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ORGANIC CHEMISTRY
SATURATED AND UNSATURATED
HYDROCARBONS
The branch of chemistry that
deals with carbon compounds is organic chemistry.
Alkanes
Saturated hydrocarbons
Hybridization SP3
Drawing Chemical Structures
Structural
formula
Condensed ( Abbreviated) formula
Skeletal formula
Molecular model
The parent name of the hydrocarbon is that given to the longest
continuous chain of carbon atoms in the molecule.
Naming organic compounds
STEP 1 FIND THE PARENT HYDROCARBON
 Find the longest
continuous carbon
chain in the molecule
and use the name of
that chain as the
parent name. The
longest chain may not
always be obvious;
you may have to “turn
corners.”
 If two chains of equal
length are present,
choose the one with
the larger number of
branch points as the
parent.
Naming Branched-Chain Alkanes
STEP 2 NUMBER THE ATOMS IN THE MAIN CHAIN
Beginning at the end nearer the
first branch point, number
each carbon atom in the parent
chain.
STEP 3 IDENTIFY AND NUMBER THE SUBSTITUENTS
Assign a number, called a locant, to each
substituent to specify its point of attachment
to the parent chain. If there are two
substituents on the same carbon, assign
them both the same number.
There must always be as many
numbers
in the name as there are substituents.
STEP 4 WRITE THE NAME AS A SINGLE WORD
Use hyphens to separate the various
prefixes and commas to separate
numbers.
If two or more different side chains are
present, cite them in alphabetical order.
If two or more identical side chains are
present, use the appropriate
multiplier prefixes di-, tri-, tetra-, and so
forth. Don’t use these prefixes for
alphabetizing, though.
NAMING
3,4-Diethyl-4-methyloctane
Isomers
Each of two or more compounds with the same
formula but a different arrangement of atoms in the
molecule and different properties.
Reactions of Alkanes
Alkanes are generally not considered
to be very reactive substances.
1. Combustion
2. Reaction with halogens
Alkanes in which one or more hydrogen
atoms have been replaced by a halogen
atom are called alkyl halides.
The best known are
chloroform (CHCl3), carbon tetrachloride (CCl4),
methylene chloride (CH2Cl2).
Chloroform is a volatile, sweet-tasting liquid that was
used for many years as an anesthetic. However, because of
its toxicity (it can severely damage the liver, kidneys, and
heart) it has been replaced by other compounds.
Carbon tetrachloride, also a toxic substance, serves as a
cleaning liquid, for it removes grease stains from clothing.
Methylene chloride is used as a solvent to decaffeinate
coffee and as a paint remover.
Cycloalkanes
Alkenes
Reactions of Alkenes
1. Combustion
2. Additional reactions:
Hydrogenation (H2)
Halogenation (Cl2)
Hydrohalogenation (HCl)
Hydration (H2O)
3. Oxidation
Polymerization
Alkynes
Reactions of Alkynes
1. Combustion
2. Additional reactions:
Hydrogenation,
Halogenation,
Hydrohalogenation
3. Oxidation
Aromatic Hydrocarbons
Nomenclature of Aromatic Compounds
Benzene can be hydrogenated
(Additional Reaction)
Substitution
Nitrobenzene is used in shoe and floor polishes,
leather dressings,
paint solvents,
and other materials to mask unpleasant odors.
nitrobenzene has been used as an inexpensive
perfume for soaps.
production of the analgesic paracetamol (also
known as acetaminophen.
Nitrobenzene is highly toxic
XII -hydrocarbons.pptx
XII -hydrocarbons.pptx
XII -hydrocarbons.pptx
XII -hydrocarbons.pptx
XII -hydrocarbons.pptx

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XII -hydrocarbons.pptx

  • 1. ORGANIC CHEMISTRY SATURATED AND UNSATURATED HYDROCARBONS
  • 2. The branch of chemistry that deals with carbon compounds is organic chemistry.
  • 5. Drawing Chemical Structures Structural formula Condensed ( Abbreviated) formula Skeletal formula Molecular model
  • 6. The parent name of the hydrocarbon is that given to the longest continuous chain of carbon atoms in the molecule. Naming organic compounds
  • 7. STEP 1 FIND THE PARENT HYDROCARBON  Find the longest continuous carbon chain in the molecule and use the name of that chain as the parent name. The longest chain may not always be obvious; you may have to “turn corners.”  If two chains of equal length are present, choose the one with the larger number of branch points as the parent. Naming Branched-Chain Alkanes
  • 8.
  • 9. STEP 2 NUMBER THE ATOMS IN THE MAIN CHAIN Beginning at the end nearer the first branch point, number each carbon atom in the parent chain.
  • 10. STEP 3 IDENTIFY AND NUMBER THE SUBSTITUENTS Assign a number, called a locant, to each substituent to specify its point of attachment to the parent chain. If there are two substituents on the same carbon, assign them both the same number. There must always be as many numbers in the name as there are substituents.
  • 11. STEP 4 WRITE THE NAME AS A SINGLE WORD Use hyphens to separate the various prefixes and commas to separate numbers. If two or more different side chains are present, cite them in alphabetical order. If two or more identical side chains are present, use the appropriate multiplier prefixes di-, tri-, tetra-, and so forth. Don’t use these prefixes for alphabetizing, though.
  • 13.
  • 14.
  • 15. Isomers Each of two or more compounds with the same formula but a different arrangement of atoms in the molecule and different properties.
  • 16.
  • 17.
  • 18. Reactions of Alkanes Alkanes are generally not considered to be very reactive substances. 1. Combustion 2. Reaction with halogens Alkanes in which one or more hydrogen atoms have been replaced by a halogen atom are called alkyl halides.
  • 19. The best known are chloroform (CHCl3), carbon tetrachloride (CCl4), methylene chloride (CH2Cl2). Chloroform is a volatile, sweet-tasting liquid that was used for many years as an anesthetic. However, because of its toxicity (it can severely damage the liver, kidneys, and heart) it has been replaced by other compounds. Carbon tetrachloride, also a toxic substance, serves as a cleaning liquid, for it removes grease stains from clothing. Methylene chloride is used as a solvent to decaffeinate coffee and as a paint remover.
  • 22.
  • 23.
  • 24.
  • 25. Reactions of Alkenes 1. Combustion 2. Additional reactions: Hydrogenation (H2) Halogenation (Cl2) Hydrohalogenation (HCl) Hydration (H2O) 3. Oxidation
  • 27.
  • 28.
  • 30.
  • 31.
  • 32. Reactions of Alkynes 1. Combustion 2. Additional reactions: Hydrogenation, Halogenation, Hydrohalogenation 3. Oxidation
  • 34.
  • 36.
  • 37. Benzene can be hydrogenated (Additional Reaction)
  • 39. Nitrobenzene is used in shoe and floor polishes, leather dressings, paint solvents, and other materials to mask unpleasant odors. nitrobenzene has been used as an inexpensive perfume for soaps. production of the analgesic paracetamol (also known as acetaminophen. Nitrobenzene is highly toxic