7. Wave nature of electrons
λ=h/mvλ=h/mv
½ mv½ mv22
=eV=eV
λλ=h/=h/√2meV√2meV
8.
9.
10.
11. Electron beam hits the sample
Producing electron and photon signals
Collected by detectors and converted to a
voltage and amplified.
Applied to grid of CRT
Image is formed
12. Figures of Merit
-higher resolving power~0.1nm
-higher magnification~10,00,000X
-higher depth of field
13.
14.
15.
16.
17. Allows for the imaging of the surfaces of metals and semiconductors at
the atomic level.
Developed by Gerd Binnig and Heinrich Rohrer at the IBM Zurich
Research Laboratory in 1982.
The two shared half of the 1986 Nobel Prize in physics for developing
STM.
Binnig Rohrer
18. In classical physics e flows are not possible without a direct connection
On an atomic scale a quantum mechanical particle behaves in its wave
function.
An electron will “jump” from one surface to the other of lower potential.
How tunnelling works?????
"... I think I can safely say that nobody
understands Quantum Mechanics"
Richard P. Feynman
L
19. Basic Principles of STM
Electrons tunnel between the tip and sample, a small current I is
generated (10 pA to 1 nA).
d ~ 6 Å
Bias voltage:
mV – V range
Transmission Probability: T ≈ 16ε(1 – ε)e-2κL
20. Two Modes of Scanning
Constant
Height Mode
Constant
Current
Mode
Usually, constant current mode is superior.
21. Instrumental Design: Controlling the
Tip
Raster scanning
Precise tip control is achieved with
Piezoelectrics
Displacement accurate to ± .05 Å
22. Raster the tip across the
surface
The tip-surface
separation is controlled
to be constant by
keeping the tunneling
current at a constant
value.
The voltage necessary
to keep the tip at a
constant separation is
used to produce a
computer image of the
surface.
23. Advantages
No damage to the sample
Vertical resolution superior to SEM
Spectroscopy of individual atoms
Relatively Low Cost
Disadvantages
Samples limited to conductors and
semiconductors
Limited Biological Applications
Generally a difficult technique to
perform
Figures of Merit
Maximum Field of View: 100 μm
Maximum Lateral
Resolution: 1 Å
Maximum Vertical
Resolution: .1 Å
30. Wikipedia
Google
Scanning Tunneling Microscopy.” National Center for Photovoltaic at the National
Renewable Energy Laboratory. http://nrel.gov/measurements/tunnel.html
“The Nobel Prize in Physics 1986.” Nobel e Museum. http://www.
nobel.se/physics/laureates/1986/index.html
STM Image Gallery. http://www.almaden.ibm.com/vis/stm/gallery.html