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The Atom
History and Theories




  All images from Wikipedia unless stated otherwise.
Atom


      The word atom means indivisible.

Indivisible means it can't be broken down into
            more things. Why not?

            Is this true for atoms?
John Dalton

   John Dalton was a British schoolteacher.

              He said that atoms:
       1. Everything is made of atoms.
2. Atoms of the same element are exactly alike,
 and atoms of different elements are different.
3. Atoms join with different atoms to make new
                  substances.
J .J . Thomson

  J. J. Thomson was another British
   scientist. In 1887 he discovered
                electrons.




Image/s: wikipedia
Plum Pudding Model


   J J Thompson
  suggested that
  electrons were
  mixed up in the
atoms like raisins in
 a 'plum pudding'.


Image/s: wikipedia
Earnest Rutherford
    Earnest Rutherford was a New Zealander. His
   famous 'gold foil' experiment showed that atoms
               must have a dense core.
            Rutherford's Conclusions:
        1. The atom is mostly empty space.
2. There is a small, dense, nucleus at the centre of
                       the atom.

If an atom was the size of a sports stadium, then
the nucleus (protons and neutrons) would be the
size of a pinhead in the centre, and the electrons
    would be orbiting around the outside of the
                     stadium.
Rutherford's Conclusions
       1. The atom is mostly empty space.
2. There is a small, dense, nucleus at the centre of
                      the atom.
Bohr's Model

Bohr (Danish) improved Rutherford's
Model by discovering that there are
  energy levels (called “electron
       shells”) for electrons.

Electrons can only be at set energy
 levels. Each energy level holds a
  maximum number of electrons.

  They are like rungs on a ladder.
Elements

   The number of protons is called the atomic
                   number.

  The atomic number tells us which element it
                belongs to.

  All the elements can be arranged by atomic
number in the periodic table. Which elements are
                     these?
The Nucleus


 Each particle in the nucleus has mass of 1
         Atomic Mass Unit (amu).

The mass number is the number of protons +
         the number of neutrons.
Electrons
                     8A not done
 Atoms are neutral if they have the same number of
              electrons as protons.

At om can l ose or gain el ect r ons t o becom ions.
     s                                        e

    If an at oml oses el ect r on/s, it becom a   es
    _ _ _ _ _ _ _ _ _ _ _ ion because it has m e  or
          _ _ _ _ _ _ _ t han _ _ _ _ _ _ _ _ _ .

     If an at omgains el ect r ons, it becom a   es
      _ _ _ _ _ _ _ _ _ ion because it has m e   or
           _ _ _ _ _ _ _ t han _ _ _ _ _ _ _ _ .
Electron Shells

Electrons orbit the nucleus in shells. They always
             fill the inside shell first.

  The first shell can contain up to 2 electrons.

The second shell can contain up to 8 electrons.

  The third shell can contain up to 8 electrons.

  The fourth shell can have up to 18 electrons.
Isotopes




All atoms have the same atomic number, which is the number
                      of _________.

 Atoms of the same element can have a different number of
                           neutrons.
           1. Are their atomic numbers the same?
           2. Are their mass numbers the same?
Animation
Make as many stable isotopes as possible, and record
them in the table: Start at the top of a page.
Element Name   Atomic Number   Mass Number   Nuclide Symbol
What is an Isotope
Isotopes are atoms with the same number of
  protons but different numbers of neutrons.
Since they have the same number of protons,
  they belong to the same element.
Since they have the same number of electrons,
  they react the same in chemical reactions. In
  nature, different isotopes are all mixed up.
However, some isotopes are radioactive (give off
 radiation) and some don't.
Example: Iodine
Iodine has many isotopes, but
  Iodine-127 is stable and most
  common.
  a) How many protons does it
  have?
  b) How many neutrons does it
  have?
  c) Write it as a nuclide symbol.

  Iodine is needed by the thyroid,
  which saves a supply of it.
  However about two billion
  people are deficient worldwide.
  Many countries add but too
  much is harmful. It is commonly    http://commons.wikimedia.org/wiki/File:Salt
  added to salt to prevent
Iodine-131
Iodine-131 is another isotope of iodine. It is
  radioactive (gives off radiation). It is produced in
  nuclear reactions and released only during
  nuclear accidents.
Since it has the same number of electrons as
  Iodine-127, the body thinks it is normal iodine,
  and saves it.
There have been about 6000 cases of thyroid
 cancer since the Chernobyl accident in (present
 day) Russia.
It can be easily prevented by taking pills of
  Iodine-127, as the body saves the Iodine-127 so it
  doesn't store any of the harmful Iodine-131.
Uranium Isotopes

Uranium has two common isotopes:
 Uranium-235, which is used for nuclear
 reactors (and weapons) and
 Uranium-238 is most common. Naturally
 these are mixed up.
What is the difference between the
 different isotopes of uranium? They
 cannot be separated using chemistry.
 How can they be separated?



                  http://en.wikipedia.org/wiki/File:Gas_centrifuge_cascade.jp
Animation
Make as many stable isotopes as possible, and record
them in the table: Start at the top of a page.
Element Name   Atomic Number   Mass Number          Nuclide Symbol

               1               1                    1
Hydrogen                                            1   H
Helium         2               3,4                      3
                                                        2   He , 4 He
                                                                 2

Lithium        3               6,7

Beryllium      4               7, 9, 10

Boron          5               10, 11

Carbon         6               11, 12, 13, 14, 15

Nitrogen       7               13, 14, 15, 16
Calculating the Atomic Mass


 The atomic mass number of an element is an
                 average.

76% of Chlorine has an atomic mass number of
                     35.
24% of Chlorine has an atomic mass number of
                     37.
 What is the atomic mass number of chlorine?
Ions
Neutral atoms have the same number of protons as electrons.
Atoms “like” (they can't think) to be neutral. But they “prefer”
 to have a full outside shell (called a valence shell).
Atoms “want” to lose or gain electrons to have a full outside
 shell. For example, Lithium could either gain ____ or lose
 _____ electrons.
Atoms lose or gain electrons by giving, receiving or sharing
 them with other atoms. This is called bonding, and is the
 basis of chemistry.
Ions are written as the element symbol with +s or -s to show
  electrons gained or lost. Eg
Atoms and Ions
        Element                Electrons it “wants”               Ion Symbol
                                to Lose or Gain

       Hydrogen*

         Lithium

        Beryllium

         Oxygen

         Flourine

          Argon

Additional blog note: According to what we learned, hydrogen could either gain or lose 1.
To become an ion, Hydrogen will always lose 1 to become H+.
Argon does not “want” to lose or gain any, because it already has a full valence shell.
Questions
1. Explain what an ion is.
2. Explain what is meant by the term “valence shell”.
3. What (in terms of ions) do Hydrogen, Lithium and
Sodium all have in common?
4. What (in terms of ions) do Oxygen and Sulfur have in
common?
5. What (in terms of ions) do Argon and Neon all have in
common?
6. How many electrons does a sodium atom “want” to
gain or lose, and why? How about a chlorine atom?
7. A sodium atom meets a flourine atom and explains her
need (from Q6) and the flourine atom explains hers in
turn. What arrangement could they come to? When they
do, what have they made?
Periodic Table

All elements can be arranged in the periodic table
              by ______________.

Rows are called periods. We will learn about them
                     soon.

  Columns are groups. What is the same about
             groups of elements?
Grouping the Elements


 A group is a column (going down) of elements.

  Elements in the same group usually have the
 same number of electrons in their outside shell.

Groups have similar reactivity. For example, alkali
          metals are very reactive.
Ions


An ion is an atom which has ________ or
________ electrons in order to have a full
        outer (__________) shell.

Atoms which can easily lose or gain up to
  three electrons in order to have a full
      ________ shell can form ions.
Ionic Bonds
In order to become an ion, an atom needs to find
another atom to 'give' its electrons to or take them
from. A positive ion and a negative ion then form
an ionic bond, making an ionic compound.

Example: Sodium Chloride:

   An excellent image of Sodium
   Chloride can be found here:

   http://www.school-for-champions.com/ch
Review
Draw atomic diagrams for magnesium-24 and
 chlorine-35.
What is the ratio of magnesium atoms to chlorine
 atoms for it to be balanced?
Write the name and the chemical symbol of the
 ionic compound created.

Blog note: Magnesium Chloride is known as
“Nigari” in Japanese, and is used to make tofu.
An image can be found here:
http://www.moris-diet.com/kasseiion/
Use the Cutouts and Make Formula
          for the Following:
                 Table salt (sodium chloride)
                      Lithium Fluoride
                     Hydrochloric Acid
                (hydrogen chloride- next unit)
                    Magnesium Chloride
                     Magnesium Oxide
                      Aluminium Oxide

  Write the chemical formula (eg MgCl2) under
                  each one.
Blog note: This was set for homework, and checked before Spring Break. Please make sure
you complete it if you haven't already.
Calcium Chloride
Calcium Chloride is a salt used to
 de-ice roads in cold conditions.
 1. What ions do calcium and
 chlorine make? Explain why. You
 may use a diagram, but you don't
 have to.
 2. How many of each atom will
 be needed to make calcium
 chloride? Explain why.
 3. Write the chemical formula for
 calcium chloride.
                    http://en.wikipedia.org/wiki/File:Calcium_chloride_CaCl2.jpg

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Chemical Reactions

  • 1. The Atom History and Theories All images from Wikipedia unless stated otherwise.
  • 2. Atom The word atom means indivisible. Indivisible means it can't be broken down into more things. Why not? Is this true for atoms?
  • 3. John Dalton John Dalton was a British schoolteacher. He said that atoms: 1. Everything is made of atoms. 2. Atoms of the same element are exactly alike, and atoms of different elements are different. 3. Atoms join with different atoms to make new substances.
  • 4. J .J . Thomson J. J. Thomson was another British scientist. In 1887 he discovered electrons. Image/s: wikipedia
  • 5. Plum Pudding Model J J Thompson suggested that electrons were mixed up in the atoms like raisins in a 'plum pudding'. Image/s: wikipedia
  • 6. Earnest Rutherford Earnest Rutherford was a New Zealander. His famous 'gold foil' experiment showed that atoms must have a dense core. Rutherford's Conclusions: 1. The atom is mostly empty space. 2. There is a small, dense, nucleus at the centre of the atom. If an atom was the size of a sports stadium, then the nucleus (protons and neutrons) would be the size of a pinhead in the centre, and the electrons would be orbiting around the outside of the stadium.
  • 7. Rutherford's Conclusions 1. The atom is mostly empty space. 2. There is a small, dense, nucleus at the centre of the atom.
  • 8. Bohr's Model Bohr (Danish) improved Rutherford's Model by discovering that there are energy levels (called “electron shells”) for electrons. Electrons can only be at set energy levels. Each energy level holds a maximum number of electrons. They are like rungs on a ladder.
  • 9. Elements The number of protons is called the atomic number. The atomic number tells us which element it belongs to. All the elements can be arranged by atomic number in the periodic table. Which elements are these?
  • 10. The Nucleus Each particle in the nucleus has mass of 1 Atomic Mass Unit (amu). The mass number is the number of protons + the number of neutrons.
  • 11. Electrons 8A not done Atoms are neutral if they have the same number of electrons as protons. At om can l ose or gain el ect r ons t o becom ions. s e If an at oml oses el ect r on/s, it becom a es _ _ _ _ _ _ _ _ _ _ _ ion because it has m e or _ _ _ _ _ _ _ t han _ _ _ _ _ _ _ _ _ . If an at omgains el ect r ons, it becom a es _ _ _ _ _ _ _ _ _ ion because it has m e or _ _ _ _ _ _ _ t han _ _ _ _ _ _ _ _ .
  • 12. Electron Shells Electrons orbit the nucleus in shells. They always fill the inside shell first. The first shell can contain up to 2 electrons. The second shell can contain up to 8 electrons. The third shell can contain up to 8 electrons. The fourth shell can have up to 18 electrons.
  • 13. Isotopes All atoms have the same atomic number, which is the number of _________. Atoms of the same element can have a different number of neutrons. 1. Are their atomic numbers the same? 2. Are their mass numbers the same?
  • 14. Animation Make as many stable isotopes as possible, and record them in the table: Start at the top of a page. Element Name Atomic Number Mass Number Nuclide Symbol
  • 15. What is an Isotope Isotopes are atoms with the same number of protons but different numbers of neutrons. Since they have the same number of protons, they belong to the same element. Since they have the same number of electrons, they react the same in chemical reactions. In nature, different isotopes are all mixed up. However, some isotopes are radioactive (give off radiation) and some don't.
  • 16. Example: Iodine Iodine has many isotopes, but Iodine-127 is stable and most common. a) How many protons does it have? b) How many neutrons does it have? c) Write it as a nuclide symbol. Iodine is needed by the thyroid, which saves a supply of it. However about two billion people are deficient worldwide. Many countries add but too much is harmful. It is commonly http://commons.wikimedia.org/wiki/File:Salt added to salt to prevent
  • 17. Iodine-131 Iodine-131 is another isotope of iodine. It is radioactive (gives off radiation). It is produced in nuclear reactions and released only during nuclear accidents. Since it has the same number of electrons as Iodine-127, the body thinks it is normal iodine, and saves it. There have been about 6000 cases of thyroid cancer since the Chernobyl accident in (present day) Russia. It can be easily prevented by taking pills of Iodine-127, as the body saves the Iodine-127 so it doesn't store any of the harmful Iodine-131.
  • 18. Uranium Isotopes Uranium has two common isotopes: Uranium-235, which is used for nuclear reactors (and weapons) and Uranium-238 is most common. Naturally these are mixed up. What is the difference between the different isotopes of uranium? They cannot be separated using chemistry. How can they be separated? http://en.wikipedia.org/wiki/File:Gas_centrifuge_cascade.jp
  • 19. Animation Make as many stable isotopes as possible, and record them in the table: Start at the top of a page. Element Name Atomic Number Mass Number Nuclide Symbol 1 1 1 Hydrogen 1 H Helium 2 3,4 3 2 He , 4 He 2 Lithium 3 6,7 Beryllium 4 7, 9, 10 Boron 5 10, 11 Carbon 6 11, 12, 13, 14, 15 Nitrogen 7 13, 14, 15, 16
  • 20. Calculating the Atomic Mass The atomic mass number of an element is an average. 76% of Chlorine has an atomic mass number of 35. 24% of Chlorine has an atomic mass number of 37. What is the atomic mass number of chlorine?
  • 21. Ions Neutral atoms have the same number of protons as electrons. Atoms “like” (they can't think) to be neutral. But they “prefer” to have a full outside shell (called a valence shell). Atoms “want” to lose or gain electrons to have a full outside shell. For example, Lithium could either gain ____ or lose _____ electrons. Atoms lose or gain electrons by giving, receiving or sharing them with other atoms. This is called bonding, and is the basis of chemistry. Ions are written as the element symbol with +s or -s to show electrons gained or lost. Eg
  • 22. Atoms and Ions Element Electrons it “wants” Ion Symbol to Lose or Gain Hydrogen* Lithium Beryllium Oxygen Flourine Argon Additional blog note: According to what we learned, hydrogen could either gain or lose 1. To become an ion, Hydrogen will always lose 1 to become H+. Argon does not “want” to lose or gain any, because it already has a full valence shell.
  • 23.
  • 24. Questions 1. Explain what an ion is. 2. Explain what is meant by the term “valence shell”. 3. What (in terms of ions) do Hydrogen, Lithium and Sodium all have in common? 4. What (in terms of ions) do Oxygen and Sulfur have in common? 5. What (in terms of ions) do Argon and Neon all have in common? 6. How many electrons does a sodium atom “want” to gain or lose, and why? How about a chlorine atom? 7. A sodium atom meets a flourine atom and explains her need (from Q6) and the flourine atom explains hers in turn. What arrangement could they come to? When they do, what have they made?
  • 25. Periodic Table All elements can be arranged in the periodic table by ______________. Rows are called periods. We will learn about them soon. Columns are groups. What is the same about groups of elements?
  • 26.
  • 27. Grouping the Elements A group is a column (going down) of elements. Elements in the same group usually have the same number of electrons in their outside shell. Groups have similar reactivity. For example, alkali metals are very reactive.
  • 28. Ions An ion is an atom which has ________ or ________ electrons in order to have a full outer (__________) shell. Atoms which can easily lose or gain up to three electrons in order to have a full ________ shell can form ions.
  • 29. Ionic Bonds In order to become an ion, an atom needs to find another atom to 'give' its electrons to or take them from. A positive ion and a negative ion then form an ionic bond, making an ionic compound. Example: Sodium Chloride: An excellent image of Sodium Chloride can be found here: http://www.school-for-champions.com/ch
  • 30. Review Draw atomic diagrams for magnesium-24 and chlorine-35. What is the ratio of magnesium atoms to chlorine atoms for it to be balanced? Write the name and the chemical symbol of the ionic compound created. Blog note: Magnesium Chloride is known as “Nigari” in Japanese, and is used to make tofu. An image can be found here: http://www.moris-diet.com/kasseiion/
  • 31. Use the Cutouts and Make Formula for the Following: Table salt (sodium chloride) Lithium Fluoride Hydrochloric Acid (hydrogen chloride- next unit) Magnesium Chloride Magnesium Oxide Aluminium Oxide Write the chemical formula (eg MgCl2) under each one. Blog note: This was set for homework, and checked before Spring Break. Please make sure you complete it if you haven't already.
  • 32. Calcium Chloride Calcium Chloride is a salt used to de-ice roads in cold conditions. 1. What ions do calcium and chlorine make? Explain why. You may use a diagram, but you don't have to. 2. How many of each atom will be needed to make calcium chloride? Explain why. 3. Write the chemical formula for calcium chloride. http://en.wikipedia.org/wiki/File:Calcium_chloride_CaCl2.jpg