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Polarity
of
Molecules
1) Predict the results of the mixture.
2) Define electronegativity
3) Find the electronegativity of elements in the
periodic table.
4) Explain the VSEPR theory
5) Draw the geometry of molecules using the
VSEPR theory
Important terms that learners will encounter
a.Electronegativity
b.Covalent bond
c.Valence electron
d. Miscible
e. Dipole
f.Immiscible
Polarity Experiment
Materials
Water
Vinegar
Vegetable oil
Gasoline
 Test tubes or graduated
cylinder
 Stirring rod
 Food coloring (optional
for coloring water and
vinegar)
Polarity Experiment
Procedure
1. Mix the following samples
well with a spoon and observe
their reactions
2. Stir the mixture.
3. Remember to wash and dry
the stirring rod after each use.
Group I: Water + vinegar
Group II: Water + oil Group
III: Water + gasoline Group
IV: Oil + vinegar Group V:
Oil + gasoline
Group VI: Honey +
gasoline
Mixture Mixed (/) Not Mixed (X)
Water + vinegar
Water + oil Water
+ gasoline Oil +
vinegar Oil +
gasoline
Honey + gasoline
Find it!
 boiling points
 melting points
 oxidation number
 Atomic number
 Atomic weight/ atomic mass
 Electronegativity
Two factors that determine the polarity of
molecules.
1.polarity of the bonds between atoms which
can be studied based on electronegativity
2.the geometrical shape of the molecule which
can be predicted via the valence shell electron
pair repulsion (VSEPR) theory
Electronegativity (EN)
- measure of the relative tendency of an atom to
attract electrons to itself when chemically combined
with another atom.
-the higher the value of electronegativity, the more
it tends to attract electrons toward itself.
Covalent bond
- is a chemical link between
two atoms or ions where the
electron pairs are shared
between them
2 Types of Covalent bond
1. Polar Covalent Bond
2. Non- polar Covalent Bond
Polar covalent bonds
Polar covalent bonds occur when
electron pairs are unequally
shared. The difference in
electronegativity between atoms is
significant
Examples of compounds having
polar covalent bonds
HCl
EN of H = 2.1 EN of Cl = 3.0 ΔEN = 0.9
Examples of compounds having
polar covalent bonds
HF
EN of H = 2.1 EN of F = 4.0 ΔEN = 1.9
The separation of charges makes the bond
polar. It creates an electric dipole. Dipole
refers to “two poles,” meaning there is a
positive and a negative pole within a
molecule.
Elements with the higher EN value
become the partial negative pole while
elements with the lower EN value become
the partial positive pole. This makes the
molecule a polar molecule.
Non-polar covalent bonds
-occur when electron pairs are
shared equally or the difference in
electronegativity between atoms is
less than 0.5.
1. H2
EN of H = 2.1 ΔEN = 0.0 NON-
POLAR MOLECULE; not a dipole
2. Cl2
EN of Cl = 3.0 ΔEN = 0.0 NON-POLAR MOLECULE; not a dipole
3. F2
EN of F = 4.0 ΔEN = 0.0 NON-POLAR MOLECULE; not a dipole
Seatwork
Compound
ΔEN Type of Covalent
Bond
Dipole/
Not Dipole
CH4
CF4
HBr
O
Polar or Non-Polar
1.H20
POLAR
2.SF2
POLA
R
3. CO2
NON-POLAR
4. BF3
NON-POLAR
Answer key
EN of C = 2.5
EN of F = 4.0
EN of Br = 2.8
ΔEN = 0.4 Non polar covalent bond
ΔEN = 1.5 Polar covalent bond
ΔEN = 0.7 Polar covalent bond
1. CH4
2. CF4
3.HBr
4. O2
EN of H = 2.1
EN of C = 2.5
EN of H= 2.1
EN of O = 3.4 ΔEN = 0.0 Non polar covalent bond
4. HI
EN of H = 2.1 EN of I = 2.5 ΔEN = 0.4
POLAR MOLECULE; a dipole
Valence Shell Electron Pair Repulsion
theory or VSEPR theory
- helps predict the spatial arrangement
of atoms in a polyatomic molecule. The
shapes are designed to minimize the
repulsion within a molecule.
Guidelines to determine the VSEPR
shape of a molecule
1.Determine the central atom of a
molecule. The central atom is the least
electronegative element.
2.Count how many valence electrons the
central atom has.
3.Count how many valence electrons
the side atoms have.
4.Create the appropriate Lewis
structure of the molecule.
5.Using the Lewis structure as a guide,
determine the appropriate VSEPR shape
for the molecule.
6.Note how many electrons are shared and
unshared. This will help determine the
appropriate VSEPR shape.
EXAMPLE
Compound
Name
Total # of
valence
electrons
Lewis
Structure
Geometric
Shape
Type of
Bond
SiS2
Compound
Name
Total # of
valence
electrons
Lewis
Structure
Geometric
Shape
Type of
Bond
CH4
Compound Total # of
valence
electrons
Lewis
Structure
Geometric
Shape
Type of Bond
Name
1. CH4
2. NH3
3. CdBr2
4. PH3
5. BCl3
Compound
Name
Total # of
valence
electrons
Lewis
Structure
Geometric
Shape
Type of Bond
1. CH4 8 tetrahedral Non-polar
2. NH3 8 Triangular
pyramidal/
tetrahedral
Polar
3. CdBr2 16 Linear Non-Polar
4. PH3 8 Triangular
pyramidal/tetr
ahedral
Polar
5. BCl3 24 Trigonal
Planar
Non-polar

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s11-12ps-iiic-15-polar-amp-non-polar_compress.ppt

  • 2. 1) Predict the results of the mixture. 2) Define electronegativity 3) Find the electronegativity of elements in the periodic table. 4) Explain the VSEPR theory 5) Draw the geometry of molecules using the VSEPR theory
  • 3. Important terms that learners will encounter a.Electronegativity b.Covalent bond c.Valence electron d. Miscible e. Dipole f.Immiscible
  • 4. Polarity Experiment Materials Water Vinegar Vegetable oil Gasoline  Test tubes or graduated cylinder  Stirring rod  Food coloring (optional for coloring water and vinegar)
  • 5. Polarity Experiment Procedure 1. Mix the following samples well with a spoon and observe their reactions 2. Stir the mixture. 3. Remember to wash and dry the stirring rod after each use. Group I: Water + vinegar Group II: Water + oil Group III: Water + gasoline Group IV: Oil + vinegar Group V: Oil + gasoline Group VI: Honey + gasoline
  • 6. Mixture Mixed (/) Not Mixed (X) Water + vinegar Water + oil Water + gasoline Oil + vinegar Oil + gasoline Honey + gasoline
  • 7. Find it!  boiling points  melting points  oxidation number  Atomic number  Atomic weight/ atomic mass  Electronegativity
  • 8. Two factors that determine the polarity of molecules. 1.polarity of the bonds between atoms which can be studied based on electronegativity 2.the geometrical shape of the molecule which can be predicted via the valence shell electron pair repulsion (VSEPR) theory
  • 9. Electronegativity (EN) - measure of the relative tendency of an atom to attract electrons to itself when chemically combined with another atom. -the higher the value of electronegativity, the more it tends to attract electrons toward itself.
  • 10. Covalent bond - is a chemical link between two atoms or ions where the electron pairs are shared between them
  • 11. 2 Types of Covalent bond 1. Polar Covalent Bond 2. Non- polar Covalent Bond
  • 12. Polar covalent bonds Polar covalent bonds occur when electron pairs are unequally shared. The difference in electronegativity between atoms is significant
  • 13. Examples of compounds having polar covalent bonds HCl EN of H = 2.1 EN of Cl = 3.0 ΔEN = 0.9
  • 14. Examples of compounds having polar covalent bonds HF EN of H = 2.1 EN of F = 4.0 ΔEN = 1.9
  • 15. The separation of charges makes the bond polar. It creates an electric dipole. Dipole refers to “two poles,” meaning there is a positive and a negative pole within a molecule.
  • 16. Elements with the higher EN value become the partial negative pole while elements with the lower EN value become the partial positive pole. This makes the molecule a polar molecule.
  • 17. Non-polar covalent bonds -occur when electron pairs are shared equally or the difference in electronegativity between atoms is less than 0.5.
  • 18. 1. H2 EN of H = 2.1 ΔEN = 0.0 NON- POLAR MOLECULE; not a dipole
  • 19. 2. Cl2 EN of Cl = 3.0 ΔEN = 0.0 NON-POLAR MOLECULE; not a dipole 3. F2 EN of F = 4.0 ΔEN = 0.0 NON-POLAR MOLECULE; not a dipole
  • 20. Seatwork Compound ΔEN Type of Covalent Bond Dipole/ Not Dipole CH4 CF4 HBr O
  • 21. Polar or Non-Polar 1.H20 POLAR 2.SF2 POLA R 3. CO2 NON-POLAR 4. BF3 NON-POLAR
  • 22.
  • 23. Answer key EN of C = 2.5 EN of F = 4.0 EN of Br = 2.8 ΔEN = 0.4 Non polar covalent bond ΔEN = 1.5 Polar covalent bond ΔEN = 0.7 Polar covalent bond 1. CH4 2. CF4 3.HBr 4. O2 EN of H = 2.1 EN of C = 2.5 EN of H= 2.1 EN of O = 3.4 ΔEN = 0.0 Non polar covalent bond
  • 24.
  • 25.
  • 26. 4. HI EN of H = 2.1 EN of I = 2.5 ΔEN = 0.4 POLAR MOLECULE; a dipole
  • 27. Valence Shell Electron Pair Repulsion theory or VSEPR theory - helps predict the spatial arrangement of atoms in a polyatomic molecule. The shapes are designed to minimize the repulsion within a molecule.
  • 28. Guidelines to determine the VSEPR shape of a molecule 1.Determine the central atom of a molecule. The central atom is the least electronegative element. 2.Count how many valence electrons the central atom has.
  • 29. 3.Count how many valence electrons the side atoms have. 4.Create the appropriate Lewis structure of the molecule.
  • 30. 5.Using the Lewis structure as a guide, determine the appropriate VSEPR shape for the molecule. 6.Note how many electrons are shared and unshared. This will help determine the appropriate VSEPR shape.
  • 31.
  • 34. Compound Total # of valence electrons Lewis Structure Geometric Shape Type of Bond Name 1. CH4 2. NH3 3. CdBr2 4. PH3 5. BCl3
  • 35. Compound Name Total # of valence electrons Lewis Structure Geometric Shape Type of Bond 1. CH4 8 tetrahedral Non-polar 2. NH3 8 Triangular pyramidal/ tetrahedral Polar 3. CdBr2 16 Linear Non-Polar 4. PH3 8 Triangular pyramidal/tetr ahedral Polar 5. BCl3 24 Trigonal Planar Non-polar