Click http://www.guidechem.com/cas-403/403-43-0.html for suppliers of this product4-Fluorobenzoyl chloride (cas 403-43-0) MSDS1.1.1IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKINGProduct identifiersProduct nameProduct NumberBrandCAS-No.::::4-Fluorobenzoyl chloride119946Anonymous403-43-01.2 Relevant identified uses of the substance or mixture and uses advised againstIdentified uses : Laboratory chemicals, Manufacture of substances188.8.131.52HAZARDS IDENTIFICATIONClassification of the substance or mixtureClassification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]Skin corrosion (Category 1B)Classification according to EU Directives 67/548/EEC or 1999/45/ECCauses burns.Label elementsLabelling according Regulation (EC) No 1272/2008 [CLP]PictogramSignal wordHazard statement(s)H314Precautionary statement(s)P280P305 + P351 + P338P310Supplemental HazardStatementsDangerCauses severe skin burns and eye damage.Wear protective gloves/ protective clothing/ eye protection/ faceprotection.IF IN EYES: Rinse cautiously with water for several minutes. Removecontact lenses, if present and easy to do. Continue rinsing.Immediately call a POISON CENTER or doctor/ physician.noneAccording to European Directive 67/548/EEC as amended.Hazard symbol(s)R-phrase(s)R34S-phrase(s)S26S36/37/39S45Causes burns.In case of contact with eyes, rinse immediately with plenty of water andseek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately(show the label where possible).184.108.40.206Other hazardsLachrymator.COMPOSITION/INFORMATION ON INGREDIENTSSubstancesFormulaMolecular WeightComponent4-Fluorobenzoyl chloride::C7H4ClFO158,56 g/molConcentrationCAS-No. 403-43-0 -
EC-No. 206-961-220.127.116.11.35.5.1FIRST AID MEASURESDescription of first aid measuresGeneral adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaledIf breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.In case of skin contactTake off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Consult aphysician.In case of eye contactRinse thoroughly with plenty of water for at least 15 minutes and consult a physician.If swallowedDo NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water.Consult a physician.Most important symptoms and effects, both acute and delayedMaterial is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, andskin., Cough, Shortness of breath, Headache, NauseaIndication of any immediate medical attention and special treatment neededno data availableFIRE-FIGHTING MEASURESExtinguishing mediaSuitable extinguishing mediaFor small (incipient) fires, use media such as "alcohol" foam, dry chemical, or carbon dioxide. For large fires,apply water from as far as possible. Use very large quantities (flooding) of water applied as a mist or spray;solid streams of water may be ineffective. Cool all affected containers with flooding quantities of water.18.104.22.168.22.214.171.124.126.96.36.199.38.8.1Special hazards arising from the substance or mixtureCarbon oxides, Hydrogen chloride gas, Hydrogen fluorideAdvice for firefightersWear self contained breathing apparatus for fire fighting if necessary.Further informationUse water spray to cool unopened containers.ACCIDENTAL RELEASE MEASURESPersonal precautions, protective equipment and emergency proceduresUse personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation.Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to formexplosive concentrations. Vapours can accumulate in low areas.Environmental precautionsPrevent further leakage or spillage if safe to do so. Do not let product enter drains.Methods and materials for containment and cleaning upContain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing andplace in container for disposal according to local regulations (see section 13). Keep in suitable, closedcontainers for disposal.Reference to other sectionsFor disposal see section 13.HANDLING AND STORAGEPrecautions for safe handlingAvoid inhalation of vapour or mist.Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostaticcharge.Conditions for safe storage, including any incompatibilitiesStore in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which areopened must be carefully resealed and kept upright to prevent leakage.Hydrolyses readily.Specific end usesno data availableEXPOSURE CONTROLS/PERSONAL PROTECTIONControl parameters
8.18.2Control parametersComponents with workplace control parametersExposure controlsAppropriate engineering controlsHandle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and atthe end of workday.Personal protective equipmentEye/face protectionTightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection testedand approved under appropriate government standards such as NIOSH (US) or EN 166(EU).Skin protectionHandle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching gloves outer surface) to avoid skin contact with this product. Dispose ofcontaminated gloves after use in accordance with applicable laws and good laboratory practices.Wash and dry hands.The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and thestandard EN 374 derived from it.Body ProtectionComplete suit protecting against chemicals, The type of protective equipment must be selectedaccording to the concentration and amount of the dangerous substance at the specific workplace.Respiratory protectionWhere risk assessment shows air-purifying respirators are appropriate use a full-face respirator withmulti-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup toengineering controls. If the respirator is the sole means of protection, use a full-face supplied airrespirator. Use respirators and components tested and approved under appropriate governmentstandards such as NIOSH (US) or CEN (EU).9.9.1PHYSICAL AND CHEMICAL PROPERTIESInformation on basic physical and chemical propertiesa)b)c)d)e)f)g)h)AppearanceOdourOdour ThresholdpHMelting point/freezingpointInitial boiling point andboiling rangeFlash pointEvaporation rateForm: liquidno data availableno data availableno data availableMelting point/range: 10 - 12 °C - lit.82 °C at 27 hPa - lit.82 °C - closed cupno data availablei) Flammability (solid, gas) no data availablej)k)l)Upper/lowerflammability orexplosive limitsVapour pressureVapour densityno data availableno data availableno data availablem) Relative density 1,342 g/cm3 at 25 °Cn)o)p)q)r)s)t)Water solubilityPartition coefficient: n-octanol/waterAutoignitiontemperatureDecompositiontemperatureViscosityExplosive propertiesOxidizing propertiesno data availableno data availableno data availableno data availableno data availableno data availableno data available9.2 Other safety informationno data available
10.10.1STABILITYAND REACTIVITYReactivityno data available10.210.310.410.510.611.11.1Chemical stabilityno data availablePossibility of hazardous reactionsno data availableConditions to avoidDo not allow water to enter container. Avoid moisture.Heat, flames and sparks.Incompatible materialsWater, Alcohols, Oxidizing agents, Strong basesHazardous decomposition productsOther decomposition products - no data availableTOXICOLOGICAL INFORMATIONInformation on toxicological effectsAcute toxicityno data availableSkin corrosion/irritationno data availableSerious eye damage/eye irritationno data availableRespiratory or skin sensitizationno data availableGerm cell mutagenicityno data availableCarcinogenicityIARC: No component of this product present at levels greater than or equal to 0.1% is identified asprobable, possible or confirmed human carcinogen by IARC.Reproductive toxicityno data availableSpecific target organ toxicity - single exposureno data availableSpecific target organ toxicity - repeated exposureno data availableAspiration hazardno data availablePotential health effectsInhalationIngestionSkinEyesMay be harmful if inhaled. Material is extremely destructive to the tissue ofthe mucous membranes and upper respiratory tract.May be harmful if swallowed. Causes burns.May be harmful if absorbed through skin. Causes skin burns.Causes eye burns.Signs and Symptoms of ExposureMaterial is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, andskin., Cough, Shortness of breath, Headache, NauseaAdditional InformationRTECS: Not available188.8.131.52.3ECOLOGICAL INFORMATIONToxicityno data availablePersistence and degradabilityno data availableBioaccumulative potential
12.412.512.6184.108.40.206.1no data availableMobility in soilno data availableResults of PBT and vPvB assessmentno data availableOther adverse effectsno data availableDISPOSAL CONSIDERATIONSWaste treatment methodsProductThis combustible material may be burned in a chemical incinerator equipped with an afterburner andscrubber. Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensedprofessional waste disposal service to dispose of this material.Contaminated packagingDispose of as unused product.TRANSPORT INFORMATIONUN number14.2ADR/RID: 3265UN proper shipping nameIMDG: 3265 IATA: 3265ADR/RID:IMDG:IATA:CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (4-Fluorobenzoyl chloride)CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (4-Fluorobenzoyl chloride)Corrosive liquid, acidic, organic, n.o.s. (4-Fluorobenzoyl chloride)14.3 Transport hazard class(es)14.414.514.615.ADR/RID: 8Packaging groupADR/RID: IIEnvironmental hazardsADR/RID: noSpecial precautions for userno data availableREGULATORYINFORMATIONIMDG: 8IMDG: IIIMDG Marine pollutant: noIATA: 8IATA: IIIATA: noThis safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.15.115.2Safety, health and environmental regulations/legislation specific for the substance or mixtureno data availableChemical Safety Assessmentno data available16. OTHER INFORMATIONFurther informationThe above information is believed to be correct but does not purport to be all inclusive andshall be used only as a guide. The information this document is based on the resent stateof our knowledge and is applicable to the product with regard to appropriate safety precautions.It does not represent any guarantee of the properties of the product. guidechem shall not beheld liable for any damage resulting from handling or from contact with the above product.See reverse side of invoice or packing slip for additional terms and conditions of sale.