2. The detailed knowledge of electron
behaviour is essential since the
characteristics of an element depends
on the electron arrangement.
3. Atomic Orbital
An atomic orbital is the volume or region of space
around the nucleus where the electron being
described is most likely to be found.
4. Each atomic orbital is
characterized by:
Energy
Shape
Orientation in space
Direction of electron spin
5. Energy
The electron energy relates to the size of
the atomic orbital.
The farther the distance of the electron
from nucleus, the higher the distance of
the electron from the nucleus, the bigger is
the size of the atomic orbital and greater is
its energy.
HYDROGEN
LITHIU
M SODIU
M
POTASSIU
6. The main energy level (designated by the
number “n”) where the orbital is found is
designated by numbers (n = 1, 2, 3, 4, 5, 6, 7)
or letters (K, L, M, N, O, P, Q).
The number n is often referred to as principal
quantum number. So far, all known elements
have only enough electrons to occupy 7 main
energy levels.
n = 1 2 3 4 5 6 7
K L M N O P Q
7. Shapes
There are four different kinds of atomic
orbital based on shapes. Each kind is
distinguished by a second quantum
number designated by l.
The quantum number l could take values
from zero to n - 1. They are referred to as s
( l = 0), p ( l = 1), d ( l = 2) and f ( l = 3).
These kinds of orbital (s,p,d,f ) are referred
to as sublevels in each main energy level.
8. The main energy level in an atom actually
consists of sublevels of energy. It means
that although a number of electrons may be
found in the same main energy level, they
may actually be found in different sublevels
of energy. It means, electrons in a particular
main energy level do not really possess the
same amount of energy.
11. Pauli’s Exclusion Principle
Pauli’s Exclusion
Principle states that an
orbital cannot hold
more than 2 electrons
(Wolfgang Pauli, 1925)
12. The Pauli’s Exclusion Principle is
based on the following theories:
1. An electron
exhibits a spin:
clockwise or
counterclockwise
.
13. 2. When 2 electrons of opposite spins are
spinning or rapidly whirling in space, they
set up opposite magnetic fields which
attracts one another. This explains why only
2 electrons can occupy the same orbital.
Electrons with the same spin repel each
other.
14. 3. A third electron
will spin in a
direction similar
to either one of
the two
electrons in an
orbital, as a
result it will be
repelled or
pushed away
by the electron
with same spin.
15. Aufbau Principle
Aufbau Principle states that as soon as
an energy level is filled up with electrons,
any additional electron is thrown to the
next outer or higher energy level.
(formulated by Neils Bohr and Wolfgang
Pauli in the 1920s).
16.
17. Hund’s Rule
Hund’s Rule states
that electrons occupy
separate orbital in the
same subshell with
parallel spins first
before pairing
(Friedrich Hund, 1927)
19. The number or distribution or arrangement
of electrons in the energy levels of a
particular atom of an element. Example is
the electron configuration of helium
demonstrated below:
1
2
Main Energy
level
Orbital/ sublevel
No. of
electron in
the sublevel
20. We use the periodic table to identify the
main energy levels and sublevels
24. References:
Chemistry: Science and Technology Textbook for
Third Year. Quezon City: Vibal Publishing House,
2009.
Chemistry Textbook in Science and Technology
Third Year. Quezon City: SD Publications, Inc.,
2001.
www.wikipedia.com
Editor's Notes
What is the relationship between the number of electrons to the size of the atom?
Review the result of flame test. What do the colors in the slide represent?
Aufbau is a German noun that means construction or "building-up". The Aufbau principle is sometimes called the building-up principle or the Aufbau rule.
What do you think do the superscript 2 and subscript 1 in He symbol stands for?
What does the “n” stands for? For answer, review on the concept of electron energy in this presentation.