Lutes, C.C., C. Holton, E. Escobar, S. Steinmacher and L. Lund Using Climate Zones, Architectural Knowledge, and Low-cost Indicators to Build Efficient Vapor Intrusion (VI) Sampling Strategies; Presented at AWMA Annual Meeting June 2019, Quebec City, Canada.
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Lund Using Climate Zones, Architectural Knowledge, and Low-cost Indicators to Build Efficient Vapor Intrusion (VI) Sampling Strategies
1. www.jacobs.com | worldwide
Innovation that provides
sustainable solutions to
complex challenges worldwide
Using Climate Zones, Architectural Knowledge,
and Low-cost Indicators to Build Efficient
Vapor Intrusion (VI) Sampling Strategies
AWMA Annual Conference June 2019
CH2M is now Jacobs
Chris Lutes (Jacobs), Chase Holton (Jacobs,
Geosyntec), Elsy Escobar Ph.D. (Jacobs), Shirley
Steinmacher (Jacobs) and Loren Lund Ph.D.
(Jacobs)
2. Current VI Site Evaluation Practice
• Many jurisdictions assume that a one-time, very short exposure to TCE (24
hours or less) at trace concentrations could cause birth defects in
developing fetuses. But for other pollutants longer-term average exposure
is key.
• The degree of “temporal variability” is generally assumed, based primarily
on studies of only two houses, to be about 100x.
• The number of sampling rounds required is unclear. EPA guidance states
“multiple rounds”. Some states require four rounds (i.e., MI), while others
(e.g., NJ) allow one winter round
• Studies suggest that even four random air samples might not provide
adequate confidence in a determination of concentration below screening
levels
• At some sites as many as 10 rounds of samples have been collected
3. How VI Sampling is Currently Scheduled
• “Convenience sampling” – based on when funding
is approved, when the technician is available, or
soon after a particular stakeholder first requests
sampling to be done.
• US practice based primarily on data from a limited
number of climate zones
• Rough national rules of thumb – “winter is worst so
sample then” and “don’t sample for a few days after
heavy rain”.
• Little consideration is given to the particular
construction of the building or climate
characteristics of the locality in scheduling
sampling.
4. Developing a New, Improved Approach
• Conducted review capturing knowledge from these key fields:
‾ Building Science: i.e., ventilation, heating/cooling, comfort;
‾ Architecture: i.e., passive solar strategies; earth-sheltered strategies
‾ Climatology
‾ Multiple long-term VOC and Radon VI studies
This information helps us understand more specifically how particular buildings behave in
particular climates.
• Both historical/vernacular buildings and architect-designed buildings are
designed to work with the particular circumstances of climate to maintain
comfort.
• Comfortable conditions – controlled temperature and adequate ventilation are
related to vapor intrusion vulnerability
5. Climate Zone Systems:
USDA
• USDA system familiar to
ordinary citizen gardeners
Based on extreme
temperatures
• Correlation of stack effect
with short-term maximum
exposure possible
• Where “Winter is worst” VI
can rise exponentially as
temperature gets colder.
Reprinted from:
https://planthardiness.ars.usda.gov/PHZMWeb/
http://planthardiness.gc.ca/images/PHZ_2014_USDA_
Map_30M.pdf
6. Climate Zone
Systems: IECC
• International Energy
Conservation Code (IECC)
• Used in building codes and
by architects
• Temperature aspect based
on degree-days – so a
measure of full winter stack
effect – and thus exposure
• Also includes moisture
considerations Figure reprinted from https://www.greenbuildingadvisor.com/article/climate-
zone-map-including-canada
7. Climate Zone
Systems: AWS
Truepower Wind
Resource Map
• Wind speed and
direction can be
important to VI
variability
• Wind not considered in
standard climate zones
• US map looks very
different than
temperature based
zones!
9. Interpreting
Local Wind
Information
In buildings without heating
systems VI driving forces
more influenced by wind
loads then temperature.
Thus temporal variability
may have a complex pattern
governed by wind shifts and
how they interact with the
openings in the building.
Example of Monthly Wind Roses - Wilmington NC
from Iowa State University http://mesonet.agron.iastate.edu/sites/windrose.phtml?network=NC_ASOS&station=ILM
Figures from: Modeled
Wind Effect on Building
from Shirazi and Pennell,
Environ Sci: Process
Impacts, 2017, 19, 1594-
1607.
10. Examples of Climate Adapted Vernacular Houses
Historic house well adapted to New
England
• Compact design, minimizes surface/volume ratio.
• Long sloping roofs deflects wind over building
• Small window area on all sides
Historic house adapted to Coastal California
Mediterranean climate – near Santa Barbara
• Encourages natural ventilation
• Uses thermal mass for cooling
• Protected from summer sun.
Photo from http://thechoatenews.choate.edu/wp-content/uploads/2018/05/Screen-Shot-2018-05-11-at-11.33.56-PM.png Phtoo from https://scholarworks.gvsu.edu/reagans_rancho_del_cielo/14/
11. Understanding Air Exchange Rates (AER)
• AERs, which protect buildings from vapor intrusion, highest in
summer in many houses that use natural ventilation
• This is especially true in northern residences without air
conditioning. Opening windows and activating attic fans can have
dramatic effects.
• Thus temporal variability would be expected to be high in these
structures.
• Given the same soil gas concentrations, newer energy efficient
residences would be expected to have the highest indoor
concentrations. While older houses may have more leaky slabs
they also have the protective effect of wall and ceiling leakage.
12. What Have We Learned From Climate Zones?
• Several different systems of climate zones can each provide insight for VI
• Temperature is not always the controlling variable for temporal variability
• Buildings can be classified as:
‾ “envelope dominated” – generally small, such as residences and small office
buildings that would be more controlled by weather vs.
‾ “internally dominated” large, tight buildings where the HVAC must operate year
around to provide adequate ventilation (regardless of VI) and cooling (because of heat
given off by people and electrical equipment)
‾ “Internally dominated” buildings are less effected by climate and thus would be
expected to be less temporally variable.
13. Vapor Intrusion
Conceptual Site Model
– Single Structure
Graphic Reprinted from Quirouette “Air Pressure and The
Building Envelope”, 2004
WELL-MIXED
DIFFUSION
SOURCE
(Soil or GW)
ADVECTION +
DIFFUSION
v
v
v
v
v
Air Exchange
Qsoil
Csoil
Cracks
EBldg = QBldg.CBldg
Qsoil
Csoil
Rain
Infiltration
Intrusion through
pipes and joints
Smear Zone
Air Mixing
Stack
Effect
Air Mixing
Air
14. Indicators, Tracers and Surrogates (ITS):
Measurable Physical Features:
• Relatively low cost, continuous measurements
• Can be statistically compared to indoor CVOC conc. for possible associations
Temperature Pressure Radon
• Measurements revealing factors/forces driving VI at a particular site and
building
• Provides insight into VI driving forces & building-factors operating at the time of
cVOC sampling (i.e., concurrent non-static measurements)
Improves interpretation (meaning/value) of contemporaneous cVOC
samples
Focus sampling on times & places having exposures of concern
Reducing # of indoor CVOC samples needed; i.e., to make decisions with
quantified/doc. percentile (%ile) of exposure represented & confidence
levels
14
15. Heating Degree
Days in USEPA
Indianapolis
Duplex Study
As Indicator
15
0
2
4
6
8
10
12
14
16
18
20
0 50 100 150 200 250 300 350
PCEconcentration(µg/m3)
Heating Degree Days)
Weekly Total Heating Degree Days vs. PCE Concentration 422
Base South; Mitigation Off or Not Installed Data Only
ColdestWarmest
16. Is Winter Always Worst?
• Underlying assumption - stack effect
caused increase in soil gas entry rate
will dominate temporal variability
• Air exchange rates can also be high in
cold weather in older structures.
• Several exceptions noted – sites with
strong shallow subslab sources, in far
northern climate, where temperature
effects on volatility dominate
• “Winter is worst” is not always true;
but very often true – we can better
identify cases that are likely to be
exceptions now.
Barnes, David L., and Mary F. McRae.
Atmospheric environment 150 (2017): 15-23.
17. Sites Providing
Large/Long Term
Data Sets across
the IECC Climate
Zones
IECC zones Reprinted form
https://basc.pnnl.gov/images/iecc-climate-zone-
map
Sun
Devil
Manor
UT
Indianapolis
Duplex
San
Antonio
MEW and Moffett Field CA
Redfield
and
Colorado
DOT
San Diego
Yorktown VA
Wendell and
Gaffney AK CRREL
(NH)
Bradford VT
17
18. Cases With Large Temporal Data Sets We are Comparing – Part 1
Case Building Type
IECC
Climate
Zone Conceptual Site Model
ΔP or
BP
ΔT1
Rn
Sun Devil Manor, Layton
UT
Single family residential,
modern
5B TCE in groundwater plume intersecting
with neighborhood scale preferential
pathway
EPA duplex, Indianapolis
IN
Duplex, historic 5A PCE, TCE, CF in groundwater plume
from multiple dry cleaners intersecting
with neighborhood scale preferential
pathways (CSO)
San Antonio, Bexar
County, TX
Single family residence
(multiple)
2A Groundwater plume, (non-”winter
worst”), PCE
Middlefield-Ellis-
Whisman and Moffett
Superfund Sites, CA
Commercial steam heated with
AC, occupied 24x7; contains
office space
3C Groundwater plume, TCE, cis-1,2-DCE
Orion Park Moffett field,
CA
Two-story connected
townhouses
3C Groundwater plume, TCE; sub-slab
spatial variability
1 measured (can also be estimated retrospectively from Tout from weather records with Tin assumption) 18
19. Cases With Large Temporal Data Sets We are Comparing – Part 2Page 2
Case Building Type
IECC
Climate
Zone
Conceptual Site Model
(primary contaminants,
source)
ΔP
or
BP
ΔT1
Rn
Yorktown VA Large commercial, unheated 3A Soil and groundwater source
beneath building, TCE;
solvents in degreasers
San Diego North
Island CA
Large Commercial Office 3B TCE, soil and groundwater;
building has history of
carpentry, machining, Tidal
Cold Regions
Research
Laboratory, NH
Large commercial office and
laboratory
6A TCE in soil, DNAPL and
groundwater plumes; process
leaks, spills
Redfield CO Single family homes
(hundreds)
5B TCE, 11-DCE in groundwater
plume; metalworking spills
CDOT MTL CO Mainly large apartment
buildings, few single family
5B TCE, 11-DCE in groundwater
plume; metalworking spills
*
Wendell and
Gaffney Sites in
Fairbanks, AK
Small commercial buildings 8 Soil sources from dry
cleaners, also shallow
groundwater impacts, non-
winter worst
Vermont sites (2),
Bradford VT
1) 6,000 sq ft Office and
45,000 sq ft manufacturing
and storage; 2) 2,800 sq ft
railroad depot (now
restaurant)
6A PCE in soil and groundwater
plume from former dry
cleaners
* is not long-term data but pre- and post mitigation for brief periods
1 outdoor-indoor measured (can also be estimated retrospectively from Tout from weather records and Tin assumption) 19
20. 0.01
0.1
1
10
100
1000
SDM (Layton,
UT), TCE , 24-
hour avg.
Indy, 422
Base. South,
Before
Mitigation,
Chloroform
Indy, 422
Base. South,
Before
Mitigation
PCE
Indy, 422 First
Floor, Before
Mitigation
Chloroform
Indy, 422 First
Floor, Before
Mitigation
PCE
MEW
Location 15-1
TCE
MEW
Location 15-1
Cis-1,2-DCE
Yorktown
Shed 3
Midway TCE
Yorktown
Shed 3 Front
Office TCE
Yorktown
Shed 6 Lunch
Room TCE
Yorktown
Shed 6 Big
Room TCE
Gaffney
Alaska PCE
Wendell
Alaska PCE
VOCIndoorAirConcentration(ug/m3) Temporal Variability: Box and Whisker Chart of Multiple Sites
Sixteen Hour to One Week Durations; VI Dominated; Four Season Data Sets
N=723
N= 61
N=155
N=80
N=83
N=27
N=32
21. 0
20
40
60
80
100
120
140
<X/128
X/128toX/64
X/64toX/32
X/32toX/16
X/16toX/8
X/8toX/4
X/4toX/2
X/2toX
Xto2X
2Xto4X
4Xto8X
8Xto16X
16Xto32X
32Xto64X
64Xto128X
>128X
Frequency
Multiple of Mean
Sun Devil Manor 24 Hr TCE
0
5
10
15
20
25
30
35
Frequency
Multiple of Mean
Indianapolis 422 Basement PCE
0
5
10
15
20
25
30
35
Frequency
Multiple of Mean
Indianapolis 422 FirstFloor PCE
0
5
10
15
20
25
Frequency
Multiple of Mean Concentration
Indianapolis 422 FirstFloor
Chloroform
0
10
20
30
40
50
60
70
Frequency
Multiples of Mean
MEW Location 15-1 TCE
0
10
20
30
40
50
60
70
80
<X/128
X/128toX/64
X/64toX/32
X/32toX/16
X/16toX/8
X/8toX/4
X/4toX/2
X/2toX
Xto2X
2Xto4X
4Xto8X
8Xto16X
16Xto32X
32Xto64X
64Xto128X
>128X
Frequency
Normalized Concentration
MEW Location 15-1: 1,2-DCE
0
5
10
15
20
25
30
35
40
<X/128
X/128toX/64
X/64toX/32
X/32toX/16
X/16toX/8
X/8toX/4
X/4toX/2
X/2toX
Xto2X
2Xto4X
4Xto8X
8Xto16X
16Xto32X
32Xto64X
64Xto128X
>128X
Frequency
Multiples of Mean
Yorktown Shed 3 Midway, TCE
0
5
10
15
20
25
30
Frequency
Multiples of Mean
Yorktown Shed 3 Front Office TCE
0
5
10
15
20
25
30
<X/128
X/128toX/64
X/64toX/32
X/32toX/16
X/16toX/8
X/8toX/4
X/4toX/2
X/2toX
Xto2X
2Xto4X
4Xto8X
8Xto16X
16Xto32X
32Xto64X
64Xto128X
>128X
Frequency
Multiples of Mean
Yorktown Shed 6 Lunch Room TCE
0
5
10
15
20
25
<X/128
X/128toX/64
X/64toX/32
X/32toX/16
X/16toX/8
X/8toX/4
X/4toX/2
X/2toX
Xto2X
2Xto4X
4Xto8X
8Xto16X
16Xto32X
32Xto64X
64Xto128X
>128X
Frequency
Multiples of Mean
Yorktown Shed 6 Big Room TCE
0
2
4
6
8
10
12
14
16
Frequency
Multiples of Mean
Gafney PCE
0
1
2
3
4
5
6
7
8
9
10
<X/128
X/128toX/64
X/64toX/32
X/32toX/16
X/16toX/8
X/8toX/4
X/4toX/2
X/2toX
Xto2X
2Xto4X
4Xto8X
8Xto16X
16Xto32X
32Xto64X
64Xto128X
>128X
Frequency
Multiples of Mean
Wendel PCE
Comparing Multiple Site Temporal
Variability Distributions Using
Histograms Normalized as Multiples
of the Mean
0
5
10
15
20
25
Frequency
Multiple of Mean
Indianapolis 422 Basement
Chloroform
22. We Now Have a Basis to Evaluate Key Questions For Your Site
• What is the most efficient sampling strategy to determine required “reasonable
maximum exposure”? How many sampling rounds are enough?
• Can I “hurry the process” with controlled pressure testing vs. waiting for the
weather/seasons?
• How large a range of temporal variability should I expect in this particular
building?
• From the two samples I have already taken, can I project how bad my third and
fourth samples could reasonably be expected to be?
• How can Indicators, Tracers and Surrogates help us better understand the
controls on vapor intrusion in particular buildings?
More data sets are needed to refine these concepts!
23. Acknowledgements
• Robert Truesdale RTI, Brian Schumacher, and John Zimmerman (EPA)
• Jay Clausen (US Army CRREL)
• David Barnes, (University of Alaska Fairbanks)
• Jeff Kurtz (Geosyntec)
• Henry Schuver, Matthew Plate, Alana Lee, Ralph Dollhopf, (EPA)
• Vitthal Hosangadi (NOREAS)
• Blayne Hartman, Mark Kram (Groundswell Technologies)
• Jill Johnston (UNC, USC)
• Alan Rossner and Michelle Crimi (Clarkson University)
Current practice is very much one site fits all, or dependent on jurisdictional judgment, not climate and building type.
Architects go to school to learn how to make a building work well in a given climate. But societies also have centuries of experience in what building features make them comfortable and use less energy that gets passed down as traditions. The conditions that make for comfort – temperature control and ventilation
The canonical VI sites on which policy is based (Sun Devil Manor, Endicott NY, Redfield CO, Indianapolis) are mostly groundwater sites in the blue and green zones.
The canonical VI sites on which policy is based (Sun Devil Manor, Endicott NY, Redfield CO, Indianapolis) are mostly groundwater sites in the blue and green zones.
If wind controls temporal variability…note importance of coasts and great lakes.
Introduce the key, red is highest blue is lowest.
A substantial percentage of commercial buildings don’t have central forced air heating and cooling systems
Here is an example of how wind interacts with buildings
But not all commercial buildings will be internally dominated, many commercial buildings like warehouses have lots of openings and so may be envelope dominated
Taller buildings have stronger stack effects, and thus would be expected to have more temporal variability if all else were equal.
Only about 60% of US commercial buildings are heated throughout. In a population of buildings at a given site, the strongest indoor/outdoor temperature differentials, and thus the strongest stack effects would be expected in temperature controlled buildings.
Simple example here of an indicator
Note how many of the key examples that guide VI policy are from zone 5 or 6 (SDM, Indianapolis, Redfield, Endicott (not shown on figure))….
This is the first time so many sites with large datasets (n=27 to 593) have been viewed on comparable scales
The interquartile range for most sites is relatively narrow – SDM the exception.
Long term means are near or sometimes even above the 75th percentile.
Total range of temporal variability is typically around 2 orders of magnitude.
Similar degree of temporal variability for commercial buildings to Indianapolis case.
Similar temporal variability across a wide range of geographies
This allows us to begin to developed statistical estimates of temporal variability for more buildings in diverse climates
Overview of format: Centered around the mean of the distribution, allows shapes of distributions to be compared.
Sun Devil Manor has the widest distribution – also more truncated because it has the most nondetects.
At most of these sites samples the chance of seeing a sample >4X the long term mean are quite low.
These are mostly quite old buildings, but there doesn’t appear to be a radical difference industrial vs. residential.