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Solutions PGCC CHM 101 Sinex
-single atoms -small molecules -ions -polyatomic ions -aggregates of atoms, molecules or ions -macromolecules (proteins) -clumps of particles, -mineral grains such as sand Comparison of Solutions, Colloids, and Suspensions solutions colloids suspensions < 1 nm > 100 nm
More Comparison… transparent with Tyndall effect translucent (cloudy) molecular motion Brownian motion- colloidal particles moved by solvent movement by gravity coagulation – can settle never settle transparent (clear) solutions colloids suspensions < 1 nm > 100 nm
Light passage… Passage of light Scattering in beam Scattering in all directions Absorption of light solutions colloids suspensions < 1 nm > 100 nm
-dissolved in water electrolytes  (salts) gases glucose -plasma proteins albumins globulins fibrinogen -cellular stuff red blood cells white blood cells platelets Using whole blood as an example… solutions colloids suspensions < 1 nm > 100 nm
Solutions: homogeneous mixtures ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Types of solutes Na + Cl - Strong Electrolyte  - 100% dissociation, all ions in solution high conductivity
Types of solutes CH 3 COOH CH 3 COO - H + Weak Electrolyte  - partial dissociation, molecules and ions in solution slight conductivity
Types of solutes sugar Non-electrolyte  - No dissociation, all molecules in solution no conductivity
Solubility of Solutes in Water Temperature Solubility, g/100 mL water Most solids (endothermic hydration) Some solids (exothermic hydration) All gases
Dissolving process in water 1. Overcome attractive forces in solid 2. Hydration of solute Orientation of water molecules around solute Click here  for Chime structure  Na + Cl -
Types of attractive forces For water: dipole-dipole For NaCl (s): ion-ion For hydrated ion:  ion-dipole Na + Cl -
How do I get sugar to dissolve faster in my iced tea? Stir, and stir, and stir Add sugar to warm tea then add ice Grind the sugar to a powder Fresh solvent contact and interaction with solute  Greater surface area, more solute-solvent interaction Faster rate of dissolution at higher temperature
Units of Concentrations amount of solute per amount of solvent or solution Percent (by mass) = Molarity (M) = moles = M x V L g solute g solution x 100 g solute g solute + g solvent x 100 = moles of solute volume in liters of solution
Examples  What is the percent of KCl if 15 g KCl are  placed in 75 g water? %KCl = 15g x 100/(15 g + 75 g) = 17% What is the molarity of the KCl if 90 mL of solution are formed? mole  KCl = 15 g x (1 mole/74.5 g) = 0.20 mole molarity = 0.20 mole/0.090L = 2.2 M KCl
How many Tums tablets, each 500 mg CaCO 3 , would it take to neutralize a quart of vinegar, 0.83 M acetic acid (CH 3 COOH)? 2CH 3 COOH(aq) + CaCO 3 (s)    Ca(CH 3 COO) 2 (aq) + H 2 O + CO 2 (g) moles acetic acid = 0.83 moles/L x 0.95 L = 0.79 moles AA mole CaCO 3  = 0.79 moles AA x (1 mole CaCO 3 /2 moles AA) = 0.39 moles CaCO 3 mass CaCO 3  = 0.39 moles x 100 g/mole = 39 g CaCO 3 number of tablets = 39 g x (1 tablet/0.500g) =  79 tablets a quart   the mole ratio molar mass

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Solutions

  • 1. Solutions PGCC CHM 101 Sinex
  • 2. -single atoms -small molecules -ions -polyatomic ions -aggregates of atoms, molecules or ions -macromolecules (proteins) -clumps of particles, -mineral grains such as sand Comparison of Solutions, Colloids, and Suspensions solutions colloids suspensions < 1 nm > 100 nm
  • 3. More Comparison… transparent with Tyndall effect translucent (cloudy) molecular motion Brownian motion- colloidal particles moved by solvent movement by gravity coagulation – can settle never settle transparent (clear) solutions colloids suspensions < 1 nm > 100 nm
  • 4. Light passage… Passage of light Scattering in beam Scattering in all directions Absorption of light solutions colloids suspensions < 1 nm > 100 nm
  • 5. -dissolved in water electrolytes (salts) gases glucose -plasma proteins albumins globulins fibrinogen -cellular stuff red blood cells white blood cells platelets Using whole blood as an example… solutions colloids suspensions < 1 nm > 100 nm
  • 6.
  • 7. Types of solutes Na + Cl - Strong Electrolyte - 100% dissociation, all ions in solution high conductivity
  • 8. Types of solutes CH 3 COOH CH 3 COO - H + Weak Electrolyte - partial dissociation, molecules and ions in solution slight conductivity
  • 9. Types of solutes sugar Non-electrolyte - No dissociation, all molecules in solution no conductivity
  • 10. Solubility of Solutes in Water Temperature Solubility, g/100 mL water Most solids (endothermic hydration) Some solids (exothermic hydration) All gases
  • 11. Dissolving process in water 1. Overcome attractive forces in solid 2. Hydration of solute Orientation of water molecules around solute Click here for Chime structure Na + Cl -
  • 12. Types of attractive forces For water: dipole-dipole For NaCl (s): ion-ion For hydrated ion: ion-dipole Na + Cl -
  • 13. How do I get sugar to dissolve faster in my iced tea? Stir, and stir, and stir Add sugar to warm tea then add ice Grind the sugar to a powder Fresh solvent contact and interaction with solute Greater surface area, more solute-solvent interaction Faster rate of dissolution at higher temperature
  • 14. Units of Concentrations amount of solute per amount of solvent or solution Percent (by mass) = Molarity (M) = moles = M x V L g solute g solution x 100 g solute g solute + g solvent x 100 = moles of solute volume in liters of solution
  • 15. Examples What is the percent of KCl if 15 g KCl are placed in 75 g water? %KCl = 15g x 100/(15 g + 75 g) = 17% What is the molarity of the KCl if 90 mL of solution are formed? mole KCl = 15 g x (1 mole/74.5 g) = 0.20 mole molarity = 0.20 mole/0.090L = 2.2 M KCl
  • 16. How many Tums tablets, each 500 mg CaCO 3 , would it take to neutralize a quart of vinegar, 0.83 M acetic acid (CH 3 COOH)? 2CH 3 COOH(aq) + CaCO 3 (s)  Ca(CH 3 COO) 2 (aq) + H 2 O + CO 2 (g) moles acetic acid = 0.83 moles/L x 0.95 L = 0.79 moles AA mole CaCO 3 = 0.79 moles AA x (1 mole CaCO 3 /2 moles AA) = 0.39 moles CaCO 3 mass CaCO 3 = 0.39 moles x 100 g/mole = 39 g CaCO 3 number of tablets = 39 g x (1 tablet/0.500g) = 79 tablets a quart the mole ratio molar mass

Editor's Notes

  1. CHM 101 Sinex