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Water Treatment
            Muhammad Fahad Ansari
                 12IEEM14



06/14/12                            1
Why do we treat water?

• The main objectives of the water treatment
  processes are the reduction in
  contamination or pollution levels present in
  water.




06/14/12                                         2
• Water treatment describes those processes used to
  make WATER more acceptable for a desired end-
  use.
• These can include use as DRINKING WATER,
  industrial processes, medical and many other uses.
• The goal of all water treatment process is to remove
  existing contaminants in the water.
• Or reduce the concentration of such contaminants so
  the water becomes fit for its desired end-use.
• One such use is returning water that has been used
  back into the natural environment without adverse
  ecological impact.
 06/14/12                                            3
• It also may be necessary to remove
  nutrients such as N and P, toxic
  components, non-biologically degradable
  compounds and dissolved solids.
• Removal of these materials are necessary
  for the simple reason that discharge to the
  environment will result in “damage”.



06/14/12                                        4
• The processes involved in treating water for
  drinking purpose may be solids separation
  using
• Physical: Such as settling and filtration,
• Chemical: Such as disinfection and
  coagulation.




 06/14/12                                        5
• The damage is a function of the type of
  pollutant discharged –
• Heavy metals = toxicity,
• Organic matter = oxygen depletion,
• N or P- eutrophication, etc.
• In the case of water treatment the objective is
  to remove contaminants from the water which
  can result in health or aesthetic problems.
 06/14/12                                       6
• Many pollutants fall into several
  categories.
• For example, some biodegradable
  organic matter is in the form of
  suspended solids.
• So removal of SS sometimes results
  in the removal of organic matter.
 06/14/12                              7
• Each solids “type” may require a different
 type of treatment process.
• Generally it is tried to remove large very
 settleable or screenable particles first and
• Then proceed to the smallest and finally to
 the soluble species.

  06/14/12                                     8
• Level needed to remove
  contaminants.
• The degree to which drinking
  water must be treated depends on
  the raw water quality and the
  desired quality of the finished
  water.

 06/14/12                            9
For example water treatment may
 require "secondary treatment" as
 shown here:
• BOD5 = 30 mg/L
• Suspended Solids = 30 mg/L
• pH (if industrial input) = 6 – 9
 06/14/12                            10
• The" secondary" standards are just the
  “basic” requirements.
• More stringent standards are placed on
  effluents which are discharged to
  potentially eutrophic lakes, etc. or
  whenever there is a known toxic
  contaminant in the wastewater (e.g.
  industrial discharges).
  06/14/12                                 11
• For drinking water treatment the requirements are, of
  course, much more stringent with many more
  categories and lower contaminant limits.
Some examples are:
• Turbidity (a measure of suspended solids): less than 0.5
  NTU in at least 95% of samples taken each month.
• Lead: 0.005 mg/L
• Copper: 1.3 mg/L
• Total Coliform: no coliform detection in more than 5%
  of samples collected
  06/14/12                                            12
• The contaminants removal from water
Contaminant removal is accomplished by
 a series of unit processes or unit
 operations.
(The system of integrated unit processes or
  unit processes used to treat a water or
  wastewater is called a treatment train.

 06/14/12                                 13
• Treatment processes are usually divided into
  two trains: liquid train, and the solids (sludge)
  train.
• The reason for this is that we usually take a
  rather dilute waste and through a series of
  phase separation processes create a more
  concentrated waste (sludge).
• The sludge then has to be treated accordingly.

  06/14/12                                        14
An example of a water treatment plant:




06/14/12                                     15
Treatment
The processes below are commonly used in water purification
  plants.
• Pumping and containment - The majority of water must be
  pumped from its source or directed into pipes or holding tanks.
• To avoid adding contaminants to the water, this physical
  infrastructure must be made from appropriate materials and
  constructed so that accidental contamination does not occur.
• Screening - The first step in purifying surface water is to remove
  large debris such as sticks, leaves, trash and other large particles
  which may interfere with subsequent purification steps.
• Most deep groundwater does not need screening before other
  purification steps.


  06/14/12                                                       16
• Storage - Water from rivers may also be stored in bank
  side reservoirs for periods between a few days and
  many months to allow natural biological purification to
  take place.
• This is especially important if treatment is by slow
  sand filters.
• Storage reservoirs also provide a buffer against short
  periods of drought or to allow water supply to be
  maintained during transitory pollution incidents in the
  source river.
• Pre-conditioning - Many waters rich in hardness salts
  are treated with soda-ash to precipitate out.
• Pre-chlorination - In many plants the incoming water is
  chlorinated to minimize the growth of fouling
  organisms on the pipe-work and tanks.
  06/14/12                                            17
pH adjustment
• Distilled water has a pH of 7 (neither alkaline nor
  acidic) and sea water has an average pH of 8.3
  (slightly alkaline).
• If the water is acidic (lower than 7), lime, soda ash or
  sodium hydroxide is added to raise the pH.
• For somewhat acidic, alkaline waters are the
  cheapest way to lower the pH.
• Lime is commonly used for pH adjustment for
  municipal water, or at the start of a treatment plant
  for process water.
  06/14/12                                              18
• Making the water slightly alkaline ensures
  that coagulation and flocculation processes
  work effectively.
• Also help to minimize the risk of lead being
  dissolved from lead pipes.
• Acid (HCl or H2SO4) may be added to alkaline
  waters in some circumstances to lower the pH.




  06/14/12                                    19
Flocculation
• Flocculation is a process which clarifies the water.
• Clarifying means removing any turbidity or colour so that
  the water is clear and colourless.
• Clarification is done by causing a precipitate to form in the
  water which can be removed using simple physical
  methods.
• Initially the precipitate forms a very small particles but as
  the water is gently stirred, these particles stick together to
  form bigger particles - this process is called flocculation.




06/14/12                                                      20
• Many of the small particles that were originally
  present in the raw water absorb onto the surface of
  these small precipitate particles and so get
  incorporated into the larger particles that
  coagulation produces.
• In this way the coagulated precipitate takes most
  of the suspended matter out of the water and is
  then filtered off, generally by passing the mixture
  through a coarse sand filter or sometimes through
  a mixture of sand and granulated anthracite (high
  carbon and low volatile coal).

06/14/12                                            21
Coagulants / flocculating agents that may be used include:

  • Iron Hydroxide: This is formed by adding a
    solution of an iron (III) compound to pre-
    treated water with a pH of 7 or greater.
  • Iron (III) hydroxide is extremely insoluble
    and forms even at a pH as low as 7.
  • Aluminum Hydroxide is also widely used
    as the flocculating precipitate although
    there have been concerns about possible
    health impacts and mis-handling led to a
    severe poisoning incident
  06/14/12                                                   22
Drinking water in U.S.
• The United States has one of the safest water
  supplies in the world.
• In recent years, microbial contamination of the
  water supply has led to highly publicized
  outbreaks of disease, causing illness and even
  death.
• How safe is our water?
• Where do these infectious microbes come from?
• How is water treated now and what’s being done
  to make it even safer?

06/14/12                                        23
Surface Water Treatment Plant
• Water treatment transforms raw surface
  and groundwater into safe drinking water.
• Water treatment involves two major
  processes:
• Physical removal of solids and
• Chemical disinfection.



06/14/12                                      24
Water Disinfection
•    Purpose of disinfection:

     •     To make Drinking water free of any disease causing
           bacteria and microbes.

•     Methods of disinfection:

      •        There are 3 mainly used disinfection methods at
               large scale.

               •   CHLORINATION
               •   OZONATION
               •   ULTRAVIOLET RADIATION



    06/14/12                                                     25
CHLORINATION
 Chlorine is the most common cost-effective means
  of disinfecting water in the U.S.

 The addition of a small amount of chlorine is highly
  effective against most bacteria, viruses, and
  protozoa.

 But cysts (durable seed-like stages) formed by
  parasitic protozoa such as Cryptosporidium and
  Giardia can survive chlorine.

 Chlorine is applied to water in one of three forms:
  elemental chlorine (chlorine gas), hypochlorite
  solution (bleach), or dry calcium hypochlorite. All
  three forms produce free chlorine in water
06/14/12                                            26
06/14/12   27
OZONATION
          OZONE is Strongest oxidant/disinfectant available.

          More effective against microbes than chlorination.

          But, costly and difficult to monitor and control under
          different condition.


•   Ozonation process:

    •    Ozone (o3) is generated on-site
         at water treatment facilities by
         passing dry oxygen or air
         through a system of high voltage
         electrodes.

    06/14/12                                                28
06/14/12   29
ULTRAVIOLET RADIATION
 When UV radiation penetrates the
  cell wall of an organism, it
  damages genetic material, and
  prevents the cell from reproducing.

 Now a days emerging technology
  made UV radiation to find a place
  in both household and large scale
  drinking water disinfection.


 •   How is UV light generated?

 •   Ultraviolet light is most typically generated
     from a low pressure or a medium pressure lamp
     generating UV light.
 06/14/12                                            30
ULTRAVIOLET RADIATION




06/14/12                           31
COMPLETE CYCLE
OF WATER TREATMENT:                          COAGULATION




                                             STORAGE
              SEDIMENTATION

                              DISINFECTION
          FILTRATION
Design of a Chlorination Process
• Based on exposing a microorganism
  for an amount of time with a minimum
  amount of disinfectant
• Rough calculation of the amount of
  time spent in a reactor is based on the
  reactor volume and the flow rate:
• Time = volume/flow rate

06/14/12                                33

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Water treatment 2 by Muhammad Fahad Ansari 12IEEM14

  • 1. Water Treatment Muhammad Fahad Ansari 12IEEM14 06/14/12 1
  • 2. Why do we treat water? • The main objectives of the water treatment processes are the reduction in contamination or pollution levels present in water. 06/14/12 2
  • 3. • Water treatment describes those processes used to make WATER more acceptable for a desired end- use. • These can include use as DRINKING WATER, industrial processes, medical and many other uses. • The goal of all water treatment process is to remove existing contaminants in the water. • Or reduce the concentration of such contaminants so the water becomes fit for its desired end-use. • One such use is returning water that has been used back into the natural environment without adverse ecological impact. 06/14/12 3
  • 4. • It also may be necessary to remove nutrients such as N and P, toxic components, non-biologically degradable compounds and dissolved solids. • Removal of these materials are necessary for the simple reason that discharge to the environment will result in “damage”. 06/14/12 4
  • 5. • The processes involved in treating water for drinking purpose may be solids separation using • Physical: Such as settling and filtration, • Chemical: Such as disinfection and coagulation. 06/14/12 5
  • 6. • The damage is a function of the type of pollutant discharged – • Heavy metals = toxicity, • Organic matter = oxygen depletion, • N or P- eutrophication, etc. • In the case of water treatment the objective is to remove contaminants from the water which can result in health or aesthetic problems. 06/14/12 6
  • 7. • Many pollutants fall into several categories. • For example, some biodegradable organic matter is in the form of suspended solids. • So removal of SS sometimes results in the removal of organic matter. 06/14/12 7
  • 8. • Each solids “type” may require a different type of treatment process. • Generally it is tried to remove large very settleable or screenable particles first and • Then proceed to the smallest and finally to the soluble species. 06/14/12 8
  • 9. • Level needed to remove contaminants. • The degree to which drinking water must be treated depends on the raw water quality and the desired quality of the finished water. 06/14/12 9
  • 10. For example water treatment may require "secondary treatment" as shown here: • BOD5 = 30 mg/L • Suspended Solids = 30 mg/L • pH (if industrial input) = 6 – 9 06/14/12 10
  • 11. • The" secondary" standards are just the “basic” requirements. • More stringent standards are placed on effluents which are discharged to potentially eutrophic lakes, etc. or whenever there is a known toxic contaminant in the wastewater (e.g. industrial discharges). 06/14/12 11
  • 12. • For drinking water treatment the requirements are, of course, much more stringent with many more categories and lower contaminant limits. Some examples are: • Turbidity (a measure of suspended solids): less than 0.5 NTU in at least 95% of samples taken each month. • Lead: 0.005 mg/L • Copper: 1.3 mg/L • Total Coliform: no coliform detection in more than 5% of samples collected 06/14/12 12
  • 13. • The contaminants removal from water Contaminant removal is accomplished by a series of unit processes or unit operations. (The system of integrated unit processes or unit processes used to treat a water or wastewater is called a treatment train. 06/14/12 13
  • 14. • Treatment processes are usually divided into two trains: liquid train, and the solids (sludge) train. • The reason for this is that we usually take a rather dilute waste and through a series of phase separation processes create a more concentrated waste (sludge). • The sludge then has to be treated accordingly. 06/14/12 14
  • 15. An example of a water treatment plant: 06/14/12 15
  • 16. Treatment The processes below are commonly used in water purification plants. • Pumping and containment - The majority of water must be pumped from its source or directed into pipes or holding tanks. • To avoid adding contaminants to the water, this physical infrastructure must be made from appropriate materials and constructed so that accidental contamination does not occur. • Screening - The first step in purifying surface water is to remove large debris such as sticks, leaves, trash and other large particles which may interfere with subsequent purification steps. • Most deep groundwater does not need screening before other purification steps. 06/14/12 16
  • 17. • Storage - Water from rivers may also be stored in bank side reservoirs for periods between a few days and many months to allow natural biological purification to take place. • This is especially important if treatment is by slow sand filters. • Storage reservoirs also provide a buffer against short periods of drought or to allow water supply to be maintained during transitory pollution incidents in the source river. • Pre-conditioning - Many waters rich in hardness salts are treated with soda-ash to precipitate out. • Pre-chlorination - In many plants the incoming water is chlorinated to minimize the growth of fouling organisms on the pipe-work and tanks. 06/14/12 17
  • 18. pH adjustment • Distilled water has a pH of 7 (neither alkaline nor acidic) and sea water has an average pH of 8.3 (slightly alkaline). • If the water is acidic (lower than 7), lime, soda ash or sodium hydroxide is added to raise the pH. • For somewhat acidic, alkaline waters are the cheapest way to lower the pH. • Lime is commonly used for pH adjustment for municipal water, or at the start of a treatment plant for process water. 06/14/12 18
  • 19. • Making the water slightly alkaline ensures that coagulation and flocculation processes work effectively. • Also help to minimize the risk of lead being dissolved from lead pipes. • Acid (HCl or H2SO4) may be added to alkaline waters in some circumstances to lower the pH. 06/14/12 19
  • 20. Flocculation • Flocculation is a process which clarifies the water. • Clarifying means removing any turbidity or colour so that the water is clear and colourless. • Clarification is done by causing a precipitate to form in the water which can be removed using simple physical methods. • Initially the precipitate forms a very small particles but as the water is gently stirred, these particles stick together to form bigger particles - this process is called flocculation. 06/14/12 20
  • 21. • Many of the small particles that were originally present in the raw water absorb onto the surface of these small precipitate particles and so get incorporated into the larger particles that coagulation produces. • In this way the coagulated precipitate takes most of the suspended matter out of the water and is then filtered off, generally by passing the mixture through a coarse sand filter or sometimes through a mixture of sand and granulated anthracite (high carbon and low volatile coal). 06/14/12 21
  • 22. Coagulants / flocculating agents that may be used include: • Iron Hydroxide: This is formed by adding a solution of an iron (III) compound to pre- treated water with a pH of 7 or greater. • Iron (III) hydroxide is extremely insoluble and forms even at a pH as low as 7. • Aluminum Hydroxide is also widely used as the flocculating precipitate although there have been concerns about possible health impacts and mis-handling led to a severe poisoning incident 06/14/12 22
  • 23. Drinking water in U.S. • The United States has one of the safest water supplies in the world. • In recent years, microbial contamination of the water supply has led to highly publicized outbreaks of disease, causing illness and even death. • How safe is our water? • Where do these infectious microbes come from? • How is water treated now and what’s being done to make it even safer? 06/14/12 23
  • 24. Surface Water Treatment Plant • Water treatment transforms raw surface and groundwater into safe drinking water. • Water treatment involves two major processes: • Physical removal of solids and • Chemical disinfection. 06/14/12 24
  • 25. Water Disinfection • Purpose of disinfection: • To make Drinking water free of any disease causing bacteria and microbes. • Methods of disinfection: • There are 3 mainly used disinfection methods at large scale. • CHLORINATION • OZONATION • ULTRAVIOLET RADIATION 06/14/12 25
  • 26. CHLORINATION  Chlorine is the most common cost-effective means of disinfecting water in the U.S.  The addition of a small amount of chlorine is highly effective against most bacteria, viruses, and protozoa.  But cysts (durable seed-like stages) formed by parasitic protozoa such as Cryptosporidium and Giardia can survive chlorine.  Chlorine is applied to water in one of three forms: elemental chlorine (chlorine gas), hypochlorite solution (bleach), or dry calcium hypochlorite. All three forms produce free chlorine in water 06/14/12 26
  • 27. 06/14/12 27
  • 28. OZONATION OZONE is Strongest oxidant/disinfectant available. More effective against microbes than chlorination. But, costly and difficult to monitor and control under different condition. • Ozonation process: • Ozone (o3) is generated on-site at water treatment facilities by passing dry oxygen or air through a system of high voltage electrodes. 06/14/12 28
  • 29. 06/14/12 29
  • 30. ULTRAVIOLET RADIATION  When UV radiation penetrates the cell wall of an organism, it damages genetic material, and prevents the cell from reproducing.  Now a days emerging technology made UV radiation to find a place in both household and large scale drinking water disinfection. • How is UV light generated? • Ultraviolet light is most typically generated from a low pressure or a medium pressure lamp generating UV light. 06/14/12 30
  • 32. COMPLETE CYCLE OF WATER TREATMENT: COAGULATION STORAGE SEDIMENTATION DISINFECTION FILTRATION
  • 33. Design of a Chlorination Process • Based on exposing a microorganism for an amount of time with a minimum amount of disinfectant • Rough calculation of the amount of time spent in a reactor is based on the reactor volume and the flow rate: • Time = volume/flow rate 06/14/12 33