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Research and Development of HCNG
     (Hydrogen enriched Natural Gas)
   Internal Combustion Engines

            Prof. Dr. Fanhua Ma
             mafh@tsinghua.edu.cn
            TEL/FAX: 86-10-62785946
     State Key Laboratory of Automotive
              Safety & Energy
             Tsinghua University
中国石油年需求与缺口数量
                 The Oil Demand and Gap in China
                                                        道路交通需求量
      500.0                                             Oil Demand in
                                                        Transportation
                中国石油总需求量
      400.0
                Total Oil Demand


      300.0
                                                  石油需求与
                                                  供给的缺口
百万吨




                                                   The gap
      200.0

                                                            中国石油年产量
                                                            Oil Production
      100.0




        0.0
              2000      2010       2020   2030   2050
Natural Gas Vehicles (NGVs) in China

 In last decade natural gas production increased
 relatively rapidly. Strongly Supported by China
 government NGVs population increased very
 rapidly from less than ten thousands in 1999 to
 0.5 millions in 2009, and the natural gas stations
 increased very rapidly from less than 50 in 1999
 to about 1000 in 2009.
中国天然气汽车从1999年不到1万辆增加到2009年50万辆,天然气加
气站从1999年不到50座增加到2009年1300多座。



                                                  3
发展CNG、HCNG汽车的背景和意义
       Background and Significance of Developing
               HCNG and CNG Vehicles
环保节能及实现我国汽车工业发展的挑战
Environment protection, energy saving and the challenges of
development of China auto industry
石油依赖性和国家能源安全

Oil dependence and China’s energy security
汽车保有量增加,污染加剧

Vehicle population growing and environment pollution
aggravating
未来氢能发展提供的机遇

Opportunity from hydrogen energy development in the future
发展HCNG汽车的背景和意义
Background and Significance of Developing HCNG Vehicles

   在天然气发动机燃料中加入适量的氢气(即氢气/天然气混合气,简称
“HCNG” ),可以提高混合气燃烧速度、扩大稀燃极限,从而提高发动机的热效
率、可降低排放,这是目前国内外正在研究的热点问题。
Taking hydrogen enriched compressed natural gas (HCNG) as a fuel in CNG
engine can increase the burning speed, widen the lean burn limit. For its
high efficiency and better emission, HCNG engine is being studied
worldwide.


    近年来,国外开展了HCNG发动机的基础研究及应用研究,其中美国、加拿大、
欧盟日本等国的研究最为活跃。在美国能源部(DOE)等支持下,美国Colorado
州立大学、HCI公司(Hydrogen Components Inc.)、加拿大Westport等单位
较早就开始了氢气/天然气发动机的研究,取得了许多研究开发及示范应用成果。
In recent years, some countries carried out the basic research on HCNG
engine actively, especially in the USA, Canada,EU and Japan.
With the supports of Department of Energy (DOE) etc., Colorado University
HCI company (Hydrogen Components Inc.) ,Westport Inc. etc. started the
research on HCNG engine early, and got lots of achievements of research
and demonstration.
发展HCNG汽车背景和意义
Background and Significance of Developing
HCNG and CNG Vehicles
                 Cummins – Westport’s
                    HCNG Engine                        Cummins-Westport
                                                             B Gas plus
                                          Engine       6 cylinders,inline,
                                                       Turbocharged and
                                                             intercooled
                                        Bore,Stroke     102mm, 120mm
                                        Compression         10.5:1
                                            Ratio
                                        Displacement          5.9 L
                                        H2/HCNG by            20%
                                          volume
                                           Power       230 BHP (172 Kw)
                                                           @ 2800 RPM
                                          Torque        677 Nm @ 1600
                                                              RPM
    HCNG buses demonstration in
    Sunline Transit, California, USA
从天然气汽车到氢能汽车的发展路径
   The Development Path from CNG Vehicles to Hydrogen Vehicles
                                              解决燃料电池电动
       H2 作为内燃机汽车燃料是过渡
示范过程


                                              汽车实用化问题
       HCNG( H2+CNG ) 解决氢能电动汽车
                       特殊性问题                    氢燃料电池汽车

                                  气-电混合电       • 零排放,
                  解决氢能汽车           动汽车         •燃料消耗下降
                  一般性问题         •满足欧Ⅳ以上        25% 以 上 , 动 力 增
  存在问题:
                   HCNG混合燃      排放标准,          加
  排放标准偏低            料汽车         •燃料消耗下降        •价 格 与 纯 电 动
  甲烷排放
                                15%以上,动力
  燃料经济性比柴         •满足欧Ⅲ以上                      汽车相当
                                增加
  油机低20%—40%      排放标准,动力
  续行里程不够长         性提高           •串联式机电混        •串 联 混 合 动 力
                                合动力系统          传动
       天然气汽车      •机械式动力传
                  动系统           •火花点燃式内        •燃 料 电 池 发 动
  •满足欧Ⅱ排放                       燃发电机组          机
                  •点燃式内燃机
  •火 花 点 燃 式 内                  •HCNG 混 合 燃
  燃机              •HCNG 混 合 燃                  •100%氢气燃料
                                料
  •100%天然气
                  料                            (压缩氢气)
                                •天然气加气站
  •天然气加气站         •天然气加气站       +制氢设备        •天然气加气站+
                  +制氢设备                      重整制氢设备
        已有基础         第一阶段            第二阶段         第三阶段
       (2004年前)    (2005年开始)       (2006年开始)    (2010年开始)
清华大学HCNG发动机试验台
   HCNG engine’s Test Bench in Tsinghua




发动机与电涡流测功相连,可测量和控制转速
与负荷。
The engine was coupled to an eddy-current
dynamometer for engine speed & load
measurement and control.
HCNG Engine’s Experimental Systems




Three performance 、emission experiment benches
Reliability test base in Nanchong Dongfeng
CVS total flow test equipment and transient test-bed
catalyst test bench
发动机缸内压力的测量系统
Engine’s In-cylinder Pressure Measurement System
Main Technical Approach

                   电控技术
                   电控点火、喷射
  后处理技术                         NG控制策略
                               空燃比、怠速、增压、
低背压、低起燃度、热抗振强
                               过渡工况、自学习控制




  可靠性技术                         NG喷射技术
新型耐磨材料、活塞表面处理                   专用混合器,均质混合




                                高能点火技术
                                 点火电压3.5万伏
     增压中冷技术
   空-空,废气旁通,水冷      稀薄燃烧技术
                     空然比26.5
Dongfeng CNG Engines’ Performances
     型号         EQD160N-30/40   EQD180N-30/40           EQD210N-30/40   EQD230N-30/40
                六缸、直列、四冲程、水冷、涡轮增压、空空中冷、电控多点喷射集中喷射、点
     型式
                               燃式发动机
    缸径X冲程                                   105X120
   总排量(L)                                       6.234
    压缩比                                         10:1
    增压器                             水冷式带废气放气阀增压器
     点火                               高能无分电器分组点火
  曲轴箱通风方式                                  闭式曲轴箱通风
    燃烧类型                                        稀燃
     燃料                                    LNG / CNG
 怠速转速(r/min)                                750±50
 额定转速(r/min)                                    2800
  额定功率(kW)           118             132                    154              172
最大扭矩(N*m)/转速(
                420/1400~1600   580 /1400~1600      620 /1400~1600      700 /1400~1600
    r/min)
全负荷最低燃气消耗率(g/
                                                ≤205
    kW*h)
    后处理器                                氧化型催化转化器
     排放                                     国Ⅲ/国Ⅳ
Dongfeng CNG Engines and Vehicles
 已开发的主要载重车型

国内首批LNG环卫车
服务北京奥运场馆

                     KZ5 /KZ4 (LNG)环卫车   EQ1141K(LNG)环卫车




 EQ5118ZYS压缩式垃圾清运车      EQ1118K53D载货车        EQ1165FJ载货车




    EQ1141K7D环卫车        EQ1165K2载货车         DQD5256KPS2洒水车
Dongfeng CNG Engines and Vehicles
已匹配主要的公交车型



自主开发的天然气发动机
用于重庆亚太市长峰会


                       重庆
        北京




三亚、海口   鄂尔多斯   四川达州     泰国     孟加拉
Dongfeng-Tsinghua Cooperated Projects:
                          LNG Engine R&D
The base engine is DCI 11 Diesel engine with
common rail
。
    Rated Power       Max torque
    (kW/r/min)       (N.m/r/min)
      295/1900       1680/1100~1300




                 EQRN400-30LNG engine and LNG truck
Technical Approach of HCNG Engine
电子控制HCNG进气管喷射
Electronic control HCNG injection in the engine’s manifold
空燃比开环控制→闭环控制
Open → Close- loop control of Air-Fuel ratio
电控高能点火
High-energy ignition with electronic control
稀薄燃烧
Lean burn
水冷式增压器
water-cooled supercharger
氧化型催化器
Oxidation catalyst
CNG Supply and Injection System of Engine




     LNG气瓶
               汽化器         缓冲罐
Injected HCNG Supply System

                                    mixer                                        Air
                                                    Turbo-charger               filter


  Throttle valve   CNG nozzle


                                   driver                  Solenoid
                                   module                   valve            Second stage
                                                                               reducer
       Engine                ECM


     CNG bottle                 High Pressure         filter          first stage reducer
                                Solenoid Valve

 CNG                        air                  mixture

exhaust                   line pencil
EQD180N-30 CNG
Engine's Structural Parameter and Performance
       Type                             EQD180N-30
      Pattern           Four strokes、water-cooled、turbocharged
                         and intercooled、single-point electronic
                            control injection、ignition engine、
 Cylinder diameter                   Oxidation catalyst
      ×stroke                         105mm×120mm
Compression ration                          10:1
   Displacement                             6.234L
        Fuel                                 CNG
      Ignition          high-energy free distributor electric control
 Combustion Form                         Lean burn
   Rated power                        132kW/2800r/min
  Maximum torque                     540N.m/1400r/min
Lowest full-load fuel                    205g/kW.h
 consumption rate
     Emission                          Europe Ⅲ、Ⅳ
Eelctric Control of HCNG Injection Engine
HCNG单点电喷系统组织示意图




      HCNG
HCNG Engine’s System Composition
      and Technical Design




                     EQD180N-30
EQD180-30
HCNG Engine          HCNG Engine
Injected HCNG Supply system -
         HCNG Gas Injector


                    low resistance
                    operation temperature range:
                     — 40 ℃ ~120℃
                    normal operation voltage:12V




HCNG Gas Injector
Injected HCNG Supply System

                               pressure regulator
                                    test-bed




Low voltage electromagnetic
 and low pressure regulator
   Output pressure:450±50kPa   High-pressure regulator
    输出压力控制在450±50kPa
                                 Output pressure:1±0.15MPa
High Energy Ignition System



                    less ignition energy loss
                    Front sealed、with air bleed hole
                    high temperature resistant :180℃




High-voltage wire
ECU Hardware System of HCNG Engine
Electronic Injection System
ECU and nozzle driver module

                               ECU
                               Function:
                                 control software
                                 calibration data
                               Application conditions :
                                 Working temperature:-40 ~ 85℃
                                 Working voltage:9 ~16 V
                                 Shell can’t be attached with iron,
                                 installed in the cab

                               Nozzle driver module
Electronic Control Simulation System


                     calibrate after upgrading ECM

                     ensure electronic injection

                   system develop successfully

                     shorten bench calibration time
Control Strategy
Validation of the Control System
Oxidation Catalyst Performance test
           and Match with Engine


                            Oxidation Catalyst made in China




Oxidation Catalyst from ECOCAT



                                                       30
HCNG Engine R&D
   in Tsinghua
焦 炉 气( Coke Oven Gas ) 简 介
   焦炉气(Coke Oven Gas,COG),又称焦炉煤气,是炼焦
工业的副产品。 一般每吨干煤可生产焦炉气300~350m3(标准
状态)。其主要成分为氢气H2(55%~60%)和甲烷CH4
(23%~27%),另外还含有少量的一氧化碳CO(5%~8%)、C2
以上不饱和烃 CnHm(2%~4%)、二氧化碳CO 2(1.5%~3%)、
氧气(0.3%~0.8%))、氮气(3%~7%)。焦炉气热值为每标准立方米
17~19MJ 。

  我国是世界上最大的焦炭生产、消费和出口国
     2008年焦炭产量3.2亿吨,占全球总产量的近60%。
  国家统计据数据显示,全国每年白白排放掉的焦炉煤气就
  有600多亿立方米(相当于3000万吨汽柴油),接近6个西
  气东输工程的输气量。

          焦炉煤气的清洁高效利用迫在眉睫!
山西2005年焦炉
煤气产量为143.91
亿立方米,占全国
总量的29.8%。产
量排在前5位的其
他4省是辽宁、
河北、山东和
湖北,产量依次
为65.3亿、43.5亿、
38.1亿、31.2亿立
方米,这5省焦炉
煤气的总产量之和
占全国的66.6%。
Schematic of HCNG fuel supply system




Schematic of the on-line hydrogen- natural gas mixing system used
Principles of HCNG on-line mixing system

                                 At first the measured NG mass flow
                                 rate is converted to an analog voltage
                                 signal which is then transferred to a
                                 computer for further processing after
                                 A/D converting. By using the stocked
                                 control software and the input value of
                                 blending ratio as well as the received
                                 signal of NG mass flow rate, the
                                 computer then calculates out the
                                 desired hydrogen mass flow rate.

This calculated value is used as an immediate input into the hydrogen
flow controller, which controls the flow rate according to the desired
value through varying the openness of the integrated valve. This resulted
hydrogen flow rate need to be re-checked by a high accuracy mass flow
meter located downstream the flow controller. If significant difference
between the measured hydrogen flow rate and previously calculated one
is found, a feedback control would become active to ensure control
accuracy.
掺氢对稀燃极限的影响
Effect of Hydrogen Addition on Lean Operation Limit
                                                        COVIMEP



                                                  稀燃极限定义为平均
                                                  指示压力的循环变动
                                                  达到10%时的过量空
                                                  气系数

                                                  The lean operation
                                                  limit was defined as
                                                  the excess air ratio
                                                  at which COVIMEP
                                                  reaches 10%.




     掺氢比的提高可以拓宽稀燃极限,改善发动机的稀燃性能。
     Hydrogen enrichment could significantly extend the lean
     operation limit, improve the engine’s lean burn ability.
燃烧持续期                   Combustion Duration




在空燃比确定的情况下,随着掺氢比的提高,燃烧持续期会缩短。
这表明,掺氢确实可以提高火焰传播速度。
At a given lambda, combustion duration shortened as hydrogen
fraction increased. This illustrated that hydrogen addition could
indeed speed up flame propagation.
发动机热效率和排放特性
Engine Thermal Efficiency and Emission Characteristics
                                                          At fixed ignition timing
                                                                 NOx

                                                         图中λm_0和
                                                         λm_10% 分别表示
                                                         CNG和掺氢比为
                                                         10%的HCNG的稀燃
                                                         极限。
                                                         λm_0 and λm_10% in
                                                         these figures represent
                                                         lean limit for NG and
                                                         10% hydrogen fraction
                                                         mixture respectively.
   同一空燃比下,掺氢比越高,NOx排放量越大。这是因为氢气的
   加入提高了燃烧温度,而高温是NOx形成的主要因素。
   More hydrogen added would result in more NOx emission at a given
   lambda, this is thought to be caused by the elevated combustion
   temperature due to hydrogen addition since high temperature was a
   catalyst for the formation of NOx
HC




由上图可看出,掺氢可降低HC的排放,这是因为氢气可以提高火焰传播速度,减
小淬熄距离,从而降低了不完全燃烧的可能性。C浓度由于氢气的加入而有所降低
也是HC排放下降的一个原因。
Reduced HC emission by hydrogen enrichment was observed in our
study which could be explained by the fact that hydrogen could speed up
flame propagation and reduce quenching distance, thus decreasing the
possibilities of incomplete combustion . Carbon concentration of the fuel
decreased due to hydrogen addition was another reason for HC emission
reduction.
CO




在过量空气系数小于1.7的区域,掺氢与否对于CO排放的影响不明显,
但一旦过量空气系数超过1.7,掺氢越多,CO排放越低。 这归功于氢气
良好的燃烧特性,特别是在稀燃料的情况下。
In the region where lambda was less than 1.7, adding hydrogen or not
showed no significant difference on CO emission, but once lambda
exceeded 1.7, more hydrogen addition resulted in much less exhaust
CO. This was also attributed to hydrogen’s ability to strengthen
combustion, especially for lean fuel-air mixtures.
指示热效率                    Indicated Thermal Efficiency




当过量空气系数小于1.5时,掺氢并没改善发动机的热效率,反而50%
掺氢时的热效率与纯天然气发动机相比有明显的下降。

when lambda was under 1.5, hydrogen addition was not beneficial to
engine’s efficiency improvement. Rather, the engine’s thermal
efficiency exhibited an obvious drop when fuelled by HCNG
containing 50% hydrogen compared to pure NG operation.
NOx




相同指示热效率下,掺氢比增加可降低NOx排放。相同NOx排放
下比较,掺氢越多,热效率越高。
At given ITE, NOx emission decreased as the increase of
hydrogen fraction and at given NOx emission, ITE increased as
more hydrogen is added.
掺氢比增加,NOx排放与HC排放相对曲线向左下角偏移,这说明
了掺氢可降低NOx排放与HC排放相互矛盾的程度。

The trade-off curve moves further to the left-bottom as more
hydrogen is added which meant that tradeoff between NOx and
HC emission was indeed alleviated by hydrogen addition.
通过HCNG燃料空燃比调整特性试验的结果对比原机燃用天然气的MAP数据,优先选择
在扭矩相近的前提下NOx比排放降低的最大空燃比点作为目标空燃比,由此得出HCNG发
动机的目标空燃比MAP图;在点火提前角的标定过程中,实际空燃比保持在HCNG发动
机的目标空燃比,在保持动力性不变的前提下尽量推迟点火,以降低NOX排放,最终得
到的点火提前角MAP图。
The calibrated air-fuel ratio and spark timing map were achieved based on the
goals of the emission ( especialy NOx ), specific fuel consumption and power
output of the HCNG engine.
HCNG Engine’s Performance

外特性标定的目的是使发动机最大功率,最大转矩和最低气
耗率达到预定要求。


                           标定后的
                           20%HCNG 动
                           力性与原天然
                           气发动机大致
                           相当,但经济
                           性要好于天然
                           气发动机
ETC Emission Test
20%HCNG and CNG Engine’s ETC Emissions Comparison
( without catalyst )




 掺入20%氢气后,在不带催化器的情况下,NOx,CO,
NMHC,CH4排放和BSFC相对于原天然气发动机分别下降
51%,36%,60%,47%和7%
 在不带催化器的情况下通过掺入氢气有潜力使发动机达到
国(欧)三排放标准。
ETC Emission Test
Fueled with 20% H2 HCNG for different catalyst:
   采用ECOCAT Ⅰ型,ECOCAT Ⅱ型和昆贵所催化器,不带加速加
   浓,进行20%掺氢比ETC循环试验。




                                 三种催化器都能使发动机排
                                放达到环境友好型汽车(EEV)
                                标准。
                                 三种氧化型催化转化器转化
                                效率大小排序为:
                                ECOCATⅡ型>国产催化器
                                >ECOCAT Ⅰ型。
                                 随着催化效率的提高,发动
                                机动力性下降逐渐增大
HCNG (20% H2) Engine ETC Emission Data


           欧Ⅳ限值    欧Ⅴ限值     EEV限值     实测值
            Euro   Euro Ⅴ     EEV    Measured
            data    data      data     data

  NOx       3.5     2.0      2.0     1.18-1.60
(g/kW.h)
   CO       4.0     4.0      3.0     0.26-0.80
(g/kW.h)
 NMHC       0.55    0.55     0.40    0.09-0.20
(g/kW.h)
  CH4       1.1     1.1      0.65    0.40-0.50
(g/kW.h)
中美双方在美国签署合作备忘录




Tuesday, November 30, 2004
Argonne National Laboratory
 3rd Joint Working Group Meeting
 Breakout Group 2:
 Hydrogen Demonstration,
 Fuel Cells, and Transportation
氢气-天然气混合燃料(HCNG)客车
HCNG混合动力城市客车 Hybrid HCNG City Bus

                        串联型混合动力系统方案




                                                                        Wheel
  APU




                                                           Motor
                                                           Electric
                         Electric
                         Generator
   CNG Fuel




                                                                      Differential
              CNG ICE




                                     Rectifier




                                                 Battery
Hybrid system -APU
HCNG Bus Max. Speed and Acceleration Time
HCNG Bus Fuel Consumption
 3 buses ,20,000Km Demo.
HCNG bus performance
          compared with CNG Bus

        Power Performance     Fuel Economy
       0~50km/h      Max     Equivalent CNG
        time (s)    Speed     consumption
                    (km/h)     (kg/100km)
CNG
Bus      17.9        84.1        38.97

HCNG
 Bus     17.9        84.1        36.11
Some Projects

● MOST 863 Project“HCNG engine R & D”


● MOST 863 Project “HCNG Bus R/D and Hydrogen
   Generation by Renewable Energy”, Cooperated with
   DOE.


● MOST 863 Project “Key Technologies Cooperation
  Research on Hydrogen Utilization based on Hydrogen
  Infrastructure”
Some Patents

● “Calibration method of HCNG Engine”。
    China patent:200710062635。

● “ HCNG fuel for optimized hydrogen fraction in
 HCNG engine”。China patent: 200710062636。


● “Control and operation methods for
 different hydrogen fraction in HCNG engine”
 China patents: 200710175797.9
Some Papers

    Combustion and emission characteristics of a port-injection HCNG engine under various
1      ignition timings, INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, JAN
                                      2008, 33(2):816-822

    Effects of hydrogen addition on cycle-by-cycle variations in a lean burn natural gas spark-
2         ignition engines, INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, JAN
                                         2008, 33(2):823-831

      Experimental study on thermal efficiency and emission characteristics of a lean burn
3           hydrogen enriched natural gas engine, INTERNATIONAL JOURNAL OF
                      HYDROGEN ENERGY, DEC 2007, 32(18):5067-5075

    Study on the extension of lean operation limit through hydrogen enrichment in a natural
4          gas spark-ignition engine, INTERNATIONAL JOURNAL OF HYDROGEN
                                ENERGY, FEB 2008, 33(4):1416-1424

    Influence of different volume percent hydrogen/natural gas mixtures on idle performance
5
               of a CNG engine, ENERGY & FUELS, MAY-JUN 2008, 22(3):1880-1887
其它具有代表性的论文目录(共26篇)

      Development and validation of a quasi-dimensional combustion model for SI engine
6      fuelled by HCNG with variable hydrogen fractions, INTERNATIONAL JOURNAL
                    OF HYDROGEN ENERGY, SEP 2008, 33(18):4863-4875
       Effects of combustion phasing, combustion duration, and their cyclic variations on
7
        Spark-Ignition (SI) engine efficiency, ENERGY & FUELS, AUG 2008, 22:3022-3028
      Study on combustion behaviors and cycle-by-cycle variations in a turbocharged lean
8           burn natural gas S.I. engine with hydrogen enrichment, INTERNATIONAL
                                    JOURNAL OF HYDROGEN
        An investigation of optimum control of a spark ignition engine fueled by NG and
9
         hydrogen mixtures, INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
     A Quasi-Dimensional Combustion Model for SI Engines Fuelled by Hydrogen Enriched
10              Compressed Natural Gas,SAE Paper No. 2008-01-1633, 2008

      Development and Validation of an On-line Hydrogen-Natural Gas Mixing System for
11          Internal Combustion Engine Testing, SAE Paper No. 2008-01-1580, 2008
Some Conclusions
Lean burn is one of the effective approach for HCNG Engine,
and Spark timing optimization is necessary.

15~25% Hydrogen fraction in volume of HCNG is a good
range for the HCNG Engine. Primary Research results
indicate that 55% Hydrogen fraction in volume of HCNG is
also another choice for the HCNG Engine.

Fueled by 20% HCNG the engine’s emission can meet Euro
EEV (Enhanced Environmental Vehicle) power output, fuel
consumption can be kept almost unchanged compared with
CNG engine.
Prof. Dr. Fanhua MA
mafh@tsinghua.edu.cn
TEL/FAX: 86-10-62785946
State Key Laboratory of Automotive
Safety & Energy
Tsinghua University,Beijing, China




Thanks for Attention !

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Fanhua ma

  • 1. Research and Development of HCNG (Hydrogen enriched Natural Gas) Internal Combustion Engines Prof. Dr. Fanhua Ma mafh@tsinghua.edu.cn TEL/FAX: 86-10-62785946 State Key Laboratory of Automotive Safety & Energy Tsinghua University
  • 2. 中国石油年需求与缺口数量 The Oil Demand and Gap in China 道路交通需求量 500.0 Oil Demand in Transportation 中国石油总需求量 400.0 Total Oil Demand 300.0 石油需求与 供给的缺口 百万吨 The gap 200.0 中国石油年产量 Oil Production 100.0 0.0 2000 2010 2020 2030 2050
  • 3. Natural Gas Vehicles (NGVs) in China In last decade natural gas production increased relatively rapidly. Strongly Supported by China government NGVs population increased very rapidly from less than ten thousands in 1999 to 0.5 millions in 2009, and the natural gas stations increased very rapidly from less than 50 in 1999 to about 1000 in 2009. 中国天然气汽车从1999年不到1万辆增加到2009年50万辆,天然气加 气站从1999年不到50座增加到2009年1300多座。 3
  • 4. 发展CNG、HCNG汽车的背景和意义 Background and Significance of Developing HCNG and CNG Vehicles 环保节能及实现我国汽车工业发展的挑战 Environment protection, energy saving and the challenges of development of China auto industry 石油依赖性和国家能源安全 Oil dependence and China’s energy security 汽车保有量增加,污染加剧 Vehicle population growing and environment pollution aggravating 未来氢能发展提供的机遇 Opportunity from hydrogen energy development in the future
  • 5. 发展HCNG汽车的背景和意义 Background and Significance of Developing HCNG Vehicles 在天然气发动机燃料中加入适量的氢气(即氢气/天然气混合气,简称 “HCNG” ),可以提高混合气燃烧速度、扩大稀燃极限,从而提高发动机的热效 率、可降低排放,这是目前国内外正在研究的热点问题。 Taking hydrogen enriched compressed natural gas (HCNG) as a fuel in CNG engine can increase the burning speed, widen the lean burn limit. For its high efficiency and better emission, HCNG engine is being studied worldwide. 近年来,国外开展了HCNG发动机的基础研究及应用研究,其中美国、加拿大、 欧盟日本等国的研究最为活跃。在美国能源部(DOE)等支持下,美国Colorado 州立大学、HCI公司(Hydrogen Components Inc.)、加拿大Westport等单位 较早就开始了氢气/天然气发动机的研究,取得了许多研究开发及示范应用成果。 In recent years, some countries carried out the basic research on HCNG engine actively, especially in the USA, Canada,EU and Japan. With the supports of Department of Energy (DOE) etc., Colorado University HCI company (Hydrogen Components Inc.) ,Westport Inc. etc. started the research on HCNG engine early, and got lots of achievements of research and demonstration.
  • 6. 发展HCNG汽车背景和意义 Background and Significance of Developing HCNG and CNG Vehicles Cummins – Westport’s HCNG Engine Cummins-Westport B Gas plus Engine 6 cylinders,inline, Turbocharged and intercooled Bore,Stroke 102mm, 120mm Compression 10.5:1 Ratio Displacement 5.9 L H2/HCNG by 20% volume Power 230 BHP (172 Kw) @ 2800 RPM Torque 677 Nm @ 1600 RPM HCNG buses demonstration in Sunline Transit, California, USA
  • 7. 从天然气汽车到氢能汽车的发展路径 The Development Path from CNG Vehicles to Hydrogen Vehicles 解决燃料电池电动 H2 作为内燃机汽车燃料是过渡 示范过程 汽车实用化问题 HCNG( H2+CNG ) 解决氢能电动汽车 特殊性问题 氢燃料电池汽车 气-电混合电 • 零排放, 解决氢能汽车 动汽车 •燃料消耗下降 一般性问题 •满足欧Ⅳ以上 25% 以 上 , 动 力 增 存在问题: HCNG混合燃 排放标准, 加 排放标准偏低 料汽车 •燃料消耗下降 •价 格 与 纯 电 动 甲烷排放 15%以上,动力 燃料经济性比柴 •满足欧Ⅲ以上 汽车相当 增加 油机低20%—40% 排放标准,动力 续行里程不够长 性提高 •串联式机电混 •串 联 混 合 动 力 合动力系统 传动 天然气汽车 •机械式动力传 动系统 •火花点燃式内 •燃 料 电 池 发 动 •满足欧Ⅱ排放 燃发电机组 机 •点燃式内燃机 •火 花 点 燃 式 内 •HCNG 混 合 燃 燃机 •HCNG 混 合 燃 •100%氢气燃料 料 •100%天然气 料 (压缩氢气) •天然气加气站 •天然气加气站 •天然气加气站 +制氢设备 •天然气加气站+ +制氢设备 重整制氢设备 已有基础 第一阶段 第二阶段 第三阶段 (2004年前) (2005年开始) (2006年开始) (2010年开始)
  • 8. 清华大学HCNG发动机试验台 HCNG engine’s Test Bench in Tsinghua 发动机与电涡流测功相连,可测量和控制转速 与负荷。 The engine was coupled to an eddy-current dynamometer for engine speed & load measurement and control.
  • 9. HCNG Engine’s Experimental Systems Three performance 、emission experiment benches Reliability test base in Nanchong Dongfeng CVS total flow test equipment and transient test-bed catalyst test bench
  • 11. Main Technical Approach 电控技术 电控点火、喷射 后处理技术 NG控制策略 空燃比、怠速、增压、 低背压、低起燃度、热抗振强 过渡工况、自学习控制 可靠性技术 NG喷射技术 新型耐磨材料、活塞表面处理 专用混合器,均质混合 高能点火技术 点火电压3.5万伏 增压中冷技术 空-空,废气旁通,水冷 稀薄燃烧技术 空然比26.5
  • 12. Dongfeng CNG Engines’ Performances 型号 EQD160N-30/40 EQD180N-30/40 EQD210N-30/40 EQD230N-30/40 六缸、直列、四冲程、水冷、涡轮增压、空空中冷、电控多点喷射集中喷射、点 型式 燃式发动机 缸径X冲程 105X120 总排量(L) 6.234 压缩比 10:1 增压器 水冷式带废气放气阀增压器 点火 高能无分电器分组点火 曲轴箱通风方式 闭式曲轴箱通风 燃烧类型 稀燃 燃料 LNG / CNG 怠速转速(r/min) 750±50 额定转速(r/min) 2800 额定功率(kW) 118 132 154 172 最大扭矩(N*m)/转速( 420/1400~1600 580 /1400~1600 620 /1400~1600 700 /1400~1600 r/min) 全负荷最低燃气消耗率(g/ ≤205 kW*h) 后处理器 氧化型催化转化器 排放 国Ⅲ/国Ⅳ
  • 13. Dongfeng CNG Engines and Vehicles 已开发的主要载重车型 国内首批LNG环卫车 服务北京奥运场馆 KZ5 /KZ4 (LNG)环卫车 EQ1141K(LNG)环卫车 EQ5118ZYS压缩式垃圾清运车 EQ1118K53D载货车 EQ1165FJ载货车 EQ1141K7D环卫车 EQ1165K2载货车 DQD5256KPS2洒水车
  • 14. Dongfeng CNG Engines and Vehicles 已匹配主要的公交车型 自主开发的天然气发动机 用于重庆亚太市长峰会 重庆 北京 三亚、海口 鄂尔多斯 四川达州 泰国 孟加拉
  • 15. Dongfeng-Tsinghua Cooperated Projects: LNG Engine R&D The base engine is DCI 11 Diesel engine with common rail 。 Rated Power Max torque (kW/r/min) (N.m/r/min) 295/1900 1680/1100~1300 EQRN400-30LNG engine and LNG truck
  • 16. Technical Approach of HCNG Engine 电子控制HCNG进气管喷射 Electronic control HCNG injection in the engine’s manifold 空燃比开环控制→闭环控制 Open → Close- loop control of Air-Fuel ratio 电控高能点火 High-energy ignition with electronic control 稀薄燃烧 Lean burn 水冷式增压器 water-cooled supercharger 氧化型催化器 Oxidation catalyst
  • 17. CNG Supply and Injection System of Engine LNG气瓶 汽化器 缓冲罐
  • 18. Injected HCNG Supply System mixer Air Turbo-charger filter Throttle valve CNG nozzle driver Solenoid module valve Second stage reducer Engine ECM CNG bottle High Pressure filter first stage reducer Solenoid Valve CNG air mixture exhaust line pencil
  • 19. EQD180N-30 CNG Engine's Structural Parameter and Performance Type EQD180N-30 Pattern Four strokes、water-cooled、turbocharged and intercooled、single-point electronic control injection、ignition engine、 Cylinder diameter Oxidation catalyst ×stroke 105mm×120mm Compression ration 10:1 Displacement 6.234L Fuel CNG Ignition high-energy free distributor electric control Combustion Form Lean burn Rated power 132kW/2800r/min Maximum torque 540N.m/1400r/min Lowest full-load fuel 205g/kW.h consumption rate Emission Europe Ⅲ、Ⅳ
  • 20. Eelctric Control of HCNG Injection Engine HCNG单点电喷系统组织示意图 HCNG
  • 21. HCNG Engine’s System Composition and Technical Design EQD180N-30 EQD180-30 HCNG Engine HCNG Engine
  • 22. Injected HCNG Supply system - HCNG Gas Injector low resistance operation temperature range: — 40 ℃ ~120℃ normal operation voltage:12V HCNG Gas Injector
  • 23. Injected HCNG Supply System pressure regulator test-bed Low voltage electromagnetic and low pressure regulator Output pressure:450±50kPa High-pressure regulator 输出压力控制在450±50kPa Output pressure:1±0.15MPa
  • 24. High Energy Ignition System less ignition energy loss Front sealed、with air bleed hole high temperature resistant :180℃ High-voltage wire
  • 25. ECU Hardware System of HCNG Engine
  • 26. Electronic Injection System ECU and nozzle driver module ECU Function: control software calibration data Application conditions : Working temperature:-40 ~ 85℃ Working voltage:9 ~16 V Shell can’t be attached with iron, installed in the cab Nozzle driver module
  • 27. Electronic Control Simulation System calibrate after upgrading ECM ensure electronic injection system develop successfully shorten bench calibration time
  • 29. Validation of the Control System
  • 30. Oxidation Catalyst Performance test and Match with Engine Oxidation Catalyst made in China Oxidation Catalyst from ECOCAT 30
  • 31. HCNG Engine R&D in Tsinghua
  • 32. 焦 炉 气( Coke Oven Gas ) 简 介 焦炉气(Coke Oven Gas,COG),又称焦炉煤气,是炼焦 工业的副产品。 一般每吨干煤可生产焦炉气300~350m3(标准 状态)。其主要成分为氢气H2(55%~60%)和甲烷CH4 (23%~27%),另外还含有少量的一氧化碳CO(5%~8%)、C2 以上不饱和烃 CnHm(2%~4%)、二氧化碳CO 2(1.5%~3%)、 氧气(0.3%~0.8%))、氮气(3%~7%)。焦炉气热值为每标准立方米 17~19MJ 。 我国是世界上最大的焦炭生产、消费和出口国 2008年焦炭产量3.2亿吨,占全球总产量的近60%。 国家统计据数据显示,全国每年白白排放掉的焦炉煤气就 有600多亿立方米(相当于3000万吨汽柴油),接近6个西 气东输工程的输气量。 焦炉煤气的清洁高效利用迫在眉睫!
  • 34. Schematic of HCNG fuel supply system Schematic of the on-line hydrogen- natural gas mixing system used
  • 35. Principles of HCNG on-line mixing system At first the measured NG mass flow rate is converted to an analog voltage signal which is then transferred to a computer for further processing after A/D converting. By using the stocked control software and the input value of blending ratio as well as the received signal of NG mass flow rate, the computer then calculates out the desired hydrogen mass flow rate. This calculated value is used as an immediate input into the hydrogen flow controller, which controls the flow rate according to the desired value through varying the openness of the integrated valve. This resulted hydrogen flow rate need to be re-checked by a high accuracy mass flow meter located downstream the flow controller. If significant difference between the measured hydrogen flow rate and previously calculated one is found, a feedback control would become active to ensure control accuracy.
  • 36. 掺氢对稀燃极限的影响 Effect of Hydrogen Addition on Lean Operation Limit COVIMEP 稀燃极限定义为平均 指示压力的循环变动 达到10%时的过量空 气系数 The lean operation limit was defined as the excess air ratio at which COVIMEP reaches 10%. 掺氢比的提高可以拓宽稀燃极限,改善发动机的稀燃性能。 Hydrogen enrichment could significantly extend the lean operation limit, improve the engine’s lean burn ability.
  • 37. 燃烧持续期 Combustion Duration 在空燃比确定的情况下,随着掺氢比的提高,燃烧持续期会缩短。 这表明,掺氢确实可以提高火焰传播速度。 At a given lambda, combustion duration shortened as hydrogen fraction increased. This illustrated that hydrogen addition could indeed speed up flame propagation.
  • 38. 发动机热效率和排放特性 Engine Thermal Efficiency and Emission Characteristics At fixed ignition timing NOx 图中λm_0和 λm_10% 分别表示 CNG和掺氢比为 10%的HCNG的稀燃 极限。 λm_0 and λm_10% in these figures represent lean limit for NG and 10% hydrogen fraction mixture respectively. 同一空燃比下,掺氢比越高,NOx排放量越大。这是因为氢气的 加入提高了燃烧温度,而高温是NOx形成的主要因素。 More hydrogen added would result in more NOx emission at a given lambda, this is thought to be caused by the elevated combustion temperature due to hydrogen addition since high temperature was a catalyst for the formation of NOx
  • 39. HC 由上图可看出,掺氢可降低HC的排放,这是因为氢气可以提高火焰传播速度,减 小淬熄距离,从而降低了不完全燃烧的可能性。C浓度由于氢气的加入而有所降低 也是HC排放下降的一个原因。 Reduced HC emission by hydrogen enrichment was observed in our study which could be explained by the fact that hydrogen could speed up flame propagation and reduce quenching distance, thus decreasing the possibilities of incomplete combustion . Carbon concentration of the fuel decreased due to hydrogen addition was another reason for HC emission reduction.
  • 40. CO 在过量空气系数小于1.7的区域,掺氢与否对于CO排放的影响不明显, 但一旦过量空气系数超过1.7,掺氢越多,CO排放越低。 这归功于氢气 良好的燃烧特性,特别是在稀燃料的情况下。 In the region where lambda was less than 1.7, adding hydrogen or not showed no significant difference on CO emission, but once lambda exceeded 1.7, more hydrogen addition resulted in much less exhaust CO. This was also attributed to hydrogen’s ability to strengthen combustion, especially for lean fuel-air mixtures.
  • 41. 指示热效率 Indicated Thermal Efficiency 当过量空气系数小于1.5时,掺氢并没改善发动机的热效率,反而50% 掺氢时的热效率与纯天然气发动机相比有明显的下降。 when lambda was under 1.5, hydrogen addition was not beneficial to engine’s efficiency improvement. Rather, the engine’s thermal efficiency exhibited an obvious drop when fuelled by HCNG containing 50% hydrogen compared to pure NG operation.
  • 42. NOx 相同指示热效率下,掺氢比增加可降低NOx排放。相同NOx排放 下比较,掺氢越多,热效率越高。 At given ITE, NOx emission decreased as the increase of hydrogen fraction and at given NOx emission, ITE increased as more hydrogen is added.
  • 43. 掺氢比增加,NOx排放与HC排放相对曲线向左下角偏移,这说明 了掺氢可降低NOx排放与HC排放相互矛盾的程度。 The trade-off curve moves further to the left-bottom as more hydrogen is added which meant that tradeoff between NOx and HC emission was indeed alleviated by hydrogen addition.
  • 45. HCNG Engine’s Performance 外特性标定的目的是使发动机最大功率,最大转矩和最低气 耗率达到预定要求。 标定后的 20%HCNG 动 力性与原天然 气发动机大致 相当,但经济 性要好于天然 气发动机
  • 46. ETC Emission Test 20%HCNG and CNG Engine’s ETC Emissions Comparison ( without catalyst ) 掺入20%氢气后,在不带催化器的情况下,NOx,CO, NMHC,CH4排放和BSFC相对于原天然气发动机分别下降 51%,36%,60%,47%和7% 在不带催化器的情况下通过掺入氢气有潜力使发动机达到 国(欧)三排放标准。
  • 47. ETC Emission Test Fueled with 20% H2 HCNG for different catalyst: 采用ECOCAT Ⅰ型,ECOCAT Ⅱ型和昆贵所催化器,不带加速加 浓,进行20%掺氢比ETC循环试验。 三种催化器都能使发动机排 放达到环境友好型汽车(EEV) 标准。 三种氧化型催化转化器转化 效率大小排序为: ECOCATⅡ型>国产催化器 >ECOCAT Ⅰ型。 随着催化效率的提高,发动 机动力性下降逐渐增大
  • 48. HCNG (20% H2) Engine ETC Emission Data 欧Ⅳ限值 欧Ⅴ限值 EEV限值 实测值 Euro Euro Ⅴ EEV Measured data data data data NOx 3.5 2.0 2.0 1.18-1.60 (g/kW.h) CO 4.0 4.0 3.0 0.26-0.80 (g/kW.h) NMHC 0.55 0.55 0.40 0.09-0.20 (g/kW.h) CH4 1.1 1.1 0.65 0.40-0.50 (g/kW.h)
  • 49. 中美双方在美国签署合作备忘录 Tuesday, November 30, 2004 Argonne National Laboratory 3rd Joint Working Group Meeting Breakout Group 2: Hydrogen Demonstration, Fuel Cells, and Transportation
  • 51. HCNG混合动力城市客车 Hybrid HCNG City Bus 串联型混合动力系统方案 Wheel APU Motor Electric Electric Generator CNG Fuel Differential CNG ICE Rectifier Battery
  • 53. HCNG Bus Max. Speed and Acceleration Time
  • 54. HCNG Bus Fuel Consumption 3 buses ,20,000Km Demo.
  • 55. HCNG bus performance compared with CNG Bus Power Performance Fuel Economy 0~50km/h Max Equivalent CNG time (s) Speed consumption (km/h) (kg/100km) CNG Bus 17.9 84.1 38.97 HCNG Bus 17.9 84.1 36.11
  • 56. Some Projects ● MOST 863 Project“HCNG engine R & D” ● MOST 863 Project “HCNG Bus R/D and Hydrogen Generation by Renewable Energy”, Cooperated with DOE. ● MOST 863 Project “Key Technologies Cooperation Research on Hydrogen Utilization based on Hydrogen Infrastructure”
  • 57. Some Patents ● “Calibration method of HCNG Engine”。 China patent:200710062635。 ● “ HCNG fuel for optimized hydrogen fraction in HCNG engine”。China patent: 200710062636。 ● “Control and operation methods for different hydrogen fraction in HCNG engine” China patents: 200710175797.9
  • 58. Some Papers Combustion and emission characteristics of a port-injection HCNG engine under various 1 ignition timings, INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, JAN 2008, 33(2):816-822 Effects of hydrogen addition on cycle-by-cycle variations in a lean burn natural gas spark- 2 ignition engines, INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, JAN 2008, 33(2):823-831 Experimental study on thermal efficiency and emission characteristics of a lean burn 3 hydrogen enriched natural gas engine, INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, DEC 2007, 32(18):5067-5075 Study on the extension of lean operation limit through hydrogen enrichment in a natural 4 gas spark-ignition engine, INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, FEB 2008, 33(4):1416-1424 Influence of different volume percent hydrogen/natural gas mixtures on idle performance 5 of a CNG engine, ENERGY & FUELS, MAY-JUN 2008, 22(3):1880-1887
  • 59. 其它具有代表性的论文目录(共26篇) Development and validation of a quasi-dimensional combustion model for SI engine 6 fuelled by HCNG with variable hydrogen fractions, INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, SEP 2008, 33(18):4863-4875 Effects of combustion phasing, combustion duration, and their cyclic variations on 7 Spark-Ignition (SI) engine efficiency, ENERGY & FUELS, AUG 2008, 22:3022-3028 Study on combustion behaviors and cycle-by-cycle variations in a turbocharged lean 8 burn natural gas S.I. engine with hydrogen enrichment, INTERNATIONAL JOURNAL OF HYDROGEN An investigation of optimum control of a spark ignition engine fueled by NG and 9 hydrogen mixtures, INTERNATIONAL JOURNAL OF HYDROGEN ENERGY A Quasi-Dimensional Combustion Model for SI Engines Fuelled by Hydrogen Enriched 10 Compressed Natural Gas,SAE Paper No. 2008-01-1633, 2008 Development and Validation of an On-line Hydrogen-Natural Gas Mixing System for 11 Internal Combustion Engine Testing, SAE Paper No. 2008-01-1580, 2008
  • 60. Some Conclusions Lean burn is one of the effective approach for HCNG Engine, and Spark timing optimization is necessary. 15~25% Hydrogen fraction in volume of HCNG is a good range for the HCNG Engine. Primary Research results indicate that 55% Hydrogen fraction in volume of HCNG is also another choice for the HCNG Engine. Fueled by 20% HCNG the engine’s emission can meet Euro EEV (Enhanced Environmental Vehicle) power output, fuel consumption can be kept almost unchanged compared with CNG engine.
  • 61. Prof. Dr. Fanhua MA mafh@tsinghua.edu.cn TEL/FAX: 86-10-62785946 State Key Laboratory of Automotive Safety & Energy Tsinghua University,Beijing, China Thanks for Attention !