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EGEE 102 – Energy Conservation
And Environmental Protection
Non-Renewable Fuels
Environmental Impact
EGEE 102-Pisupati 2
US Energy Consumption by
Source (1999)
Nuclear
8%
Natural
Gas
23%
Petroleum
38%
Coal
23%
1
5
44
49
1
Wind
Hydroelectric
Biomass
Geothermal
Solar
Renewables , 8%
All Energy Sources 96.7 QUADS
Renewables 7.2 QUADS
EGEE 102-Pisupati 3
Non Renewable Fuels
• Coal
• Petroleum
• Natural Gas
• Nuclear Fission
EGEE 102-Pisupati 4
EGEE 102-Pisupati 5
World Coal Consumption
• World coal consumption is projected to
increase from 5.3 billion tons in 1997 to
7.6 billion tons in 2020.
• US annual coal consumption is
approximately 1 billion tons
EGEE 102-Pisupati 6
Coal Reserves (M metric
tons)
Africa, 67.7
Far East
and
Oceania,
322.2
C & S.
America,
23.7
North
America,
286.6
W. Europe,
99.6
E. Europe
& FSU,
288.3
Middle
East, 0.2
Source: http://www.eia.doe.gov/emeu/iea/table82.html
US – 275.5
World -1088.6
EGEE 102-Pisupati 7
Coal Analyses
• Proximate Analysis
• Ultimate Analysis
• Calorific Value
EGEE 102-Pisupati 8
Proximate Analysis
• Moisture
• Volatile Matter
• Ash
• Fixed Carbon (obtained by difference)
EGEE 102-Pisupati 9
Ultimate Analysis
(elemental composition)
Carbon 60 - 96%
Hydrogen 2 - 6%
Nitrogen 1-2%
Sulfur 0.5 - 5%
Oxygen 1 - 30%
EGEE 102-Pisupati 10
Calorific Value (Heating
Value)
• Heating or Calorific Value is the amount
of heat released when a unit mass of
fuel is burned (Btu/lb. or cal/g)
• Calorific value has implications for
pollution measurements such as SO2
whose emissions are calculated on a lb
per million Btu basis
EGEE 102-Pisupati 11
Coal Ranks
• There are 4 general ranks for coals:
• Lignite low rank
• Subbituminous
• Bituminous
• Anthracite High rank
EGEE 102-Pisupati 12
Reserves to Production Ratio (R/P Ratio)
World 1173 G Tons / 4.33 G Tons/y
= 271 Years
USA 277 G Tons/0.99 G Tons/y
= 280 Years
Lifetime (of a resource) = Reserves
Annual Use
Note: Reserves are likely to increase as well as decrease,
usage is also expected to change
Coal’s Future
EGEE 102-Pisupati 13
EGEE 102-Pisupati 14
EGEE 102-Pisupati 15
Petroleum
• Naturally occurring liquid containing a
complex mixture of hydrocarbons
(molecules made of C and H atoms)
• Also contains few compounds
containing N, S, and O atoms
EGEE 102-Pisupati 16
Petroleum Composition
Element Range (wt%)
Carbon 85-90%
Hydrogen 9-15%
Nitrogen 0-0.1%
Sulfur ppm- 4%
Oxygen ppm
EGEE 102-Pisupati 17
Crude Oil Reserves (B bbls)
Middle East,
675.6
Africa, 74.9
Far East and
Oceania, 44
W. Europe,
18.8
S. and
Central
America, 89.5
North
America, 55.1
E Europe &
FSU, 58.9
US – 21.8
World – 1,016
EGEE 102-Pisupati 18
Production and Consumption (mn
bbls/day)
BP Amoco Statistical Review of World Energy 2000
(http://www.bp.com)
• World
• Production – 73
• United States
• Production – 9.2
• Consumption – 18.9
EGEE 102-Pisupati 19
EGEE 102-Pisupati 20
One Barrel of Oil (42 US
gallons) produces …
• Gasoline (19.5 Gallons)
• Distillate Fuel Oil (9.2)
• Kerosene (4.1)
• Residual Fuel Oil (2.3)
• Lubricating Oil, Asphalt, Wax (2)
• Petrochemicals for plastics and polymers (2)
• Total Yield: 44.4 gallons
EGEE 102-Pisupati 21
How long can we
depend on Petroleum?
• World =
1016,000 million barrels/73 million bbls/day =
13,967 days= 38.1 years
US
= 21,800 million bbls/18.9 million bbls/day
= 1,153 days or 3.16 years
if we keep importing at the current rate
= 21,800 million bbls/9.3 million bbls/day
= 2,344 days or 6.4 years
EGEE 102-Pisupati 22
EGEE 102-Pisupati 23
Natural Gas
WHAT IS IT?
• Principally methane, CH4, with some
ethane (C2H6) and propane (C3H8), and
impurities such as CO2, H2S, and N2.
CALORIFIC VALUE
• Approximately 1,000 Btu/cu.ft (22,500
Btu/lb)
EGEE 102-Pisupati 24
Natural Gas Types
• WET- contains HCS other than Methane
and ethane
• SOUR- contains H 2S,which is highly
undesirable due to corrosion, and SO2
formation upon combustion.
EGEE 102-Pisupati 25
Reserves (Trillion Cu. Ft)
Far East and
Oceania, 375.4
Africa, 409.7
C. & S.
America, 227.9
North
America, 261.3
W. Europe,
159.5
E. Europe and
FSU, 1947.6
Middle East,
1836.2
US - 167 T Cu. ft
World - 5210 T cu. ft
EGEE 102-Pisupati 26
• US = 166 T. Cu. Ft / 21.7 T. Cu. Ft per year
(1999) = 7.6 years
• World = 5240 T cu. Ft/84.2 T. Cu.ft per year
=62 years
How long can we
depend on Natural Gas?
EGEE 102-Pisupati 27
Utilization-Combustion
Premium Fuel
• Highest calorific value of any fossil fuel
(1,000 Btu/cu. ft. or 24,000 Btu/lb)
• No ash in the fuel - no mess
• Easy transportation and no storage
space required
• Better combustion efficiency
• Less CO2 emissions compared to oil
and coal for the same heat release
EGEE 102-Pisupati 28
Composition Heating Value
Coal CH 0.8 13,000 Btu/lb
Oil CH2 20,000 Btu/lb
Natural Gas CH4 22,000 Btu/lb
All also contain oxygen, sulfur, nitrogen etc.
1 gal of Petroleum = 10 lb of Coal = 150 cu.ft
Gas
Comparison of Fossil
Fuels
EGEE 102-Pisupati 29
Cost of Energy/MMBtu
for oil
• Price of oil is usually given in $ / barrel
• If the price is $22/barrel
• One Barrel of oil has 5,800,000 Btu
MMBtu
Barrel
x
Barrel
MMBtu
per
Cost
8
.
5
1
1
22
$

EGEE 102-Pisupati 30
Cost of Energy per
MMBtu- Natural gas
• Usually price is given as $/1,000 Cu. Ft
• Say $7.44/1000Cu. Ft (PA)
• Energy Content 1,000 Btu/Cu. Ft
MMBtu
Btu
x
Btu
ft
Cu
one
x
Ft
Cu
MMBtu
per
Cost
6
10
000
,
1
.
.
1000
44
.
7
$

EGEE 102-Pisupati 31
Cost of Energy- $/Million
Btu
• Price is given in $/ton. Approximate
average price is $33.26/ton in PA
• Calorific value = 13,000 Btu/lb or 20.77
million BTUs/ton
EGEE 102-Pisupati 32
US Energy use and
Environmental
Consequences
Fossil Fuels
Combustion
Carbon
Hydrogen
Nitrogen
Sulfur
Oxygen
CO2
CO
SO2
NOx
Emissions
Particulate Matter
PM10
PM2.5
NH3
EGEE 102-Pisupati 33
US Air Emissions, Mtons
(1999)
Gas Emissions
Carbon Dioxide 1,520
Carbon Monoxide 97.4
Lead 4.1
NOx 25.4
SO2 18.8
Particulate Matter 23.7
EGEE 102-Pisupati 34
EGEE 102-Pisupati 35
Greenhouse Gas
Emissions
EGEE 102-Pisupati 36
Nitrogen Oxides (NOx)
• Nitrogen oxides, like hydrocarbons, are
precursors to the formation of ground level
ozone and thereby to photochemical smog
• Precursors to the formation of acid rain
• Long-term exposures to NO2 may lead to
increased susceptibility to respiratory
infection and may cause permanent
alterations in the lung.
EGEE 102-Pisupati 37
Carbon Monoxide
• Product of incomplete combustion
• Reduces the flow of oxygen in the
bloodstream
• Particularly dangerous to persons with
heart disease.
EGEE 102-Pisupati 38
Sulfur Dioxide
• High concentrations of SO2 can result in
temporary breathing impairment for asthmatic
children and adults
• in conjunction with high levels of PM,
include respiratory illness, alterations in
the lungs’ defenses, and aggravation of
existing cardiovascular disease.
• Together, SO2 and NOx are the major
precursors to acidic deposition (acid rain)
• major precursor to PM2.5, which is a
significant health concern
EGEE 102-Pisupati 39
Particulate Matter
• Health effects
• Visibility impairment
• Atmospheric deposition
• Aesthetic damage
EGEE 102-Pisupati 40
Additional Resources
• http://www.epa.gov/air/aqtrnd00/
• http://www.eia.doe.gov
• http://www.epa.gov/airmarkets/acidrain/
• http://www.epa.gov/globalwarming/
• http://www.epa.gov/oar/oaqps/gooduphi
gh/
• http://www.epa.gov/air/concerns/#smog

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3. Non Renewable Fuels.ppt

  • 1. EGEE 102 – Energy Conservation And Environmental Protection Non-Renewable Fuels Environmental Impact
  • 2. EGEE 102-Pisupati 2 US Energy Consumption by Source (1999) Nuclear 8% Natural Gas 23% Petroleum 38% Coal 23% 1 5 44 49 1 Wind Hydroelectric Biomass Geothermal Solar Renewables , 8% All Energy Sources 96.7 QUADS Renewables 7.2 QUADS
  • 3. EGEE 102-Pisupati 3 Non Renewable Fuels • Coal • Petroleum • Natural Gas • Nuclear Fission
  • 5. EGEE 102-Pisupati 5 World Coal Consumption • World coal consumption is projected to increase from 5.3 billion tons in 1997 to 7.6 billion tons in 2020. • US annual coal consumption is approximately 1 billion tons
  • 6. EGEE 102-Pisupati 6 Coal Reserves (M metric tons) Africa, 67.7 Far East and Oceania, 322.2 C & S. America, 23.7 North America, 286.6 W. Europe, 99.6 E. Europe & FSU, 288.3 Middle East, 0.2 Source: http://www.eia.doe.gov/emeu/iea/table82.html US – 275.5 World -1088.6
  • 7. EGEE 102-Pisupati 7 Coal Analyses • Proximate Analysis • Ultimate Analysis • Calorific Value
  • 8. EGEE 102-Pisupati 8 Proximate Analysis • Moisture • Volatile Matter • Ash • Fixed Carbon (obtained by difference)
  • 9. EGEE 102-Pisupati 9 Ultimate Analysis (elemental composition) Carbon 60 - 96% Hydrogen 2 - 6% Nitrogen 1-2% Sulfur 0.5 - 5% Oxygen 1 - 30%
  • 10. EGEE 102-Pisupati 10 Calorific Value (Heating Value) • Heating or Calorific Value is the amount of heat released when a unit mass of fuel is burned (Btu/lb. or cal/g) • Calorific value has implications for pollution measurements such as SO2 whose emissions are calculated on a lb per million Btu basis
  • 11. EGEE 102-Pisupati 11 Coal Ranks • There are 4 general ranks for coals: • Lignite low rank • Subbituminous • Bituminous • Anthracite High rank
  • 12. EGEE 102-Pisupati 12 Reserves to Production Ratio (R/P Ratio) World 1173 G Tons / 4.33 G Tons/y = 271 Years USA 277 G Tons/0.99 G Tons/y = 280 Years Lifetime (of a resource) = Reserves Annual Use Note: Reserves are likely to increase as well as decrease, usage is also expected to change Coal’s Future
  • 15. EGEE 102-Pisupati 15 Petroleum • Naturally occurring liquid containing a complex mixture of hydrocarbons (molecules made of C and H atoms) • Also contains few compounds containing N, S, and O atoms
  • 16. EGEE 102-Pisupati 16 Petroleum Composition Element Range (wt%) Carbon 85-90% Hydrogen 9-15% Nitrogen 0-0.1% Sulfur ppm- 4% Oxygen ppm
  • 17. EGEE 102-Pisupati 17 Crude Oil Reserves (B bbls) Middle East, 675.6 Africa, 74.9 Far East and Oceania, 44 W. Europe, 18.8 S. and Central America, 89.5 North America, 55.1 E Europe & FSU, 58.9 US – 21.8 World – 1,016
  • 18. EGEE 102-Pisupati 18 Production and Consumption (mn bbls/day) BP Amoco Statistical Review of World Energy 2000 (http://www.bp.com) • World • Production – 73 • United States • Production – 9.2 • Consumption – 18.9
  • 20. EGEE 102-Pisupati 20 One Barrel of Oil (42 US gallons) produces … • Gasoline (19.5 Gallons) • Distillate Fuel Oil (9.2) • Kerosene (4.1) • Residual Fuel Oil (2.3) • Lubricating Oil, Asphalt, Wax (2) • Petrochemicals for plastics and polymers (2) • Total Yield: 44.4 gallons
  • 21. EGEE 102-Pisupati 21 How long can we depend on Petroleum? • World = 1016,000 million barrels/73 million bbls/day = 13,967 days= 38.1 years US = 21,800 million bbls/18.9 million bbls/day = 1,153 days or 3.16 years if we keep importing at the current rate = 21,800 million bbls/9.3 million bbls/day = 2,344 days or 6.4 years
  • 23. EGEE 102-Pisupati 23 Natural Gas WHAT IS IT? • Principally methane, CH4, with some ethane (C2H6) and propane (C3H8), and impurities such as CO2, H2S, and N2. CALORIFIC VALUE • Approximately 1,000 Btu/cu.ft (22,500 Btu/lb)
  • 24. EGEE 102-Pisupati 24 Natural Gas Types • WET- contains HCS other than Methane and ethane • SOUR- contains H 2S,which is highly undesirable due to corrosion, and SO2 formation upon combustion.
  • 25. EGEE 102-Pisupati 25 Reserves (Trillion Cu. Ft) Far East and Oceania, 375.4 Africa, 409.7 C. & S. America, 227.9 North America, 261.3 W. Europe, 159.5 E. Europe and FSU, 1947.6 Middle East, 1836.2 US - 167 T Cu. ft World - 5210 T cu. ft
  • 26. EGEE 102-Pisupati 26 • US = 166 T. Cu. Ft / 21.7 T. Cu. Ft per year (1999) = 7.6 years • World = 5240 T cu. Ft/84.2 T. Cu.ft per year =62 years How long can we depend on Natural Gas?
  • 27. EGEE 102-Pisupati 27 Utilization-Combustion Premium Fuel • Highest calorific value of any fossil fuel (1,000 Btu/cu. ft. or 24,000 Btu/lb) • No ash in the fuel - no mess • Easy transportation and no storage space required • Better combustion efficiency • Less CO2 emissions compared to oil and coal for the same heat release
  • 28. EGEE 102-Pisupati 28 Composition Heating Value Coal CH 0.8 13,000 Btu/lb Oil CH2 20,000 Btu/lb Natural Gas CH4 22,000 Btu/lb All also contain oxygen, sulfur, nitrogen etc. 1 gal of Petroleum = 10 lb of Coal = 150 cu.ft Gas Comparison of Fossil Fuels
  • 29. EGEE 102-Pisupati 29 Cost of Energy/MMBtu for oil • Price of oil is usually given in $ / barrel • If the price is $22/barrel • One Barrel of oil has 5,800,000 Btu MMBtu Barrel x Barrel MMBtu per Cost 8 . 5 1 1 22 $ 
  • 30. EGEE 102-Pisupati 30 Cost of Energy per MMBtu- Natural gas • Usually price is given as $/1,000 Cu. Ft • Say $7.44/1000Cu. Ft (PA) • Energy Content 1,000 Btu/Cu. Ft MMBtu Btu x Btu ft Cu one x Ft Cu MMBtu per Cost 6 10 000 , 1 . . 1000 44 . 7 $ 
  • 31. EGEE 102-Pisupati 31 Cost of Energy- $/Million Btu • Price is given in $/ton. Approximate average price is $33.26/ton in PA • Calorific value = 13,000 Btu/lb or 20.77 million BTUs/ton
  • 32. EGEE 102-Pisupati 32 US Energy use and Environmental Consequences Fossil Fuels Combustion Carbon Hydrogen Nitrogen Sulfur Oxygen CO2 CO SO2 NOx Emissions Particulate Matter PM10 PM2.5 NH3
  • 33. EGEE 102-Pisupati 33 US Air Emissions, Mtons (1999) Gas Emissions Carbon Dioxide 1,520 Carbon Monoxide 97.4 Lead 4.1 NOx 25.4 SO2 18.8 Particulate Matter 23.7
  • 36. EGEE 102-Pisupati 36 Nitrogen Oxides (NOx) • Nitrogen oxides, like hydrocarbons, are precursors to the formation of ground level ozone and thereby to photochemical smog • Precursors to the formation of acid rain • Long-term exposures to NO2 may lead to increased susceptibility to respiratory infection and may cause permanent alterations in the lung.
  • 37. EGEE 102-Pisupati 37 Carbon Monoxide • Product of incomplete combustion • Reduces the flow of oxygen in the bloodstream • Particularly dangerous to persons with heart disease.
  • 38. EGEE 102-Pisupati 38 Sulfur Dioxide • High concentrations of SO2 can result in temporary breathing impairment for asthmatic children and adults • in conjunction with high levels of PM, include respiratory illness, alterations in the lungs’ defenses, and aggravation of existing cardiovascular disease. • Together, SO2 and NOx are the major precursors to acidic deposition (acid rain) • major precursor to PM2.5, which is a significant health concern
  • 39. EGEE 102-Pisupati 39 Particulate Matter • Health effects • Visibility impairment • Atmospheric deposition • Aesthetic damage
  • 40. EGEE 102-Pisupati 40 Additional Resources • http://www.epa.gov/air/aqtrnd00/ • http://www.eia.doe.gov • http://www.epa.gov/airmarkets/acidrain/ • http://www.epa.gov/globalwarming/ • http://www.epa.gov/oar/oaqps/gooduphi gh/ • http://www.epa.gov/air/concerns/#smog

Editor's Notes

  1. 3. Non Renewable Fuels and Environmental Impact
  2. 3. Non Renewable Fuels and Environmental Impact
  3. 3. Non Renewable Fuels and Environmental Impact