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10. Here i will discuss about :
History
Introduction
Properties
Electrical applications
Other applications
Challenges
Presented by:
Muhammad Kashif Hanif
M.Sc Chemistry
University of Education,Lahore
Pakistan
11. Introduction
Graphene is an allotropic form of carbon
consisting of a single layer of carbon atoms
arranged in a hexagonal lattice.
It is a flat monolayer of carbon atoms tightly
packed into a two dimensional honeycomb
lattice.
An isolated single layer of graphite.
12.
13. Discovery:
Graphene was discovered by Russian Professor Andre
Gein and former student Konstantin Novoselov at the
university of manchestor, England in 2004.
They discovered thin graphene flakes on the scotch
tape, While cleaning a block of graphite.
They got Noble Prize for this ground breaking
achievement in 2010.
16. Structure:
It is composed of carbon atoms only that are
arranged together in a honeycomb like
structure.
It is a hexagonal 2D material comprising of sp2
hybridized carbon atoms.
Although it has single atom thickness yet it
can be seen with naked eye.
Covalent Bond
Carbon
17. Each atom has four bonds, three of which are σ and one is π-bond that
is oriented out of plane.
Its honeycomb like structure can bee seen with the help of :
• Transmission electron microscopy.
• Electron microscopy
• Optical microscope
22. • Strongest material ever
discovered, about 200 times more
stronger than steel with Young’s
Modulus of 1TPa. (for steel 0.2
Tpa).
• 1 square meter graphene
hammock would support a 4 kg
cat but would weigh only as much
as one of the cat's whiskers, at
0.77 mg.
23. This picture clarifies graphene’s
toughness, light weightness and
flexibility properties.
0.77mg of
graphene lifting
up a 4 kg cat.
Stronger than steel
25. Perfect graphene can
take about 100
Gigapascals (14 million
pounds per square inch)
of force before it breaks.
But the imperfect
graphene the
researchers made can
withstand about 4
Megapascals (580
pounds per square inch).
26. • Thinnest imaginable 2D material, just one atom thickness.(~0.345 nm thick)
• Hardest known material, four times harder than diamond.
• Most stretchable crystal ,can stretch upto 20% of its total volume.
29. One-atom-thick crystal.
Can be seen with the naked eye.
Absorbs approximately 2.3% of
white light while rest 97.7% is
transmitted.
FIG; 4 inch scale graphene film
on Stretchable Substrate
30. It would take 3 million stacked sheets of it to equal the width…
33. • Charge carriers behave
massless
• High mobility
5000 W/mK.
• High electrical, 1million times more
conductive than copper
conductivity about
• Zero Band Gap
• Least Resistivity 10-6Ω cm
36. Graphene can self-repair holes in its
sheets, when exposed to molecules
containing carbon, such as
hydrocarbons.
Bombarded with pure carbon
atoms, the atoms perfectly align
into hexagons completely filling the
holes.
StructuralStructural
38. Atoms have high degree of freedom due to 2D
structure and more production of phonons.
Because of it’s large specific area, smaller mass
density, and larger number of phonons that
transmit the heat away makes it thermal
conductivity excellent.
43. • Very fast recharge
• Longer life span
• Two sheet of graphene with electrolyte
in between
• May replace batteries
• High surface to mass ratio
• Highest current retention time
48. Will definitely replace silicon and germanium as a device
material.
Conducting material on PCBs.
Single molecule sensors
Touchscreens
Graphene chips.
It will replace copper as conducting material
54. Water Filtration :
It allows nothing to pass through it
except water,so it is perfect way for
water purification.
55. Rust RemovalRust Removal
• Most impermeable material
• Can be applied over rusting
substances by mixing with paints as
anti-corrosion material.
56. One of the biggest problem of the world today is to
manage nuclear waste as it is extremely dangerous
and highly radioactive.
Can be used as radiations adsorbent and thus waste
can be disposed off.
58. Graphene can be used for production LECs, inexpensive plastic-based lighting and
display components in the form of large flexible sheets. This kind of illumination or
display can be rolled up or can be applied as wallpaper or on ceilings.
59. It is attached to the rubber and polymers in
their stretching form, it contracts back with
these materials .It can be expanded again by
applying heat or electrical energy.
60. Night Vision CamerasNight Vision Cameras
If sensors of cameras are made from graphene, then it becomes
very easy to see in darkness.
So it is used for making night vision cameras and contact lenses.
62. Body armour
It can remain intact even if diamond is used to
perforate through it. Thus can be used to make super
strong body armour protecting the body.
63. Hair dying
Other hair diers are somewhat toxic while graphene
based hair diers are non-toxic, anti-bacterial and
thermal dissipation properties. A gel based on
graphene oxide is applied onto the hairs. Dyes can
remain even after more than 30 washes.
64. Detecting Cancer cells
Graphene can assist to detect cancer cells in the
body. Researchers in university of texas have
invented temporary Tatoos made from graphene
that can inform body’s vitals like dehydration, skin
temperature and even glucose level.
65. This idea arises in 1979 by arthur clark in a sci-fi novel
called the fountain of paradise. The elevator looked like a
tower having paper thin walls and hollow interior. Tower
was 12 miles apart and 22000 miles high.