2. Organic Chemistry of Esters
Esterification:
O O
R—C—OH + R’—OH R—C—O—R’ + H2O
ACID ALCOHOL ESTER
Carboxylic acid derivatives in which hydroxyl group
(-OH) is replaced by an alkoxy group (-OR)
3. Synthesis of Alkyl Polyglucosides
OH
O
OH
OH OH HO H+
OH +
n -H O
2
GLUCOSE FATTY
OH ALCOHOL
O
OH
OH O
OH
O
OH
OH O
OH
n
m
ALKYL
POLYGLUCOSIDE
4. Synthesis of Alkyl Polyglucoside Esters (AGEs)
OH
O
OH
OH O
OH
O
OH
OH O
OH
n
m
Alkylpolyglucoside
+
1) Maleic Anhydride 1) Citric Acid 1) Tartaric Acid
2) Sodium Sulfite 2) Sodium Hydroxide 2) Sodium Hydroxide
Alkylpolyglucoside Alkylpolyglucoside Alkylpolyglucoside
Sulfosuccinate Citrate Tartrate
5. AGEs Retain Favorable APG
Properties…
Free from dioxane,
Derived from Biodegradable, ethylene oxide, and
natural, renewable not harmful to nitrosamine
raw materials the environment precursors
Strong biological
Mild to skin and performance as
non-irritating to built-in and tank
the eyes mix adjuvants