3. Potentiometric Electrodes
• Electrode of the First Kind:
• Metal in contact with Cation: M/Mn+
• Example: Ag/Ag+
• Ag+ + 1 e- Ag(s)
• Nernst Equation:
• E = Eo
Ag+/Ag – 2.303RT/nF(log1/aAg+)
• Where aAg+ = activity of silver ion
• Emeasured = Ecell = Eind vs NHE = Eind – ENHE
• Why does Ecell = Eind ?
• Eref solution Eind
4. Potentiometric Electrodes
• Electrode of the Second Kind:
• General Form: MMXXn-
• Example: AgAgCl(S)Cl-
• AgCl + 1 e- Ag(s) + Cl-
• Nernst Equation:
• E = Eo
AgCl/Ag – 2.303RT/nF(log aCl-)
• What observation can you make about potential
for this electrode?