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Domestic Waste Water Treatment


                                          by
                            Pritilata Sarker
                         Bhabi Mazumder
                        Ranjan Kumar Das
                           Sharmin Akhter
Objectives
• Domestic waste water treatment and major ways
  of classifying wastewater treatment plants
• How to design major unit operations and
  processes for treating wastewater
• Microbial growth in heterogeneous cultures
• Sludge volume and weight relationships
• How to design sludge thickening systems
• How to design aerobic and anaerobic sludge
  digestion systems
Introduction
• Wastewater is water that has been
  contaminated to the degree that it is no
  longer beneficial, and therefore must be
  treated before it can be used or released back
  into the environment.
• Four major types of wastewater are 1.
  Domestic/Municipal wastewater 2. Industrial
  3. Urban runoff and 4. Agricultural runoff
Wastewater Treatment
   Categorization
Secondary Wastewater Treatment Plant

• TSS
• BOD
Advanced Wastewater Treatment Plant

• Remove N & P
• Remove additional BOD & TSS that secondary
  treatment cannot remove
• AWT utilizes chemical, biological & physical
N removal by AWT
• Nitrification
• Denitrification
Nitrification
• Nitrification is an aerobic process that
  transforms ammonium nitrogen (reduced
  state) into an oxidized form (NO-3)
• This process is carried out by autotropic
  bacteria of the genera Nitrosomonas &
  Nitrobacter
• The overall reaction
• NH+4 + 2O2      NO-3 +2H+ + H2O
Denitrification
• To remove the nitrate that formed during nitrification , a
  second biological process known as denitrification must
  be used in an anoxic environment (void of dissolved
  oxygen)
• Denitrifying , heterotrophic microorganisms reduce
  nitrate into nitrogen gas, which is released into the
  atmosphere
• The equation is
• 6NO-3 + 5CH3OH              3N2 + 6OH- + 5CO2 + 7H2O
P removal by AWT- EBPR
• Biological phosphorus removal may be
  accomplished by providing alternating
  anaerobic/aerobic treatment of the waste water.
• Such systems promote the growth of
  phosphorus accumulating organisms (PAOs) such
  as Acinetobacter.
• PAOs takes up excess amount of P from
  wastewater during the aerobic phase of
  biological treatment.
• These process is known as enhanced biological
  phosphorus removal (EBPR)
Overview of Wastewater Treatment System


Influent                                Secondary
            Grit     Flow    Aeration                Chlorine   Effluent
                                         clarifier
                     meter    basin                  contact
           removal                                    basin
Preliminary Treatment
•   Bar racks and screens
•   Grit removal
•   Pumping
•   Flow measurement
•   Equalization
•   Pre-aeration
•   Pre-disinfection
•   Shredding
•   Flotation
Screening
• Mechanically cleaned bar racks-
     -clear opening 1.5 -6 inch
     -remove large objects such as logs or other
      debris
• Bar screen
     -opening 1-2 inch
     -remove rags, paper & other debris
Grit Removal
• Grit consists of sand, silt, small gravel, cinder,
  coffee grounds, eggshells, and other inert
  materials, which typically have specific gravity
  around 2.65
• These material are abrasive and will cause pump
  impellers to wear excessively, and they will
  accumulate in tanks, digester and pipes.
• Three major types of grit removal are aerated
  chamber, horizontal flow through basin and
  vortex removal system
Primary Treatment
• Primary treatment is clarification, or separation of
  suspended solids from the wastewater.
• Primary Treatment follows preliminary treatment,
  settling of SS & removal of oil, grease, and scum that
  floats on surface of wastewater.
• Since these species contain organic matter, BOD
  removal is accomplished.
• Primary Treatment does not remove organics soluble
  or colloidal organic materials. Light weight organics
  that floats to the surface are skimmed off & pumped
  to the digesters for treatment
Primary Treatment (continued)
• The sludge that accumulates at the bottom of
  a primary clarifier is normally stabilized by
  anaerobic digestion before disposal.
• Primary sludge is is called “raw” sludge and
  contain pathogens and organics that produces
  odors
Primary Treatment (continued)

• Primary clarifier:
    Sl     Particulars           Specifications
    1      Size                  Circular/ Rectangular
    2      Depth                 10-16 ft
    3      Length                50-300 ft
    4      Width                 10-80 ft
    5      Dia                   10-200 ft
    6      Detention time        1.5-2.5 hrs
    7      Avg. over flow rate   800-1200 gpd/ft2
    8      Weir loading rate     10000-40000 gpd/ft2
Primary Treatment (continued)
• Design of Primary clarifier:
  Design of Primary clarifier is based on:
     -Avg. over flow rate
     -Detention time
     -Weir loading rate
Design of Primary clarifier (continued)
• The overflow rate (Vo) is defined as the flow rate divided by
  the surface area of the clarifier

  where Vo= over flow rate, gpd/ft2
           Q= design flow rate, MGD,
           As= surface area of the clarifier, ft2
• The surface area of the clarifier is determined by dividing
  the design flow rate by the overflow rate. This area
  calculated is then converted into either a circular or a
  rectangular area
• Selecting detention time the total volume is calculated and
  clarifier depth is determined.
Design of Primary clarifier (continued)
• Detention time (θ) is the average unit of time
  that the wastewater remains in the clarifier & is
  determined as follows:
                where V= volume of the primary
  clarifier, Q= Design flow rate
• Weir loading rate (q) is the third parameter that
  must be determined when designing primary
  clarifiers.
  q= weir loading rate, gpd
  weir length= length of primary clarifier effluent
  weir
Secondary Treatment
• Secondary wastewater treatment implies that a
  biological process is being used for treating the
  wastewater.
• Microorganisms indigenous to the wastewater
  use organic carbon, along with N & P, to grow
  more microorganisms, primarily bacteria.
• Bacteria use the organic matter as measured by
  BOD & COD for their energy and carbon source.
• Oxidation of the organic matter produces energy
  that is captured in the microbe’s biochemical
  pathways, while a portion of a organic material is
   used in the synthesis of biomass.
Secondary Treatment (continued)
• The following equations shows the organic
  materials is being oxidized for energy and
  organic materials is being synthesized into
  new microbial cells respectively-
  organics + O2         CO2+ H2O + energy
  organics + O2 + N + P        C60H87O23N42P
Activated Sludge
• It is an aerobic, suspended growth, biological
  process characterized by two major steps-
       1. Substrate adsorption and utilization in
  the aeration basin.
       2. Solids/liquid separation in the secondary
  clarifier
Activated Sludge
• Wastewater flows into the aeration basin,
  where it is brought into contact with a
  heterogeneous culture of microbes, consisting
  primarily of heterotrophic bacteria. The liquid
  inside the aeration basin is called “mixed
  liquor” or “Activated sludge”. A schematic of
  the process is presented in the next slide
System boundary


                          Air                        Alternative sludge wasting


     Q + Qr                                                            Secondary   Effluent
                                                                       clarifier
      So       Aeration basin            X, V, S e
Q
                                                          (Q+Qr)                   (Q-Qr)
Xi
                                                          Xe, Se                   Xe, Se
Si


                                                                        RAS/WAS
                                                                                   WAS
                                                                        Pumping
           Return activated                           Q, X, Se
                                                                         station
           sludge, RAS
                                                                                   Qw Xr




                Schematic of Activated Sludge
Design and operational parameters
• The main Design and operational parameters
  for the activated sludge process is the mean
  cell residence time (MCTR).MCTR represents
  the average time that the microorganisms or
  biomass remain in the system. MCTR is also
  called sludge age, solid retention time (SRT) or
  θc. Mathematically
Design and operational parameters
• Where :
• X= biomass or microorganism concentration in aeration basin
  expressed as TSS or VSS, mg/L,
• Xe= secondary effluent TSS or VSS concentration, mg/L,
• Xr= TSS or VSS concentration in return activated sludge, mg/L,
• V= volume of the aeration basin, mg/L, (m3)
• Q= influent wastewater flow rate, MGD (m3 /d)
• Qr= return activated sludge flow rate, MGD (m3 /d)
• Qw= sludge wastage flow rate, MDG (m3 /d)
• Qe= Q-Qw= effluent wastewater flow rate, MDG, (m3 /d)
Design and operational parameters

• MCTR typically varies from 5 to 30 days and
  determines the overall removal efficiency of the
  process. Generally, the longer the MCTR the lower
  the effluent substrate concentration as measured by
  BOD or COD. MCTR is longer than the hydraulic
  detention time θ. The hydraulic detention time θ is
  defined as the volume of the reactor or the basin
  divided by the volumetric flow rate.
Design and operational parameters

• θ= detention time based on influent wastewater flow
  rate, d or h and
• θ’= actual detention time for recycle system, d or h.
• Another design and operational parameter is the
  food-to-microorganism ratio which is defined as
• F:M= food-to-microorganism ratio

• So=influent substrate concentration to aeration basin
  expressed as BOD, COD or TOC, mg/L
Biochemical kinematics of activated sludge in
           completely mixed system

The relationship between the MCRT and net microbial
cultures growth rate is


Substrate utilization can be modeled by a Michaelis-Minton
type equation as proposed by Lawrence and McCarty (1970)

where k= maximum specific substrate utilization rate, d-1.
The effluent soluble substrate concentration Se
Biochemical kinematics of activated sludge in
              completely mixed system

• The microorganism concentration (X)

• where So and Se= influent and effluent soluble organic
  concentration, mass/volume. The volume of the aeration
  basin, V

• The total quantity of biomass produced daily(Px)
Oxygen requirement
• Oxygen serves as electron acceptor in the activated sludge
  process, so sufficient quantities of oxygen must be provided.
  The following equation is used for estimating the quantity of
  oxygen required to meet the total oxygen demand. The
  nitrogenous demand (NOD) is the amount of oxygen required
  for the nitrifying bacteria.



  where O2 is the total oxygen required to meet the
  carbonaceous and nitrogenous oxygen demand.
Aerator System

• There are two types of Aerator System 1.
  Mechanical aerator 2. Diffuser
• Mechanical aerator consists of mixers or
  brush rotors that transfer oxygen into the
  wastewater by spraying the wastewater into
  the air. Diffused aerator systems are similar to
  fish aquarium tanks in which oxygen diffuses
  through a diffuser stone or membrane,
  thereby transfer oxygen into the wastewater.
Trickling Filters
• Alternate secondary wastewater treatment
  process.
• Wastewater is applied to some type of filter
  medium.
• Media:- Past -Rock or Slag.
• Media:- Present- Plastic.
• Biomass growing on the media uses the organic
  matter along with a portion of the nitrogen &
  phosphorus to grow new microorganisms.
Trickling Filters
                       Recirculation           Pump


    Primary                                    Secondary




               Trickling filter humus sludge


Primary & Secondary humus sludge
SECONDARY CLARIFICATION

• -It must separate the suspended & biological
  solids from the liquid wastewater.
• - The design requires calculating the area of
  the clarifier based on clarification is
  determined by dividing the design flow rate by
  the overflow rate according to the following
  equation:
                  Ac =
SECONDARY CLARIFICATION
• Where:
• Ac = the area of clarifier based on
  clarification,ft2 (m2)
• Q = Design flow rate, excluding sludge return
  flow applied to the secondary clarifier, MGD
  (m3/d), and
• Vo = Overflow rate or surface loading rate,
  gpd/ft2 [m3/d.m2]
SECONDARY CLARIFICATION
• Based on thickening consideration, the following equation
  is used for determining the secondary clarifier area.
                       AT=
• Where:
• AT= secondary clarifier surface area.
• Q = wastewater design flow rate applied to the secondary
  clarifier excluding the return activated sludge flow rate,
  MGD (m3/d)
• QR= return activated sludge flow rate, MGD (m3/d)
• MLSS= suspended solids concentration in the aeration
  basin, and
• SLR = solids loading rate design criteria, typically 25 ppd/ft2
  at average daily flow.
Disinfectants used in Wastewater Treatment

• -Disinfectants-Cl2, O3 & ultraviolet (UV)
  radiations.
• -These disinfectants offer the advantage of
  eliminating the production of trihalmethanes
  (THMs), which are chlorinated organic species
  and suspected carcinogens that result when
  chlorine is added to water containing organic
  compounds.
Chlorination of Wastewater
• -Chlorine is delivered to wastewater treatment
  facilities in pressurized containers, which range in
  size from 150-lb to 1-ton cylinders.
• -Chlorine is liquefied under high pressure &
  withdrawn as a gas or liquid, depending on the
  withdrawal rate.
• - At large waste water treatment plant, chlorine
  is withdrawn as a liquid & must pass through an
  evaporator to be converted to a gas.
Chlorine Contact Basin
• -When chlorine is added to secondary
  effluent, it must have sufficient contact with
  the wastewater to kill pathogens.
• -Long, rectangular serpentine channels
  simulating the plug flow regime are used in
  the design of chlorine contact basins.
Sludge Treatment & Disposal
• Sludge or bio-solids and other residuals are generated
  at wastewater treatment facilities.
• Screening & grit from preliminary treatment unit are
  normally collected in dumpsters; volume is reduced &
  hauled off to sanitary landfills for ultimate disposal.
• Primary sludge contains organic solids & pathogens.
• Secondary sludge consists of biological organisms,i.e.
  biomass & is stabilized using aerobic or anaerobic
  digestion.
• Aerobic & anaerobic digestion decrease the volume &
  quantity of sludge
4 Steps of Sludge treatment & disposal

• Sludge volume is reduced through thickening
  operation.
• Stabilization with aerobic or anaerobic
  digestion.
• Dewatering operations to increase the
  concentration of solids.
• Ultimate disposal.
Sludge Weight & Volume Relationships
4 Steps of Sludge treatment & disposal

• The volume (V) occupiedby wet sludge (ft3 or
  m3) is determined using the following
  equation:
                 V=
• Where:
• S= Solids content,%
• ϒ= Specific weight of water, 62.4 lb/ft3
Thickening Operations
• Important because
• It reduces the volume of the sludge to be handled,
  thereby reducing the size of subsequent solids
  handling processes such as sludge stabilization.
• Sludge thickening operations & the approximate solid
  concentration associated with each include
• a) gravity thickening (2% -10% solids)
• b)gravity belt thickeners (3%-6%)
• c)dissolved air flotation (3%-6%)
• d)thickening centrifuges (4%-8%)
Stabilization
• Anaerobic Digestion
• -A biological process that takes place in an enclosed
  reactor with no oxygen present.
• -It produces a stable sludge & a valuable by-product,
  methane gas,which can be combustedto provide heat
  for the digesters or used for generating electricity.
• -It is sensitive to operate & prone to biological upsets.
• -Anaerobically digested sludge is usually difficult to
  dewater by mechanical means.
• - 3 step process- Hydrolysis
                      Acidogenesis
                      Methanogenesis
Anaerobic Digestion
• Hydrolysis:
• -Complex organic solids are hydrolyzed by bacteria.
• -Carbohydrates,proteins & fats are converted to simple
  carbohydrates, amino acids and fatty acids.
•
• Acidogenesis
• -Involves the conversion of soluble carbon formed during
  hydrolysis into organic acids & H2.
•
• Methanogenesis
• -Bacterial conversion of fatty acids & hydrogen into CH4 &
  Co2 by strict anaerobes.
Anaerobic Digestion
• Low or standard-rate anaerobic digester volume can
  be estimated as follows:

• V=         T1+ Q2T2

• Where:
• V =total digester capacity, ft3 (m3)
• Q1 =volume of raw sludge fed daily, cfd (m3/d)
• T1 =period required for digestion, approximately 25 d
• Q2 =volume of daily digested sludge accumulation in
  tank, cfd (m3/d)
• T2 =period of digested storage, 20 to 120 days.
Anaerobic Digestion
• For determining the volume of a high-rate
  anaerobic digester.
•          V1= Q1xT
• V1=digester capacity required for 1st-stage or
  high-rate digestion, ft3 (m3)
• T=period required for digestion, d.
• The volume of a 2nd-stage,
  VH= T1+ Q2T2
Anaerobic Digestion
• Where:
• VH=digester capacity required for 2nd-stage, ft3 (m3)
• Q1=volume of digested sludge feed=volume of
  average daily raw sludge feed cfd (m3/d)
• Q2=volume of daily digested sludge accumulation
  in tank, cfd (m3/d)
• T1=period required for thickening, days
• T2= period required for digested sludge storage,
  days
Aerobic Digestion
• Similar to the activated sludge process.
• -Organic sludge is aerated for extended
  periods to oxidized organic material.
• -Works best on waste activated sludge.
• -Reduces significant pathogens.

  Organic matter+O2   new cells+energy+CO2+H2O+end products
Dewatering
• -Consists of reducing the sludge volume &
  increasing the solids content.
• -Concentration includes-
• * Centrifuges (5% to 40% solids)
• * Belt filter presses (12% to 50%)
• * Vacuum filtration (20% to 30%)
• * Plate & frame presses (34% to 60%)
• * Sand drying beds (up to 50%)
Sludge Disposal
• Various options are available for proper
  disposal.
• Incineration of sludge is an option that is
  becoming less attractive because of the high
  cost of building & operating incinerators, plus
  the creation of air pollution & need to landfill
  the ash.
THANKS

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Wastewater treatment

  • 1. Welcome to the presentation on Domestic Waste Water Treatment by Pritilata Sarker Bhabi Mazumder Ranjan Kumar Das Sharmin Akhter
  • 2. Objectives • Domestic waste water treatment and major ways of classifying wastewater treatment plants • How to design major unit operations and processes for treating wastewater • Microbial growth in heterogeneous cultures • Sludge volume and weight relationships • How to design sludge thickening systems • How to design aerobic and anaerobic sludge digestion systems
  • 3. Introduction • Wastewater is water that has been contaminated to the degree that it is no longer beneficial, and therefore must be treated before it can be used or released back into the environment. • Four major types of wastewater are 1. Domestic/Municipal wastewater 2. Industrial 3. Urban runoff and 4. Agricultural runoff
  • 4. Wastewater Treatment Categorization
  • 5. Secondary Wastewater Treatment Plant • TSS • BOD
  • 6. Advanced Wastewater Treatment Plant • Remove N & P • Remove additional BOD & TSS that secondary treatment cannot remove • AWT utilizes chemical, biological & physical
  • 7. N removal by AWT • Nitrification • Denitrification
  • 8. Nitrification • Nitrification is an aerobic process that transforms ammonium nitrogen (reduced state) into an oxidized form (NO-3) • This process is carried out by autotropic bacteria of the genera Nitrosomonas & Nitrobacter • The overall reaction • NH+4 + 2O2 NO-3 +2H+ + H2O
  • 9. Denitrification • To remove the nitrate that formed during nitrification , a second biological process known as denitrification must be used in an anoxic environment (void of dissolved oxygen) • Denitrifying , heterotrophic microorganisms reduce nitrate into nitrogen gas, which is released into the atmosphere • The equation is • 6NO-3 + 5CH3OH 3N2 + 6OH- + 5CO2 + 7H2O
  • 10. P removal by AWT- EBPR • Biological phosphorus removal may be accomplished by providing alternating anaerobic/aerobic treatment of the waste water. • Such systems promote the growth of phosphorus accumulating organisms (PAOs) such as Acinetobacter. • PAOs takes up excess amount of P from wastewater during the aerobic phase of biological treatment. • These process is known as enhanced biological phosphorus removal (EBPR)
  • 11. Overview of Wastewater Treatment System Influent Secondary Grit Flow Aeration Chlorine Effluent clarifier meter basin contact removal basin
  • 12. Preliminary Treatment • Bar racks and screens • Grit removal • Pumping • Flow measurement • Equalization • Pre-aeration • Pre-disinfection • Shredding • Flotation
  • 13. Screening • Mechanically cleaned bar racks- -clear opening 1.5 -6 inch -remove large objects such as logs or other debris • Bar screen -opening 1-2 inch -remove rags, paper & other debris
  • 14. Grit Removal • Grit consists of sand, silt, small gravel, cinder, coffee grounds, eggshells, and other inert materials, which typically have specific gravity around 2.65 • These material are abrasive and will cause pump impellers to wear excessively, and they will accumulate in tanks, digester and pipes. • Three major types of grit removal are aerated chamber, horizontal flow through basin and vortex removal system
  • 15. Primary Treatment • Primary treatment is clarification, or separation of suspended solids from the wastewater. • Primary Treatment follows preliminary treatment, settling of SS & removal of oil, grease, and scum that floats on surface of wastewater. • Since these species contain organic matter, BOD removal is accomplished. • Primary Treatment does not remove organics soluble or colloidal organic materials. Light weight organics that floats to the surface are skimmed off & pumped to the digesters for treatment
  • 16. Primary Treatment (continued) • The sludge that accumulates at the bottom of a primary clarifier is normally stabilized by anaerobic digestion before disposal. • Primary sludge is is called “raw” sludge and contain pathogens and organics that produces odors
  • 17. Primary Treatment (continued) • Primary clarifier: Sl Particulars Specifications 1 Size Circular/ Rectangular 2 Depth 10-16 ft 3 Length 50-300 ft 4 Width 10-80 ft 5 Dia 10-200 ft 6 Detention time 1.5-2.5 hrs 7 Avg. over flow rate 800-1200 gpd/ft2 8 Weir loading rate 10000-40000 gpd/ft2
  • 18. Primary Treatment (continued) • Design of Primary clarifier: Design of Primary clarifier is based on: -Avg. over flow rate -Detention time -Weir loading rate
  • 19. Design of Primary clarifier (continued) • The overflow rate (Vo) is defined as the flow rate divided by the surface area of the clarifier where Vo= over flow rate, gpd/ft2 Q= design flow rate, MGD, As= surface area of the clarifier, ft2 • The surface area of the clarifier is determined by dividing the design flow rate by the overflow rate. This area calculated is then converted into either a circular or a rectangular area • Selecting detention time the total volume is calculated and clarifier depth is determined.
  • 20. Design of Primary clarifier (continued) • Detention time (θ) is the average unit of time that the wastewater remains in the clarifier & is determined as follows: where V= volume of the primary clarifier, Q= Design flow rate • Weir loading rate (q) is the third parameter that must be determined when designing primary clarifiers. q= weir loading rate, gpd weir length= length of primary clarifier effluent weir
  • 21. Secondary Treatment • Secondary wastewater treatment implies that a biological process is being used for treating the wastewater. • Microorganisms indigenous to the wastewater use organic carbon, along with N & P, to grow more microorganisms, primarily bacteria. • Bacteria use the organic matter as measured by BOD & COD for their energy and carbon source. • Oxidation of the organic matter produces energy that is captured in the microbe’s biochemical pathways, while a portion of a organic material is used in the synthesis of biomass.
  • 22. Secondary Treatment (continued) • The following equations shows the organic materials is being oxidized for energy and organic materials is being synthesized into new microbial cells respectively- organics + O2 CO2+ H2O + energy organics + O2 + N + P C60H87O23N42P
  • 23. Activated Sludge • It is an aerobic, suspended growth, biological process characterized by two major steps- 1. Substrate adsorption and utilization in the aeration basin. 2. Solids/liquid separation in the secondary clarifier
  • 24. Activated Sludge • Wastewater flows into the aeration basin, where it is brought into contact with a heterogeneous culture of microbes, consisting primarily of heterotrophic bacteria. The liquid inside the aeration basin is called “mixed liquor” or “Activated sludge”. A schematic of the process is presented in the next slide
  • 25. System boundary Air Alternative sludge wasting Q + Qr Secondary Effluent clarifier So Aeration basin X, V, S e Q (Q+Qr) (Q-Qr) Xi Xe, Se Xe, Se Si RAS/WAS WAS Pumping Return activated Q, X, Se station sludge, RAS Qw Xr Schematic of Activated Sludge
  • 26. Design and operational parameters • The main Design and operational parameters for the activated sludge process is the mean cell residence time (MCTR).MCTR represents the average time that the microorganisms or biomass remain in the system. MCTR is also called sludge age, solid retention time (SRT) or θc. Mathematically
  • 27. Design and operational parameters • Where : • X= biomass or microorganism concentration in aeration basin expressed as TSS or VSS, mg/L, • Xe= secondary effluent TSS or VSS concentration, mg/L, • Xr= TSS or VSS concentration in return activated sludge, mg/L, • V= volume of the aeration basin, mg/L, (m3) • Q= influent wastewater flow rate, MGD (m3 /d) • Qr= return activated sludge flow rate, MGD (m3 /d) • Qw= sludge wastage flow rate, MDG (m3 /d) • Qe= Q-Qw= effluent wastewater flow rate, MDG, (m3 /d)
  • 28. Design and operational parameters • MCTR typically varies from 5 to 30 days and determines the overall removal efficiency of the process. Generally, the longer the MCTR the lower the effluent substrate concentration as measured by BOD or COD. MCTR is longer than the hydraulic detention time θ. The hydraulic detention time θ is defined as the volume of the reactor or the basin divided by the volumetric flow rate.
  • 29. Design and operational parameters • θ= detention time based on influent wastewater flow rate, d or h and • θ’= actual detention time for recycle system, d or h. • Another design and operational parameter is the food-to-microorganism ratio which is defined as • F:M= food-to-microorganism ratio • So=influent substrate concentration to aeration basin expressed as BOD, COD or TOC, mg/L
  • 30. Biochemical kinematics of activated sludge in completely mixed system The relationship between the MCRT and net microbial cultures growth rate is Substrate utilization can be modeled by a Michaelis-Minton type equation as proposed by Lawrence and McCarty (1970) where k= maximum specific substrate utilization rate, d-1. The effluent soluble substrate concentration Se
  • 31. Biochemical kinematics of activated sludge in completely mixed system • The microorganism concentration (X) • where So and Se= influent and effluent soluble organic concentration, mass/volume. The volume of the aeration basin, V • The total quantity of biomass produced daily(Px)
  • 32. Oxygen requirement • Oxygen serves as electron acceptor in the activated sludge process, so sufficient quantities of oxygen must be provided. The following equation is used for estimating the quantity of oxygen required to meet the total oxygen demand. The nitrogenous demand (NOD) is the amount of oxygen required for the nitrifying bacteria. where O2 is the total oxygen required to meet the carbonaceous and nitrogenous oxygen demand.
  • 33. Aerator System • There are two types of Aerator System 1. Mechanical aerator 2. Diffuser • Mechanical aerator consists of mixers or brush rotors that transfer oxygen into the wastewater by spraying the wastewater into the air. Diffused aerator systems are similar to fish aquarium tanks in which oxygen diffuses through a diffuser stone or membrane, thereby transfer oxygen into the wastewater.
  • 34. Trickling Filters • Alternate secondary wastewater treatment process. • Wastewater is applied to some type of filter medium. • Media:- Past -Rock or Slag. • Media:- Present- Plastic. • Biomass growing on the media uses the organic matter along with a portion of the nitrogen & phosphorus to grow new microorganisms.
  • 35. Trickling Filters Recirculation Pump Primary Secondary Trickling filter humus sludge Primary & Secondary humus sludge
  • 36. SECONDARY CLARIFICATION • -It must separate the suspended & biological solids from the liquid wastewater. • - The design requires calculating the area of the clarifier based on clarification is determined by dividing the design flow rate by the overflow rate according to the following equation: Ac =
  • 37. SECONDARY CLARIFICATION • Where: • Ac = the area of clarifier based on clarification,ft2 (m2) • Q = Design flow rate, excluding sludge return flow applied to the secondary clarifier, MGD (m3/d), and • Vo = Overflow rate or surface loading rate, gpd/ft2 [m3/d.m2]
  • 38. SECONDARY CLARIFICATION • Based on thickening consideration, the following equation is used for determining the secondary clarifier area. AT= • Where: • AT= secondary clarifier surface area. • Q = wastewater design flow rate applied to the secondary clarifier excluding the return activated sludge flow rate, MGD (m3/d) • QR= return activated sludge flow rate, MGD (m3/d) • MLSS= suspended solids concentration in the aeration basin, and • SLR = solids loading rate design criteria, typically 25 ppd/ft2 at average daily flow.
  • 39. Disinfectants used in Wastewater Treatment • -Disinfectants-Cl2, O3 & ultraviolet (UV) radiations. • -These disinfectants offer the advantage of eliminating the production of trihalmethanes (THMs), which are chlorinated organic species and suspected carcinogens that result when chlorine is added to water containing organic compounds.
  • 40. Chlorination of Wastewater • -Chlorine is delivered to wastewater treatment facilities in pressurized containers, which range in size from 150-lb to 1-ton cylinders. • -Chlorine is liquefied under high pressure & withdrawn as a gas or liquid, depending on the withdrawal rate. • - At large waste water treatment plant, chlorine is withdrawn as a liquid & must pass through an evaporator to be converted to a gas.
  • 41. Chlorine Contact Basin • -When chlorine is added to secondary effluent, it must have sufficient contact with the wastewater to kill pathogens. • -Long, rectangular serpentine channels simulating the plug flow regime are used in the design of chlorine contact basins.
  • 42. Sludge Treatment & Disposal • Sludge or bio-solids and other residuals are generated at wastewater treatment facilities. • Screening & grit from preliminary treatment unit are normally collected in dumpsters; volume is reduced & hauled off to sanitary landfills for ultimate disposal. • Primary sludge contains organic solids & pathogens. • Secondary sludge consists of biological organisms,i.e. biomass & is stabilized using aerobic or anaerobic digestion. • Aerobic & anaerobic digestion decrease the volume & quantity of sludge
  • 43. 4 Steps of Sludge treatment & disposal • Sludge volume is reduced through thickening operation. • Stabilization with aerobic or anaerobic digestion. • Dewatering operations to increase the concentration of solids. • Ultimate disposal.
  • 44. Sludge Weight & Volume Relationships
  • 45. 4 Steps of Sludge treatment & disposal • The volume (V) occupiedby wet sludge (ft3 or m3) is determined using the following equation: V= • Where: • S= Solids content,% • ϒ= Specific weight of water, 62.4 lb/ft3
  • 46. Thickening Operations • Important because • It reduces the volume of the sludge to be handled, thereby reducing the size of subsequent solids handling processes such as sludge stabilization. • Sludge thickening operations & the approximate solid concentration associated with each include • a) gravity thickening (2% -10% solids) • b)gravity belt thickeners (3%-6%) • c)dissolved air flotation (3%-6%) • d)thickening centrifuges (4%-8%)
  • 47. Stabilization • Anaerobic Digestion • -A biological process that takes place in an enclosed reactor with no oxygen present. • -It produces a stable sludge & a valuable by-product, methane gas,which can be combustedto provide heat for the digesters or used for generating electricity. • -It is sensitive to operate & prone to biological upsets. • -Anaerobically digested sludge is usually difficult to dewater by mechanical means. • - 3 step process- Hydrolysis Acidogenesis Methanogenesis
  • 48. Anaerobic Digestion • Hydrolysis: • -Complex organic solids are hydrolyzed by bacteria. • -Carbohydrates,proteins & fats are converted to simple carbohydrates, amino acids and fatty acids. • • Acidogenesis • -Involves the conversion of soluble carbon formed during hydrolysis into organic acids & H2. • • Methanogenesis • -Bacterial conversion of fatty acids & hydrogen into CH4 & Co2 by strict anaerobes.
  • 49. Anaerobic Digestion • Low or standard-rate anaerobic digester volume can be estimated as follows: • V= T1+ Q2T2 • Where: • V =total digester capacity, ft3 (m3) • Q1 =volume of raw sludge fed daily, cfd (m3/d) • T1 =period required for digestion, approximately 25 d • Q2 =volume of daily digested sludge accumulation in tank, cfd (m3/d) • T2 =period of digested storage, 20 to 120 days.
  • 50. Anaerobic Digestion • For determining the volume of a high-rate anaerobic digester. • V1= Q1xT • V1=digester capacity required for 1st-stage or high-rate digestion, ft3 (m3) • T=period required for digestion, d. • The volume of a 2nd-stage, VH= T1+ Q2T2
  • 51. Anaerobic Digestion • Where: • VH=digester capacity required for 2nd-stage, ft3 (m3) • Q1=volume of digested sludge feed=volume of average daily raw sludge feed cfd (m3/d) • Q2=volume of daily digested sludge accumulation in tank, cfd (m3/d) • T1=period required for thickening, days • T2= period required for digested sludge storage, days
  • 52. Aerobic Digestion • Similar to the activated sludge process. • -Organic sludge is aerated for extended periods to oxidized organic material. • -Works best on waste activated sludge. • -Reduces significant pathogens. Organic matter+O2 new cells+energy+CO2+H2O+end products
  • 53. Dewatering • -Consists of reducing the sludge volume & increasing the solids content. • -Concentration includes- • * Centrifuges (5% to 40% solids) • * Belt filter presses (12% to 50%) • * Vacuum filtration (20% to 30%) • * Plate & frame presses (34% to 60%) • * Sand drying beds (up to 50%)
  • 54. Sludge Disposal • Various options are available for proper disposal. • Incineration of sludge is an option that is becoming less attractive because of the high cost of building & operating incinerators, plus the creation of air pollution & need to landfill the ash.