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Advancement in Sportech
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ADVANCEMENTS IN SPORT TEXTILE
Abstract
As we all know that sports textiles holds a great potential in the textile sector, it has
proved its dominance by the incorporation of smart textiles into ultimate goal of providing
comfort, protection, thermal insulation, moisture management and heat regulation to the
wearers. Smart textiles are inheriting of artificial intelligence into the sportswear. To simply
say smart textiles sports wears are to be under stood as self-thinking garments. It is of at most
important that we discuss and know about active smart textiles that are dominating in the
sports textiles. The prime objective of this paper to bring out the importance of active smart
textile materials like phase change material, shape memory material, auxetic materials,
holofibeand d3o materials. These material‟s principal, working mechanisms, properties,
methods of incorporation in textiles and its application in sports textiles are highlighted in
this paper. More over smart textiles in sportswear has played its key role in the London
Olympics 2012, which is also clearly proved in this paper, which gives clear evidenceof the
contribution of textiles for technology and development of standard of human life. Smart
textiles have come out with solutions for various researches carried out by the scientists and
multinational companies investing millions of dollars in it. The phase change materials are
used in wears of athletes, football, mountain climbing and snow skiing, where extreme
climatic conditions are to be tackled. The d3o materials are used in bike race, jumping events
and rugby where high impact forces are involved.
Introduction
The sports textile has taken its place from the floor (Ex. Artificial turf)
to the roof (Ex. PTFE roofing). The consumption of textile material used in sports was
1382000 tons in 2010. This figure itself shows the potential of the textile in sports sector
Sportech segment comprises of technical textile products used in sports (sportswear, sports
equipment and sports footwear)
Examples of sportswear are: aerobic clothing, athletic clothing, football clothing,
cricket clothing, games shorts, gloves, jackets, pants, shirts, shorts, socks, swimwear and
tennis clothing. Examples of sport equipment are: sails, trampolines, camping gear, leisure
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bags, bikes and rackets. Examples of sports footwear are: athletic shoes, football boots, gym
shoes, tennis shoes and walking boots.
Basically Textile materials were designed for having protection against extreme
natural condition of heat and cold, then gradually the purpose of clothing until it took a new
face (In the name of trend , ascetic use , and many more)now a days they are designed for
specific purposes and tasks.
In earlier days mostly cotton was preferred, with innovations and raise in requirement
blends of fibre like cotton/polyester, cotton/viscose and polyester/viscose were used. Smart
textile is expected to solve all the demands and the shortcomings of the sportsman like
moisture level maintenance, heat regulation, comfort, protection from UV rays and protection
against various impact forces.Smart textile materials readily interact with
human/environmentalconditions thereby creating changes in the material properties. For
example, thephase-change materials and shape-memory polymers embedded in fabric
layerswill be able to interact with a human body and produce thermoregulatory controlby
affecting the microclimate between the clothing and the human skin. Inaddition to the two
dimensions of functionality and aesthetics, if `intelligence'can be embedded or integrated into
clothing as a third dimension, it would leadto the realization of protective and safety clothing
as a personalized wearableinformation infrastructure.
Properties required for Sportswear
 The clothing should be capable of protecting the wearer from external climatic
conditions such as wind, sun, rain and snow, extreme temperatures.
 Good tactile properties
 Thermal insulation
 Good stretch ability
 Being capable of transporting perspiration from skin and then quickly dispersing it.
 Fabric should be capable of protecting the wearer from any impact forces.
 Good energy storing/ absorbing capacity
 The fabric should be designed in such a way that the wearer should experience less
drag (due to air or water).
 Fabric should provide psychological comfort to the wearer.
 Maintain the body temperature by thermoregulation.
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Necessity in advancement (up gradation) of materials
 High strength
 Flame and heat resistance.
 High specific strength and modulus
 High chemical resistance and high abrasion resistance.
 High resistance to acid, solvents, steam, chemicals and fuels.
 Moisture regain and soft hand (comfort).
Present scenario of sportswear market
As Olympics being the biggest recognition of the sports activity throughout the world,
it is considered as the biggest stage to exhibit the innovations of the sportswear companies. In
London Olympics 2012 one of the clear favourites to be benefit will be one of the main
sponsors, Adidas of Germany, which anticipates £ 100 million in directly related sales of
merchandise alone. It is also seeking to use the games to overtake its rival Nike (U.S.A), as
the biggest sportswear company in the UK. Nike is currently the market leader with an 18%
share of the UK‟s £ 4.3 billon sportswear markets, with Adidas in second place with 15%
share.
New innovations by Market leaders
Nike (U.S) has recently introduced series of light weight performance sportswear,
designed for such as athletics and basketball, including its Nike Flyknit and Nike Pro Turbo
speed uniforms. Nike‟s Pro turboSpeed suit (based on AeroSwift technology), which Nike
claims enables an athlete to run 0.023sec faster over 100m than when wearing previous best
running kit.
This suit is based on polyster fabric approximately 82% of the raw material being
derived from recycled plastic bottles(13 bottles are needed for each garment on average).
Smart Textile in Sports Wear
The smart textile in the sports clothing industry has resulted in the use of engineered
textiles for highly specialized performances in different sports. Smart materials providing
such a strong focus in the textile industry generally, companies are increasingly looking for
„value added‟ textiles and functional design in sportswear as well as intelligent textiles which
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monitor performance with in-built sensors. In this paper we are mainly concentrating on the
second level of smart textile that is the active sports textile which consists of the materials
like phase change material, shape memory material, auxetic materials, chromic material.
Classification of Smart Textile
Smart textiles are classified into three categories depending on functional activity, as follows:
Passive smart textiles: -The first generation of smart textiles, which can provide additional
features in passive mode that is not concerning with alteration in environment are called
passive smart textiles. Optical fiber embedded fabrics and conductive fabrics are good
examples of passive smart textiles.
UV protective clothing, multilayer composite yarn and textiles, plasma treated clothing,
ceramic coated textiles, conductive fibers, fabrics with optical sensors, are some examples of
passive smart textiles.
Active smart textiles:- The second generation of smart textiles have both actuators and
sensors and tune functionality to specific agents or environments, are called active smart
textiles. These are shape memory, chameleonic, water resistant and vapor permeable
(hydrophilic/ non porous), heat storage, thermo regulated, vapor absorbing, heat evolving
fabric and electrically heated suits.
Phase change materials and shape memory materials, heat sensitive dyes etc. in textiles form
active smart textiles.
Ultra smart textiles:-Very smart textiles are the third generation of smart textiles, which can
sense, react, and adapt themselves to environmental conditions or stimuli. They are the
highest levels of smart textiles. These may deal actively with life threatening situations
(battlefield or during accidents) or to keep high levels of comfort even during extreme
environmental changes. These very smart textiles essentially comprise of a unit, which works
like the brain; with cognition, reasoning and activating capacities.Ultra smart textiles are an
attempt to make electronic devices a genuine part of our daily life by embedding entire
systems into clothing and accessories. Though the entire potential has not been completely
realized, the developments so far can be termed as only rudiments of very smart textiles.
For example, spacesuits, musical jackets, I-wear, data wear, sports jacket, intelligent bra,
smart clothes, wearable computer etc.
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Passive smart textiles are lifeless but very smart textiles, are the most dynamic levels
of artificial intelligence in textiles5
. In fact, passive textiles may not be termed as really smart
since they do not think for themselves. Nevertheless they perform special functions in the
passive mode and hence the term passive smart textiles.
Phase Change Material for Sports Wear
Phase change materials
Phase change material (PCM) the has a inherent property of lateral heat that can be
stored or released from a material over a narrow temperature range. These materials absorbs
energy (latent heat) during the heating process as phase change state takes place and release
energy (latent heat) to the environment in the phase change range during a reverse cooling
process.
Phase change process
In general the phase change material is that they change between solid and liquid state
in the temperature range where the material in used. A change from solid to liquid (melting)
involves the absorption of heat, and similarly a change from liquid to solid (crystallisation)
involves the release of heat. A melting heat absorption temperature of 20 to 40o
c and the
crystallisation heat releasing temperature of 30 to 10o
c are effecting in clothing. PCM‟s
currently used in textile structures are in the most cases different types of paraffin. Phase
change temperatures (solid and liquid) and the heat of melting depends on the chain length of
the linear hydrocarbon paraffin.
Phase change
material
Melting
Temperature
(degree celsius)
Crystallisation
Temperature
(degree celsius)
Heat
storage
capacity
(J/g)
Eicosane 36.1 30.6 247
Nanodecane 32.1 26.4 222
Octadecane 28.2 25.4 244
Heptadecane 22.5 21.5 214
Phase change paraffin and their properties
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The phase-change effect occurs in transient wear situations, when the meltingor
crystallisation temperature limit is crossed. Situations where this can beoptimally utilised are,
for example, when a person is moving frequently betweenwarm and cold environments or
handling cold pieces, or when the physical stressis changing frequently between hard work
and rest. The absorption and releaseof heat is a repeatable cycle, which takes place at the skin
temperature withoutunpleasant low and high temperatures.Incorporation of PCM into textile
fibres and structures is done throughencapsulating the paraffin in microcapsules (diameter
10±50 _m), to preventleakage in the liquid phase. The microcapsules are then incorporated in
eitherthe spinning dope, in insulating foams or in coating paste. As the textilecharacter of the
structure has to be maintained (mechanical strength, handle,etc.), only a fraction of the
product will actually be PCM, the main part being thematrix material. Scientists are therefore
somewhat sceptical about the truethermo physiological benefits of PCMs integrated in textile
materials.
Classification of phase change material
The materials used for the thermal energy storage are classified by the A.Abhat
.These materials are classified on the base of Thermal energy storage type and phase change
states.
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Phase Change material for Sportswear
Phase change materials have the potential to change the state at constant temperature and
store large quantity of energy. One of the most efficient uses of phase change materials can
be done in textiles by choosing materials that have large Thermal Energy Storage (TES) and
melting point from 15°C to 35°C.The required properties of Phase Change Material (PCM)
for the sportswear are mentioned below:
 Large heat of fusion
 Melting point temperature between 15°C to 35°C
 Low toxicity
 Non-flammability
 Ease of availability
 Low price
 For effective heat transfer, large thermal conductivity
 Harmless to environment
 Little temperature difference between the solidification and the melting temperature
 Stability for repetition of solidification and melting point
On the bases of the heat storage capacities, phase change temperature and properties
mentioned above the types of materials suitable for textiles especially sportswear are
given below with brief description.
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a. Hydrated Inorganic Salt
Hydrated salts are significant importance to use in Thermal Energy Storage (TES) due
to relatively high thermal conductivity (~0.5W/m°C), high volumetric storage density
(~350MJ/m3) and moderate costs compared to the linear chain hydrocarbons.
Hydrated inorganic salts with “n” water molecules are very important due to the heat
absorbing and heat releasing temperature interval is from 20°C to 40°C.
b. Linear long chain hydrocarbon
Hydrophobic linear hydrocarbons are the by products of the oil refinery and have the
general formula CnH2n+2. These materials are inexpensive, having no toxicity and
bigger source of raw materials available at different melting temperature ranges
according to the no. of carbon items present in the Paraffin. The mostly suitable linear
chain hydrocarbons have temperature -5.5°C and 37.5 °C. The phase change
temperature can be chosen for the specific applications by selecting the no. of carbon
atoms of the hydrocarbons. These are the most important materials used thermal
energy storage (TES) and the thermo regulated textiles such as sportswear. The
melting temperature of n-Eisocane is 37.5 °C which is about human body and heat
emission of the hydrocarbons.
c. Poly Ethylene Glycol
One of the important PCMs for the textile applications is Poly Ethylene Glycol (PEG). The
commercially available paraffin is cheap which contains a moderate thermal storage density
of (~200kJ/kg) and wide range of melting temperatures. The repeating unit of PEG is ox
ethylene (-o-CH2-CH2-) n. The melting temperature of the PEG is usually proportional to the
molecular weight.
PCM working in sports wear
The phase change materials could be encapsulated in the form of liquid before
applying to the textile structure. The capsules diameter varies between 1Om to 30 Om. The
benefits of applying the PCMs in the capsule form are these are resistant to the mechanical
actions, heat and chemical resistant. These materials reply to the changing environment in the
following manners.
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The temperature rises: When the temperature of the body raised due to the higher
ambient temperature more than the melting temperature of the PCM, the core material (Phase
change material) reacts accordingly and absorbs heat. By absorbing heat chemical bonds are
broken and phase change material is started converting from solid to liquid state. During the
melting process PCMs absorbs heat energy from the surrounding and stores extra energy.
The temperature falls: when the temperature of the body decreased due to lower ambient
temperature less than the crystallization temperature of the PCM, the core material (phase
change material) reacts accordingly and releases the previous stored heat. By releasing heat
the chemical bond are formed and the core phase change material started converting from
liquid to the solid phase. During the crystallization process releases heat to the surrounding
and wearer feels thermal comfort.
Microcapsules have the following benefits when applied to the garments:
 A Cooling effect due to the heat absorption of the Phase change materials
 A heating effect due to the heat emission of the phase change materials
 A thermo regulating effect for the body by heat absorption or heat emission of the
PCMs which keeps the temperature nearly at the constant level.
 As an active thermal barrier effect that is resulted by the heat absorbed or released by
the PCM which helps in regulation of the heat flux generated in the garment, from
human body to the environment and make it suitable according to the thermal needs(
ambient temperature, humidity, pressure of air and physical activity performed).
The fabrics treated with micro capsulated PCMs can absorb 4.44 J/g of heat if it contained
about 23% of the capsule material melamine formaldehyde during the melting process. The
heat absorbed by the capsule material 4.44J/g delayed the increase of temperature on the
clothing. In this manner it helped in increasing thermal comfort and reduced heat stress.
Incorporation of PCM’s in textile
The design and development of PCM have an ability to maintain the thermal energy
storage at worse and normal condition. They are incorporated in textile through
microencapsulation that are consisted on shell and surrounded core material. They are applied
through coating, melt spinning, fiber extrusion method, injection moulding, foam
manufacturing. PCM have linear hydrocarbon chain known as paraffin waxes, hydrated salt,
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polyethylene glycol, fatty acid and mixture of organic and non organic compounds.
Microcapsule application in textile has an advantage that encapsulation prevents the PCM
dispersion in structure, minimizes its evaporation and reduces the reaction of PCM with
environment, provides by increasing heat transfer area and constant volume and permits easy
application without any side effect. In fiber 5-10% microcapsule are incorporated without
effecting softness, drape and strength and no need of processing or washing.
Microcapsules are particles with thickness may be less than one Om and particle size
are vary within the range of less than 1Om and more than 300Om depends on the method of
encapsulation and diameter vary in between 20 to 40 Om. Microcapsules can be produced by
physical and chemical method that are limited to the cost of processing, regulatory affairs and
the use of organic solvents that are concerning to environment and health. Physical
techniques are employed through spray, centrifugal and fluidized bed process and the
chemical are employed through polymerization techniques.
The Cooperation is a miscible process in which the material in dispersed form is
added to the polymer solution and then suspended in aqueous phase condition containing
surface active agent. Micro capsulation is possible by mixing both water in oil or oil in water
method. In this case paraffin/wax in encapsulatation has high energy storage about 145 to
240j/g.
In situ polymerization two liquids water and organic solvent are bringing together to
react each other and form a solid pre condensate. The situ polymerization has the ability to
form a microcapsule with the best ability of diffusion tightness of their walls. In the Micro
capsulation study the situ polymerization methods, effect of stirring rate, ph of reaction
mixture, content of emulsifying agent, capsule diameter etc. in all these study our purpose is
to build a manufacturing that have based on situ polymerization in order to form a
microcapsule of PCM that is used in textile application. Second thing is to make it suitable
for laboratory scale and industrial scale work to save the energy and time.
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It’s Application in Sports Textile
During the sports activity the heat generated by the body can‟t be released properly
into the environment, this is the main cause of increasing thermal stress. But the when the
wearer uses the PCM active garments, the heat is released when it is necessary. In snow
skiing, mountain climbing, cycling and running are the sports where PCM active textile is
widely used.
D3o(de-three-oh)
A new material for different types of impact protection has been introduced under the
trade name d3o. In the normal state, the molecules flow past each other at low rates of
movement, but when they are subject to an impact that would require them to move very
quickly they instantaneously lock together to form a rigid protective barrier. As soon as the
impact has passed, they unlock to provide normal flexibility. Thus the garment does not
restrict body movements as conventional body armour products but give protection when it is
needed. Two versions are described: the three-layer d3o flex where the impact protection is
situated between a stretch outer layer and a moisture wicking inner textile, and the four-layer
d3o armour with an additional armour layer to provide penetration resistance. The base
material for d3o is generally polyurethane, but other polymers are also used. Applications are
foreseen in head, foot and body protection for motorbike riders, downhill skiers, etc.To the
question what does this mean to the average person walking down the street? Basically d3o
offers superior lightweight, flexible impact protection which when integrated into apparel
maintains style, comfort and practicality without compromising mobility. This integration
offers individuals "the edge" through increased control with flexible yet highly effective
protection.
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About D3O
D3O Labs is the name of the company that manufactures and markets their d3o
protective material. The name d3o is basically a mystery - the manufacturers have only given
vague speculations of its origin, that d3o came from the name of the room it was invented or
it's a secret chemical compound that is used in its manufacture, D3O Labs will only say "No
comment".
D3O Labs is the provider of solutions for impact protection material. They
manufacture and license their unique patented material, which combines enhanced chemistry
and engineering to produce a high performance shock absorbing protective system. It is a
high-tech material, in D3O Lab's own words, "intelligent molecules", so for lightweight top-
quality protective material, built into BMX, mountain bike, ski and snowboard body armor,
you ARE getting what you pay for. Material that is as comfortable as, for instance, a soft
knee pad but with intelligent molecules that react to impacts, tightening and reflecting the
force throughout the material allowing d3o to protect as well as any hard shell knee pad.
D3O Material Development
D3O is comprised of a polymer composite which contains a chemically engineered
dilatants, an energy absorber. This basic material has been adapted and enhanced to meet
specific performance standards and applications. Initially d3o is formed as a gel, almost like a
Silly Putty, except that it's, well, bullet proof. The d3o material used in protective gear
applications is almost taffy like, softer and a bit stiffer then any regular foam rubber, a
consistency like unto an old foam camping pad, but it doesn't feel like you could pull chunks
off (because you can't).
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Partner d3o Materials
D3O has patented a unique polymer composite which contains a chemically engineered
dilatant so that it functions as an energy absorber. This basic material has been chemically
enhanced to allow the material to be adapted to meet specific performance applications and
typically is offered in three solutions: ST, XT and SHOCK+.
 ST is a lightweight material formulation typically applied to components in the
automotive market. It‟s flexible and high performing so you can feel safe when you
use it. It is Lightweight, Flexible and Strong performance at ambient temperatures.
 The XT material is our newest formulation and the best performing shock absorber
across a wide range of temperatures. It is lightweight and particularly impressive at
high temperatures. The material is temperature stable, lightweight and high
performing shock absorber.
 Shock+ is extremely durable. It performs particularly well at cold temperatures and
can be used in a wide variety of products. The material has great shock
absorption,durable, andideal for extreme environments.
Application of d3o
A few examples of d3o's use to date can be seen in a vast range of products such as
GS race suits from Spyder as worn by the US ski team in the 2006 Winter Olympics; Sell's
Contour goal keeper gloves for football (soccer) and Pro Pad shinguards; Racer MCR
motorcycle gloves; ski and snow apparel manufacturers such as Schoeffel, Reusche, Kjus
and Sessions have all adopted d3o, Sessions producing the world's first base layer combined
with the impact protection technology and finally the 07/08 winter season is set to introduce
Quiksilver and Ignite beanies containing d3o to the market for soft headwear with added
protection, not a replacement to a helmet but better than a beanie!
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Shape Memory Materials
Shape memory materials (SMMs) react to changing environmental conditions
generally increasing and decreasing temperature by changing their geometrical shape. Shape
memory materials are smart materials that have the ability to return from a deformed state
(temporary shape) to their original (permanent) shape induced by an external right stimulus
(trigger), such as temperature change.This phenomenon is known as the shape memory effect
(SME), and it has been found in a number of material systems, including some alloys,
polymers and ceramics etc. Shape memory effects can also be utilised in several types of
functional textile and clothing products:
· Variable thermal insulation through SMM spacer elements between liner and outer fabric.
· Variable moisture permeability membranes.
· Shock damping materials.
Shape memory alloys (SMAs) were first developed where the transition is due to a
phase change between austenite and martensite. In shape memory polymers (SMPs) the
change occurs as glass transition or melting. SMPs have several advantages over SMAs,
which are valuable in the textile applications: low density, good mould ability, low cost, glass
transition temperature variable between 30o
c and .70o
C, potential biocompatibility and
biodegradability, high capacity for elastic deformation.
Shape memory Polymer
Shape memory polymers are polymers whose qualities have been altered to give them
dynamic shape "memory" properties. Using thermal stimuli, shape memory polymers can
exhibit a radical change from a rigid polymer to a very elastic state, and then back to a rigid
state again. In its elastic state, it will recover its “memory” shape if left unrestrained.
However, while pliable it can be stretched, folded, or otherwise conformed to other shapes,
tolerating up to 200% elongation.While manipulated, the shape memory polymer can be
cooled and therefore returned to a rigid state, maintaining its manipulated shape indefinitely.
This manipulation process can be repeated many times without degradation. Word done on
the polymer to solidify gets stored in the polymer as latent strain energy. Shape memory
polymers (SMP) can be stimulated by temperature, pH (the level of acidity or alkalinity),
chemicals, electrical energy and light. They are able to sense and respond to external stimuli
in pre-determined shape.
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In terms of chemical structure, SMP's can be considered as phase segregated linear
block co-polymers having a hard segment and a soft segment. The hard segment acts as a
frozen phase and the soft segment acts as the reversible phase. The ratio by weight of the
hard segment: soft segments are between about 5:95 and 95:5, preferably between 20:80 and
80:20. The reversible phase transformation of the soft segment is responsible for the shape
memory effect.The polymer materials have various characteristics such as from hard glass to
soft rubber. Shape memory polymers however, have the characteristic of both of them and
their elasticity modulus show reversible change with the transition temperature.
Most of the thermally induced shape memory polymers (SMP‟s) have a one-way
shapememory effect: they remember one permanent shape formed at the higher temperature,
while many temporary shapes are possible at lower temperatures for which the systems do not
haveany memory. A two-way thermally induced SMP will remember two permanent shapes,
one formed at higher temperature and one formed at lower temperature. Bythermally cycling
the system, these types of polymeric materials will take two different shapes depending on the
temperature. These shape memory systems areengineered at the molecular level for the
requiredbehaviour.
Bi-component fibres with substantially different coefficients of thermal expansion
(CTE) can also produce thermally-induced shape memory effects viaone structurally
engineering the fibre rather than engineering the polymer. Bi-component fibres also havetwo
distinct phases,one with the high CTE component and one with the low CTE phase. The net
thermal and elasticity effects on the fibre, resulting from the competition of thermally
induced expansions, result in the system remembering all of the temperature dependent
“permanent” shapes, and thus providing a multitude of permanent shapes or two-way
variablememory effects.
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Features of Shape Memory Polymers:
 Super elasticity (high deformability) above the transition temperature to avoid
residual strain (permanent deformation).
 Rapid fixing of temporary shape by immobilising the polymeric chains without creep.
 SMPs possess two material phases. The glass and the rubber phases. In the glass
phase, the material is rigid and cannot be easily deformed.
 When the temperature is greater than "Glass transition temperature", the material
enters the soft rubber phase and becomes easily deformable.
Properties of SMP
 Extent of deformation (%) = up to 200%
 Density / g cm3
= 0.9 to 1.1
 Critical temperature / °c = -10°C to 100°C
 Recovery speeds minutes = <1second to several min.
 Corrosion performance = excellent
 Processing conditions = < 200°C , low pressure
 Can be biodegradable
Application of SMP in Sportswear
It can be used to provide thermal insulation in both hot and cold climatic situations. In
cold protective clothing, a high thermal insulation is generally achieved by using a low-
density wadding or similar material between the outer shell and the lining fabrics. The air
content of the wadding provides most of the insulation. A bi-material laminated film
consisting of a layer of SMP and a layer of a compatible film can be used as a substitute for
the wadding. With a glass transition temperature of, say, 25o
C, the SMP will shrink by some
3% and become rigid at that temperature, with an out-of-plane deformation (Fig). The
increased distance y between the fabric layers gives increased thermal insulation at the lower
temperature.
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Fig .The SMP component of the laminated film shrinks at 25o
C and causes anincreased
distance y between the two clothing layers.
Actuation for heat protection at elevated temperatures (steam, boiling water, hot
fluids, etc.) is achieved with a thin film that has been pretextured with an embossed pattern.
A temporary flat shape is achieved by calendaring the embossed film, and this flat film will
be used in the clothing. On exposure to high temperatures of 55o
C and above, a reversion of
the textured shape occurs and provides heat protection.
An SMP membrane with flexible moisture barrier property has beenpresented with
the trade name Diaplex by Mitsubishi Heavy Industry. The function is based on a change in
the micro-Brownian motion in the segmental polyurethane structure. The molecular structure
is rigid at temperatures below the activation point and prevents permeation of water
molecules. When the temperature rises above the activation point the thermal vibration of the
softmolecule segments creates gaps between the membrane molecules, thusincreasing the
moisture permeability. The activation temperature can betailored by changing the polymer
structure.
A drysuit (developed by U.S army) keeps the wearer dry in cold water and which can
also be worn in a warm air environment without causing discomfort from sweating can be
used as sportswear.
For clothing applications, the desirable temperatures for the shape memory effect to
be triggered will be near body temperature. In practice, a shape memory alloy is usually in
the shape of a spring. The spring is flat below the activation temperature but becomes
extended above it. By incorporating these alloys between the layers of a garment, the gap
between the layers can be substantially increased above the activation temperature.
Consequently, considerably improved protection against external heat is provided.
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The SMP membrane can be applied on to the sportswear, due to which when the
temperature raises above certain critical temperature the intermolecular rupture of membrane
takes place which increases the pores due to which breathability, moisture and heat regulation
of the body increases.
Auxetic material
When stretched in the longitudinal direction, auxetic materials get fatter rather than
thinner, in contrast to conventional materials. Poisson's ratio, which is defined as the ratio of
the lateral contractile strain to the longitudinal tensile strain for materials undergoing uniaxial
tension in the longitudinal direction, is in the region of 0.2±0.4 for most solids. Auxetic
materials have a negative Poisson's ratio.
Auxetic materials have previously been utilised, for example as graphite core
structures in nuclear reactors. Polymeric and metallic auxetic foams with convoluted cell
structures were developed in the 1980s and found various uses in packaging, sound
insulation, filtration, shock absorption and sponge materials. As a result of more recent
research work, production of auxetic polymers with specifically tailored properties is now
possible, and fibres of auxetic polypropylene have been produced at the Bolton Institute in
the UK. Currently, the use of auxetic materials in textiles is limited to the expanded PTFE
membranes, where the auxetic property is not really utilised. However,there is a growing
interest in future clothing applications for personal protection (energy absorption and impact
resistance) and supportive garments (constant pressure structures). Other auxetic fibre
applications are expected in fibre-reinforced composites (fibre pull-out resistance, tough
fracture, energy absorption and impact resistance), filtration (release of entrapped particles,
microporous structure), medical bandages (wear resistance, constant pressure).
Advancement in Sportech
vigneshdhanabalan@hotmail.com Page 19
Conclusion
 The possible use of smart materials and wearable technologies opens new
perspectives in the field of functional clothing for sports textile.
 Extensive research activities in universities and research institutes as well as in
companies worldwide had proceeded and brought new solutions to the market.
 The applications that have been presented here are just the tips of the eyesberg of
products that would become a commercial product in the nearby future.
 Sportswear is the one of the most promising applications for SFIT (smart fabrics and
intelligent textile).
 Products which change their properties according to the physical performance and/are
the environmental conditions are practically obtaining more focus in the sports wear
market.
 Through the presentation of the paper we find ourselves proud to show the future of
sports textile.
 At this stage we cannot describe it completely because this technology is in the
developing stage.
References
 Textile in sports edited by R.Shishoo
 The Indian Textile Journal (December 2010) Page no. 11
 Technical Textile International (July/August 2012) Page no. 9
 Wikipedia
 http://www.crgrp.com/technology/portfolio/veriflex.html
 http://www.azom.com/article.aspx?ArticleID=6038
 http://www.gzespace.com/gzenew/index.php?pg=shape_memory_polimer&lang=en
 http://www.ntcresearch.org/pdf-rpts/AnRp05/M05-GT14-A5.pdf
 University of Boras ( Application of Ultra Smart Textiles in Sportswear and
Garments) 26.05.2010
 World Active Sportswear Journal (June 2011) Page no. 20
 Textile Asia Journal (January 2009) Page no. 12
 Texincon (1991 to 2010)
 Textilveredlung (1993, April) Page no.5
 www.fibresource.com

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Advancements in Smart Sports Textiles

  • 1. Advancement in Sportech vigneshdhanabalan@hotmail.com Page 1 ADVANCEMENTS IN SPORT TEXTILE Abstract As we all know that sports textiles holds a great potential in the textile sector, it has proved its dominance by the incorporation of smart textiles into ultimate goal of providing comfort, protection, thermal insulation, moisture management and heat regulation to the wearers. Smart textiles are inheriting of artificial intelligence into the sportswear. To simply say smart textiles sports wears are to be under stood as self-thinking garments. It is of at most important that we discuss and know about active smart textiles that are dominating in the sports textiles. The prime objective of this paper to bring out the importance of active smart textile materials like phase change material, shape memory material, auxetic materials, holofibeand d3o materials. These material‟s principal, working mechanisms, properties, methods of incorporation in textiles and its application in sports textiles are highlighted in this paper. More over smart textiles in sportswear has played its key role in the London Olympics 2012, which is also clearly proved in this paper, which gives clear evidenceof the contribution of textiles for technology and development of standard of human life. Smart textiles have come out with solutions for various researches carried out by the scientists and multinational companies investing millions of dollars in it. The phase change materials are used in wears of athletes, football, mountain climbing and snow skiing, where extreme climatic conditions are to be tackled. The d3o materials are used in bike race, jumping events and rugby where high impact forces are involved. Introduction The sports textile has taken its place from the floor (Ex. Artificial turf) to the roof (Ex. PTFE roofing). The consumption of textile material used in sports was 1382000 tons in 2010. This figure itself shows the potential of the textile in sports sector Sportech segment comprises of technical textile products used in sports (sportswear, sports equipment and sports footwear) Examples of sportswear are: aerobic clothing, athletic clothing, football clothing, cricket clothing, games shorts, gloves, jackets, pants, shirts, shorts, socks, swimwear and tennis clothing. Examples of sport equipment are: sails, trampolines, camping gear, leisure
  • 2. Advancement in Sportech vigneshdhanabalan@hotmail.com Page 2 bags, bikes and rackets. Examples of sports footwear are: athletic shoes, football boots, gym shoes, tennis shoes and walking boots. Basically Textile materials were designed for having protection against extreme natural condition of heat and cold, then gradually the purpose of clothing until it took a new face (In the name of trend , ascetic use , and many more)now a days they are designed for specific purposes and tasks. In earlier days mostly cotton was preferred, with innovations and raise in requirement blends of fibre like cotton/polyester, cotton/viscose and polyester/viscose were used. Smart textile is expected to solve all the demands and the shortcomings of the sportsman like moisture level maintenance, heat regulation, comfort, protection from UV rays and protection against various impact forces.Smart textile materials readily interact with human/environmentalconditions thereby creating changes in the material properties. For example, thephase-change materials and shape-memory polymers embedded in fabric layerswill be able to interact with a human body and produce thermoregulatory controlby affecting the microclimate between the clothing and the human skin. Inaddition to the two dimensions of functionality and aesthetics, if `intelligence'can be embedded or integrated into clothing as a third dimension, it would leadto the realization of protective and safety clothing as a personalized wearableinformation infrastructure. Properties required for Sportswear  The clothing should be capable of protecting the wearer from external climatic conditions such as wind, sun, rain and snow, extreme temperatures.  Good tactile properties  Thermal insulation  Good stretch ability  Being capable of transporting perspiration from skin and then quickly dispersing it.  Fabric should be capable of protecting the wearer from any impact forces.  Good energy storing/ absorbing capacity  The fabric should be designed in such a way that the wearer should experience less drag (due to air or water).  Fabric should provide psychological comfort to the wearer.  Maintain the body temperature by thermoregulation.
  • 3. Advancement in Sportech vigneshdhanabalan@hotmail.com Page 3 Necessity in advancement (up gradation) of materials  High strength  Flame and heat resistance.  High specific strength and modulus  High chemical resistance and high abrasion resistance.  High resistance to acid, solvents, steam, chemicals and fuels.  Moisture regain and soft hand (comfort). Present scenario of sportswear market As Olympics being the biggest recognition of the sports activity throughout the world, it is considered as the biggest stage to exhibit the innovations of the sportswear companies. In London Olympics 2012 one of the clear favourites to be benefit will be one of the main sponsors, Adidas of Germany, which anticipates £ 100 million in directly related sales of merchandise alone. It is also seeking to use the games to overtake its rival Nike (U.S.A), as the biggest sportswear company in the UK. Nike is currently the market leader with an 18% share of the UK‟s £ 4.3 billon sportswear markets, with Adidas in second place with 15% share. New innovations by Market leaders Nike (U.S) has recently introduced series of light weight performance sportswear, designed for such as athletics and basketball, including its Nike Flyknit and Nike Pro Turbo speed uniforms. Nike‟s Pro turboSpeed suit (based on AeroSwift technology), which Nike claims enables an athlete to run 0.023sec faster over 100m than when wearing previous best running kit. This suit is based on polyster fabric approximately 82% of the raw material being derived from recycled plastic bottles(13 bottles are needed for each garment on average). Smart Textile in Sports Wear The smart textile in the sports clothing industry has resulted in the use of engineered textiles for highly specialized performances in different sports. Smart materials providing such a strong focus in the textile industry generally, companies are increasingly looking for „value added‟ textiles and functional design in sportswear as well as intelligent textiles which
  • 4. Advancement in Sportech vigneshdhanabalan@hotmail.com Page 4 monitor performance with in-built sensors. In this paper we are mainly concentrating on the second level of smart textile that is the active sports textile which consists of the materials like phase change material, shape memory material, auxetic materials, chromic material. Classification of Smart Textile Smart textiles are classified into three categories depending on functional activity, as follows: Passive smart textiles: -The first generation of smart textiles, which can provide additional features in passive mode that is not concerning with alteration in environment are called passive smart textiles. Optical fiber embedded fabrics and conductive fabrics are good examples of passive smart textiles. UV protective clothing, multilayer composite yarn and textiles, plasma treated clothing, ceramic coated textiles, conductive fibers, fabrics with optical sensors, are some examples of passive smart textiles. Active smart textiles:- The second generation of smart textiles have both actuators and sensors and tune functionality to specific agents or environments, are called active smart textiles. These are shape memory, chameleonic, water resistant and vapor permeable (hydrophilic/ non porous), heat storage, thermo regulated, vapor absorbing, heat evolving fabric and electrically heated suits. Phase change materials and shape memory materials, heat sensitive dyes etc. in textiles form active smart textiles. Ultra smart textiles:-Very smart textiles are the third generation of smart textiles, which can sense, react, and adapt themselves to environmental conditions or stimuli. They are the highest levels of smart textiles. These may deal actively with life threatening situations (battlefield or during accidents) or to keep high levels of comfort even during extreme environmental changes. These very smart textiles essentially comprise of a unit, which works like the brain; with cognition, reasoning and activating capacities.Ultra smart textiles are an attempt to make electronic devices a genuine part of our daily life by embedding entire systems into clothing and accessories. Though the entire potential has not been completely realized, the developments so far can be termed as only rudiments of very smart textiles. For example, spacesuits, musical jackets, I-wear, data wear, sports jacket, intelligent bra, smart clothes, wearable computer etc.
  • 5. Advancement in Sportech vigneshdhanabalan@hotmail.com Page 5 Passive smart textiles are lifeless but very smart textiles, are the most dynamic levels of artificial intelligence in textiles5 . In fact, passive textiles may not be termed as really smart since they do not think for themselves. Nevertheless they perform special functions in the passive mode and hence the term passive smart textiles. Phase Change Material for Sports Wear Phase change materials Phase change material (PCM) the has a inherent property of lateral heat that can be stored or released from a material over a narrow temperature range. These materials absorbs energy (latent heat) during the heating process as phase change state takes place and release energy (latent heat) to the environment in the phase change range during a reverse cooling process. Phase change process In general the phase change material is that they change between solid and liquid state in the temperature range where the material in used. A change from solid to liquid (melting) involves the absorption of heat, and similarly a change from liquid to solid (crystallisation) involves the release of heat. A melting heat absorption temperature of 20 to 40o c and the crystallisation heat releasing temperature of 30 to 10o c are effecting in clothing. PCM‟s currently used in textile structures are in the most cases different types of paraffin. Phase change temperatures (solid and liquid) and the heat of melting depends on the chain length of the linear hydrocarbon paraffin. Phase change material Melting Temperature (degree celsius) Crystallisation Temperature (degree celsius) Heat storage capacity (J/g) Eicosane 36.1 30.6 247 Nanodecane 32.1 26.4 222 Octadecane 28.2 25.4 244 Heptadecane 22.5 21.5 214 Phase change paraffin and their properties
  • 6. Advancement in Sportech vigneshdhanabalan@hotmail.com Page 6 The phase-change effect occurs in transient wear situations, when the meltingor crystallisation temperature limit is crossed. Situations where this can beoptimally utilised are, for example, when a person is moving frequently betweenwarm and cold environments or handling cold pieces, or when the physical stressis changing frequently between hard work and rest. The absorption and releaseof heat is a repeatable cycle, which takes place at the skin temperature withoutunpleasant low and high temperatures.Incorporation of PCM into textile fibres and structures is done throughencapsulating the paraffin in microcapsules (diameter 10±50 _m), to preventleakage in the liquid phase. The microcapsules are then incorporated in eitherthe spinning dope, in insulating foams or in coating paste. As the textilecharacter of the structure has to be maintained (mechanical strength, handle,etc.), only a fraction of the product will actually be PCM, the main part being thematrix material. Scientists are therefore somewhat sceptical about the truethermo physiological benefits of PCMs integrated in textile materials. Classification of phase change material The materials used for the thermal energy storage are classified by the A.Abhat .These materials are classified on the base of Thermal energy storage type and phase change states.
  • 7. Advancement in Sportech vigneshdhanabalan@hotmail.com Page 7 Phase Change material for Sportswear Phase change materials have the potential to change the state at constant temperature and store large quantity of energy. One of the most efficient uses of phase change materials can be done in textiles by choosing materials that have large Thermal Energy Storage (TES) and melting point from 15°C to 35°C.The required properties of Phase Change Material (PCM) for the sportswear are mentioned below:  Large heat of fusion  Melting point temperature between 15°C to 35°C  Low toxicity  Non-flammability  Ease of availability  Low price  For effective heat transfer, large thermal conductivity  Harmless to environment  Little temperature difference between the solidification and the melting temperature  Stability for repetition of solidification and melting point On the bases of the heat storage capacities, phase change temperature and properties mentioned above the types of materials suitable for textiles especially sportswear are given below with brief description.
  • 8. Advancement in Sportech vigneshdhanabalan@hotmail.com Page 8 a. Hydrated Inorganic Salt Hydrated salts are significant importance to use in Thermal Energy Storage (TES) due to relatively high thermal conductivity (~0.5W/m°C), high volumetric storage density (~350MJ/m3) and moderate costs compared to the linear chain hydrocarbons. Hydrated inorganic salts with “n” water molecules are very important due to the heat absorbing and heat releasing temperature interval is from 20°C to 40°C. b. Linear long chain hydrocarbon Hydrophobic linear hydrocarbons are the by products of the oil refinery and have the general formula CnH2n+2. These materials are inexpensive, having no toxicity and bigger source of raw materials available at different melting temperature ranges according to the no. of carbon items present in the Paraffin. The mostly suitable linear chain hydrocarbons have temperature -5.5°C and 37.5 °C. The phase change temperature can be chosen for the specific applications by selecting the no. of carbon atoms of the hydrocarbons. These are the most important materials used thermal energy storage (TES) and the thermo regulated textiles such as sportswear. The melting temperature of n-Eisocane is 37.5 °C which is about human body and heat emission of the hydrocarbons. c. Poly Ethylene Glycol One of the important PCMs for the textile applications is Poly Ethylene Glycol (PEG). The commercially available paraffin is cheap which contains a moderate thermal storage density of (~200kJ/kg) and wide range of melting temperatures. The repeating unit of PEG is ox ethylene (-o-CH2-CH2-) n. The melting temperature of the PEG is usually proportional to the molecular weight. PCM working in sports wear The phase change materials could be encapsulated in the form of liquid before applying to the textile structure. The capsules diameter varies between 1Om to 30 Om. The benefits of applying the PCMs in the capsule form are these are resistant to the mechanical actions, heat and chemical resistant. These materials reply to the changing environment in the following manners.
  • 9. Advancement in Sportech vigneshdhanabalan@hotmail.com Page 9 The temperature rises: When the temperature of the body raised due to the higher ambient temperature more than the melting temperature of the PCM, the core material (Phase change material) reacts accordingly and absorbs heat. By absorbing heat chemical bonds are broken and phase change material is started converting from solid to liquid state. During the melting process PCMs absorbs heat energy from the surrounding and stores extra energy. The temperature falls: when the temperature of the body decreased due to lower ambient temperature less than the crystallization temperature of the PCM, the core material (phase change material) reacts accordingly and releases the previous stored heat. By releasing heat the chemical bond are formed and the core phase change material started converting from liquid to the solid phase. During the crystallization process releases heat to the surrounding and wearer feels thermal comfort. Microcapsules have the following benefits when applied to the garments:  A Cooling effect due to the heat absorption of the Phase change materials  A heating effect due to the heat emission of the phase change materials  A thermo regulating effect for the body by heat absorption or heat emission of the PCMs which keeps the temperature nearly at the constant level.  As an active thermal barrier effect that is resulted by the heat absorbed or released by the PCM which helps in regulation of the heat flux generated in the garment, from human body to the environment and make it suitable according to the thermal needs( ambient temperature, humidity, pressure of air and physical activity performed). The fabrics treated with micro capsulated PCMs can absorb 4.44 J/g of heat if it contained about 23% of the capsule material melamine formaldehyde during the melting process. The heat absorbed by the capsule material 4.44J/g delayed the increase of temperature on the clothing. In this manner it helped in increasing thermal comfort and reduced heat stress. Incorporation of PCM’s in textile The design and development of PCM have an ability to maintain the thermal energy storage at worse and normal condition. They are incorporated in textile through microencapsulation that are consisted on shell and surrounded core material. They are applied through coating, melt spinning, fiber extrusion method, injection moulding, foam manufacturing. PCM have linear hydrocarbon chain known as paraffin waxes, hydrated salt,
  • 10. Advancement in Sportech vigneshdhanabalan@hotmail.com Page 10 polyethylene glycol, fatty acid and mixture of organic and non organic compounds. Microcapsule application in textile has an advantage that encapsulation prevents the PCM dispersion in structure, minimizes its evaporation and reduces the reaction of PCM with environment, provides by increasing heat transfer area and constant volume and permits easy application without any side effect. In fiber 5-10% microcapsule are incorporated without effecting softness, drape and strength and no need of processing or washing. Microcapsules are particles with thickness may be less than one Om and particle size are vary within the range of less than 1Om and more than 300Om depends on the method of encapsulation and diameter vary in between 20 to 40 Om. Microcapsules can be produced by physical and chemical method that are limited to the cost of processing, regulatory affairs and the use of organic solvents that are concerning to environment and health. Physical techniques are employed through spray, centrifugal and fluidized bed process and the chemical are employed through polymerization techniques. The Cooperation is a miscible process in which the material in dispersed form is added to the polymer solution and then suspended in aqueous phase condition containing surface active agent. Micro capsulation is possible by mixing both water in oil or oil in water method. In this case paraffin/wax in encapsulatation has high energy storage about 145 to 240j/g. In situ polymerization two liquids water and organic solvent are bringing together to react each other and form a solid pre condensate. The situ polymerization has the ability to form a microcapsule with the best ability of diffusion tightness of their walls. In the Micro capsulation study the situ polymerization methods, effect of stirring rate, ph of reaction mixture, content of emulsifying agent, capsule diameter etc. in all these study our purpose is to build a manufacturing that have based on situ polymerization in order to form a microcapsule of PCM that is used in textile application. Second thing is to make it suitable for laboratory scale and industrial scale work to save the energy and time.
  • 11. Advancement in Sportech vigneshdhanabalan@hotmail.com Page 11 It’s Application in Sports Textile During the sports activity the heat generated by the body can‟t be released properly into the environment, this is the main cause of increasing thermal stress. But the when the wearer uses the PCM active garments, the heat is released when it is necessary. In snow skiing, mountain climbing, cycling and running are the sports where PCM active textile is widely used. D3o(de-three-oh) A new material for different types of impact protection has been introduced under the trade name d3o. In the normal state, the molecules flow past each other at low rates of movement, but when they are subject to an impact that would require them to move very quickly they instantaneously lock together to form a rigid protective barrier. As soon as the impact has passed, they unlock to provide normal flexibility. Thus the garment does not restrict body movements as conventional body armour products but give protection when it is needed. Two versions are described: the three-layer d3o flex where the impact protection is situated between a stretch outer layer and a moisture wicking inner textile, and the four-layer d3o armour with an additional armour layer to provide penetration resistance. The base material for d3o is generally polyurethane, but other polymers are also used. Applications are foreseen in head, foot and body protection for motorbike riders, downhill skiers, etc.To the question what does this mean to the average person walking down the street? Basically d3o offers superior lightweight, flexible impact protection which when integrated into apparel maintains style, comfort and practicality without compromising mobility. This integration offers individuals "the edge" through increased control with flexible yet highly effective protection.
  • 12. Advancement in Sportech vigneshdhanabalan@hotmail.com Page 12 About D3O D3O Labs is the name of the company that manufactures and markets their d3o protective material. The name d3o is basically a mystery - the manufacturers have only given vague speculations of its origin, that d3o came from the name of the room it was invented or it's a secret chemical compound that is used in its manufacture, D3O Labs will only say "No comment". D3O Labs is the provider of solutions for impact protection material. They manufacture and license their unique patented material, which combines enhanced chemistry and engineering to produce a high performance shock absorbing protective system. It is a high-tech material, in D3O Lab's own words, "intelligent molecules", so for lightweight top- quality protective material, built into BMX, mountain bike, ski and snowboard body armor, you ARE getting what you pay for. Material that is as comfortable as, for instance, a soft knee pad but with intelligent molecules that react to impacts, tightening and reflecting the force throughout the material allowing d3o to protect as well as any hard shell knee pad. D3O Material Development D3O is comprised of a polymer composite which contains a chemically engineered dilatants, an energy absorber. This basic material has been adapted and enhanced to meet specific performance standards and applications. Initially d3o is formed as a gel, almost like a Silly Putty, except that it's, well, bullet proof. The d3o material used in protective gear applications is almost taffy like, softer and a bit stiffer then any regular foam rubber, a consistency like unto an old foam camping pad, but it doesn't feel like you could pull chunks off (because you can't).
  • 13. Advancement in Sportech vigneshdhanabalan@hotmail.com Page 13 Partner d3o Materials D3O has patented a unique polymer composite which contains a chemically engineered dilatant so that it functions as an energy absorber. This basic material has been chemically enhanced to allow the material to be adapted to meet specific performance applications and typically is offered in three solutions: ST, XT and SHOCK+.  ST is a lightweight material formulation typically applied to components in the automotive market. It‟s flexible and high performing so you can feel safe when you use it. It is Lightweight, Flexible and Strong performance at ambient temperatures.  The XT material is our newest formulation and the best performing shock absorber across a wide range of temperatures. It is lightweight and particularly impressive at high temperatures. The material is temperature stable, lightweight and high performing shock absorber.  Shock+ is extremely durable. It performs particularly well at cold temperatures and can be used in a wide variety of products. The material has great shock absorption,durable, andideal for extreme environments. Application of d3o A few examples of d3o's use to date can be seen in a vast range of products such as GS race suits from Spyder as worn by the US ski team in the 2006 Winter Olympics; Sell's Contour goal keeper gloves for football (soccer) and Pro Pad shinguards; Racer MCR motorcycle gloves; ski and snow apparel manufacturers such as Schoeffel, Reusche, Kjus and Sessions have all adopted d3o, Sessions producing the world's first base layer combined with the impact protection technology and finally the 07/08 winter season is set to introduce Quiksilver and Ignite beanies containing d3o to the market for soft headwear with added protection, not a replacement to a helmet but better than a beanie!
  • 14. Advancement in Sportech vigneshdhanabalan@hotmail.com Page 14 Shape Memory Materials Shape memory materials (SMMs) react to changing environmental conditions generally increasing and decreasing temperature by changing their geometrical shape. Shape memory materials are smart materials that have the ability to return from a deformed state (temporary shape) to their original (permanent) shape induced by an external right stimulus (trigger), such as temperature change.This phenomenon is known as the shape memory effect (SME), and it has been found in a number of material systems, including some alloys, polymers and ceramics etc. Shape memory effects can also be utilised in several types of functional textile and clothing products: · Variable thermal insulation through SMM spacer elements between liner and outer fabric. · Variable moisture permeability membranes. · Shock damping materials. Shape memory alloys (SMAs) were first developed where the transition is due to a phase change between austenite and martensite. In shape memory polymers (SMPs) the change occurs as glass transition or melting. SMPs have several advantages over SMAs, which are valuable in the textile applications: low density, good mould ability, low cost, glass transition temperature variable between 30o c and .70o C, potential biocompatibility and biodegradability, high capacity for elastic deformation. Shape memory Polymer Shape memory polymers are polymers whose qualities have been altered to give them dynamic shape "memory" properties. Using thermal stimuli, shape memory polymers can exhibit a radical change from a rigid polymer to a very elastic state, and then back to a rigid state again. In its elastic state, it will recover its “memory” shape if left unrestrained. However, while pliable it can be stretched, folded, or otherwise conformed to other shapes, tolerating up to 200% elongation.While manipulated, the shape memory polymer can be cooled and therefore returned to a rigid state, maintaining its manipulated shape indefinitely. This manipulation process can be repeated many times without degradation. Word done on the polymer to solidify gets stored in the polymer as latent strain energy. Shape memory polymers (SMP) can be stimulated by temperature, pH (the level of acidity or alkalinity), chemicals, electrical energy and light. They are able to sense and respond to external stimuli in pre-determined shape.
  • 15. Advancement in Sportech vigneshdhanabalan@hotmail.com Page 15 In terms of chemical structure, SMP's can be considered as phase segregated linear block co-polymers having a hard segment and a soft segment. The hard segment acts as a frozen phase and the soft segment acts as the reversible phase. The ratio by weight of the hard segment: soft segments are between about 5:95 and 95:5, preferably between 20:80 and 80:20. The reversible phase transformation of the soft segment is responsible for the shape memory effect.The polymer materials have various characteristics such as from hard glass to soft rubber. Shape memory polymers however, have the characteristic of both of them and their elasticity modulus show reversible change with the transition temperature. Most of the thermally induced shape memory polymers (SMP‟s) have a one-way shapememory effect: they remember one permanent shape formed at the higher temperature, while many temporary shapes are possible at lower temperatures for which the systems do not haveany memory. A two-way thermally induced SMP will remember two permanent shapes, one formed at higher temperature and one formed at lower temperature. Bythermally cycling the system, these types of polymeric materials will take two different shapes depending on the temperature. These shape memory systems areengineered at the molecular level for the requiredbehaviour. Bi-component fibres with substantially different coefficients of thermal expansion (CTE) can also produce thermally-induced shape memory effects viaone structurally engineering the fibre rather than engineering the polymer. Bi-component fibres also havetwo distinct phases,one with the high CTE component and one with the low CTE phase. The net thermal and elasticity effects on the fibre, resulting from the competition of thermally induced expansions, result in the system remembering all of the temperature dependent “permanent” shapes, and thus providing a multitude of permanent shapes or two-way variablememory effects.
  • 16. Advancement in Sportech vigneshdhanabalan@hotmail.com Page 16 Features of Shape Memory Polymers:  Super elasticity (high deformability) above the transition temperature to avoid residual strain (permanent deformation).  Rapid fixing of temporary shape by immobilising the polymeric chains without creep.  SMPs possess two material phases. The glass and the rubber phases. In the glass phase, the material is rigid and cannot be easily deformed.  When the temperature is greater than "Glass transition temperature", the material enters the soft rubber phase and becomes easily deformable. Properties of SMP  Extent of deformation (%) = up to 200%  Density / g cm3 = 0.9 to 1.1  Critical temperature / °c = -10°C to 100°C  Recovery speeds minutes = <1second to several min.  Corrosion performance = excellent  Processing conditions = < 200°C , low pressure  Can be biodegradable Application of SMP in Sportswear It can be used to provide thermal insulation in both hot and cold climatic situations. In cold protective clothing, a high thermal insulation is generally achieved by using a low- density wadding or similar material between the outer shell and the lining fabrics. The air content of the wadding provides most of the insulation. A bi-material laminated film consisting of a layer of SMP and a layer of a compatible film can be used as a substitute for the wadding. With a glass transition temperature of, say, 25o C, the SMP will shrink by some 3% and become rigid at that temperature, with an out-of-plane deformation (Fig). The increased distance y between the fabric layers gives increased thermal insulation at the lower temperature.
  • 17. Advancement in Sportech vigneshdhanabalan@hotmail.com Page 17 Fig .The SMP component of the laminated film shrinks at 25o C and causes anincreased distance y between the two clothing layers. Actuation for heat protection at elevated temperatures (steam, boiling water, hot fluids, etc.) is achieved with a thin film that has been pretextured with an embossed pattern. A temporary flat shape is achieved by calendaring the embossed film, and this flat film will be used in the clothing. On exposure to high temperatures of 55o C and above, a reversion of the textured shape occurs and provides heat protection. An SMP membrane with flexible moisture barrier property has beenpresented with the trade name Diaplex by Mitsubishi Heavy Industry. The function is based on a change in the micro-Brownian motion in the segmental polyurethane structure. The molecular structure is rigid at temperatures below the activation point and prevents permeation of water molecules. When the temperature rises above the activation point the thermal vibration of the softmolecule segments creates gaps between the membrane molecules, thusincreasing the moisture permeability. The activation temperature can betailored by changing the polymer structure. A drysuit (developed by U.S army) keeps the wearer dry in cold water and which can also be worn in a warm air environment without causing discomfort from sweating can be used as sportswear. For clothing applications, the desirable temperatures for the shape memory effect to be triggered will be near body temperature. In practice, a shape memory alloy is usually in the shape of a spring. The spring is flat below the activation temperature but becomes extended above it. By incorporating these alloys between the layers of a garment, the gap between the layers can be substantially increased above the activation temperature. Consequently, considerably improved protection against external heat is provided.
  • 18. Advancement in Sportech vigneshdhanabalan@hotmail.com Page 18 The SMP membrane can be applied on to the sportswear, due to which when the temperature raises above certain critical temperature the intermolecular rupture of membrane takes place which increases the pores due to which breathability, moisture and heat regulation of the body increases. Auxetic material When stretched in the longitudinal direction, auxetic materials get fatter rather than thinner, in contrast to conventional materials. Poisson's ratio, which is defined as the ratio of the lateral contractile strain to the longitudinal tensile strain for materials undergoing uniaxial tension in the longitudinal direction, is in the region of 0.2±0.4 for most solids. Auxetic materials have a negative Poisson's ratio. Auxetic materials have previously been utilised, for example as graphite core structures in nuclear reactors. Polymeric and metallic auxetic foams with convoluted cell structures were developed in the 1980s and found various uses in packaging, sound insulation, filtration, shock absorption and sponge materials. As a result of more recent research work, production of auxetic polymers with specifically tailored properties is now possible, and fibres of auxetic polypropylene have been produced at the Bolton Institute in the UK. Currently, the use of auxetic materials in textiles is limited to the expanded PTFE membranes, where the auxetic property is not really utilised. However,there is a growing interest in future clothing applications for personal protection (energy absorption and impact resistance) and supportive garments (constant pressure structures). Other auxetic fibre applications are expected in fibre-reinforced composites (fibre pull-out resistance, tough fracture, energy absorption and impact resistance), filtration (release of entrapped particles, microporous structure), medical bandages (wear resistance, constant pressure).
  • 19. Advancement in Sportech vigneshdhanabalan@hotmail.com Page 19 Conclusion  The possible use of smart materials and wearable technologies opens new perspectives in the field of functional clothing for sports textile.  Extensive research activities in universities and research institutes as well as in companies worldwide had proceeded and brought new solutions to the market.  The applications that have been presented here are just the tips of the eyesberg of products that would become a commercial product in the nearby future.  Sportswear is the one of the most promising applications for SFIT (smart fabrics and intelligent textile).  Products which change their properties according to the physical performance and/are the environmental conditions are practically obtaining more focus in the sports wear market.  Through the presentation of the paper we find ourselves proud to show the future of sports textile.  At this stage we cannot describe it completely because this technology is in the developing stage. References  Textile in sports edited by R.Shishoo  The Indian Textile Journal (December 2010) Page no. 11  Technical Textile International (July/August 2012) Page no. 9  Wikipedia  http://www.crgrp.com/technology/portfolio/veriflex.html  http://www.azom.com/article.aspx?ArticleID=6038  http://www.gzespace.com/gzenew/index.php?pg=shape_memory_polimer&lang=en  http://www.ntcresearch.org/pdf-rpts/AnRp05/M05-GT14-A5.pdf  University of Boras ( Application of Ultra Smart Textiles in Sportswear and Garments) 26.05.2010  World Active Sportswear Journal (June 2011) Page no. 20  Textile Asia Journal (January 2009) Page no. 12  Texincon (1991 to 2010)  Textilveredlung (1993, April) Page no.5  www.fibresource.com