The document presents the results of an environmental risk assessment for soil and air contamination by heavy metals in Baghdad, Iraq. Heavy metal concentrations were collected from previous studies of soil in residential, industrial, and commercial areas, and of air in residential and industrial areas. Potential health risks from exposure were calculated based on ingestion, dermal contact, and inhalation intake. Risks were highest for individual elements in both adults and children. Cumulative risk indices showed adults and children faced chronic health risks from exposure. The study aimed to assess health risks from heavy metals in Baghdad soil and air to compare to risks in other areas and identify risk-based remediation needs.
2. Dr. Nabaa Shakir Hadi
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soil of the Baghdad city because of overlapping set of factors increase the population of the city and
the consequent environmental problems resulting from the depletion of natural resources and
increasing waste of factories, landfills and increase the number of vehicles and other factors that lead
to the introduction of many pollutants into the soil. These problems have increased the risks of
environmental balance and ecosystem constituted a breach of the city [4].
Environmental Risk Assessment (ERA) which defined as a tool used to evaluate the risks due to
fate and transport of chemical in an environment which leads to harmful effects of receptors. ERA
includes examinations of risk caused by natural events (flooding, extreme, weather events, etc.),
technology, practice, processes, products, agents (chemical, biological, radiological, etc.) and
adversely affect posed by industrial activities [5]. In this thesis risk assessment concerns with human
health which defined as the process to estimate the nature and probability of adverse health effects in
humans, who may be exposed to chemicals in contaminated environmental media, exist or
potential[6].
Environmental Risk Assessments typically fall into one of two areas:
Human health risk assessment
Ecological risk assessment
Risk assessment addresses human health concerns and ecological risk assessment addresses
environmental media and organisms. This study deals with human health risk assessment.
2. AIM OF THE STUDY
Create a database for including heavy metals concentration in environmental soil and Air media at
contaminated sites in Baghdad City.
Create a database for including heavy metals concentration in environmental Iraq soil(Baghdad City)
with other data from different towns, (mean)
Calculate and assess human health risks associated with these contaminants from three exposure
routes(ingestion, dermal contact and inhalation) by using (ERA) tool.
Comprise between Environmental Risk Assessments for heavy metals in Iraq (Baghdad city) soil with
world soil.
3. HEALTH RISK ASSESSMENT
3.1. Hazard Identification
Hazard identification includes identifying those sources that cause damage to receptors, especially
human, living organisms, and ecosystem. This stage usually focuses on the most dangerous chemicals
(which are classified as hazardous chemicals on humans and sorted according to toxicity carcinogenic
or non-carcinogenic) [9].
3.2. Exposure Assessment
Exposure assessment defined as the estimation of the magnitude, frequency, duration, and route of
exposure. The purpose of exposure assessment is the estimation of the contaminant concentrations and
dosages to the populations at risk. More specifically, the primary tasks in exposure assessments
include:
Identifying potentially exposed populations,
Identifying potential exposure pathways,
Estimating exposure concentrations, and
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Estimating chemical intakes [7].
For estimation of Intake, EPA recommends the use of exposure data normalizedfortime andbody
weight, which is formulated into an equation for intake (I), the general equation for chemical in take
is:
=
( )( )( )
( )( )
(1)
Where:
I = intake (the amount of chemical at the exchange boundary) (mg/kg-day).
C = the average exposure concentration over the period (e.g., mg/L for water or mg/m3
for air and
mg/kg for soil).|
CR= contact rate, the amount of contaminated medium contacted per unit time (L/day or m3/day or
mg/day).
EFD = exposure frequency and duration, a variable that describes how long and how often exposure
occurs. The EFD is usually divided into two terms:
EF - exposure frequency (days/year).
ED = exposure duration (years).
BW = the average body mass over the exposure period (kg).
AT = averaging time; the period over which the exposure is averaged (days).
Basic formulas and values used for the calculation of ingestion and dermal of soil and ingestion,
dermal and inhalation of air are presented in Table (1&2).
Table 1 Contaminated media and corresponding routes of exposure [10].
Routes of exposureMedia
Ingestion, Dermal contactSoil
Ingestion, Dermal contact, Inhalation of airborne chemicalsAir
Table 2 Basic formulas used for calculation of intake for environmental media and exposure route [10].
EquationExposure
route
Environmental
media
=
( )( )( )( )( )( )
( )( )
Ingestion
Soil
=
( )( )( )( )( )( )( )( )
( )( )
dermal
=
( )( )( )( )
( )( )
IngestionAir
=
( )( )( )( )( )( )( )
( )( )
dermal
=
( )( )( )( )( )
( )( )
inhalation
Where:
ABS= absorption factor for soil contaminant, unit less
AD= absorbed dose, mg/kg.d
AF= soil-to-skin Adherence Factor, mg/c m2
.event.
4. Dr. Nabaa Shakir Hadi
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AT= averaging time, d
BW= body weight, kg
CA= contaminant concentration in air, mgm3
CDI= chronic daily intake, mg/kg.d
CF= volumetric conversion factor for water= 1L/1.000 cm3
= conversion factor for soil = 10-6
kg/mg
CR= contact rate, L/h
CS= chemical concentration in soil, mg/kg
CW= chemical concentration in water, mg/L
ED= exposure duration, y
EF= exposure frequency, d/y or events/y
ET= exposure time, h/d or h/event
EV = Event Frequency (events/day).
FI= fraction ingested, unit less
IR= ingestion rate, L/d or mg soil/d or kg/meal
= inhalation rate, m3
/h
PC= chemical-specific dermal permeability constant, cm/h
SA= skin surface area, cm2
.
4. EXPOSURE PARAMETERS
4.1. Soil Media
IR=200mg/day (child) and 100mg/day (adult) [7]
CF=0.000001kg/mg
FI=1[8].
EF=350 days/year [Residential], 250 days/year [Industrial, Commercial][7]
ED=30 years (adult)[Residential], 25 years (adult)[Industrial, Commercial]and 6 years (child) [7]
BW= (70kg for adult) and (15 kg for child) [10]
AT= (365*30) for adult and (365*6) for child. [7]
SA=5700 cm2
(adult) [Residential], 3300(adult) [Industrial, Commercial][11,12].
SA=2800 cm2
(child) [Residential], NA cm2
(child) [Industrial, Commercial][11,12].
AF=0.07mg/cm2
(adult)[Residential],0.2mg/cm2
(adult)[Industrial,Commercial][11,12]
AF=0.2mg/cm2
(child)[Residential],NAmg/cm2
(child)[Industrial,Commercial][11,12].
EV=1 event/d [3]
ABS = 0.001(adult), 0.03(child) [12,13].
4.2. Air Media
IR=20m3
/day (adult) and 5m3/day (child) [7].
ET=24 hour/day [7].
ED=70 year (carcinogen) [7].
AT=70*365[7].
The other parameter is the same used in previous items.
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4.3. Toxicity Assessment
Toxicity assessment expresses the acquisition and evaluation of Toxicity data for each contaminant
and then evaluated. This evaluation includes toxic carcinogenic and non-carcinogenic substances, In
this method, (RfDs) and (SFs) used for determining non-carcinogenic and carcinogenic toxicity
respectively. Almost all toxicity assessments make use of available data such as the list of reference
doses and slope factors; therefore, toxicity assessment often includes obtaining tabular RfDs and SF
information related chemicals to which receptors are exposed as shown in Table3.From this
quantitative dose response relationship, toxicity values (e.g., reference doses and slope factors) are
derived that can be used to estimate the incidence or potential for adverse effects as a function of
human exposure to the agent. These toxicity values are used in the risk characterization step to
estimate the likelihood of adverse effects occurring in humans at different exposure levels [14].
Table 3 Oral and Inhalation Slope Factors and RfDs[7].
Inhalation SF
(kg.day/mg)
Inhalation RfD
(mg/kg.day)
Oral SF
(kg.day/mg)
Oral RfD
(mg/kg.day)
Compound
6.10.0005Cadmium
410.005Chromium
0.3Zinc
0.02Nickle
0.0850.006Lead
For evaluating Dermal Exposure, Oral RfDs converted to Dermal RfDs By multiplying with
gastrointestinal absorption fraction (ABSGI), Oral SF can be converted to Dermal SF by dividing the
Oral SF by the ABSGI.
When ABSGI values are not available, USEPA recommends the following defaults for ABSGI:
80% for volatile organics; 50% for semi-volatile organics and nonvolatile organics; and 20% for
inorganic [8].
4.4. Risk Characterization
Risk characterization defined as the calculation of riskforbothnoncarcinogens and carcinogens for
allreceptors that maybeexposed to hazardouswastes. Some of the general requirements include
calculating risk for all of the exposure routes to hazardous chemicals (ingestion and inhalation and
dermal) for both noncarcinogens and carcinogens. Thel non-carcinogenicriskl is calculatedl as
Hazard Index (HI), which is thel ratio of the daily intake to the referenceldosel (RfDl
)[7].
= (2)
Where:
HI = hazard index (dimensionless).
I = intake (mg/kg.day).
RfD = reference dose (mg/kg.day).
Hazard Index <1.0 provides acceptable risk; however, the cumulative acceptable risk for all
contaminants and routes of exposure must be <1.0. If the hazard index is <1.0, the receptors are
exposed to concentrations that do not present a hazard. In such cases, detoxification and other
mechanisms allow the receptor exposure to the contaminant with no toxic effects. Note that the
quantitative value obtained for the HI is not a value of risk; that is, it does not provide a value for the
probability of harm as the result of exposure. Instead, the hazard index quantifies the absence of
effects from exposure to noncarcinogens [7]. To account HI for multiple substances in one way,
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EPA sums the hazard indexes for each constituent as follow:
Hazard Index T = ∑ HI
For multiple pathways:
Hazard Index T = ∑ HI
Where: i=the compound and j= pathways [13].
The carcinogenic risk may be defined as the chronic daily intake dose (developed in the exposure
assessment) multiplied by the carcinogenic slope factor (selected by the toxicity assessment).The
product is a real term: the probability of excess lifetime cancer from exposure to this chemical. The
computation is as follows:
Risk = CDI × SF (3)
Where:
Risk = the probability of carcinogenic risk (dimensionless).
CDI = chronic daily intake (mg/kg.day).
SF = carcinogen slope factor (kg.day/mg)[14].
In a like manner, the risk for multiple substances and pathways is estimated as:
Risk = risk
Where: i=the compound and j= pathways [14].
5. MATERIALS AND METHODS
5.1. Soil Media Samples
Were collected environmental data and information on soil contaminants in the city of Baghdad from
the previous studies. Selected stations located on different parts of the city of Baghdad for the purpose
of collecting samples of soil, plants have been distributed on a regular basis so as to cover most areas
of the city, with a focus on the type of each area as commercial, industrial or residential, as shown in
Table4.
Table 4 Samples of heavy metal in the soil of Baghdadcity[ 1].
Contaminants Concentration(mg/kg)MeanLocations
of samples
Environmen-
tal media PbNiZnCrCd
87.0686.7651.2423.090.29Roadside soilResidential
area
Soil
94.9080.4246.5126.460.23Open area soil
90.9883.5948.8824.770.26All soils
156.1480.8294.9232.690.94Roadside soilIndustrial
area 131.6888.6386.7235.240.93Open area soil
143.9184.7390.8233.960.93All soils
110.3072.7668.8824.210.45Roadside soilCommercial
area 103.8176.8560.0928.270.40Open area soil
107.0674.8164.4926.240.43All soils
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5.2. Air Media Samples
Table (5 & 6) shows the concentration of lead in air was taken from previous studies conducted in
Baghdad city as a trial for evaluation of lead in air from variable source at different type of stations as
follow:
A study evaluated air lead concentration in air-borne dust samples in Baghdad city as a result of
the industrial expansion and population increase and increasing number of cars at different locations in
industrial, residential region. Also study taken into account on the concentration of lead in streets-dust
samples in Baghdad city air.
5.3. Concentration of Lead in Baghdad City Air
Table 5 Lead concentration (ppm) in air-borne dust samples in Baghdad city air [2].
Lead
Concentratio
n
Sample
weight (gm)
Sampling
height(m)
District
name
Locations
of samples
Environme
nt-al
media
610.356Bunouk
Residential
area
Air
Air-borne
dust
290.98GroundAdhamiya
220.783Adhamiya
150.376Adhamiya
351.05GroundMansour
280.883Mansour
180.506Mansour
460.686Al-Atibaa
140.556Saydia
350.406Doura
850.476WaziriaIndustrial area
Table 6 Lead concentration (ppm) in streets-dust samples in Baghdad city air [2].
Lead ConcentrationDistrict nameLocations
of samples
Environmental
media
42Shaab
Residential area
areAir
streets-dust
51Al-Sadir
47Washash
38Mansour
24Al-Atibaa
95Waziria
Industrial area 211Shaikh Umar
170Shaikh Maarouf
5.4. Heavy Metals in Baghdad City Soil with World Soil
The environmental data of the concentrations of trace elements in soils and areas of Baghdad,
compared with the determinants of global concentrations in the soilwas taken from previous studies
[4], Table7 show summarize the comparison between the concentrations of trace elements in the soil
of the city of Baghdad with Bas soils in the world.
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Table 7 Comparison between heavy metal in Baghdad city soil with world soil.
ReferencePbNiZnCdCountry
[1]113.9881.0468.060.54Baghdad
[4]
48052220012USA
700803000-England
1805115676.7Sweden
6. RESULTS
Example of calculation of ingestion intake and non carcinogen HI of water (Cadmium -adult) by using
average value of concentration at Residential land use in Baghdad city by using suitable equation and
assumption.
I =
(CS)(IR)(CF)(FI)(EF)(ED)
(BW)(AT)
= (0.26mg/kg)(100mg/day)(0.000001kg/mg)(1)(350day/y)(30y) / (70 kg) (10950 day)
=3.56164×10-4
mg/kg.day
HI=I/RfD =3.56164×10-4
/0.0005=0.71232
By the same manner for each contaminants, exposure route and environmental media, the
following result were obtained. Indicators, abbreviations and units for parameters used were shown in
Table8.
Table 8 Indicators, Abbreviations and Units for parameter
Indicators Abbreviations Units
Ingestion Intake Iing mg/kg.day
Absorbed dose from dermal contact Ider mg/kg.day
Inhalation Intake Iinh mg/kg.day
Hazard Index for ingestion HIing -------
Hazard Index for dermal contact HIder -------
Hazard Index for Inhalation HIinh -------
Risk from ingestion Ring -------
Risk from dermal contact Rder -------
Risk from Inhalation Rinh -------
Reference Dose RfD mg/kg.day
Slop Factor SF kg.day/mg
Concentration Conc. mg/kg for soil , mg/m3
for air
Total noncarcinogen Hazard Index HI -------
Total carcinogen Risk R -------
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6.1. Soil Media
Table 9 Noncarcinogen Hazard Index and Carcinogen Risk for adult, at Residential area in Baghdad city.
Contamina
nt
HI (adult) (noncarcinogen) R (adult) (carcinogen)
HIing HIder HI
inh
+
+ HI )
R
ing
R
der
R
inh
+
+ R )
Cadmium 0.71232 2.84×10-6
0 0.71232 0 0 0 0
Chromium 6.78×10-3
2.70×10-5
0 6.81×10-3
0 0 0 0
Zinc 2.23×10-4
8.90×10-7
0 2.24×10-4
0 0 0 0
Nickle 5.72×10-3
2.28×10-5
0 5.74×10-3
0 0 0 0
Lead 0.02077 8.28×10-5
0 0.02085 0 0 0 0
∑∑ + + HI 0.74594 ∑∑ +
+ R )
0
Table 10 Noncarcinogen Hazard Index and Carcinogen Risk for child, at Residential area use in Baghdad city.
Contamina
nt
HI (child) (noncarcinogen) R (child) (carcinogen)
HIing HIder HI
inh
+
+ HI )
R
ing
R
der
R
inh
+
+ R )
Cadmium 6.64×10-3
5.58×10-4
0 7.19×10-3
0 0 0 0
Chromium 0.06333 5.32×10-3
0 0.06865 0 0 0 0
Zinc 2.08×10-3
1.74×10-4
0 2.25×10-3
0 0 0 0
Nickle 0.05343 4.48×10-3
0 0.05791 0 0 0 0
Lead 0.19386 0.016285 0 0.21014 0 0 0 0
∑∑ + + HI 0.34614 ∑∑ +
+ R )
0
Table 11 Noncarcinogen Hazard Index and Carcinogen Risk for adult, at Industrial area in Baghdad city.
Contamin
ant
HI (adult) (noncarcinogen) R (adult) (carcinogen)
HIing HIder HI
inh
+
+ HI )
R
ing
R
der
R
inh
+
+ R )
Cadmium 1.81×10-3
1.20×10-5
0 1.82×10-3
0 0 0 0
Chromium 6.64×10-3
4.38×10-5
0 6.68×10-3
0 0 0 0
Zinc 2.96×10-4
1.95×10-6
0 2.98×10-4
0 0 0 0
Nickle 4.14×10-3
2.73×10-5
0 4.17×10-3
0 0 0 0
Lead 0.02346 1.54×10-4
0 0.02361 0 0 0 0
∑∑ + + HI 0.03658 ∑∑ +
+ R )
0
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Table 12 Noncarcinogen Hazard Index and Carcinogen Risk for child, at Industrial area in Baghdad city.
Contamin
ant
HI(child)(noncarcinogen) R(child)(carcinogen)
HIing HI
der
HI
inh
+
+ HI )
R
ing
R
der
R
inh
+
+ R )
Cadmium 0.01698 0 0 0.01698 0 0 0 0
Chromium 0.06202 0 0 0.06202 0 0 0 0
Zinc 2.76×10-3
0 0 2.76×10-3
0 0 0 0
Nickle 0.03868 0 0 0.03868 0 0 0 0
Lead 0.21904 0 0 0.21904 0 0 0 0
∑∑ + + HI 0.33672 ∑∑ +
+ R )
0
Table 13 Noncarcinogen Hazard Index and Carcinogen Risk for adult, at Commercial area in Baghdad city.
Contamin
ant
HI(adult)(noncarcinogen) R(adult)(carcinogen)
HIing HIder HI
inh
+
+ HI )
R
ing
R
der
R
inh
+
+ R )
Cadmium 8.41×10-4
5.55×10-6
0 8.46×10-4
0 0 0 0
Chromium 5.13×10-3
3.38×10-5
0 5.16×10-3
0 0 0 0
Zinc 2.10×10-4
1.38×10-6
0 2.11×10-4
0 0 0 0
Nickle 3.65×10-3
2.41×10-5
0 3.67×10-3
0 0 0 0
Lead 0.01745 1.15×10-4
0 0.01756 0 0 0 0
∑∑ + + HI 0.02744 ∑∑ +
+ R )
0
Table 14 Noncarcinogen Hazard Index and Carcinogen Risk for child, at Commercial area in Baghdad city.
Contamin
ant
HI(child)(noncarcinogen) R(child)(carcinogen)
HIing HI
der
HI
inh
+
+ HI )
R
ing
R
der
R
inh
+
+ R )
Cadmium 7.85×10-3
0 0 7.85×10-3
0 0 0 0
Chromium 0.04792 0 0 0.04792 0 0 0 0
Zinc 1.96×10-3
0 0 1.96×10-3
0 0 0 0
Nickle 0.03415 0 0 0.03415 0 0 0 0
Lead 0.16295 0 0 0.16295 0 0 0 0
∑∑ + + HI 0.25483 ∑∑ +
+ R )
0
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6.2. Air Media
Table 15 Noncarcinogen Hazard Index and Carcinogen Risk for selected sites for adults in air-borne dust
samples in Baghdad city air.
R(adult)(carcinogen)HI(adult)(noncarcinogen)
District
name
Locations
of samples
+
+ R )
R
inh
R
der
R
ing
+
+ HI )
HI
inh
HI
der
HI
ing
1.41×10-3
1.41×10-3
002.7853901.90×10-5
2.78538Bunouk
Residential
area
6.75×10-4
6.75×10-4
001.3242109.05×10-6
1.32420Adhamiya
5.12×10-4
5.12×10-4
001.0045706.87×10-6
1.00456Adhamiya
3.49×10-4
3.49×10-4
000.6849304.68×10-6
0.68493Adhamiya
8.14×10-4
8.14×10-4
001.5981801.09×10-5
1.59817Mansour
6.51×10-4
6.51×10-4
001.2785408.74×10-6
1.27853Mansour
4.19×10-4
4.19×10-4
000.8219305.62×10-6
0.82192Mansour
1.07×10-3
1.07×10-3
002.1004601.43×10-5
2.10045Al-Atibaa
3.25×10-4
3.25×10-4
000.6392604.37×10-6
0.63926Saydia
8.14×10-4
8.14×10-4
001.5981801.09×10-5
1.59817Doura
1.41×10-3
1.41×10-3
002.7723501.10×10-5
2.77234WaziriaIndustrial
Area
Table 16 Noncarcinogen Hazard Index and Carcinogen Risk for selected sites for child in air-borne dust
samples in Baghdad city air.
R(child)(carcinogen)HI(child)(noncarcinogen)
District
name
Locations
of samples
+
+ R )
R
inh
R
der
R
ing
+
+ HI )
HI
inh
HI
der
HI
ing
1.65×10-3
1.65×10-3
003.2496504.36×10-5
3.24961Bunouk
Residential
area
7.86×10-4
7.86×10-4
001.5449202.07×10-5
1.54490Adhamiya
5.96×10-4
5.96×10-4
001.1720001.57×10-5
1.17199Adhamiya
4.06×10-4
4.06×10-4
000.7990901.07×10-5
0.79908Adhamiya
9.49×10-4
9.49×10-4
001.8645502.50×10-5
1.86453Mansour
7.59×10-4
7.59×10-4
001.4916402.01×10-5
1.49162Mansour
4.88×10-4
4.88×10-4
000.9589101.28×10-5
0.95890Mansour
1.24×10-3
1.24×10-3
002.4505603.29×10-5
2.45053Al-Atibaa
3.79×10-4
3.79×10-4
000.7458201.01×10-5
0.74581Saydia
9.49×10-4
9.49×10-4
001.8645502.50×10-5
1.86453Doura
1.64×10-3
1.64×10-3
003.23439003.23439WaziriaIndustrial
area
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Table 17 Noncarcinogen Hazard Index and Carcinogen Risk for selected sites for adults in streets-dust samples
in Baghdad city air.
R(adult)(carcinogen)HI(adult)(noncarcinogen)District
name
Locations
of
samples
+
+ R )
R
inh
R
der
R
ing
+
+ HI )
H
I
inh
HI
der
HI
ing
9.77×10-4
9.77×10-4
001.9178101.31×10-5
1.91780Shaab
Residentia
l area
1.18×10-3
1.18×10-3
002.3287701.59×10-5
2.32876Al-Sadir
1.09×10-3
1.09×10-3
002.1461201.46×10-5
2.14611Washash
8.84×10-4
8.84×10-4
001.7351601.18×10-5
1.73515Mansour
5.58×10-4
5.58×10-4
001.0958907.49×10-6
1.09589Al-Atibaa
1.57×10-3
1.57×10-3
003.0985001.22×10-5
3.09849Waziria
Industrial
area
3.50×10-3
3.50×10-3
006.8819502.72×10-5
6.88193Shaikh
Umar
2.82×10-3
2.82×10-3
005.5447002.19×10-5
5.54468Shaikh
Maarouf
Table 18 Noncarcinogen Hazard Index and Carcinogen Risk for selected sites for child in streets-dust samples
in Baghdad city air.
R(child)(carcinogen)HI(child)(noncarcinogen)District
name
Locations
of
samples
+
+ R )
R
inh
R
der
R
ing
+
+ HI )
H
I
inh
HI
der
HI
ing
1.13×10-3
1.13×10-3
002.2374703.01×10-5
2.23744Shaab
Residentia
l area
1.38×10-3
1.38×10-3
002.7169203.65×10-5
2.71689Al-Sadir
1.27×10-3
1.27×10-3
002.5038303.36×10-5
2.50380Washash
1.03×10-3
1.03×10-3
002.0243702.72×10-5
2.02435Mansour
6.51×10-4
6.51×10-4
001.2785401.71×10-5
1.27853Al-Atibaa
1.84×10-3
1.84×10-3
003.61491003.61491Waziria
Industrial
area
4.08×10-3
4.08×10-3
008.02891008.02891Shaikh
Umar
3.29×10-3
3.29×10-3
006.46879006.46879Shaikh
Maarouf
6.3. Comprise Iraq soil Media with World Soil
Table 19 Noncarcinogen Hazard Index and Carcinogen Risk for Adult, Average Heavy Metals in Iraq Soil
(Baghdad city).
Contamin
ant
HI (adult) (noncarcinogen) R (adult) (carcinogen)
HIing HIder HI
inh
+
+ HI )
R
ing
R
der
R
inh
+
+ R )
Cadmium 1.54×10-3
5.90×10-4
0 2.13×10-3
0 0 0 0
Zinc 3.24×10-4
1.24×10-4
0 4.48×10-4
0 0 0 0
Nickle 5.78×10-3
2.21×10-3
0 7.99×10-3
0 0 0 0
Lead 0.02713 0.01039 0 0.03752 0 0 0 0
∑∑ + + HI 0.04808 ∑∑ +
+ R )
0
13. Potential Health Risk Assessment for Soil and Air Heavy Metal Contamination in Baghdad City
http://www.iaeme.com/IJCIET/index.asp 248 editor@iaeme.com
Table 20 Noncarcinogen Hazard Index and Carcinogen Risk for Child, Average Heavy Metals in Iraq Soil
(Baghdad city).
Contamina
nt
HI (child) (noncarcinogen) R (child) (carcinogen)
HIing HIder HI
inh
+
+ HI )
R
ing
R
der
R
inh
+
+ R )
Cadmium 0.01440 0.05441 0 0.06881 0 0 0 0
Zinc 3.02×10-3
0.01143 0 0.01445 0 0 0 0
Nickle 0.05402 0.20416 0 0.25818 0 0 0 0
Lead 0.25328 0.95718 0 1.21046 0 0 0 0
∑∑ + + HI 1.5519 ∑∑ +
+ R )
0
Table 21 Noncarcinogen Hazard Index and Carcinogen Risk for Adult, Average Heavy Metals in USA Soil.
Contamin
ant
HI(adult)(noncarcinogen) R(adult)(carcinogen)
HIing HIder HI
inh
+
+ HI )
R
ing
R
der
R
inh
+
+ R )
Cadmium 0.03428 0.01313 0 0.04741 0 0 0 0
Zinc 0.01047 4.01×10-3
0 0.01448 0 0 0 0
Nickle 3.71×10-3
1.42×10-3
0 5.13×10-3
0 0 0 0
Lead 0.11428 0.04376 0 0.15804 0 0 0 0
∑∑ + + HI 0.22506 ∑∑ +
+ R )
0
Table 22 Noncarcinogen Hazard Index and Carcinogen Risk for Child, Average Heavy Metals in USA Soil.
Contamina
nt
HI(child)(noncarcinogen) R(child)(carcinogen)
HIing HIder HI
inh
+
+ HI )
R
ing
R
der
R
inh
+
+ R )
Cadmium 0.32 1.20928 0 1.52928 0 0 0 0
Zinc 0.09778 0.36950 0 0.46728 0 0 0 0
Nickle 0.03467 0.13100 0 0.16567 0 0 0 0
Lead 1.06667 4.03094 0 5.09761 0 0 0 0
∑∑ + + HI 7.25984 ∑∑ +
+ R )
0
Table 23 Noncarcinogen Hazard Index and Carcinogen Risk for Adult, Average Heavy Metals in England Soil.
Contamin
ant
HI(adult)(noncarcinogen) R(adult)(carcinogen)
HIing HIder HI
inh
+
+ HI )
R
ing
R
der
R
inh
+
+ R )
Cadmium --- --- --- --- -- -- -- ---
Zinc 0.01428 5.47×10-3
0 0.01975 0 0 0 0
Nickle 5.71×10-3
2.18×10-3
0 7.89×10-3
0 0 0 0
Lead 0.16667 0.06382 0 0.23049 0 0 0 0
∑∑ + + HI 0.25813 ∑∑ +
+ R )
0
14. Dr. Nabaa Shakir Hadi
http://www.iaeme.com/IJCIET/index.asp 249 editor@iaeme.com
Table 24 Noncarcinogen Hazard Index and Carcinogen Risk for Child, Average Heavy Metals in England Soil.
Contamina
nt
HI(child)(noncarcinogen) R(child)(carcinogen)
HIing HIder HI
inh
+
+ HI )
R
ing
R
der
R
inh
+
+ R )
Cadmium --- --- --- --- -- -- -- ---
Zinc 0.13333 0.50386 0 0.63719 0 0 0 0
Nickle 0.05333 0.20154 0 0.25487 0 0 0 0
Lead 1.55556 5.87846 0 7.43402 0 0 0 0
∑∑ + + HI 8.32608 ∑∑ +
+ R )
0
Table 25 Noncarcinogen Hazard Index and Carcinogen Risk for Adult, Average Heavy Metals in Sweden Soil.
Contamin
ant
HI(adult)(noncarcinogen) R(adult)(carcinogen)
HIing HIder HI
inh
+
+ HI )
R
ing
R
der
R
inh
+
+ R )
Cadmium 0.01914 7.33×10-3
0 0.02647 0 0 0 0
Zinc 7.46×10-3
2.85×10-3
0 0.01031 0 0 0 0
Nickle 3.64×10-3
1.39×10-3
0 5.03×10-3
0 0 0 0
Lead 0.04285 0.01641 0 0.05926 0 0 0 0
∑∑ + + HI 0.10107 ∑∑ +
+ R )
0
Table 26 Noncarcinogen Hazard Index and Carcinogen Risk for Child, Average Heavy Metals in Sweden Soil.
Contamina
nt
HI(child)(noncarcinogen) R(child)(carcinogen)
HIing HIder HI
inh
+
+ HI )
R
ing
R
der
R
inh
+
+ R )
Cadmium 0.17867 0.67518 0 0.85385 0 0 0 0
Zinc 0.06964 0.26318 0 0.33282 0 0 0 0
Nickle 0.034 0.12848 0 0.16248 0 0 0 0
Lead 0.4 1.51160 0 1.9116 0 0 0 0
∑∑ + + HI 3.26075 ∑∑ +
+ R )
0
7. DISCUSSION
This study which contained Environmental Risk Assessment (ERA) that estimating the amount and
seriousness of released pollutants. Which used in directories of environment for large filed (oral
exposure of inhabitants) in the Baghdad city indicated that the non-carcinogenic risk tends to become
significant for children and adults with exposure duration of 6yrs and 30yrs respectively.
1- Air media in Baghdad city was high polluted by lead, especially at industrial. Therefore inhalation
intake and risk were very high which may cause cancer or other diseases related to lead poisoning.
2- For soil media, noncarcinogen HI resulted from ingestion of soil was insignificant but the
cumulative non-carcinogenic risk resulted from dermal contact tends to become significant , mainly
15. Potential Health Risk Assessment for Soil and Air Heavy Metal Contamination in Baghdad City
http://www.iaeme.com/IJCIET/index.asp 250 editor@iaeme.com
for children , since it approaches unacceptable values and there was no particularly dangerous single
heavy metal , but their cumulative effect, , is for concern.
3-From the comparison between the results of the Noncarcinogen Hazard Index Adult and Child
[HIing+HIder+HIinh] for Heavy Metal in Baghdad city soil with World soil media as shown in Fig
[1&2], it was noticed that there were significant difference between the results in Baghdad city soil
with World soil.USA and England were high polluted by lead. therefore [ingestion intake and dermal
intake]risk were very high which may cause cancer or other diseases related to lead poisoning.
Figure 1 Noncarcinogen Hazard Index Adult [HIing+HIder+HIinh] for Heavy Metal in World Soil Media.
Figure 2 Noncarcinogen Hazard Index Child [HIing+HIder+HIinh] for Heavy Metal in World Soil Media.
8. ACKNOWLEDGMENT
Author is grateful to Prof. Dr. Mohammad Abed Muslim Al-Tufaily for the assistance given me to
complete the work study involved in writing this paper.
HIing+HIder
Baghdad USA England Sweden
HIing+HIder
Baghdad USA England Sweden
16. Dr. Nabaa Shakir Hadi
http://www.iaeme.com/IJCIET/index.asp 251 editor@iaeme.com
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