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SPECTROSCOPY
Contents
Introduction
History
Types
Spectrometer
INTRODUCTION
Spectroscopy is the study of
  the  interaction  between matter and 
electromagnetic radiation
originated  through  the  study  of visible  light 
dispersed according to its wavelength, by a prism
Introduction
Spectra Refers to:-
the distribution of colors produced when white
light is dispersed by a prism 
continuous change in wavelength from red, the
longest wavelength, to violet, the shortest. 
 Spectroscopic data is represented by
spectrum, a plot of the response of interest as a
function of wavelength or frequency.
Conti…
Spectroscopy Used in
  Physical chemistry
 Analytical chemistry
 Research telescopes
 Astronomy
Remote sensing
History
Newton's Concept
In 1666–1672
spectroscopy  began  with Isaac  Newton's  optics 
experiments
describe  the  rainbow  of  colors  that  combine  to 
form  white  light  and  that  are  revealed  when  the 
white light is passed through a prism.
Joseph von Fraunhofer
 early 1800s
 made experimental advances with spectrometers
that enabled spectroscopy to become a more
precise and quantitative scientific technique.
TYPES OF
SPECTROSCOPY
Conti…
 Flame
 X-ray
 Atomic Emission Spectroscopy (AE)
 Atomic absorption spectroscopy (AA)
 Spark or arc (emission) spectroscopy
Conti…
 Visible/Ultraviolet (UV)
 Infrared (IR) and Near Infrared (NIR)
 Nuclear magnetic resonance
Atomic Emission Spectroscopy (AE)
 uses atoms excited from the heat of a flame to
emit light.
 analysis can be done with a high resolution
Polychromator to produce an emission
intensity.
 wavelength spectrum to detect multiple
elements simultaneously.
Atomic absorption spectroscopy
A spectroanalytical procedure for the quantitative
determination of chemical elements using
the absorption of optical radiation (light) by
free atoms in the gaseous state.
Mass Spectrometry
Is an analytical chemistry technique that helps
identify the amount and type of chemicals present
in a sample by measuring the mass-to-charge
ratio and abundance of gas-phase ions
19
Infrared Spectroscopy
Is the spectroscopy that deals with
the infrared region of the electromagnetic
spectrum that is light with a longer wavelength and
lower frequency than visible light.
Spectrometer
A spectrometer is an apparatus
 to measure a spectrum
It shows intensity as a function of
 Wavelength
 Frequency
 Energy
 Momentum
 Mass
Optical spectrometer
 Mass spectrometer
Time-of-flight spectrometer
Magnetic spectrometer
Optical Spectrometer
  show  the  intensity  of light as  a  function  of 
wavelength or of frequency
 The  deflection  is  produced  either 
by refraction in  a prism or  by diffraction in 
a diffraction grating
Mass spectrometer
A mass  spectrometer is  an  analytical  instrument 
that is used to
identify the amount and type of chemicals present 
in a sample by measuring the mass-to-charge ratio
abundance of gas-phase ions
Time-of-flight spectrometer
  determining the time of flight between
two detectors
  if the velocity is known, masses can be
determined
Spectroscopy Techniques Explained
Spectroscopy Techniques Explained

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