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07/03/12




Reactivity of Metals
07/03/12
    Reactions of metals with oxygen
When a metal reacts with oxygen it will form a METAL
OXIDE. This is what happens when a metal rusts. We can
make this reaction happen quicker by burning the metal.


      METAL + OXYGEN                METAL OXIDE


Copy and complete the following reactions:
•    Magnesium + oxygen
•    Copper + oxygen
•    Calcium + oxygen
•    Iron + oxygen
07/03/12
    Reactions of metals with water
When a metal reacts with water hydrogen is always given
off. The other product will be either a metal hydroxide or
a metal oxide.

      METAL + WATER          METAL OXIDE + HYDROGEN
    METAL + WATER          METAL HYDROXIDE + HYDROGEN



Copy and complete the following reactions:
•    Sodium + water
•    Potassium + water
•    Calcium + water
•    Iron + steam
07/03/12
    Reactions of metals with acids
When a metal reacts with an acid it gives off hydrogen
(which can be “popped” using a lit splint). The other
product is a salt.

    METAL + ACID                        SALT + HYDROGEN

e.g. magnesium + hydrochloric acid   magnesium chloride + hydrogen


Copy and complete the following reactions:
•   Calcium + hydrochloric acid
•   Zinc + hydrochloric acid
•   Iron + hydrochloric acid
•   Lithium + sulphuric acid
07/03/12
    Complete the following reactions:

•   Lithium + water               Lithium hydroxide + hydrogen
•   Lithium + hydrochloric acid   Lithium chloride + hydrogen
•   Silver + oxygen               Silver oxide
•   Magnesium + sulphuric acid    Magnesium sulphate + hydrogen
•   Potassium + oxygen            Potassium oxide
•   Aluminium + oxygen            Aluminium oxide
•   Manganese + water             Manganese oxide + hydrogen
•   Sodium + sulphuric acid       Sodium sulphate + hydrogen
•   Lithium + oxygen              Lithium oxide
•   Nickel + hydrochloric acid    Nickel chloride + hydrogen
07/03/12
An example question on reactivity
Metal   Reaction with      Reaction       Reaction
         dilute acid      with water     with oxygen
        Some reaction   Slow reaction    Burns brightly
  A

        No reaction     No reaction      Reacts slowly
  B

        No reaction     No reaction      No reaction
  C

        Violent reaction Slow reaction   Burns brightly
  D

        Reasonable      Reacts with      Reacts slowly
  E     reaction        steam only
07/03/12

       The Reactivity Series
                                 Potassium
                                  Sodium
                                  Calcium
                                 Magnesium

The Reactivity Series lists      Aluminium
metals in order of reactivity:    Carbon
                                   Zinc
                                   Iron
                                   Lead
                                  Copper
                                   Silver
                                   Gold
Displacement reactions
                                                             07/03/12




A displacement reaction is one where a MORE REACTIVE metal will
      DISPLACE a LESS REACTIVE metal from a compound.

Magnesium                                          Copper sulphate

 Mg                                                  Cu     SO4

                 The magnesium
                 DISPLACES the copper
                 from copper sulphate



            Mg      SO4                    Cu

        Magnesium sulphate                Copper
07/03/12

       Displacement reactions
A displacement reaction is one where a MORE REACTIVE
metal will DISPLACE a LESS REACTIVE metal from a
compound.

For example, if you drop some magnesium into copper
sulphate a reaction will happen because magnesium is more
reactive than copper, so the reaction is:


 Magnesium + copper sulphate     copper + magnesium sulphate



However, if you drop some copper into magnesium sulphate
NOTHING will happen.
07/03/12

      Some example reactions…
      Reaction            Prediction     Observations

Zinc + copper sulphate


Zinc + lead nitrate


Copper + lead nitrate


Copper + silver nitrate



Extension work – write down the equations for these
reactions
07/03/12

      Some example reactions…
      Reaction            Prediction      Observations

Zinc + copper sulphate                 Reaction DID happen


Zinc + lead nitrate                    Reaction DID happen


Copper + lead nitrate                  Reaction DID NOT
                                       happen

Copper + silver nitrate                Reaction DID happen



Extension work – write down the equations for these
reactions
07/03/12

           Extracting Metals
Some definitions:


A METAL ORE is a mineral or mixture of minerals from
which it is “economically practical” to extract some
metal.


Most ores contain METAL OXIDES (e.g. rust = iron
oxide).


To “extract” a metal from a metal oxide we need to
REDUCE the oxygen. This is called a REDUCTION
reaction.
How do we do it?                          07/03/12


Potassium
 Sodium
              Metals ABOVE CARBON, because
 Calcium
              of their high reactivity, are
Magnesium     extracted by ELECTROLYSIS
Aluminium
 Carbon
                   Metals BELOW CARBON are
  Zinc             extracted by heating them with
  Iron             carbon in a BLAST FURNACE
   Tin
  Lead
 Copper     These LOW REACTIVITY metals
            blatantly won’t need to be extracted
  Silver
            because they are SO unreactive you’ll
  Gold      find them on their own, not in a metal
 Platinum   oxide
07/03/12

               Extracting metals
•   What is an ore?
•   In what form are metals usually found in the Earth?
•   How do you get a metal out of a metal oxide?
•   What is this type of reaction called?

    Type of metal          Extraction process         Examples


  High reactivity (i.e
anything above carbon)

 Middle reactivity (i.e.
anything below carbon)

    Low reactivity
07/03/12

                  The Blast Furnace
                                1) HAEMATITE (iron ore),
                                limestone and coke (carbon) are
                                fed in here


  2) Hot air is
                                      3) The carbon reacts with
  blasted in
                                      oxygen from the air to form
  here
                                      carbon dioxide.
                                      4) The carbon dioxide reacts
                                      with more carbon to form
                                      carbon monoxide

6) Molten slag                       5) Carbon monoxide reduces
(waste) is                           iron oxide to iron. The
tapped off here                      molten iron is tapped off here

 Iron oxide + carbon monoxide            iron + carbon dioxide
07/03/12

           Electrolysis


                    Molecule of solid
                    copper chloride




                       Molecule of solid
                       copper chloride after
                       being dissolved
Chloride   Copper
  ion        ion
07/03/12

                 Electrolysis
Electrolysis is used to extract a HIGHLY REACTIVE metal.

                                When we electrolysed
                                  copper chloride the
                                 negative chloride ions
                                 moved to the positive
                              electrode and the positive
                               copper ions moved to the
                                  negative electrode –
                               OPPOSITES ATTRACT!!!

                                    = chloride ion

                                    = copper ion
Redox reactions                         07/03/12


These happen during electrolysis:
                           At the positive electrode the
                          negative ions LOSE electrons to
                              become neutral – this is
                                   OXIDATION
                           At the negative electrode the
                          positive ions GAIN electrons to
                              become neutral – this is
                                    REDUCTION
                             These two processes are
                            called REDOX REACTIONS

        OILRIG –     Oxidation Is Loss of electrons
                     Reduction Is Gain of electrons
07/03/12



Purifying
Aluminium


Aluminium has to be extracted from its ore (called ________) by
electrolysis. This is because aluminium is very ___________. The
ore is mixed with cryolite to lower its ________ ________. The ore
is then melted so that the ions can ______. The positively charged
aluminium ions gather at the ___________ electrode. Oxygen forms
at the positive electrode and causes it to wear away, which means that
they have to be __________ frequently.

Words – melting point, replaced, negative, bauxite, reactive, move
07/03/12

       Rusting Experiment




RUST      NO RUST –   NO RUST –
          no water    no oxygen
Rusting
                                                         07/03/12



Rust is formed when iron reacts with water AND oxygen.
   It’s an example of an oxidation reaction which can be
   sped up using salt. There are several ways of dealing
   with rust:
•   Regular painting or oiling
•   Galvanising – this is when iron objects are coated with
    zinc
•   Making objects out of a non-rusting metal, such as
    stainless steel
•   Attaching zinc bars to ships – the water will react
    with the zinc before it reacts with the iron, because
    zinc is more reactive

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Reactivity with metals

  • 2. 07/03/12 Reactions of metals with oxygen When a metal reacts with oxygen it will form a METAL OXIDE. This is what happens when a metal rusts. We can make this reaction happen quicker by burning the metal. METAL + OXYGEN METAL OXIDE Copy and complete the following reactions: • Magnesium + oxygen • Copper + oxygen • Calcium + oxygen • Iron + oxygen
  • 3. 07/03/12 Reactions of metals with water When a metal reacts with water hydrogen is always given off. The other product will be either a metal hydroxide or a metal oxide. METAL + WATER METAL OXIDE + HYDROGEN METAL + WATER METAL HYDROXIDE + HYDROGEN Copy and complete the following reactions: • Sodium + water • Potassium + water • Calcium + water • Iron + steam
  • 4. 07/03/12 Reactions of metals with acids When a metal reacts with an acid it gives off hydrogen (which can be “popped” using a lit splint). The other product is a salt. METAL + ACID SALT + HYDROGEN e.g. magnesium + hydrochloric acid magnesium chloride + hydrogen Copy and complete the following reactions: • Calcium + hydrochloric acid • Zinc + hydrochloric acid • Iron + hydrochloric acid • Lithium + sulphuric acid
  • 5. 07/03/12 Complete the following reactions: • Lithium + water Lithium hydroxide + hydrogen • Lithium + hydrochloric acid Lithium chloride + hydrogen • Silver + oxygen Silver oxide • Magnesium + sulphuric acid Magnesium sulphate + hydrogen • Potassium + oxygen Potassium oxide • Aluminium + oxygen Aluminium oxide • Manganese + water Manganese oxide + hydrogen • Sodium + sulphuric acid Sodium sulphate + hydrogen • Lithium + oxygen Lithium oxide • Nickel + hydrochloric acid Nickel chloride + hydrogen
  • 6. 07/03/12 An example question on reactivity Metal Reaction with Reaction Reaction dilute acid with water with oxygen Some reaction Slow reaction Burns brightly A No reaction No reaction Reacts slowly B No reaction No reaction No reaction C Violent reaction Slow reaction Burns brightly D Reasonable Reacts with Reacts slowly E reaction steam only
  • 7. 07/03/12 The Reactivity Series Potassium Sodium Calcium Magnesium The Reactivity Series lists Aluminium metals in order of reactivity: Carbon Zinc Iron Lead Copper Silver Gold
  • 8. Displacement reactions 07/03/12 A displacement reaction is one where a MORE REACTIVE metal will DISPLACE a LESS REACTIVE metal from a compound. Magnesium Copper sulphate Mg Cu SO4 The magnesium DISPLACES the copper from copper sulphate Mg SO4 Cu Magnesium sulphate Copper
  • 9. 07/03/12 Displacement reactions A displacement reaction is one where a MORE REACTIVE metal will DISPLACE a LESS REACTIVE metal from a compound. For example, if you drop some magnesium into copper sulphate a reaction will happen because magnesium is more reactive than copper, so the reaction is: Magnesium + copper sulphate copper + magnesium sulphate However, if you drop some copper into magnesium sulphate NOTHING will happen.
  • 10. 07/03/12 Some example reactions… Reaction Prediction Observations Zinc + copper sulphate Zinc + lead nitrate Copper + lead nitrate Copper + silver nitrate Extension work – write down the equations for these reactions
  • 11. 07/03/12 Some example reactions… Reaction Prediction Observations Zinc + copper sulphate Reaction DID happen Zinc + lead nitrate Reaction DID happen Copper + lead nitrate Reaction DID NOT happen Copper + silver nitrate Reaction DID happen Extension work – write down the equations for these reactions
  • 12. 07/03/12 Extracting Metals Some definitions: A METAL ORE is a mineral or mixture of minerals from which it is “economically practical” to extract some metal. Most ores contain METAL OXIDES (e.g. rust = iron oxide). To “extract” a metal from a metal oxide we need to REDUCE the oxygen. This is called a REDUCTION reaction.
  • 13. How do we do it? 07/03/12 Potassium Sodium Metals ABOVE CARBON, because Calcium of their high reactivity, are Magnesium extracted by ELECTROLYSIS Aluminium Carbon Metals BELOW CARBON are Zinc extracted by heating them with Iron carbon in a BLAST FURNACE Tin Lead Copper These LOW REACTIVITY metals blatantly won’t need to be extracted Silver because they are SO unreactive you’ll Gold find them on their own, not in a metal Platinum oxide
  • 14. 07/03/12 Extracting metals • What is an ore? • In what form are metals usually found in the Earth? • How do you get a metal out of a metal oxide? • What is this type of reaction called? Type of metal Extraction process Examples High reactivity (i.e anything above carbon) Middle reactivity (i.e. anything below carbon) Low reactivity
  • 15. 07/03/12 The Blast Furnace 1) HAEMATITE (iron ore), limestone and coke (carbon) are fed in here 2) Hot air is 3) The carbon reacts with blasted in oxygen from the air to form here carbon dioxide. 4) The carbon dioxide reacts with more carbon to form carbon monoxide 6) Molten slag 5) Carbon monoxide reduces (waste) is iron oxide to iron. The tapped off here molten iron is tapped off here Iron oxide + carbon monoxide iron + carbon dioxide
  • 16. 07/03/12 Electrolysis Molecule of solid copper chloride Molecule of solid copper chloride after being dissolved Chloride Copper ion ion
  • 17. 07/03/12 Electrolysis Electrolysis is used to extract a HIGHLY REACTIVE metal. When we electrolysed copper chloride the negative chloride ions moved to the positive electrode and the positive copper ions moved to the negative electrode – OPPOSITES ATTRACT!!! = chloride ion = copper ion
  • 18. Redox reactions 07/03/12 These happen during electrolysis: At the positive electrode the negative ions LOSE electrons to become neutral – this is OXIDATION At the negative electrode the positive ions GAIN electrons to become neutral – this is REDUCTION These two processes are called REDOX REACTIONS OILRIG – Oxidation Is Loss of electrons Reduction Is Gain of electrons
  • 19. 07/03/12 Purifying Aluminium Aluminium has to be extracted from its ore (called ________) by electrolysis. This is because aluminium is very ___________. The ore is mixed with cryolite to lower its ________ ________. The ore is then melted so that the ions can ______. The positively charged aluminium ions gather at the ___________ electrode. Oxygen forms at the positive electrode and causes it to wear away, which means that they have to be __________ frequently. Words – melting point, replaced, negative, bauxite, reactive, move
  • 20. 07/03/12 Rusting Experiment RUST NO RUST – NO RUST – no water no oxygen
  • 21. Rusting 07/03/12 Rust is formed when iron reacts with water AND oxygen. It’s an example of an oxidation reaction which can be sped up using salt. There are several ways of dealing with rust: • Regular painting or oiling • Galvanising – this is when iron objects are coated with zinc • Making objects out of a non-rusting metal, such as stainless steel • Attaching zinc bars to ships – the water will react with the zinc before it reacts with the iron, because zinc is more reactive