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1. CE4102
Petrochemical Processes
Rinaldi M Rachman S.T., M.S.
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2. Petrochemical Processes
Class Administration
CLASS HOURS
Today meeting link: https://bit.ly/MsTeamsPetro
[1st week] Monday, 8.00 – 9.40 GMT+7
[Following weeks] Wednesday, 15.00 – 16.40 GMT+7
Join Team of Petro Class: http://bit.ly/JoinPetroTeam
OFFICE HOURS
Online discussion - by appointment
COURSE CONTRACT
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3. Petrochemical Processes
Recommended References
1. U.R. Chaudhury, Fundamentals of Petroleum and
Petrochemicals Engineering, CRC Press.
2. R.A. Meyers, Handbook Of Petrochemicals Production
Processes 2nd Ed., McGraw Hill.
3. S. Matar and L.F. Hatch, Chemistry of Petrochemical
Processes 2nd Ed., Gulf Publishing Company.
4. D. Seddon, Petrochemical Economics - Technology
selection in a carbon constrained world, Imperial College
Press.
5. A. Bahadori, Dictionary of Oil, Gas, and Petrochemical
Processing, CRC Press.
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4. Petrochemical Processes
Course Objectives
The CE4102 Petrochemical Processes is designed so that the students can:
1. Understand the definition of Petrochemical Processes and do classification of
feedstocks, intermediate product, and final product of petrochemicals.
2. Analyze the reaction pathways involved in the production chain of petrochemical
products.
3. Compare and evaluate the technologies to manufacture petrochemicals.
4. Explain the driver of supply and demand of petrochemical products at global market
5. Design a process simulation in the topic of petrochemical processes.
6. Analyze the environmental impacts caused by petrochemical industry and its
mitigation
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5. Petrochemical Processes
Course Outline – 1st Half
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Week# Topics
1 Introduction to Petrochemicals, Petrochemical Processes, Classification, and Global Trends
2 Olefins Production: Steam Cracking
3 Olefins Production: Steam Cracking (2)
4 Manufacture of Methanol & Methanol-derived Chemicals
5 Manufacture of Ethylene-Derived Chemicals
6 Manufacture of Ethylene-Derived Chemicals (2)
7 Manufacture of Propylene-Derived Chemicals
MIDTERM

6. Petrochemical Processes
Course Outline – 2nd Half
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Week# Topics
8 Manufacture of Propylene-Derived Chemicals (2)
9 Manufacture of C4-Derived Chemicals
10 Manufacture of Aromatics-Derived Chemicals
11 Petrochemical Processes Simulation (Unisim)
12 Basic of Polymer Science
13 Manufacture of Important Polymers (LDPE, HDPE, PP
, PET)
14 Environmental Aspects of Petrochemcial Industry
FINAL EXAM

7. Petrochemical Processes
Course Objectives
The CE4102 Petrochemical Processes is designed so that the students can:
1. Understand the definition of Petrochemical Processes and do classification of
feedstocks, intermediate product, and final product of petrochemicals.
2. Analyze the reaction pathways involved in the production chain of petrochemical
products.
3. Compare and evaluate the technologies to manufacture petrochemicals.
4. Explain the driver of supply and demand of petrochemical products at global market
5. Design a process simulation in the topic of petrochemical processes.
6. Analyze the environmental impacts caused by petrochemical industry and its
mitigation
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8. CE4102
Petrochemical Processes
Learning Outcomes:
1. Definition of Petrochemicals & Petrochemical Processes
2. Classification of Feedstocks, Building Blocks, Intermediate Chemicals, Final Products
3. Market Driver of Petrochemical Industry
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Lecture 1
INTRODUCTION TO PETROCHEMICAL PROCESSES

9. Petrochemical Processes
What are petrochemicals?
Petrochemicals
i. Chemicals derived from oil and gas
ii. Value-added chemicals made from crude oil or natural gas.
iii. Chemicals derived from petroleum, hydrocarbon liquids, or natural gas.
Petrochemical Processes refers to routes and process topology of manufacturing
petrochemicals. Process topology: Reaction & Reactors, Separation, and Heat Utilization.
“Petrochemical processes is part of the oil and gas value chain”
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10. Petrochemical Processes
Petrochemicals are all around us
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https://www.iea.org/news/petrochemicals-set-to-be-the-
largest-driver-of-world-oil-demand-latest-iea-analysis-finds

11. Petrochemical Processes
Petrochemicals are all around us
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Group of Product Areas
Plastics and
Polymers
Agricultural water management, packaging, automobiles,
telecommunication, health and hygiene, education, transportation,
building
Synthetic rubber
Transportation industry, chemical, electrical, electronics, adhesives,
sealants, coatings
Synthetic fiber Textile, transportation, industrial fabrics, geo-textile, non-woven fabrics
Synthetic detergents Heat and hygiene
Industrial Chemicals
Drugs, pesticides, explosives, surface coating, dyes, adhesives,
antioxidants, corrosion inhibitors, solvents, perfumes, food additives, metal
extraction

12. Petrochemical Processes
Oil & Gas Value Chain
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Fig: https://stein-analytics.com/img/oil_supply_chain.jpg

13. Petrochemical Processes
Oil & Gas Value Chain
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https://www.youtube.com/watch?v=6ozmKhahk8M

14. Petrochemical Processes
Downstream Operations
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Linde Olefins Academy 2016
Relating the Petroleum Products (from Crude Oil & Natural Gas) to Petrochemicals

15. Petrochemical Processes
Petrochemicals Hierarchy
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▪ Plastics
▪ Fibres
▪ Solvents
▪ Dyes
▪ Etc.
▪ Monomers
▪ Oxides
▪ Acids
▪ Alcohols
▪ Etc.
The group of 7:
▪ Ethylene
▪ Propylene
▪ C4 Olefins
▪ BTX
▪ Syn Gas
Primary &
Secondary
FEEDSTOCKS:
▪ Ethane
▪ Propane
▪ Naphtha
▪ Gas Oil
▪ Condensate
FEEDSTOCKS BUILDING BLOCKS INTERMEDIATE FINAL PRODUCTS

16. Petrochemical Processes
PONA
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▪ PARAFFINS: single bonded hydrocarbon
chains (saturated)
▪ OLEFINS: double bonded hydrocarbon chains
(unsaturated)
▪ NAPTHENIC: cyclic aliphatic hydrocarbons
(cycloalkanes)
▪ AROMATICS: contained conjugated planar
ring systems with delocalized pi electron clouds
instead od discrete alternating single and
double bonds
WHICH one is useful for
PETROCHEMISTRY??

17. Petrochemical Processes
Petrochemicals Building Blocks
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18. Petrochemical Processes
Petrochemicals Products Network
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19. Petrochemical Processes
Global Petrochemicals Profile
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Linde Olefins Academy 2016
Asia dominates both global primary chemical production and naphtha feedstock consumptions. America is the leader in ethane-based petrochemical production.
https://www.iea.org/news/petrochemicals-set-to-be-the-
largest-driver-of-world-oil-demand-latest-iea-analysis-finds

20. Petrochemical Processes
Petrochemicals in Oil & Gas Demand
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https://www.iea.org/news/petrochemicals-set-to-be-the-
largest-driver-of-world-oil-demand-latest-iea-analysis-finds
Petrochemicals account for 14% of global oil, and 8% of global gas demand.

21. Petrochemical Processes
Growth of Petrochemicals
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https://www.iea.org/news/petrochemicals-set-to-be-the-
largest-driver-of-world-oil-demand-latest-iea-analysis-finds
Demand for plastic has grown faster than for any other bulk material, nearly doubling since the millennium

22. Petrochemical Processes
World Plastics Production
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Linde Olefins Academy 2016

23. Petrochemical Processes
Ethylene Production Worldwide
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Linde Olefins Academy 2016

24. Petrochemical Processes
Ethylene Production Worldwide
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Linde Olefins Academy 2016

25. Petrochemical Processes
Financial-driven: Value Creation
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Linde Olefins Academy 2016

26. Petrochemical Processes
Cost Breakdown
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Linde Olefins Academy 2016

27. Petrochemical Processes
Demand & Capacity Development
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Linde Olefins Academy 2016

28. Petrochemical Processes
Major Ethylene Producers
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Linde Olefins Academy 2016

29. Petrochemical Processes
Competitive Landscape of Ethylene Production
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Linde Olefins Academy 2016

30. Petrochemical Processes
Value Chain Coverage
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Linde Olefins Academy 2016

31. Petrochemical Processes
Global Long-Term Trend of Petrochemicals
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Linde Olefins Academy 2016

32. Learning Outcomes Check!
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Learning Outcomes:
1. Definition of Petrochemicals & Petrochemical Processes
2. Classification of Feedstocks, Building Blocks, Intermediate Chemicals, Final Products
3. Market Driver of Petrochemical Industry

33. Petrochemical Processes
The following weeks…
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Pertamina

34. Petrochemical Processes
Next Week..
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Pertamina

35. Thank You..
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36. Petrochemical Processes
Petrochemical Industry Structure
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37. Petrochemical Processes
Chemicals from Ethylene
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38. Petrochemical Processes
Chemicals from Propylene
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39. Petrochemical Processes
Chemicals from BTX
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