MSDS

1. MARPOZOL W-505 (1/5)
SAFETY DATA SHEET
(Complying with GHS)
Ref. No.: First issue : Apr. 9, 2013
Revised :
1. IDENTIFICATION
Product name : MARPOZOL W-505
GHS product identifier : None.
Other means of identification : None.
Recommended use of the chemical and restrictions on use:
A sizing agent for weaving.
Supplier : PT.MATSUMOTOYUSHI INDONESIA
Jl.Jababeka XI Blok G-8 Kawasan Industri
Jababeka, Cikarang Jawa Barat - Indonesia
Phone: +62-21-8934091 Fax: +62-21-8934094
Emergency contact : PT.MATSUMOTOYUSHI INDONESIA
Jl.Jababeka XI Blok G-8 Kawasan Industri
Jababeka, Cikarang Jawa Barat - Indonesia
Phone: +62-21-8934091 Fax: +62-21-8934094
2. HAZARD IDENTIFICATION
Classification of the substance or mixture: Mixture
Hazard category:
Acute toxicity (oral) : Not classified.
Acute toxicity (dermal) : Not classified.
Acute toxicity (inhalation of gas) : Off the subject of classification.
Acute toxicity (inhalation of vapor): Classification not possible.
Acute toxicity (inhalation of dust or mist): Classification not possible.
Skin corrosion/irritation : Classification not possible.
Serious eye damage/eye irritation: Category 2A-2B.
Respiratory sensitization : Classification not possible.
Skin sensitization : Classification not possible.
Germ cell mutagenicity : Category 1.
Carcinogenicity : Classification not possible.
Reproductive toxicity : Category 1.
Specific Target Organ toxicity (single exposure): Category 1 (central
nervous system, kidney), Category 3 (respiratory tract irritation)
Specific Target Organ toxicity (repeated exposure): Category 2 (blood
vessel, liver, spleen)
Aspiration hazard : Classification not possible.
Environmental toxicity:
Aquatic toxicity (acute) : Classification not possible.
Aquatic toxicity (chronic) : Classification not possible.
Hazardous to the ozone layer : Classification not possible.
GHS label elements, including precautionary statements:

2. MARPOZOL W-505 (2/5)
Precautionary statement: Danger
Hazardous effect: Causes serious eye irritation; May cause genetic defects;
May damage fertility or the unborn child; Causes damage to organs (central
nervous system, kidney); May cause respiratory irritation; May cause damage to
organs (blood vessel, liver, spleen), through prolonged or repeated exposure.
Safety precautions:
Preventive measures: Obtain special instructions before use. Read and
understand all of the safety precautions before handling the product.
Wash hands well after handling the product.
Response:
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel
unwell.
IF ON SKIN: Wash with plenty of soap and water.
IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
Storage: Store in a closed container.
Disposal: Dispose of contents/container to waste in accordance with
local/regional/national/international regulations.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance/Mixture : Mixture.
Chemical name : Mixture of alkyl acrylate copolymer,
isopropyl alcohol, ethanol, wax emulsion and
water.
Components and percentage : 19.5～20.5%.
Synonyms : None.
CAS registry number : Trade secret.
4. FIRST-AID MEASURES
Eye contact: Gently rinse the affected eyes, including under the eyelids,
with clean water for at least 15 minutes, and seek medical attention.
Skin contact: Wash the affected area under tepid running water using a
mild soap.
Inhalation: Remove the victim from the contamination immediately to fresh
air.
Ingestion: Rinse mouth with water or saline. Arrange for transport to
the nearest medical facility for examination and treatment by a physician
as soon as possible.
Major symptoms: No data available.
Personal protective equipment for first-aid responders: Wear safety gloves and
safety goggles.
Notice to physicians: No specific antidotes are available. Treat
symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media: Foam, powder, CO2, sand or water fog.
Inapplicable extinguishing media: No information available.

3. MARPOZOL W-505 (3/5)
Specific hazard arising from the chemical: May produced toxic fumes of carbon
monoxide and other toxic gases if burning.
Fire-fighting procedure: Shut off source of fuel, if possible and without risk.
Extinguish with a proper extinguishing media. Keep fire-fighting personnel
upwind of fire. Evacuate the area. Cool down the surroundings of the fire with
water spray. Do not spill the product and extinguishing water into surface
water and sewage.
Special protective equipment and precautions for fire fighters: Wear
protective equipment including self-contained breathing apparatus not to
inhale the toxic fumes.
6. ACCIDENTAL RELEASE MEASURES
Personal protection: Wear safety gloves and goggles. Evacuate the area where
lot of the product has spilled. Ventilate the area if necessary.
Care for environment: Do not discharge the spilled product into surface water
and sewage.
Methods and materials for containment and cleaning up: Absorb small spillage
with sand or cloth. Then wipe the place with waste cloth and flush with a lot
of water. For treating a lot of spillage, at first evacuate the place. Then
dam up the spillage with sand, transfer the spillage to a safe place, and
contain it in containers.
Prevention of secondary disaster: Remove source of ignition and prepare
extinguishing media. Do not leave spilled product because it causes slips. Do
not walk on spilled product. Use spark-free tools for removing the spillage.
7. HANDLING & STORAGE
Handling: Keep away from fire. Wear protective equipment to avoid eye and skin
contact. Stopper the containers after handling.
Storage: Store in cool place with proper ventilation. Keep away from
fire, and follow the domestic regulations.
8. EXPOSURE CONTROL/PERSONAL PROTECTION
Engineering measures: Use with local exhaust ventilation. Make available
emergency shower and eye wash in the work area.
Control parameters:
Japanese Association of Industrial Hygiene (2009):
400 ppm or less, 980 mg/m3
or less (Isopropyl alcohol)
ACGIH (2009): 200ppm (TWA), 400ppm(STEL) (2-Propanol)
1000ppm(TWA)(Ethyl alcohol)
Personal protective equipment: Wear safety goggles, impervious protective
gloves, and work clothing with long sleeves.
Hygiene practice: Wash hands and face, and gargle well after handling. Do not
inhale mist, steam, and vapor from the product. Do not eat, drink, nor smoke
during the handling of the product.
9. PHYSICAL & CHEMICAL PROPERTIES
Appearance : Light yellowish liquid.
Odor : Characteristic odor.
pH : 8.8 (1% aq. Soln.)
Boiling point : 100 deg. C. (water in the product)
Melting point : Less than or equal to 0 deg. C.
Decomposition temperature : No data available.

4. MARPOZOL W-505 (4/5)
Flash point : 52.0 deg. C. (Seta-Flash-Closed-
Cup/negative in the sustained
combustibility test).
Ignition temperature : No data available.
Explosion limit : Ethanol 3.3-19 vol%.
Isopropyl alcohol 2.0-12.7 vol. %.
Vapor pressure : No data available.
Vapor density : No data available.
Specific gravity : 1.029 (20/4 deg. C.).
Solubility : Solubility in water.
Octanol/water partition coefficient : No data available.
10. STABILITY & REACTIVITY
Stability & Reactivity: This material is stable. Hazardous decomposition
and polymerization will not occur.
Conditions to avoid : No data available
Incompatible materials : No data available
Hazardous decomposition products : No data available
11. TOXICOLOGICAL INFORMATION
Acute toxicity (oral) : No data available.
Acute toxicity (dermal) : No data available.
Acute toxicity (inhalation of gas) : No data available.
Acute toxicity (inhalation of vapor) : No data available.
Acute toxicity (inhalation of dust or mist): No data available.
Skin corrosion/irritation : No data available.
Serious eye damage/eye irritation: Category 2 (as Isopropyl alcohol,
rabbit, [EHC 103(1990),SIDS(1997),PATTY(4th,1994)]).
Respiratory sensitization: No data available.
Skin sensitization: No data available for GHS classification.
Germ cell mutagenicity: Category 1 (as ethanol, Oral administration using
mouse and rat, [SIDS(2009),IARC(1988)]).
Carcinogenicity : No data available for GHS classification.
Reproductive toxicity : Category 1: (as ethanol, pregnant woman’s habitual
drinking for embryo, [IAEC vol.44(1987),SIDS(2009)]).
Specific Target Organ toxicity (single exposure):
Category 1 :(central nervous system, kidney, as Isopropyl alcohol, human,
[ACGIH(2003), human,[ACGIH(2003),CERI(1999)])
Category 3 :(respiratory tract irritation, as Isopropyl alcohol, human,
[ACGIH(2003)])
Specific Target Organ toxicity (repeated exposure) : Category 2 (blood
vessel, liver, spleen, as Isopropyl alcohol, rat,[EHC(1990)])
Aspiration hazard : No data available for GHS classification.
12.ECOLOGICAL INFORMATION
Degradability : No data available.
Bioaccumulative potential : No data available.
Aquatic toxicity (acute) : No data available.
Aquatic toxicity (chronic) : No data available.
Hazardous to the ozone layer : none
Other information/Appraisal: BOD
5
39 ppm

5. MARPOZOL W-505 (5/5)
COD
M
21 ppm
n-Hex. 7 ppm
(solution containing 0.1 % of the product)
13. DISPOSAL CONSIDERATION
Product: Follow the note of HANDLING AND STORAGE and general handling procedure.
Containers: Burn up in a proper incinerator, or entrust the disposal to a
certified contractor.
14. TRANSPORT INFORMATION
Domestic transportation: Follow the domestic regulation for transporting
surfactants.
International transportation: Follow the rules of IATA for air transportation
and the rules of IMDG for marine transportation.
UN Number : Not applicable.
UN Proper Shipping Name : Not applicable.
Transport hazard classes : Not applicable.
Packing Group : Not applicable.
Follow the note of HANDLING AND STORAGE, and the general handling procedure for
such products. Handle carefully to avoid the leakage of the product and the
damage, falling or tumbling of the containers. Fix the containers with packing
during transportation.
15. REGULATORY INFORMATION
The product is defined or regulated under the following Japanese laws. Please
refer to domestic regulations that may be relevant.
Chemical Substance Control Law: None of regulated substances is contained.
Fire Service Law: Not applicable.
Industrial Safety and Health Law: Isopropyl alcohol (3-5 wt %) is defined as
the substances to be displayed under the article 57. Propyl alcohol (3-5 wt %)
is defined as the substances to be notified under the article 57.2 with the
number 494.Ethanol(1 wt % below) is defined as the substances to be notified
under the article 57-2 with the number 61.
Poisonous and Deleterious Substances Control Law: Not applicable.
Ship Safety Law: Not applicable.
Explosives Control Law: Not applicable.
High Pressure Gas Safety Law: Not applicable.
Law concerning Reporting, etc., of Release of Specific Chemical Substances to
the Environment and Promotion of the Improvement of their Management: Not
applicable.
Marine Pollution and Disaster Prevention Law: Not applicable.
TSCA: Registered.
EINECS: Registered.
16.OTHER INFORMATION
To the best of our knowledge, the information contained herein is
accurate. All materials may present unknown hazards and should be used
in caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards which exist.