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Inkjet-Printed Nanotechnology-Enabled Zero-Power Wireless Sensor Nodes for Internet-of-Things (IoT) and M2M Applications 
Manos M. Tentzeris 
Professor, IEEE Fellow and Distinguished Microwave Lecturer 
(etentze@ece.gatech.edu) 
ATHENA Research Group, 
School of ECE , 
Georgia Institute of Technology, 
Atlanta, GA, 30332-250, USA 
www.ece.gatech.edu/~etentze
ATHENA Research Group 
•10 PhD students 
•5 MS students 
•5 GT-ORS Undergraduate Students 
•5 Visiting Faculty+Stuff (Japan, France, Italy, Spain, China) 
•Strong collaboration with Georgia Tech Ireland - Athlone (visited Summer 2009) 
•Featured in IEEE The Institute, Wall Street Journal, Discovery Channel, CNN, Boston Globe, CBS Smartplanet, Yahoo, EE Times, engadget.com, gizmag.com 
•Co-founders of the RF-DNA anti-counterfeiting technology listed among the 25 technologies featured in the 20-year anniversary issue of the Microsoft Research Center 
•http://www.athena-gatech.org
ATHENA Focus Areas 
•RFID's, mmID's and RFID-enabled Sensors 
•Inkjet-Printed RF electronics, antennas and sensors 
•Nanotechnology-based "zero-power" wireless sensors 
•Ubiquitous WSN's and Internet of Things 
•"Smart Skin" and "Smart Energy" Applications 
•Wearable and Implantable WBAN's 
•Flexible 3D Wireless " Smart Cube" Modules up to sub-THz 
•Multiform Power Scavenging and Wireless Power Transfer 
•Conformal ultra broadband/multiband antennas and antenna arrays 
•Paper/PET/Fabric-based Electronics
Selected Awards 
•IEEE Fellow 
•NSF CAREER Award 
•IEEE MTT-S Distinguished Microwave Lecturer 
•2009 E.T.S. Walton Award from SFI 
•2010 IEEE APS Society P.L.E.Uslenghi Letters Prize Paper Award 
•2010 Georgia Tech Senior Faculty Outstanding Undergraduate Research Mentor Award 
•2009 IEEE Trans. Components and Packaging Technologies Best Paper Award 
•2006 IEEE MTT Outstanding Young Engineer Award 
•2006 Asian-Pacific Microwave Conference Award 
•2003 NASA Godfrey "Art" Anzic Collaborative Distinguished Publication Award
3D Integrated Platforms 
Sensor node 
Comm. node 
Power management 
Nanowire Sensor 
Multi-mode Nanowire Interface for Sensing/Energy Harvesting/storing 
Nanowire Battery 
Multi-mode Wireless Interface for Comm. and Energy Harvesting 
.... 
.... 
Wireless Interface for Comm/Sensor/Power 
Nanowire Energy Harvest 
Electronic Interface for Nanowire 
Organic Substrate 
Si-CMOS 
Substrate
Enabling Technologies in the future 
BGA 
BGA 
Filter Antenna 
Cavitˇ 
Micro-BGA 
Structure MCM-L 
en LCP Puces digitales et MMIC 
MEMS 
Switch, inductanceÉ 
MCM-L 
LCP 
Digital & Analog IC 
RF MEMS 
Switch & Inductor 
Hermetic Packaging 
FPGA#1 
FPGA#2 
Transceiver 
MUX/DEMU 
X
Inkjet-Printed RF Electronics and Modules on Paper
Internet of Things - at its most basic level… 
Interrogator / Gate way device 
Interrogator / Gate way device 
Host Information Management System 
Host Information Management System 
Actuators 
Actuators 
Wider area communications and Networks 
Application commands and responses 
Physical interface zone 
Internet + 
Passive RFID data carriers and UID
RFID Ink-jet Printed on Paper Using Conductive Ink 
PAPER ELECTRONICS: 
• Environmental Friendly and is the LOWEST COST MATERIAL MADE 
• Large Reel to Reel Processing 
• Compatible for printing circuitry by direct write methodologies 
• Can be made hydrophobic and can host nano-scale additives (e.g. fire retardant textiles) 
• Dielectric constant εr (~3) close to air’s 
• Potentially setting the foundation for truly 
“green” RF electronics
RFID printed on paper: conductive ink 
PAPER: 
• Environmental Friendly and low cost 
(LOWEST COST MATERIAL MADE BY HUMANKIND) 
• Large Reel to Reel Processing 
• Compatible for printing circuitry by direct write methodologies 
• Can be made hydrophobic and can host nano-scale additives (e.g. fire retardant 
textiles) 
• Dielectric constant εr (~2) close to air’s 
INK: 
• Consisting of nano-spheres melting and sintering at low temperatures (100 °C) 
• After melting a good percolation channel is created for electrons flow. 
• Provides better results than traditional polymer thick film material approach. 
SEM images of printed silver nano-particle ink, after 15 
minutes of curing at 100°C and 150°C 
The ONLY group able to inkjet-print carbon-nanotubes for ultrasensitive gas 
sensors (ppb) and structural integrity (e.g.aircraft crack detection) non-invasive 
sensors
Characteristics: 
• Piezo-driven jetting device to preserve 
polymeric properties of ink 
• 10 pL drops give ~ 21 μm 
• Drop placement accuracy ±10 μm gives 
a resolution of 5080 dpi 
• Drop repeatability about 99.95% 
• Printability on organic substrates (LCP, 
paper …) 
Inkjet-printing Technology - Printer 
High resolution inkjet 
printed copper (20 μm) 
SEM Images of a Layer of Printed ink, Before and 
After a 15 Minute Cure at 150ºC
•15x cheaper than metallic nanoparticles 
•Uniform, non-porous films 
•Can be deposited on glass and wafers (Future integration w/ CMOS) 
•Zero oxidation 
Novel Method for Inkjet Cu 
Silver Nanoparticle 
Catalyst Copper
Printed Dielectrics For Multi-Layer Passives/Actives 
•Inkjet Multi-Layer Process 
–Metal/Dielectric/Via layers (All Printed) 
–Post-Processing on-chip antennas/interconnects 
–MEMS 
–MIM Caps 
–Transistor Gates 
–Substrate Surface Energy Modification 
Silver M1M2
B 
Treated Si 
One Layer GO Ink 
A 
Inkjet Printing on Si/Glass 
Surface modification enables inkjet printing on silicon/glass that was not possible before.
Inkjet Printing on Si/Glass 
Cu as well as some other metals such as Au, Ag, Pd, Ni and Co can be printed on Si/glass in our novel approach by combining inkjet printing technology and electroless deposition. 
A Cu pattern printed on glass slide
Wireless Sensor Module: 904.2 MHz 
• Single Layer Module Circuit printed on Paper using 
inkjet technology 
• Integrated microcontroller and wireless transmitter 
operating @ 904.2 MHz 
• Module can be custom programmed to operate with 
any kind of commercial sensor, environment & 
Communication requirement 
• Rechargeable Li-ion battery for remote operation 
• Maximum Range: 1.86 miles 
Wireless Temperature Sensor Signal 
sent out by module, measured by 
Spectrum Analyzer 
Wireless Signal Strength 
sent out by module, 
measured by Spectrum 
Analyzer 
Circuit +Sensor+ Antenna on Paper 
Antenna on Paper 
Antenna Radiation Pattern 
showing high gain
Wireless Sensor Module: 904.5 MHz•Double Layer Module Circuit printed on Paper using inkjet technology•Integrated microcontroller and wireless transmitter operating @ 904.5 MHz•Module can be custom programmed to operate with any kind of commercial sensor, environment & Communication requirement•Rechargeable Li-ion battery for remote operation•Maximum Range: < 8 milesWireless ASK modulated Temperature Sensor Signal sent out by module, measured by Spectrum AnalyzerWireless Signal Strength sent out by module, measured by Spectrum AnalyzerCircuit + Sensor+ Antenna on PaperAntenna Radiation Patter showing high gain
SenSprout: Inkjet-Printed Soil Moisture and Leaf Wetness 
Sensor 
18 
Features: 
Inkjet-printed capacitive sensor for 
soil moisture and rain detection 
Applications: 
Irregation optimization, quality 
control of high-value fruit, and 
land-slide detection in mountains
Inkjet-Printed Radar on Flexible Substrates (headed by A.Traille (Doctorant-LAAS) and Prof. H.Aubert (LAAS) 
A.Traille, A.Coustou, H.Aubert, S.Kim and M.M.Tentzeris,“Monolithic Paper-Based & Inkjet- Printed Technology for Conformal Stepped-FMCW GPR Applications”, accepted for Podium Presentation to the 2013 European Microwave Week, Nurnberg 2013
UWB Inkjet-Printed Antennas on Paper: Is it possible?
Inkjet Printing on LCP: Up to mm-Wave 
Frequencies 
21 5/24/2013
Working prototype
3D-”Magic Cube” Antennas 
•Typical RFID/Wireless Sensor antennas tend to be limited in miniaturization by their length 
•What if used a cube instead of a planar structure to decrease length dimension? 
•Interior of cubic antenna used for sensing equipment as part of a wireless sensor network 
•Can lead to the implementation of UWB sensors and the maximization of power scavenging efficiency, potentially enabling trully autonomous distributed sensing networks 
Feed loop 
30 mm 
30 mm 
30 mm 
The first trully 3D maximum power-scavenging antenna on paper
ORIENTATION #1 
ORIENTATION #2 
ORIENTATION #3 
Orientations 
TX 
RX 
Transmit Module 
Receive Module 
Experimental Set-Up 
June 2010 - 24 
Tx and Rx co-polarized 
Tx and Rx orthogonal 
Tx and Rx random
Min/Max Distance Ratio for All Orientations 
Outdoor Range Measurement 
June 2010 - 25 
•Maximum Whip-Whip Distance is 0.12 miles 
•Maximum Cube-Cube Distance is 0.116 miles 
0 
10 
20 
30 
40 
50 
60 
70 
80 
90 
100 
C0 
C3 
C7 
Sensor Cube 
Stacked Whip 
Channels 
Min/Max Ratio 
Channel 0 = 903.37 MHz 
Channel 3 = 909.37 MHz 
Channel 7= 921.37 MHz 
More variability with orientation 
for the whip antenna (65% vs. 95% 
for the cube antenna)
Isotropic Radiator 
-4.67 
-1.67 
1.33 
0° 
45° 
90° 
135° 
180° 
225° 
270° 
315° 
Radiation Pattern of 915MHz Printed Antenna Folded Around FSS Cube 
Horizontal 
Vertical 
Horizontal Orientation 
Vertical Orientation
Omnidirectional Broadband CP Antenna 
The first CP Antenna with 30%+ AR Bandwidth (10x better than state of the art) Also: omni, flex independent
“Autonomous” Wireless Sensor Node Powered by RF Energy Harvesting 
Tokyo Tower 
5-stage Cockcroft- walton circuit 
Paper Antenna 
MSP430+CC2500 
28 
Features: 
•A dipole antenna + rectifier for 550MHz (Digital TV) harvests ~100uW from TV tower 6.5km away 
•MSP430 + CC2500 for sensing and communication 
•Dynamic duty cycle control software for maximize scarce energy intake
Ambient RF: How much is out there? 
Ambient RF: Atlanta 
Digital TV 
Analog TV 
Mobile Phone, MCA 
Ambient RF: Tokyo
Wireless Energy Harvesting Circuit: Field Measurements 
•At 6.5 km from source 
•100uF Cap charges to 2.9V in 3mins 
•Energy Harvested – 0.45 m-Joules in 3 mins 
•Enough to power on embedded sensors and low power radios 
Digital TV Broadcast Tower. 6.5km 
WEH-1 & its output (3V) 
R.Vyas et al., “A Battery-Less, Energy Harvesting Device for Long Range Scavenging of Wireless Power from Terrestrial TV Broadcasts”, IEEE International Microwave Symposium, June 2012
Wireless Energy Harvesting Circuit: Field Measurements 
•At 6.5 km from source 
•100uF Cap charges to 2.9V in 3mins 
•Energy Harvested – 0.45 m-Joules in 3 mins 
•Enough to power on embedded sensors and low power radios 
Digital TV Broadcast Tower. 6.5km 
WEH-1 & its output (3V) 
R.Vyas et al., “A Battery-Less, Energy Harvesting Device for Long Range Scavenging of Wireless Power from Terrestrial TV Broadcasts”, IEEE International Microwave Symposium, June 2012
Introduction 
Health Monitoring 
Physical Activity Monitoring 
Safety 
Rehabilitation Methods Improvements 
Instantaneous data elaboration 
Wearable Electronics 
In the new area of the Internet of Things the focus of this work is about..
EBG Ground Plane 
•Reflection phase characteristic method 
•Illuminate plane wave to the EBG ground plane 
•Monitoring phase of the reflected wave (S11) 
Fig6. (a) Antenna Geometry 
(b) Layout of EBG surface
Communication Range Improvement 
•Communication range is improved 
- Original chip antenna: 18.3 m 
- The proposed antenna: 82.8 m 
•Range is increased by a factor of four 
34/21 
Fig13. Communication range measurement
“Smart Skin” Platform
•Microfluidic-integrated RFID antenna 
–Utilizes capacitive microfluidic gap to load antenna 
–Change in fluid ɛr causes change in fr 
–RFID chip provides digital backscatter modulation 
Proposed Microfluidic RFID Tag
Inkjet Microfluidic Fabrication
•Laser engraved channels 
–Etch acrylic 
–Vary laser power/focus 
–Depths as low as 50 um 
•Bonded channels 
–Ultra-thin bonding layer 
–No channel clogging 
Inkjet Microfluidic Fabrication
•Fabricate capacitor to extract gap impedance 
•Requires 1 uL of fluid 
•Load capacitor with: 
–1-Hexanol (Er = 3) 
–Ethanol (Er = 15) 
–Water (Er = 73) 
Inkjet Microfluidic Varactor
Inkjet Microfluidic Varactor
Beacon Oscillator 
Solar Cell 
Oscillator circuit 
• Solar powered inkjet printed stand alone beacon oscillator 
• Green environmentally friendly technology 
• Localization application
Beacon Oscillator 
10 
4 
10 
5 
10 
6 -130 
-120 
-110 
-100 
-90 
-80 
-70 
-60 
-50 
-40 
Frequency [Hz] 
Phase noise [dBc/Hz] 
• The carrier frequency: 874.65 MHz 
• Low phase noise: -68.27 dBc/Hz @ 10kHz from the carrier frequency 
-123.6 dBc/Hz @ 1MHz from the carrier frequency
Parylene Coating for Protection 
Water drops 
• The antenna covers 900 MHz & 2.4 GHz 
• Linearly polarized 
• Parylene C type is deposited ( about 1um ) 
• Hydrophobic & waterproof surface is created
Parylene Coating for Protection 
•No performance degradation after water contact 
00.511.522.533.54-40-35-30-25-20-15-10-50Frequency [dB] S11 [dB] SimulationNo coatingAntenna with coatingAntenna after 4 days in water w/ coatingAntenna after 4 days in water w/o coating
Inkjet-Printed Passives - Waveguide 
•Substrate Integrated Waveguide (SIW) 
- High system integrity 
- Innumerable applications on organic paper 
substrate in mmWave area 
(ex: Radar, traveling wave antenna, etc) 
< SIWs in different length >
Inkjet-printed Via on Vertical Via Hole 
•A vertical via hole on thick substrate (> 500 μm): 
- Crack formation due to the sintering process and the gravity 
(a) Inkjet-printed via on the vertical via hole 
(b) SEM image of the crack 
< Crack formation of inkjet-printed via on the vertical via hole >
Stepped-via Fabrication 
(i) Laser drilling: Top 
(ii) Drilled via hole: Top 
(iii) Laser drilling: Bottom 
(iv) Drilled via hole: Bottom 
(v) Inkjet printing & Sintering 
(vi) Fabricated stepped via hole
Stepped Via Hole: Top view 
•Substrate: PMMA (polymethyl methacrylate) 
•Thickness: 1 mm 
< Geometry of stepped via hole and SEM images: Top view > 
(a) Radii table 
(b) Via geometry 
(c) SEM images
GATech-FIU Ideas 
• GATech and FIU inventions address all 
the above problems of traditional SCMR in 
order to develop a WPT that is: 
– Highly efficient (mid-range) 
– Compact in size 
– Misalignment insensitive 
– Broadband
WPT Techniques
Misalignment Insensitive 
Highly Efficient WPT 
Source Element 
TX 3D loop resonator 
Load Element 
RX 3D loop resonator 
0 10 20 30 40 50 60 70 80 90 
0 
0.2 
0.4 
0.6 
0.8 
1 
Angle() 
Normalized Efficiency 
Standard SCMR 
Embedded TX + Loops RX 
All Embedded 
Provisional patent # 61/658,636
50 100 150 200 
0 
10 
20 
30 
40 
50 
60 
70 
80 
90 
100 
Frequency (MHz) 
Efficiency(%) 
Distance = 7 cm 
Legends 
RX 
resonator 
RX load 
TX 
resonator 
TX Source 
Broadband & Highly Efficient WPT 
Provisional patent # 61/662,674 
Measurements
Legends 
RX resonator 
RX load 
TX resonator 
TX Source 
Design 2: Embedded 3-D loops Each 3-D loop comprises of three connected orthogonal loops 
•The RX and TX resonator elements as well as the source and load elements are 3-D continuous loops 
•Each 3-D loop comprises of three connected orthogonal loops. 
•The source and load loops are embedded inside the TX and RX resonators, respectively 
•This type of system has a spherical symmetry and therefore, it is expected to have misalignment insensitive performance.
0 10 20 30 40 50 60 70 80 90 
0 
10 
20 
30 
40 
50 
60 
70 
80 
90 
Efficiency (%) 
Azimuth misalignment angle,  () 
Simulation 
Measurement 
  °   45°   90° 
Design 2- Embedded 3-D loops 
Angular Azimuth Misalignment
Preliminary Implantable Results
Solar Antennas 
•Silicon in PV cell used as an antenna substrate 
•Novel Slot type Antenna 
•Gain 2-4dBi 
•Directive Pattern
Motivation 
CHALLENGE Battery limits usability and autonomy An alternative source of energy is required to power up the device GOAL Power up an RFID node to allow communication from the body to the reader without the use of battery AVOIDING BATTERY REPLACING IN RFID BODY AREA NETWORK 
Body Area Network-Usage Scenarios 
Body life sign monitoring 
Fitness monitoring 
Wearable audio devices
Wearable Tag Antenna Design 
Measured and Simulated Return Loss 
Far Field Radiation Pattern 
Bent antenna electromagnetic model of the foot 
2.7 dBi @ 397 MHz
Circuit Implementation 
SHDN GND 
Vset LBI 
LBO 
Vin 
Vout 
Sense 
GND ANT 
D0 GND 
D1 
GND 
A9 
A8 
D4 A3 
D5 A2 
D6 
D7 
A1 
A0 
Vcc A7 
TE A6 
D2 
D3 
A5 
A4 
4.7 pF 
1 MΩ 
1.3 MΩ 
1.3 KΩ 
Vcc 
Piezo Element 
25:1 
Transformer MAX666 
TXE-433-KH2 
Antenna 
Logo Antenna 
Diode Bridge 
Storage 
Capacitor 
MAX666 
Voltage Regulator 
RF Transmitter 
Port to Antenna 
Connection to Transformer
Circuit Implementation 
Capacitor voltage 
Max 666 output voltage 
19 V 
3V 
Transmitted signal captured by the RTSA 
V waveform of C and Regulator 
One Word Transmission 
ENERGY PROVIDED BY THE PUSHBUTTON 
stored in the capacitor 
848.4 μJ 
UNUTILIZED ENERGY 
below 2.7 V capacitor voltage, the active RFID tag stops transmitting 
17.1 μJ 
AVAILABLE ENERGY 
848.4μJ - 17.1 μJ 
831.3μJ 
ENERGY REQUIRED BY THE CIRCUIT FOR A ONE-WORD TRANSMISSION 
POWER needed for 50 ms operation: 9mW 
450 μJ 
> 60 ms
Human motion powered wireless tag 
Pilot and Sync. Bits 10-bit ID 8-bit Data 
Diode Bridge 
Storage 
Capacitor 
MAX666 
Voltage Regulator 
RF Transmitter Port to Antenna 
Connection to 
Transformer 
Logo Antenna 
(a) 
(b) 
Nike logo 
printed 
antenna 
performance 
Step powered 
RFID 
communication 
Tag circuit
Introduction 
Power Autonomous 
Unobtrusive 
Enabling Technology has to be 
Objective of this project  design a wearable, partially self-powered health monitoring and indoor localization shoe-mounted sensor module
Localization: Overview 
Personal Area Network 
«Smart Tile» mapped matrix of NFC tags embedded in the floor for localization purposes 
Partially self-powered shoe-mounted NFC reader
Dual-Band Wearable Adidas-Shaped Atnenna 
•Unobtrusive wearable antenna design 
• Dual Band: 900 MHz and 2.4 GHz 
•Deopsited nano particle silver ink on organic substrate (photo paper) technology
System Architecture Description 
Temperature Sensor 
TI NFC Reader Board (Transceiver + MCU + Antenna) 
Dual-band (900 MHz and 2.4 GHz) Adidas- shaped Antenna 
NFC tags embedded into the floor for localization purposes
Comparison Between Simulated and Measured Return Loss 
-50 
-45 
-40 
-35 
-30 
-25 
-20 
-15 
-10 
-5 
0 
0.4 
0.65 
0.9 
1.15 
1.4 
1.65 
1.9 
2.15 
2.4 
2.65 
2.9 
Mag. S11 (dB) 
Freq (GHz) 
Return Loss (dB) 
Simulation 
Measurement
Simulated Antenna Radiation Patterns 
Freq=900 MHz 
Freq=2.4 GHz 
•Excellent performance in term of radiation pattern for both 900 MHz and 2.4 GHz standards, considering the presence of the foot 
•Gain > 3dB
Localization: NFC system test 
Test  moving the tag from position 1 to 8 (shown in the figure) the maximum reading distance has been measured. The reader is placed at the center of the tile either vertically and horizontally.
Why 6LoWPAN? 
•IPv6 over Low-power Wireless Personal Area Networks -> native support of the IPv6 protocol stack on the end device 
•A low-power communication protocol based on the IEEE 802.15.4 PHY and MAC layer 
•Backed up by an active IETF Working group with real prototypes 
•The network, transport and application layers of the 6lowPAN protocol stack (right) are the same as those of the IPv6 stack (left) and the necessary changes exist in the adaptation layer on top of the IEEE 802.15.4 medium access control and physical layer.
Sensing site 
RF Wireless Pressure Transducer 
Processing Data 
Antenna functions as sensor 
Receiver Site 
 Fewer components 
 Smaller system size 
 Less power consumption
Carbon Nanotubes as Gas Sensor 
CNTs structure can be conceptualized by wrapping a one-atom-thick layer of graphite into a seamless cylinder. 
Single-walled CNTs and Multi-walled CNTs 
A diameter of close to 1 nanometer, with a tube length that can be many thousands of times longer. 
CNTs composites have electrical conductance highly sensitive to extremely small quantities of gases, such as ammonia (NH3) and nitrogen oxide (NOx). 
The conductance change can be explained by the charge transfer of reactive gas molecules with semiconducting CNTs. 
Fabrication of CNTs film: 
-Vacuum Filtering, dip coating, spray coating, and contact printing, requiring at least two steps to achieve the patterns. 
-Can it be inkjet-printed? Yes, if you can develop the recipe!
Inkjet-printed SWCNT Films 
Overlapping Zone 
500um 
10L 
15L 
20L 
25L 
SWCNT Film 
Silver Electrode 
Silver electrodes were patterned before depositing the SWCNT film, followed by a 140˚C sintering. 
The electrode finger is 2mm by 10mm with a gap of 0.8mm. SWCNT film was 2mm by 3mm. 
1.1mm overlapping zone to ensure the good contact between the SWCNT film and the electrodes.
Gas Detection 
   
 
 
   
 
 
 
P  P  G  G  d r t t r 10 10 40log 
4 
2 2 40log 
SWCNT Film @868MHz 
Z=51.6-j6.1 Ohm in air 
Z=97.1-j18.8 Ohm in NH3 
Tag Antenna @ 686MHz 
Zant=42.6+j11.4 Ohm 
2 
* 
load ANT 
Ioad ANT 
Z Z 
Z Z 
 
 
  
+ 
+ 
 Power reflection coefficient changes from - 
18.4dB to -7.6dB. At reader’s side, this 
means 10.8dBi increase of the received 
power level. 
 By detecting this backscattered power 
differnce, the sensing function is fulfilled.
Inkjet-Printed Graphene/CNT-Based Wireless 
Gas Sensor Modules 
Charge Transfer 
CNT 
Graphene 
Chemical Absorption 
ChangingMaterial Properties 
Measureable Electrical Quantities 
Gas Sensor Technology
Inkjet-Printed Graphene/CNT-Based Wireless 
Gas Sensor Experiment 
ADC Input 
Graphene-based 
Inkjet-printed 
Gas Sensor 
Regulated 1.8 V 
• Prototype 
• Set-up
The in-house developed novel sensor material demonstrates: 
- 6% normalized resistance change within 15 minutes of exposure to a concentration of 500 ppm of NH3. 
-excellent recovery time with over 30% of material recovery observed within 5 minutes without exposure to high temperature or any UV treatments. 
Inkjet-Printed Graphene-Based Wireless Gas Sensor Experiment
Inkjet-Printed CNT-Based Wireless 
Gas Sensor Experiment 
5 
10 
15 
20 
25 
30 
4 5 10 20 30 50 70 90 
Sensitivity (%) 
Concentration (ppm) 
864MHz NO2 
864MHz NH3 
2.4GHz NO2 
2.4GHz NH3 
! 
! 
0 
5 
10 
15 
20 
25 
30 
35 
40 
1 20 40 
Sensitivity (%) 
Time (min) 
864MHz NO2 
864MHz NH3 
2.4GHz NO2 
2.4GHz NH3 
10ppm 
Test Gas Nitrogen 
-Sensitivity of 21.7% and 9.4% was achieved for 10 ppm NO2 and 4 ppm 
NH3, respectively at 864 MHz 
-MWNT-based gas sensor demonstrates fast response to both gases (few 
seconds); the sensitivity achieved at 864 MHz is 24.2% for NO2 and 12.7% 
for NH3 in just 2 minutes’ time. Note that after testing, the sensor exposed 
to NH3 shows more rapid recovery
Inkjet-Printed CNT-Based Wireless 
Gas Sensor Experiment 
5 
10 
15 
20 
25 
30 
4 5 10 20 30 50 70 90 
Sensitivity (%) 
Concentration (ppm) 
864MHz NO2 
864MHz NH3 
2.4GHz NO2 
2.4GHz NH3 
! 
! 
0 
5 
10 
15 
20 
25 
30 
35 
40 
1 20 40 
Sensitivity (%) 
Time (min) 
864MHz NO2 
864MHz NH3 
2.4GHz NO2 
2.4GHz NH3 
10ppm 
Test Gas Nitrogen 
-Sensitivity of 21.7% and 9.4% was achieved for 10 ppm NO2 and 4 ppm 
NH3, respectively at 864 MHz 
-MWNT-based gas sensor demonstrates fast response to both gases (few 
seconds); the sensitivity achieved at 864 MHz is 24.2% for NO2 and 12.7% 
for NH3 in just 2 minutes’ time. Note that after testing, the sensor exposed 
to NH3 shows more rapid recovery
Solar Powered Smart Skins for Structural Health Monitoring 
•Novel Antenna based smart skins detect strains and cracks in civil structures 
•Remotely interrogated using novel RF reader 
•Reader uses 2.9 GHz to remotely interrogate tag. Tag returns strain information using 5.8GHz for better strain sensitivity 
•Uses Solar Powered Frequency doubling mechanism for long range
Solar Powered Smart Skins for Structural Health Monitoring 
•Latest prototypes show capability to detect 20 u-strain 
•Range extended to 10 meters through the use of Solar Power
ATHENA 
 Power Scavevenging 
Technologies: 
 Mechanical Motion 
 Power Density: 4μw/cm2 
 Resonance: Hz 
 Thermal 
 Seebeck or peltier effect 
 Power Density: 60 μw/cm2 
 Wireless 
 Power Density ≤ 1μw/cm2 
 Solar 
 Power Density: 100 mw/cm2 
 Does Not require differential 
936 MHz: -41dBm (0.08μw) 
Power Scavenging

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Indonesia ieee dml_2014

  • 1. Inkjet-Printed Nanotechnology-Enabled Zero-Power Wireless Sensor Nodes for Internet-of-Things (IoT) and M2M Applications Manos M. Tentzeris Professor, IEEE Fellow and Distinguished Microwave Lecturer (etentze@ece.gatech.edu) ATHENA Research Group, School of ECE , Georgia Institute of Technology, Atlanta, GA, 30332-250, USA www.ece.gatech.edu/~etentze
  • 2. ATHENA Research Group •10 PhD students •5 MS students •5 GT-ORS Undergraduate Students •5 Visiting Faculty+Stuff (Japan, France, Italy, Spain, China) •Strong collaboration with Georgia Tech Ireland - Athlone (visited Summer 2009) •Featured in IEEE The Institute, Wall Street Journal, Discovery Channel, CNN, Boston Globe, CBS Smartplanet, Yahoo, EE Times, engadget.com, gizmag.com •Co-founders of the RF-DNA anti-counterfeiting technology listed among the 25 technologies featured in the 20-year anniversary issue of the Microsoft Research Center •http://www.athena-gatech.org
  • 3. ATHENA Focus Areas •RFID's, mmID's and RFID-enabled Sensors •Inkjet-Printed RF electronics, antennas and sensors •Nanotechnology-based "zero-power" wireless sensors •Ubiquitous WSN's and Internet of Things •"Smart Skin" and "Smart Energy" Applications •Wearable and Implantable WBAN's •Flexible 3D Wireless " Smart Cube" Modules up to sub-THz •Multiform Power Scavenging and Wireless Power Transfer •Conformal ultra broadband/multiband antennas and antenna arrays •Paper/PET/Fabric-based Electronics
  • 4. Selected Awards •IEEE Fellow •NSF CAREER Award •IEEE MTT-S Distinguished Microwave Lecturer •2009 E.T.S. Walton Award from SFI •2010 IEEE APS Society P.L.E.Uslenghi Letters Prize Paper Award •2010 Georgia Tech Senior Faculty Outstanding Undergraduate Research Mentor Award •2009 IEEE Trans. Components and Packaging Technologies Best Paper Award •2006 IEEE MTT Outstanding Young Engineer Award •2006 Asian-Pacific Microwave Conference Award •2003 NASA Godfrey "Art" Anzic Collaborative Distinguished Publication Award
  • 5. 3D Integrated Platforms Sensor node Comm. node Power management Nanowire Sensor Multi-mode Nanowire Interface for Sensing/Energy Harvesting/storing Nanowire Battery Multi-mode Wireless Interface for Comm. and Energy Harvesting .... .... Wireless Interface for Comm/Sensor/Power Nanowire Energy Harvest Electronic Interface for Nanowire Organic Substrate Si-CMOS Substrate
  • 6. Enabling Technologies in the future BGA BGA Filter Antenna Cavitˇ Micro-BGA Structure MCM-L en LCP Puces digitales et MMIC MEMS Switch, inductanceÉ MCM-L LCP Digital & Analog IC RF MEMS Switch & Inductor Hermetic Packaging FPGA#1 FPGA#2 Transceiver MUX/DEMU X
  • 7. Inkjet-Printed RF Electronics and Modules on Paper
  • 8. Internet of Things - at its most basic level… Interrogator / Gate way device Interrogator / Gate way device Host Information Management System Host Information Management System Actuators Actuators Wider area communications and Networks Application commands and responses Physical interface zone Internet + Passive RFID data carriers and UID
  • 9. RFID Ink-jet Printed on Paper Using Conductive Ink PAPER ELECTRONICS: • Environmental Friendly and is the LOWEST COST MATERIAL MADE • Large Reel to Reel Processing • Compatible for printing circuitry by direct write methodologies • Can be made hydrophobic and can host nano-scale additives (e.g. fire retardant textiles) • Dielectric constant εr (~3) close to air’s • Potentially setting the foundation for truly “green” RF electronics
  • 10. RFID printed on paper: conductive ink PAPER: • Environmental Friendly and low cost (LOWEST COST MATERIAL MADE BY HUMANKIND) • Large Reel to Reel Processing • Compatible for printing circuitry by direct write methodologies • Can be made hydrophobic and can host nano-scale additives (e.g. fire retardant textiles) • Dielectric constant εr (~2) close to air’s INK: • Consisting of nano-spheres melting and sintering at low temperatures (100 °C) • After melting a good percolation channel is created for electrons flow. • Provides better results than traditional polymer thick film material approach. SEM images of printed silver nano-particle ink, after 15 minutes of curing at 100°C and 150°C The ONLY group able to inkjet-print carbon-nanotubes for ultrasensitive gas sensors (ppb) and structural integrity (e.g.aircraft crack detection) non-invasive sensors
  • 11. Characteristics: • Piezo-driven jetting device to preserve polymeric properties of ink • 10 pL drops give ~ 21 μm • Drop placement accuracy ±10 μm gives a resolution of 5080 dpi • Drop repeatability about 99.95% • Printability on organic substrates (LCP, paper …) Inkjet-printing Technology - Printer High resolution inkjet printed copper (20 μm) SEM Images of a Layer of Printed ink, Before and After a 15 Minute Cure at 150ºC
  • 12. •15x cheaper than metallic nanoparticles •Uniform, non-porous films •Can be deposited on glass and wafers (Future integration w/ CMOS) •Zero oxidation Novel Method for Inkjet Cu Silver Nanoparticle Catalyst Copper
  • 13. Printed Dielectrics For Multi-Layer Passives/Actives •Inkjet Multi-Layer Process –Metal/Dielectric/Via layers (All Printed) –Post-Processing on-chip antennas/interconnects –MEMS –MIM Caps –Transistor Gates –Substrate Surface Energy Modification Silver M1M2
  • 14. B Treated Si One Layer GO Ink A Inkjet Printing on Si/Glass Surface modification enables inkjet printing on silicon/glass that was not possible before.
  • 15. Inkjet Printing on Si/Glass Cu as well as some other metals such as Au, Ag, Pd, Ni and Co can be printed on Si/glass in our novel approach by combining inkjet printing technology and electroless deposition. A Cu pattern printed on glass slide
  • 16. Wireless Sensor Module: 904.2 MHz • Single Layer Module Circuit printed on Paper using inkjet technology • Integrated microcontroller and wireless transmitter operating @ 904.2 MHz • Module can be custom programmed to operate with any kind of commercial sensor, environment & Communication requirement • Rechargeable Li-ion battery for remote operation • Maximum Range: 1.86 miles Wireless Temperature Sensor Signal sent out by module, measured by Spectrum Analyzer Wireless Signal Strength sent out by module, measured by Spectrum Analyzer Circuit +Sensor+ Antenna on Paper Antenna on Paper Antenna Radiation Pattern showing high gain
  • 17. Wireless Sensor Module: 904.5 MHz•Double Layer Module Circuit printed on Paper using inkjet technology•Integrated microcontroller and wireless transmitter operating @ 904.5 MHz•Module can be custom programmed to operate with any kind of commercial sensor, environment & Communication requirement•Rechargeable Li-ion battery for remote operation•Maximum Range: < 8 milesWireless ASK modulated Temperature Sensor Signal sent out by module, measured by Spectrum AnalyzerWireless Signal Strength sent out by module, measured by Spectrum AnalyzerCircuit + Sensor+ Antenna on PaperAntenna Radiation Patter showing high gain
  • 18. SenSprout: Inkjet-Printed Soil Moisture and Leaf Wetness Sensor 18 Features: Inkjet-printed capacitive sensor for soil moisture and rain detection Applications: Irregation optimization, quality control of high-value fruit, and land-slide detection in mountains
  • 19. Inkjet-Printed Radar on Flexible Substrates (headed by A.Traille (Doctorant-LAAS) and Prof. H.Aubert (LAAS) A.Traille, A.Coustou, H.Aubert, S.Kim and M.M.Tentzeris,“Monolithic Paper-Based & Inkjet- Printed Technology for Conformal Stepped-FMCW GPR Applications”, accepted for Podium Presentation to the 2013 European Microwave Week, Nurnberg 2013
  • 20. UWB Inkjet-Printed Antennas on Paper: Is it possible?
  • 21. Inkjet Printing on LCP: Up to mm-Wave Frequencies 21 5/24/2013
  • 23. 3D-”Magic Cube” Antennas •Typical RFID/Wireless Sensor antennas tend to be limited in miniaturization by their length •What if used a cube instead of a planar structure to decrease length dimension? •Interior of cubic antenna used for sensing equipment as part of a wireless sensor network •Can lead to the implementation of UWB sensors and the maximization of power scavenging efficiency, potentially enabling trully autonomous distributed sensing networks Feed loop 30 mm 30 mm 30 mm The first trully 3D maximum power-scavenging antenna on paper
  • 24. ORIENTATION #1 ORIENTATION #2 ORIENTATION #3 Orientations TX RX Transmit Module Receive Module Experimental Set-Up June 2010 - 24 Tx and Rx co-polarized Tx and Rx orthogonal Tx and Rx random
  • 25. Min/Max Distance Ratio for All Orientations Outdoor Range Measurement June 2010 - 25 •Maximum Whip-Whip Distance is 0.12 miles •Maximum Cube-Cube Distance is 0.116 miles 0 10 20 30 40 50 60 70 80 90 100 C0 C3 C7 Sensor Cube Stacked Whip Channels Min/Max Ratio Channel 0 = 903.37 MHz Channel 3 = 909.37 MHz Channel 7= 921.37 MHz More variability with orientation for the whip antenna (65% vs. 95% for the cube antenna)
  • 26. Isotropic Radiator -4.67 -1.67 1.33 0° 45° 90° 135° 180° 225° 270° 315° Radiation Pattern of 915MHz Printed Antenna Folded Around FSS Cube Horizontal Vertical Horizontal Orientation Vertical Orientation
  • 27. Omnidirectional Broadband CP Antenna The first CP Antenna with 30%+ AR Bandwidth (10x better than state of the art) Also: omni, flex independent
  • 28. “Autonomous” Wireless Sensor Node Powered by RF Energy Harvesting Tokyo Tower 5-stage Cockcroft- walton circuit Paper Antenna MSP430+CC2500 28 Features: •A dipole antenna + rectifier for 550MHz (Digital TV) harvests ~100uW from TV tower 6.5km away •MSP430 + CC2500 for sensing and communication •Dynamic duty cycle control software for maximize scarce energy intake
  • 29. Ambient RF: How much is out there? Ambient RF: Atlanta Digital TV Analog TV Mobile Phone, MCA Ambient RF: Tokyo
  • 30. Wireless Energy Harvesting Circuit: Field Measurements •At 6.5 km from source •100uF Cap charges to 2.9V in 3mins •Energy Harvested – 0.45 m-Joules in 3 mins •Enough to power on embedded sensors and low power radios Digital TV Broadcast Tower. 6.5km WEH-1 & its output (3V) R.Vyas et al., “A Battery-Less, Energy Harvesting Device for Long Range Scavenging of Wireless Power from Terrestrial TV Broadcasts”, IEEE International Microwave Symposium, June 2012
  • 31. Wireless Energy Harvesting Circuit: Field Measurements •At 6.5 km from source •100uF Cap charges to 2.9V in 3mins •Energy Harvested – 0.45 m-Joules in 3 mins •Enough to power on embedded sensors and low power radios Digital TV Broadcast Tower. 6.5km WEH-1 & its output (3V) R.Vyas et al., “A Battery-Less, Energy Harvesting Device for Long Range Scavenging of Wireless Power from Terrestrial TV Broadcasts”, IEEE International Microwave Symposium, June 2012
  • 32. Introduction Health Monitoring Physical Activity Monitoring Safety Rehabilitation Methods Improvements Instantaneous data elaboration Wearable Electronics In the new area of the Internet of Things the focus of this work is about..
  • 33. EBG Ground Plane •Reflection phase characteristic method •Illuminate plane wave to the EBG ground plane •Monitoring phase of the reflected wave (S11) Fig6. (a) Antenna Geometry (b) Layout of EBG surface
  • 34. Communication Range Improvement •Communication range is improved - Original chip antenna: 18.3 m - The proposed antenna: 82.8 m •Range is increased by a factor of four 34/21 Fig13. Communication range measurement
  • 36. •Microfluidic-integrated RFID antenna –Utilizes capacitive microfluidic gap to load antenna –Change in fluid ɛr causes change in fr –RFID chip provides digital backscatter modulation Proposed Microfluidic RFID Tag
  • 38. •Laser engraved channels –Etch acrylic –Vary laser power/focus –Depths as low as 50 um •Bonded channels –Ultra-thin bonding layer –No channel clogging Inkjet Microfluidic Fabrication
  • 39. •Fabricate capacitor to extract gap impedance •Requires 1 uL of fluid •Load capacitor with: –1-Hexanol (Er = 3) –Ethanol (Er = 15) –Water (Er = 73) Inkjet Microfluidic Varactor
  • 41. Beacon Oscillator Solar Cell Oscillator circuit • Solar powered inkjet printed stand alone beacon oscillator • Green environmentally friendly technology • Localization application
  • 42. Beacon Oscillator 10 4 10 5 10 6 -130 -120 -110 -100 -90 -80 -70 -60 -50 -40 Frequency [Hz] Phase noise [dBc/Hz] • The carrier frequency: 874.65 MHz • Low phase noise: -68.27 dBc/Hz @ 10kHz from the carrier frequency -123.6 dBc/Hz @ 1MHz from the carrier frequency
  • 43. Parylene Coating for Protection Water drops • The antenna covers 900 MHz & 2.4 GHz • Linearly polarized • Parylene C type is deposited ( about 1um ) • Hydrophobic & waterproof surface is created
  • 44. Parylene Coating for Protection •No performance degradation after water contact 00.511.522.533.54-40-35-30-25-20-15-10-50Frequency [dB] S11 [dB] SimulationNo coatingAntenna with coatingAntenna after 4 days in water w/ coatingAntenna after 4 days in water w/o coating
  • 45. Inkjet-Printed Passives - Waveguide •Substrate Integrated Waveguide (SIW) - High system integrity - Innumerable applications on organic paper substrate in mmWave area (ex: Radar, traveling wave antenna, etc) < SIWs in different length >
  • 46. Inkjet-printed Via on Vertical Via Hole •A vertical via hole on thick substrate (> 500 μm): - Crack formation due to the sintering process and the gravity (a) Inkjet-printed via on the vertical via hole (b) SEM image of the crack < Crack formation of inkjet-printed via on the vertical via hole >
  • 47. Stepped-via Fabrication (i) Laser drilling: Top (ii) Drilled via hole: Top (iii) Laser drilling: Bottom (iv) Drilled via hole: Bottom (v) Inkjet printing & Sintering (vi) Fabricated stepped via hole
  • 48. Stepped Via Hole: Top view •Substrate: PMMA (polymethyl methacrylate) •Thickness: 1 mm < Geometry of stepped via hole and SEM images: Top view > (a) Radii table (b) Via geometry (c) SEM images
  • 49. GATech-FIU Ideas • GATech and FIU inventions address all the above problems of traditional SCMR in order to develop a WPT that is: – Highly efficient (mid-range) – Compact in size – Misalignment insensitive – Broadband
  • 51. Misalignment Insensitive Highly Efficient WPT Source Element TX 3D loop resonator Load Element RX 3D loop resonator 0 10 20 30 40 50 60 70 80 90 0 0.2 0.4 0.6 0.8 1 Angle() Normalized Efficiency Standard SCMR Embedded TX + Loops RX All Embedded Provisional patent # 61/658,636
  • 52. 50 100 150 200 0 10 20 30 40 50 60 70 80 90 100 Frequency (MHz) Efficiency(%) Distance = 7 cm Legends RX resonator RX load TX resonator TX Source Broadband & Highly Efficient WPT Provisional patent # 61/662,674 Measurements
  • 53. Legends RX resonator RX load TX resonator TX Source Design 2: Embedded 3-D loops Each 3-D loop comprises of three connected orthogonal loops •The RX and TX resonator elements as well as the source and load elements are 3-D continuous loops •Each 3-D loop comprises of three connected orthogonal loops. •The source and load loops are embedded inside the TX and RX resonators, respectively •This type of system has a spherical symmetry and therefore, it is expected to have misalignment insensitive performance.
  • 54. 0 10 20 30 40 50 60 70 80 90 0 10 20 30 40 50 60 70 80 90 Efficiency (%) Azimuth misalignment angle,  () Simulation Measurement   °   45°   90° Design 2- Embedded 3-D loops Angular Azimuth Misalignment
  • 56. Solar Antennas •Silicon in PV cell used as an antenna substrate •Novel Slot type Antenna •Gain 2-4dBi •Directive Pattern
  • 57. Motivation CHALLENGE Battery limits usability and autonomy An alternative source of energy is required to power up the device GOAL Power up an RFID node to allow communication from the body to the reader without the use of battery AVOIDING BATTERY REPLACING IN RFID BODY AREA NETWORK Body Area Network-Usage Scenarios Body life sign monitoring Fitness monitoring Wearable audio devices
  • 58. Wearable Tag Antenna Design Measured and Simulated Return Loss Far Field Radiation Pattern Bent antenna electromagnetic model of the foot 2.7 dBi @ 397 MHz
  • 59. Circuit Implementation SHDN GND Vset LBI LBO Vin Vout Sense GND ANT D0 GND D1 GND A9 A8 D4 A3 D5 A2 D6 D7 A1 A0 Vcc A7 TE A6 D2 D3 A5 A4 4.7 pF 1 MΩ 1.3 MΩ 1.3 KΩ Vcc Piezo Element 25:1 Transformer MAX666 TXE-433-KH2 Antenna Logo Antenna Diode Bridge Storage Capacitor MAX666 Voltage Regulator RF Transmitter Port to Antenna Connection to Transformer
  • 60. Circuit Implementation Capacitor voltage Max 666 output voltage 19 V 3V Transmitted signal captured by the RTSA V waveform of C and Regulator One Word Transmission ENERGY PROVIDED BY THE PUSHBUTTON stored in the capacitor 848.4 μJ UNUTILIZED ENERGY below 2.7 V capacitor voltage, the active RFID tag stops transmitting 17.1 μJ AVAILABLE ENERGY 848.4μJ - 17.1 μJ 831.3μJ ENERGY REQUIRED BY THE CIRCUIT FOR A ONE-WORD TRANSMISSION POWER needed for 50 ms operation: 9mW 450 μJ > 60 ms
  • 61. Human motion powered wireless tag Pilot and Sync. Bits 10-bit ID 8-bit Data Diode Bridge Storage Capacitor MAX666 Voltage Regulator RF Transmitter Port to Antenna Connection to Transformer Logo Antenna (a) (b) Nike logo printed antenna performance Step powered RFID communication Tag circuit
  • 62. Introduction Power Autonomous Unobtrusive Enabling Technology has to be Objective of this project  design a wearable, partially self-powered health monitoring and indoor localization shoe-mounted sensor module
  • 63. Localization: Overview Personal Area Network «Smart Tile» mapped matrix of NFC tags embedded in the floor for localization purposes Partially self-powered shoe-mounted NFC reader
  • 64. Dual-Band Wearable Adidas-Shaped Atnenna •Unobtrusive wearable antenna design • Dual Band: 900 MHz and 2.4 GHz •Deopsited nano particle silver ink on organic substrate (photo paper) technology
  • 65. System Architecture Description Temperature Sensor TI NFC Reader Board (Transceiver + MCU + Antenna) Dual-band (900 MHz and 2.4 GHz) Adidas- shaped Antenna NFC tags embedded into the floor for localization purposes
  • 66. Comparison Between Simulated and Measured Return Loss -50 -45 -40 -35 -30 -25 -20 -15 -10 -5 0 0.4 0.65 0.9 1.15 1.4 1.65 1.9 2.15 2.4 2.65 2.9 Mag. S11 (dB) Freq (GHz) Return Loss (dB) Simulation Measurement
  • 67. Simulated Antenna Radiation Patterns Freq=900 MHz Freq=2.4 GHz •Excellent performance in term of radiation pattern for both 900 MHz and 2.4 GHz standards, considering the presence of the foot •Gain > 3dB
  • 68. Localization: NFC system test Test  moving the tag from position 1 to 8 (shown in the figure) the maximum reading distance has been measured. The reader is placed at the center of the tile either vertically and horizontally.
  • 69. Why 6LoWPAN? •IPv6 over Low-power Wireless Personal Area Networks -> native support of the IPv6 protocol stack on the end device •A low-power communication protocol based on the IEEE 802.15.4 PHY and MAC layer •Backed up by an active IETF Working group with real prototypes •The network, transport and application layers of the 6lowPAN protocol stack (right) are the same as those of the IPv6 stack (left) and the necessary changes exist in the adaptation layer on top of the IEEE 802.15.4 medium access control and physical layer.
  • 70. Sensing site RF Wireless Pressure Transducer Processing Data Antenna functions as sensor Receiver Site  Fewer components  Smaller system size  Less power consumption
  • 71. Carbon Nanotubes as Gas Sensor CNTs structure can be conceptualized by wrapping a one-atom-thick layer of graphite into a seamless cylinder. Single-walled CNTs and Multi-walled CNTs A diameter of close to 1 nanometer, with a tube length that can be many thousands of times longer. CNTs composites have electrical conductance highly sensitive to extremely small quantities of gases, such as ammonia (NH3) and nitrogen oxide (NOx). The conductance change can be explained by the charge transfer of reactive gas molecules with semiconducting CNTs. Fabrication of CNTs film: -Vacuum Filtering, dip coating, spray coating, and contact printing, requiring at least two steps to achieve the patterns. -Can it be inkjet-printed? Yes, if you can develop the recipe!
  • 72. Inkjet-printed SWCNT Films Overlapping Zone 500um 10L 15L 20L 25L SWCNT Film Silver Electrode Silver electrodes were patterned before depositing the SWCNT film, followed by a 140˚C sintering. The electrode finger is 2mm by 10mm with a gap of 0.8mm. SWCNT film was 2mm by 3mm. 1.1mm overlapping zone to ensure the good contact between the SWCNT film and the electrodes.
  • 73. Gas Detection            P  P  G  G  d r t t r 10 10 40log 4 2 2 40log SWCNT Film @868MHz Z=51.6-j6.1 Ohm in air Z=97.1-j18.8 Ohm in NH3 Tag Antenna @ 686MHz Zant=42.6+j11.4 Ohm 2 * load ANT Ioad ANT Z Z Z Z     + +  Power reflection coefficient changes from - 18.4dB to -7.6dB. At reader’s side, this means 10.8dBi increase of the received power level.  By detecting this backscattered power differnce, the sensing function is fulfilled.
  • 74. Inkjet-Printed Graphene/CNT-Based Wireless Gas Sensor Modules Charge Transfer CNT Graphene Chemical Absorption ChangingMaterial Properties Measureable Electrical Quantities Gas Sensor Technology
  • 75. Inkjet-Printed Graphene/CNT-Based Wireless Gas Sensor Experiment ADC Input Graphene-based Inkjet-printed Gas Sensor Regulated 1.8 V • Prototype • Set-up
  • 76. The in-house developed novel sensor material demonstrates: - 6% normalized resistance change within 15 minutes of exposure to a concentration of 500 ppm of NH3. -excellent recovery time with over 30% of material recovery observed within 5 minutes without exposure to high temperature or any UV treatments. Inkjet-Printed Graphene-Based Wireless Gas Sensor Experiment
  • 77. Inkjet-Printed CNT-Based Wireless Gas Sensor Experiment 5 10 15 20 25 30 4 5 10 20 30 50 70 90 Sensitivity (%) Concentration (ppm) 864MHz NO2 864MHz NH3 2.4GHz NO2 2.4GHz NH3 ! ! 0 5 10 15 20 25 30 35 40 1 20 40 Sensitivity (%) Time (min) 864MHz NO2 864MHz NH3 2.4GHz NO2 2.4GHz NH3 10ppm Test Gas Nitrogen -Sensitivity of 21.7% and 9.4% was achieved for 10 ppm NO2 and 4 ppm NH3, respectively at 864 MHz -MWNT-based gas sensor demonstrates fast response to both gases (few seconds); the sensitivity achieved at 864 MHz is 24.2% for NO2 and 12.7% for NH3 in just 2 minutes’ time. Note that after testing, the sensor exposed to NH3 shows more rapid recovery
  • 78. Inkjet-Printed CNT-Based Wireless Gas Sensor Experiment 5 10 15 20 25 30 4 5 10 20 30 50 70 90 Sensitivity (%) Concentration (ppm) 864MHz NO2 864MHz NH3 2.4GHz NO2 2.4GHz NH3 ! ! 0 5 10 15 20 25 30 35 40 1 20 40 Sensitivity (%) Time (min) 864MHz NO2 864MHz NH3 2.4GHz NO2 2.4GHz NH3 10ppm Test Gas Nitrogen -Sensitivity of 21.7% and 9.4% was achieved for 10 ppm NO2 and 4 ppm NH3, respectively at 864 MHz -MWNT-based gas sensor demonstrates fast response to both gases (few seconds); the sensitivity achieved at 864 MHz is 24.2% for NO2 and 12.7% for NH3 in just 2 minutes’ time. Note that after testing, the sensor exposed to NH3 shows more rapid recovery
  • 79.
  • 80. Solar Powered Smart Skins for Structural Health Monitoring •Novel Antenna based smart skins detect strains and cracks in civil structures •Remotely interrogated using novel RF reader •Reader uses 2.9 GHz to remotely interrogate tag. Tag returns strain information using 5.8GHz for better strain sensitivity •Uses Solar Powered Frequency doubling mechanism for long range
  • 81. Solar Powered Smart Skins for Structural Health Monitoring •Latest prototypes show capability to detect 20 u-strain •Range extended to 10 meters through the use of Solar Power
  • 82. ATHENA  Power Scavevenging Technologies:  Mechanical Motion  Power Density: 4μw/cm2  Resonance: Hz  Thermal  Seebeck or peltier effect  Power Density: 60 μw/cm2  Wireless  Power Density ≤ 1μw/cm2  Solar  Power Density: 100 mw/cm2  Does Not require differential 936 MHz: -41dBm (0.08μw) Power Scavenging