Life style diseases : diabetes, obesity, hair loss 45
  • 46.
    Itai -itai • firstdocumented occurrence of mass cadmium poisoning  osteomalacia (softening of the bones) & osteoporosis (loss of bone mass and weakness)  Poisons liver and kidneys  carcinogen
  • 47.
    Heavy metal contentin sediments of estuaries of Kerala Metals Akkulam Beypore Ashtamudi Vembanad Cr 39-118 - 80-155 85-120 Pb 88-243 43-172 29-98 30-165 Zn 71-109 79-187 57-208 35-780 Cu 20-39 3-9 20-42 27-49 Cd - - 4-27 5-8.5 Hg 0.09-0.27 0.05-2.0 0.22-0.85 0.12-11.5
  • 48.
    Average heavy metalcontent in Meenachil river, Kottayam indicates concentration above perrmissible limit Indu et al., 2011 7 Heavy metal (mg/l ) Cu Fe Mn Pb Zn Cd Pre-monsoon 0.18 0.70 0.42 0.10 ND 0.11 Post-monsoon 0.06 1.80 0.15 0.76 0.16 0.06
  • 49.
    Pollution and climatechange – Global scenario • CO2 level – increases by 1.9ppm/year • CH4 level – 1774ppb • N2O level – 319ppb (from 270ppb) • Temperature - 0.760C (last 100years) • Sea level rise : 0.09 – 0.88m • Alarm : Surface temperature : 0.6 – 2.5 0C by 2050
  • 50.
    Pollution and climatechange – Kerala scenario • CO2 emission – Burning of fuels, deforestation, land degradation. – 93 % from burning of fossil fuel and fire wood – (80% from fossil fuel)
  • 51.
    Case study • Bhopaltragedy Carbaryl production, MIC, 22,000 people died • Ganga pollution (National river of India) • 1300million Ltrs of sewage and 250 million Ltrs of chemical waste (Industry) per day • Release of dead bodies of animals and human beings • Yamuna pollution
  • 52.
  • 53.