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Doppler Broadening 
M.Zeeshan Khalid 
09050610-039
Introduction 
• It is the broadening of the spectral line due to Doppler 
Effect of the random thermal motion of the molecules. 
• Lack of sharpness in the spectrum line causes the 
broadening and is related to the distribution of velocities 
of the atoms or molecules. 
• Causes red shifted and blue shifted wavelengths
• Emitting atoms are in motion with a range of speeds Δν along 
the line of sight to the observer then Doppler Broadening is 
given as 
• For a gas of atoms of mass m at a temperature T, the velocity 
dispersion is given by 
where k is the Boltzmann constant (1.38 × 10−23 J K−1)
Thermal Doppler broadening 
• Atoms and molecules move in a haphazard direction with 
average velocity is given as (1/2mv2 )= 3/2kT 
• The spreading of the spectral line due to the temperature of 
the emitting medium is called as thermal Doppler broadening. 
• Spreading of the spectral line depends on the frequency, mass 
of the emitting particles and the temperature.
Doppler broadening on nuclear reactors 
• The Doppler effect arises when the temperature of the fuel 
changes. 
• When the uranium is heated, its nuclei move more rapidly in 
random directions, and therefore generate a wider range of 
relative neutron speeds. 
• Pebble bed nuclear reactors
Doppler Broadening 
Applications and other causes 
• Thermal Doppler broadening 
• Causes of velocity distribution 
Turbulent motion Accretion disc 
• Stark broadening

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Doppler broadening

  • 1. Doppler Broadening M.Zeeshan Khalid 09050610-039
  • 2. Introduction • It is the broadening of the spectral line due to Doppler Effect of the random thermal motion of the molecules. • Lack of sharpness in the spectrum line causes the broadening and is related to the distribution of velocities of the atoms or molecules. • Causes red shifted and blue shifted wavelengths
  • 3. • Emitting atoms are in motion with a range of speeds Δν along the line of sight to the observer then Doppler Broadening is given as • For a gas of atoms of mass m at a temperature T, the velocity dispersion is given by where k is the Boltzmann constant (1.38 × 10−23 J K−1)
  • 4. Thermal Doppler broadening • Atoms and molecules move in a haphazard direction with average velocity is given as (1/2mv2 )= 3/2kT • The spreading of the spectral line due to the temperature of the emitting medium is called as thermal Doppler broadening. • Spreading of the spectral line depends on the frequency, mass of the emitting particles and the temperature.
  • 5.
  • 6. Doppler broadening on nuclear reactors • The Doppler effect arises when the temperature of the fuel changes. • When the uranium is heated, its nuclei move more rapidly in random directions, and therefore generate a wider range of relative neutron speeds. • Pebble bed nuclear reactors
  • 7. Doppler Broadening Applications and other causes • Thermal Doppler broadening • Causes of velocity distribution Turbulent motion Accretion disc • Stark broadening