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Chemistry Lectures By Al-Chemist
Youtube Channel 1/9/2021
1/9/2021
Chemistry Lectures By Al-Chemist
Youtube Channel
 Chemical kinetics - speed or rate at which a
reaction occurs
 How are rates of reactions affected by
◦ Reactant concentration?
◦ Temperature?
◦ Reactant states?
◦ Catalysts?
Chemistry Lectures By Al-Chemist
Youtube Channel 1/9/2021
Chemical Equilibrium = how far
Chemical kinetics = how fast
 The domain of chemistry in which we study
the speed with which the reaction proceeds
and the factors affecting the speed or rate.
 Hence,
 1. Rate of Reactions
 2. Factors Affecting The Reaction rate
 3. Pathway of a reaction from reactants to
products
1/9/2021
Chemistry Lectures By Al-Chemist
Youtube Channel
 The rate of a chemical reaction is defined as
the change of concentration of reactants or
product divided by the time taken for the
change.
 Rate of Reaction= Change in concentration
Time taken for change
The rate of Reaction never remains uniform
during the course of reaction. It decreases
continuously till the reaction stops
1/9/2021
Chemistry Lectures By Al-Chemist
Youtube Channel
 Rate of a Reaction=moles dm -3
Seconds
= moles dm -3 Sec- 1
1/9/2021
Chemistry Lectures By Al-Chemist
Youtube Channel
 The rate at any one instant is called
Instantaneous rate
 Consider the following reaction
A + B  C
 Define the instantaneous rate of consumption
of reactant A, A
 
dt
Ad
A 
 The reaction rate during two specific intervals
is called Average rate of a reaction
 Average rate=dx/dt
 During the start of reaction Instantaneous
rate is higher than average rate.. Near the end
the reverse happens
 As the time interval becomes smaller
Instantaneous rate becomes closer to average
rate
1/9/2021
Chemistry Lectures By Al-Chemist
Youtube Channel
 If a reaction proceeds in more than one steps
the slowest step shall be counted as the rate
determining step
 A+B--------- D
 A+B--------- C --------(i) fast
 C+B--------- D--------(ii) slow
 Ii will rate determing step
1/9/2021
Chemistry Lectures By Al-Chemist
Youtube Channel
1/9/2021
Chemistry Lectures By Al-Chemist
Youtube Channel

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Chemical kinetics lec 1

  • 1. Chemistry Lectures By Al-Chemist Youtube Channel 1/9/2021
  • 2. 1/9/2021 Chemistry Lectures By Al-Chemist Youtube Channel
  • 3.  Chemical kinetics - speed or rate at which a reaction occurs  How are rates of reactions affected by ◦ Reactant concentration? ◦ Temperature? ◦ Reactant states? ◦ Catalysts? Chemistry Lectures By Al-Chemist Youtube Channel 1/9/2021 Chemical Equilibrium = how far Chemical kinetics = how fast
  • 4.  The domain of chemistry in which we study the speed with which the reaction proceeds and the factors affecting the speed or rate.  Hence,  1. Rate of Reactions  2. Factors Affecting The Reaction rate  3. Pathway of a reaction from reactants to products 1/9/2021 Chemistry Lectures By Al-Chemist Youtube Channel
  • 5.  The rate of a chemical reaction is defined as the change of concentration of reactants or product divided by the time taken for the change.  Rate of Reaction= Change in concentration Time taken for change The rate of Reaction never remains uniform during the course of reaction. It decreases continuously till the reaction stops 1/9/2021 Chemistry Lectures By Al-Chemist Youtube Channel
  • 6.  Rate of a Reaction=moles dm -3 Seconds = moles dm -3 Sec- 1 1/9/2021 Chemistry Lectures By Al-Chemist Youtube Channel
  • 7.  The rate at any one instant is called Instantaneous rate  Consider the following reaction A + B  C  Define the instantaneous rate of consumption of reactant A, A   dt Ad A 
  • 8.  The reaction rate during two specific intervals is called Average rate of a reaction  Average rate=dx/dt  During the start of reaction Instantaneous rate is higher than average rate.. Near the end the reverse happens  As the time interval becomes smaller Instantaneous rate becomes closer to average rate 1/9/2021 Chemistry Lectures By Al-Chemist Youtube Channel
  • 9.  If a reaction proceeds in more than one steps the slowest step shall be counted as the rate determining step  A+B--------- D  A+B--------- C --------(i) fast  C+B--------- D--------(ii) slow  Ii will rate determing step
  • 10. 1/9/2021 Chemistry Lectures By Al-Chemist Youtube Channel
  • 11. 1/9/2021 Chemistry Lectures By Al-Chemist Youtube Channel