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DR.B.M.N College of Home
Science (Autonomous)
Matunga,Mumbai-19
Presented by
SYBSc - TSAD
Sonal Gaikwad
Pooja jakhar
Kalyani Kadam
Khadija Khan
Rutuja Kadam
• Acetate Rayon is a manufactured regenerated cellulose fiber.
• Purified cellulose , primarily from wood pulp.
• Converted into a soluble compound.
• Dissolved and forced through a spinneret.
• To produce filaments.
• Chemically solidified, resulting in synthetic fiber, pure
cellulose.
• Rayon is manufactured from naturally occurring polymer.
• It is considered a semi-synthetic fiber.
• Acetate rayon a synthetic filament, yarn, or fabric
composed of a derivative of the acetic ester of cellulose.
• Differing from viscose rayon in having greater strength
when wet and greater sensitivity to high temperatures.
High quality Acetate
fabric
• Origin :
• Acetate, which is properly called as cellulose acetate, was
first made by Paul Schützen berger, in 1869.
• The basic raw material for rayon is cellulose.
• Natural cellulose are – wood pulp, spruce, hemlock tree
and cotton linters.
• Cotton linters are residue fibers .
• Acetate Rayon is a manufactured fiber composed of
regenerated cellulose.
• It is a manufactured fiber in which substitutes have not
replaced more than 15 percent of the hydrogens.
• The manufacturing acetate include cellulose, acetate
anhydride, plus sulphuric acid as a catalyst.
• Primarily from wood pulp, purified, bleached and shredded.
• The shredded is fed into pre-treatment tanks, mixed with
glacial acetic acid and held for a specified length of time.
• To kneading machines called acetylates and acetic
anhydride is added.
• Dissolved and becomes cellulose acetate. Clear liquid called
acid dope.
• The dope is aged, in special storage tanks ; water is added
as needed reduce the acid concentration.
• Hydrolysis occurs during the ripening; formation of
acetate.
• Secondary acetate solution in mixed with water.
• Precipitate out in the form of small flakes.
• The flakes are washed and dried
• Dissolved in acetone to form a spinning dope.
• This spinning solution is forced through filters to remove any
undissolved acetate and impurities and then through the
spinnerette into a warm air chamber.
• The acetone evaporates and the acetate coagulates as it falls
through the chamber.
• The filaments travelling downward are twisted together to form
yarn.
• Fiber manufacture is called dry spinning.
FIBRE PROPERTIES
• Manufactures can produce a wide variety of fiber shapes
and confirmations.
• Acetate Rayon has low strength and requires careful
handling.
• But the desirable properties of hand, drape, and
appearance make the fabrics manufactured from these
fibres results in fabrics that become easily wrinkled and
permanently deformed.
• Moisture regain is slightly less than cottonattractive to
designers and consumers.
• The low elastic recovery of acetate, with its low resiliency,.
• Dilute alkalis have little effect on acetate.
• Concentrated acids weaken the fibres drastically and in
most instances cause complete disintegration.
• Dilute hot acids may cause, a loss of strength.
• Cold dilute acids weaken the fibre if exposure is prolonged.
• Petroleum solvents used in dry cleaning do not damage
acetate, phenol and chloroform will destroy the fibres.
• Storage may result in weaker acetate fibres.
• All acetate develops static charges, especially when dry,
because they are poor conductors of electricity.
• Fungi such as mildew and bacteria may discolour acetate
fibres.
• Moths and other households pests do not damage acetate.
• However, silverfish may attack heavily sized fibers in order
to eat the starch sizing.
• Acetate rayon is a thermoplastic fibre.
• Melt and burn, forming a hard, black bead ash.
• Odour is similar to that of hot vinegar.
• A manufactured fiber in which the fibre-forming substance
is a long-chain synthetic polyamide, in which at least 85%
of the amide linkages are attached directly to two aromatic
rings.
• Kevlar is a heat-resistant and strong synthetic fiber, related
to other aramids such as Nomex and Tecnora.
• Developed by Stephaine Kwolek at Dupont in 1965.
• First commercially in the early 1970s as a replacement for
steel in racing tires.
• Typically it is spun into ropes as an ingredient in composite
material components.
• Properties
• It is resistant to alkalis at room temperature.
• Kevlar is spun the resulting fiber has a tensile strength
about 3,620 Mpa and a relative density of 1.44.
• The polymer owns its high strength to the many inter chain
bounds .
• Hydrogen bounds form between the carbonyl group and NH
centres.
• Additions strength is derived from aromatic stacking
interaction between adjacent strands.
• Uses
• Bullet/stab proof vest or jackets.
• Diving gloves, walking boots, military helmet, cut resistant
gloves.
• Bicycle tyres cars tyres and fire proof clothing.
• Nomex is a brand of lightweight, heat resistant aramid fiber
used in clothing especially for fire fighter and protective
fabrics.
• Properties
• Inherent dielectric strength
• Mechanical toughness
• Thermal stability
• Chemical compatibility
• Radiation resistance
• Flame resistance
• Moisture insensitivity
• Cryogenic capabilities.
• Inherent Dielectric Strength
• Nomex® products withstand short-term electrical stresses
of 18 kV/mm to 34 kV/mm (460 V/mil to 870 V/mil),
depending on product type and thickness.
• Mechanical Toughness
• Nomex® products are strong, resilient and (in the thinner
grades) flexible, with good resistance to tearing and
abrasion.
• Thermal Stability
• Temperatures up to 200°C have little or no effect on the
electrical and mechanical properties of Nomex® products.
• At temperature 370c (700f) Nomex degrades.
• Nomex® products are essentially unaffected by most
solvents and are unusually resistant to attacks by acids and
alkalis at room temperature.
• They are not attacked by insects, fungi or mold.
• Prolonged exposure to sodium hydroxide in concentration
greater than 50% at elevated temperature degrades nomex.
• Radiation Resistance
• Nomex® is essentially unaffected by 800 me garads (8
Mgy) of ionizing radiation and still retains useful
mechanical and electrical properties after eight times this
exposure.
• Flame Resistance
• Nomex® products do not produce known toxic reactions in
humans
• Nomex® products do not melt and, with a limiting oxygen
index (LOI) at 220°C above 20.8—the critical value for
combustion in air—they do not support combustion.
• Cryogenic Capabilities
• Nomex® products have found acceptance in a variety of
cryogenic applications due to their unique polymer
structure.
• Uses
• Gloves , nomex hood, Divers protection, Driving shoes ,
protective socks , firefighter protection, filtering material
• Title : Essential of Textiles. Publisher: Holt, Rinehart and
Winston, INC. Year : Oct 1987.
Web Refernces:
• https://en.wikipedia.org/wiki/Rayon
• https://www.dupont.com/products/nomex-fibers.html
• https://www.dupont.com/what-is-kevlar.html
Dr bmn college -  acetate rayon , aramid fibers

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Dr bmn college - acetate rayon , aramid fibers

  • 1. DR.B.M.N College of Home Science (Autonomous) Matunga,Mumbai-19
  • 2. Presented by SYBSc - TSAD Sonal Gaikwad Pooja jakhar Kalyani Kadam Khadija Khan Rutuja Kadam
  • 3.
  • 4. • Acetate Rayon is a manufactured regenerated cellulose fiber. • Purified cellulose , primarily from wood pulp. • Converted into a soluble compound. • Dissolved and forced through a spinneret. • To produce filaments. • Chemically solidified, resulting in synthetic fiber, pure cellulose. • Rayon is manufactured from naturally occurring polymer. • It is considered a semi-synthetic fiber.
  • 5. • Acetate rayon a synthetic filament, yarn, or fabric composed of a derivative of the acetic ester of cellulose. • Differing from viscose rayon in having greater strength when wet and greater sensitivity to high temperatures. High quality Acetate fabric
  • 6. • Origin : • Acetate, which is properly called as cellulose acetate, was first made by Paul Schützen berger, in 1869.
  • 7. • The basic raw material for rayon is cellulose. • Natural cellulose are – wood pulp, spruce, hemlock tree and cotton linters. • Cotton linters are residue fibers . • Acetate Rayon is a manufactured fiber composed of regenerated cellulose. • It is a manufactured fiber in which substitutes have not replaced more than 15 percent of the hydrogens.
  • 8.
  • 9.
  • 10.
  • 11. • The manufacturing acetate include cellulose, acetate anhydride, plus sulphuric acid as a catalyst. • Primarily from wood pulp, purified, bleached and shredded. • The shredded is fed into pre-treatment tanks, mixed with glacial acetic acid and held for a specified length of time. • To kneading machines called acetylates and acetic anhydride is added. • Dissolved and becomes cellulose acetate. Clear liquid called acid dope. • The dope is aged, in special storage tanks ; water is added as needed reduce the acid concentration. • Hydrolysis occurs during the ripening; formation of acetate. • Secondary acetate solution in mixed with water. • Precipitate out in the form of small flakes. • The flakes are washed and dried
  • 12. • Dissolved in acetone to form a spinning dope. • This spinning solution is forced through filters to remove any undissolved acetate and impurities and then through the spinnerette into a warm air chamber. • The acetone evaporates and the acetate coagulates as it falls through the chamber. • The filaments travelling downward are twisted together to form yarn. • Fiber manufacture is called dry spinning.
  • 13.
  • 15. • Manufactures can produce a wide variety of fiber shapes and confirmations. • Acetate Rayon has low strength and requires careful handling. • But the desirable properties of hand, drape, and appearance make the fabrics manufactured from these fibres results in fabrics that become easily wrinkled and permanently deformed. • Moisture regain is slightly less than cottonattractive to designers and consumers. • The low elastic recovery of acetate, with its low resiliency,.
  • 16. • Dilute alkalis have little effect on acetate. • Concentrated acids weaken the fibres drastically and in most instances cause complete disintegration. • Dilute hot acids may cause, a loss of strength. • Cold dilute acids weaken the fibre if exposure is prolonged. • Petroleum solvents used in dry cleaning do not damage acetate, phenol and chloroform will destroy the fibres. • Storage may result in weaker acetate fibres. • All acetate develops static charges, especially when dry, because they are poor conductors of electricity.
  • 17. • Fungi such as mildew and bacteria may discolour acetate fibres. • Moths and other households pests do not damage acetate. • However, silverfish may attack heavily sized fibers in order to eat the starch sizing.
  • 18. • Acetate rayon is a thermoplastic fibre. • Melt and burn, forming a hard, black bead ash. • Odour is similar to that of hot vinegar.
  • 19.
  • 20. • A manufactured fiber in which the fibre-forming substance is a long-chain synthetic polyamide, in which at least 85% of the amide linkages are attached directly to two aromatic rings.
  • 21.
  • 22. • Kevlar is a heat-resistant and strong synthetic fiber, related to other aramids such as Nomex and Tecnora. • Developed by Stephaine Kwolek at Dupont in 1965. • First commercially in the early 1970s as a replacement for steel in racing tires. • Typically it is spun into ropes as an ingredient in composite material components.
  • 23. • Properties • It is resistant to alkalis at room temperature. • Kevlar is spun the resulting fiber has a tensile strength about 3,620 Mpa and a relative density of 1.44. • The polymer owns its high strength to the many inter chain bounds . • Hydrogen bounds form between the carbonyl group and NH centres. • Additions strength is derived from aromatic stacking interaction between adjacent strands.
  • 24. • Uses • Bullet/stab proof vest or jackets. • Diving gloves, walking boots, military helmet, cut resistant gloves. • Bicycle tyres cars tyres and fire proof clothing.
  • 25.
  • 26. • Nomex is a brand of lightweight, heat resistant aramid fiber used in clothing especially for fire fighter and protective fabrics.
  • 27. • Properties • Inherent dielectric strength • Mechanical toughness • Thermal stability • Chemical compatibility • Radiation resistance • Flame resistance • Moisture insensitivity • Cryogenic capabilities. • Inherent Dielectric Strength • Nomex® products withstand short-term electrical stresses of 18 kV/mm to 34 kV/mm (460 V/mil to 870 V/mil), depending on product type and thickness. • Mechanical Toughness • Nomex® products are strong, resilient and (in the thinner grades) flexible, with good resistance to tearing and abrasion.
  • 28. • Thermal Stability • Temperatures up to 200°C have little or no effect on the electrical and mechanical properties of Nomex® products. • At temperature 370c (700f) Nomex degrades. • Nomex® products are essentially unaffected by most solvents and are unusually resistant to attacks by acids and alkalis at room temperature. • They are not attacked by insects, fungi or mold. • Prolonged exposure to sodium hydroxide in concentration greater than 50% at elevated temperature degrades nomex.
  • 29. • Radiation Resistance • Nomex® is essentially unaffected by 800 me garads (8 Mgy) of ionizing radiation and still retains useful mechanical and electrical properties after eight times this exposure. • Flame Resistance • Nomex® products do not produce known toxic reactions in humans • Nomex® products do not melt and, with a limiting oxygen index (LOI) at 220°C above 20.8—the critical value for combustion in air—they do not support combustion. • Cryogenic Capabilities • Nomex® products have found acceptance in a variety of cryogenic applications due to their unique polymer structure.
  • 30. • Uses • Gloves , nomex hood, Divers protection, Driving shoes , protective socks , firefighter protection, filtering material
  • 31.
  • 32. • Title : Essential of Textiles. Publisher: Holt, Rinehart and Winston, INC. Year : Oct 1987. Web Refernces: • https://en.wikipedia.org/wiki/Rayon • https://www.dupont.com/products/nomex-fibers.html • https://www.dupont.com/what-is-kevlar.html