Total internal reflection occurs when light travels from an optically denser medium to a less dense one at an angle of incidence greater than the critical angle. The critical angle is the angle at which the refracted ray travels parallel to the interface between the two media. When the angle of incidence exceeds the critical angle, the light ray is fully reflected back into the denser medium rather than refracting into the less dense medium. This phenomenon of total internal reflection is used in applications like fiber optics, periscopes, and binoculars.