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Chapter 4
REACTIVITY OF METALS
 MINERALS IN THE EARTH CRUST
 Each type of ore is different in terms of colour, structure, shape and texture
because the ores contain different minerals.
 NATURAL ELEMENTS
 NON REACTIVE ELEMENTS
 DOESN’T COMBINE WITH OTHER ELEMENTS
 EXAMPLES : GOLD (AURUM) AND SILVER ( ARGENTUM)
 NATURAL COMPOUNDS
 COMBINATION OF TWO OR MORE ELEMENTS
 COMBINATION BETWEEN METAL ELEMENTS AND NON-METALS ELEMENTS
1. MINERALS
1.Sedimentary rock
limestone, sand stone
2. Igneous rock
Granite,basalt,
3. Metamorphic rock
Marble, gneiss
EXAMPLE OF ROCK
Earth’s crust  rock  mineral
Natural elements
(gold)
Natural compound
Bauxite ( Al, O )
Gold, diamond, silver
Diamond contain 100% atom
carbon
Gold=100% atom gold
Silver= 100% atom of silver
ELEMENTS MINERALS
(MINERAL BENTUK ELEMENTS)
Rock : lime stone
Contained mineral
 calcium carbonate [compound], calcite
Elements contained in calcium carbonate are
calcium,oxygen and carbon
NATURAL COMPOUND
= NOT elements
But Compound
Elements in Quartz are Silicon
and Oxygen
QUARTZ
MINERAL IN GRANITE(ROCK)
CAN BE DETERMINED BY MINERAL
Hardness
Resistance against erosion and scratches
Example - diamond has the highest hardness
Solubility in water
Whether mineral dissolves in water or not
Effects of heat
Whether minerals decomposed (breakdown into simpler
substances/elements) upon heating
CHARACTERISTICS OF MINERALS
Common name Scientific name Combination of
elements
Diamond Diamond carbon
Gold Gold Gold
Silver Silver Silver
NATURAL ELEMENTS
Common name Scientific name Combination of
elements
Hematite (Iron
ore)
Ferum(III) oxide Ferum(iron),oxygen
Pyrite Ferum (II) sulphide Ferum, sulphur
Cassiterite
(Tin Ore)
Stanum (IV) oxide Stanum,oxygen
EXAMPLES OF NATURAL COMPOUNDS
Bauxite
 elements of aluminium and oxygen
Quartz
element of silicon and oxygen
Galena
element lead and sulphur
EXAMPLES OF COMPOUNDS AND THEIR ELEMENTS
Common name Scientific name Combination of
elements
Lime stone Calcium
carbonate
Calcium, carbon
,oxygen
Sand stone Silicon dioxide Silicon,
oxygen
ELEMENTS OF LIME STONE
 Limestone is a natural compound
 Formed from the combination of calcium, carbon and oxygen.
 Also known as CALCIUM CARBONATE
 Properties of Limestone
 Insoluble in water
 Decomposed upon heating to form CALCIUM OXIDE and CARBON DIOXIDE IS RELEASED.
 = HEATED
 Reacts with dilute acid to form SALT, WATER AND CARBON DIOXIDE.
LIMESTONE
CALCIUM CARBONATE CALCIUM OXIDE + CARBON DIOXIDE
CALCIUM CARBONATE +DILUTE ACID SALT + WATER + CARBON DIOXIDE
Limewater shown CLOUDY
because Carbon dioxide
(CO2) is released
HEATING OF LIMESTONE ( CALCIUM CARBONATE)
■ Calcium oxide is
produced upon heating
After mixed hydrochloric
acid:
lime water turns
cloudy/chalky/milky
Because carbon dioxide
gas released
REACTION BETWEEN LIMESTONE AND DILUTE ACID
OBSERVATION
transparent
transparent
cloudy
cloudy
WORD EQUATIONS
REACTION BETWEEN CALCIUM CARBONATE WITH
DILUTE ACID
CALCIUM CARBONATE + DILUTE SULPHURIC ACID CALCIUM SULPHATE + WATER + CARBON DIOXIDE
CALCIUM CARBONATE + DILUTE HYDROCHLORIC ACID CALCIUM CHLORIDE + WATER + CARBON DIOXIDE
CALCIUM CARBONATE + DILUTE NITRIC ACID CALCIUM NITRATE + WATER + CARBON DIOXIDE
METALS AND NON-METALS
NATURAL ELEMENTS
 Metal reacts with non metals to form a more stable compounds
 The rate of reaction is different of each metals
 This is because some metals are reactive and some are less reactive
 A more reactive metal such as potassium is more reactive than ferum because
potassium reacts readily with other metals compare to ferum.
 A more reactive metal doesn’t need heat to react, some need to be heated to react
with other elements
 In fig 4.3, potassium has the highest reactivity compare to other elements, whereas,
Aurum or gold is a non reactive metal.
REACTIVITY SERIES OF METALS
REACTIVE METALS
NON REACTIVE
 Metal reacts with oxygen to form METAL OXIDE
 The rate of reaction is different of each metal (based on the reactivity series)
 Heat energy and/maybe light energy will be produced
 Non-reactive metals such as silver, gold and platinum do not react with oxygen
 Reactive metals such as potassium and sodium will react with oxygen even without the
presence of heat
 Other metals react with oxygen need heating.
 To supply oxygen to the reaction, POTASSIUM MANGANATE (VII) CRYSTAL is heated.
 Precautions when carrying out this experiment
 Do not mix the metal fillings with potassium manganate (VII) crystal – mixture will cause explosion
 Don’t look directly at the flame of burning reactive metal (such as magnesium) – it can damage
your eyes
 Asbestos paper and glass are dangerous, handle them with extra caution.
REACTION BETWEEN METAL AND OXYGEN
METAL + OXYGEN METAL OXIDE
EXPERIMENT
METAL OBSERVATION
RATE OF REACTION COLOUR OF FLAME COLOUR OF
PRODUCTS/RESIDUE
MAGNESIUM Metal burns very quickly and
brightly
Bright white flame Solid white
Magnesium oxide
ALUMINIUM Metal burns quickly and brightly Bright white flame Solid white
Aluminium oxide
ZINC Metal burns slowly Bright green blue flame Solid yellow-hot
Solid white – cold
Zinc oxide
IRON Metal glows brightly Bright yellow Solid brown
Iron oxide
LEAD Metal glows dimly No flame (glow) Solid brown – hot
Solid yellow – cold
Lead oxide
OBSERVATION
REACTION BETWEEN METAL AND OXYGEN
CONCLUSION
Burns very fast with oxygen
 Page 133
QUESTIONS AND ANSWERS
Magnesium oxide
 Carbon is a non-metal
 Carbon reacts with oxygen to form carbon dioxide
 The position of carbon in the reactivity series can be determined by the reaction of
carbon with other metals
 When a mixture of carbon and metal oxide is heated strongly,
 REACTION WILL OCCUR if carbon is MORE REACTIVE than metal (CARBON WILL REMOVE METAL
FROM ITS METAL OXIDE)
 NO REACTION will occur if Carbon is LESS REACTIVE than the metal
POSITION OF CARBON IN THE REACTIVITY SERIES IN
METALS
CARBON + METAL OXIDE METAL + CARBON DIOXIDE
 1.mixture of carbon and zinc oxide
 Repeated by:-
 Carbon and aluminium oxide
 Carbon and lead oxide
DETERMINING THE POSITION OF CARBON IN THE
REACTIVITY SERIES OF METALS
Aluminium Oxide + Carbon  NO REACTION
CARBON + ALUMINIUM OXIDE
BEFORE HEATING
Aluminium oxide
carbon
AFTER HEATING … NO REACTION
Aluminium oxide carbon
CARBON CANNOT REMOVE ALUMINIUM FROM ALUMINIUM OXIDE BECAUSE ALUMINIUM IS MORE REACTIVE
THAN CARBON ( CARBON IS LESS REACTIVE THAN ALUMINIUM)
ZINC OXIDE + CARBON  ZINC + CARBON DIOXIDE
CARBON + ZINC OXIDE
LEAD OXIDE + CARBON  LEAD + CARBON DIOXIDE
CARBON + LEAD OXIDE
BEFORE
Lead oxide carbon
 LEAD
CARBON DIOXIDE
 CARBON CAN REMOVE OXIDE FROM LEAD OXIDE BECAUSE CARBON IS MORE REACTIVE
THAN LEAD.
AFTER
RESULTS
MIXTURE OBSERVATION INFERENCE
ZINC OXIDE + CARBON MIXTURE GLOWS BRIGHTLY CARBON IS MORE REACTIVE THAN
ZINC
ALUMINIUM OXIDE + CARBON NO REACTION CARBON IS LESS REACTIVE THAN
ALUMINIUM
LEAD (II) OXIDE + CARBON MIXTURE GLOWS CARBON IS MORE REACTIVE THAN
LEAD
Aluminium, carbon, zinc, copper
CARBON
POSITION OF CARBON IN THE REACTIVITY OF METALS
 Hydrogen is a non-metal
 The position of hydrogen in the reactivity series of metal is also determined by its
ability to remove oxygen from metal oxide.
 If HYDROGEN is MORE REACTIVE than the metal, HYDROGEN WILL REMOVE OXYGEN
from the METAL OXIDE.
 HYDROGEN
POSITION OF HYDROGEN IN THE REACTIVITY SERIES
APPARATUS SET-UP TO DETERMINE THE POSITION OF
HYDROGEN IN THE REACTIVITY SERIES OF METALS
RESULTS
Aluminium Oxide + Hydrogen NO REACTION
Zinc Oxide + Hydrogen  NO REACTION
Iron oxide + Hydrogen  IRON + WATER
Copper oxide + Hydrogen COPPER + WATER
WORD EQUATIONS
 Most metals in metal ores exist in the form of metal oxides, metal sulphides and metal
carbonates
 Extraction of metals involve in the reducing of metal ores to metal or obtaining metal
from their ores
 Position of metals in the reactivity series will determine the suitable method for the
extraction of metals
 Carbon is widely used to extract iron, tin, zinc and lead from their ores because carbon
is more reactive than these metals.
 CARBON IS KNOWN AS REDUCING AGENT
EXTRACTION OF METALS FROM THEIR ORES
 THANK YOU AND GOOD LUCK
 IF YOU HAVE DONE YOUR VERY BEST, YOUR BEST IS ENOUGH!
 TCER P

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CHAPTER 4 REACTIVITY OF METALS.pptx

  • 2.  MINERALS IN THE EARTH CRUST  Each type of ore is different in terms of colour, structure, shape and texture because the ores contain different minerals.  NATURAL ELEMENTS  NON REACTIVE ELEMENTS  DOESN’T COMBINE WITH OTHER ELEMENTS  EXAMPLES : GOLD (AURUM) AND SILVER ( ARGENTUM)  NATURAL COMPOUNDS  COMBINATION OF TWO OR MORE ELEMENTS  COMBINATION BETWEEN METAL ELEMENTS AND NON-METALS ELEMENTS 1. MINERALS
  • 3. 1.Sedimentary rock limestone, sand stone 2. Igneous rock Granite,basalt, 3. Metamorphic rock Marble, gneiss EXAMPLE OF ROCK
  • 4. Earth’s crust  rock  mineral Natural elements (gold) Natural compound Bauxite ( Al, O )
  • 5. Gold, diamond, silver Diamond contain 100% atom carbon Gold=100% atom gold Silver= 100% atom of silver ELEMENTS MINERALS (MINERAL BENTUK ELEMENTS)
  • 6. Rock : lime stone Contained mineral  calcium carbonate [compound], calcite Elements contained in calcium carbonate are calcium,oxygen and carbon NATURAL COMPOUND
  • 7. = NOT elements But Compound Elements in Quartz are Silicon and Oxygen QUARTZ
  • 9.
  • 10. CAN BE DETERMINED BY MINERAL Hardness Resistance against erosion and scratches Example - diamond has the highest hardness Solubility in water Whether mineral dissolves in water or not Effects of heat Whether minerals decomposed (breakdown into simpler substances/elements) upon heating CHARACTERISTICS OF MINERALS
  • 11. Common name Scientific name Combination of elements Diamond Diamond carbon Gold Gold Gold Silver Silver Silver NATURAL ELEMENTS
  • 12. Common name Scientific name Combination of elements Hematite (Iron ore) Ferum(III) oxide Ferum(iron),oxygen Pyrite Ferum (II) sulphide Ferum, sulphur Cassiterite (Tin Ore) Stanum (IV) oxide Stanum,oxygen EXAMPLES OF NATURAL COMPOUNDS
  • 13. Bauxite  elements of aluminium and oxygen Quartz element of silicon and oxygen Galena element lead and sulphur EXAMPLES OF COMPOUNDS AND THEIR ELEMENTS
  • 14. Common name Scientific name Combination of elements Lime stone Calcium carbonate Calcium, carbon ,oxygen Sand stone Silicon dioxide Silicon, oxygen ELEMENTS OF LIME STONE
  • 15.  Limestone is a natural compound  Formed from the combination of calcium, carbon and oxygen.  Also known as CALCIUM CARBONATE  Properties of Limestone  Insoluble in water  Decomposed upon heating to form CALCIUM OXIDE and CARBON DIOXIDE IS RELEASED.  = HEATED  Reacts with dilute acid to form SALT, WATER AND CARBON DIOXIDE. LIMESTONE CALCIUM CARBONATE CALCIUM OXIDE + CARBON DIOXIDE CALCIUM CARBONATE +DILUTE ACID SALT + WATER + CARBON DIOXIDE
  • 16. Limewater shown CLOUDY because Carbon dioxide (CO2) is released HEATING OF LIMESTONE ( CALCIUM CARBONATE) ■ Calcium oxide is produced upon heating
  • 17. After mixed hydrochloric acid: lime water turns cloudy/chalky/milky Because carbon dioxide gas released REACTION BETWEEN LIMESTONE AND DILUTE ACID
  • 19. WORD EQUATIONS REACTION BETWEEN CALCIUM CARBONATE WITH DILUTE ACID CALCIUM CARBONATE + DILUTE SULPHURIC ACID CALCIUM SULPHATE + WATER + CARBON DIOXIDE CALCIUM CARBONATE + DILUTE HYDROCHLORIC ACID CALCIUM CHLORIDE + WATER + CARBON DIOXIDE CALCIUM CARBONATE + DILUTE NITRIC ACID CALCIUM NITRATE + WATER + CARBON DIOXIDE
  • 21.  Metal reacts with non metals to form a more stable compounds  The rate of reaction is different of each metals  This is because some metals are reactive and some are less reactive  A more reactive metal such as potassium is more reactive than ferum because potassium reacts readily with other metals compare to ferum.  A more reactive metal doesn’t need heat to react, some need to be heated to react with other elements  In fig 4.3, potassium has the highest reactivity compare to other elements, whereas, Aurum or gold is a non reactive metal. REACTIVITY SERIES OF METALS REACTIVE METALS NON REACTIVE
  • 22.  Metal reacts with oxygen to form METAL OXIDE  The rate of reaction is different of each metal (based on the reactivity series)  Heat energy and/maybe light energy will be produced  Non-reactive metals such as silver, gold and platinum do not react with oxygen  Reactive metals such as potassium and sodium will react with oxygen even without the presence of heat  Other metals react with oxygen need heating.  To supply oxygen to the reaction, POTASSIUM MANGANATE (VII) CRYSTAL is heated.  Precautions when carrying out this experiment  Do not mix the metal fillings with potassium manganate (VII) crystal – mixture will cause explosion  Don’t look directly at the flame of burning reactive metal (such as magnesium) – it can damage your eyes  Asbestos paper and glass are dangerous, handle them with extra caution. REACTION BETWEEN METAL AND OXYGEN METAL + OXYGEN METAL OXIDE
  • 24. METAL OBSERVATION RATE OF REACTION COLOUR OF FLAME COLOUR OF PRODUCTS/RESIDUE MAGNESIUM Metal burns very quickly and brightly Bright white flame Solid white Magnesium oxide ALUMINIUM Metal burns quickly and brightly Bright white flame Solid white Aluminium oxide ZINC Metal burns slowly Bright green blue flame Solid yellow-hot Solid white – cold Zinc oxide IRON Metal glows brightly Bright yellow Solid brown Iron oxide LEAD Metal glows dimly No flame (glow) Solid brown – hot Solid yellow – cold Lead oxide OBSERVATION
  • 25. REACTION BETWEEN METAL AND OXYGEN CONCLUSION Burns very fast with oxygen
  • 26.  Page 133 QUESTIONS AND ANSWERS Magnesium oxide
  • 27.  Carbon is a non-metal  Carbon reacts with oxygen to form carbon dioxide  The position of carbon in the reactivity series can be determined by the reaction of carbon with other metals  When a mixture of carbon and metal oxide is heated strongly,  REACTION WILL OCCUR if carbon is MORE REACTIVE than metal (CARBON WILL REMOVE METAL FROM ITS METAL OXIDE)  NO REACTION will occur if Carbon is LESS REACTIVE than the metal POSITION OF CARBON IN THE REACTIVITY SERIES IN METALS CARBON + METAL OXIDE METAL + CARBON DIOXIDE
  • 28.  1.mixture of carbon and zinc oxide  Repeated by:-  Carbon and aluminium oxide  Carbon and lead oxide DETERMINING THE POSITION OF CARBON IN THE REACTIVITY SERIES OF METALS
  • 29. Aluminium Oxide + Carbon  NO REACTION CARBON + ALUMINIUM OXIDE
  • 31. AFTER HEATING … NO REACTION Aluminium oxide carbon CARBON CANNOT REMOVE ALUMINIUM FROM ALUMINIUM OXIDE BECAUSE ALUMINIUM IS MORE REACTIVE THAN CARBON ( CARBON IS LESS REACTIVE THAN ALUMINIUM)
  • 32. ZINC OXIDE + CARBON  ZINC + CARBON DIOXIDE CARBON + ZINC OXIDE
  • 33. LEAD OXIDE + CARBON  LEAD + CARBON DIOXIDE CARBON + LEAD OXIDE
  • 35.  LEAD CARBON DIOXIDE  CARBON CAN REMOVE OXIDE FROM LEAD OXIDE BECAUSE CARBON IS MORE REACTIVE THAN LEAD. AFTER
  • 36. RESULTS MIXTURE OBSERVATION INFERENCE ZINC OXIDE + CARBON MIXTURE GLOWS BRIGHTLY CARBON IS MORE REACTIVE THAN ZINC ALUMINIUM OXIDE + CARBON NO REACTION CARBON IS LESS REACTIVE THAN ALUMINIUM LEAD (II) OXIDE + CARBON MIXTURE GLOWS CARBON IS MORE REACTIVE THAN LEAD Aluminium, carbon, zinc, copper
  • 37. CARBON POSITION OF CARBON IN THE REACTIVITY OF METALS
  • 38.  Hydrogen is a non-metal  The position of hydrogen in the reactivity series of metal is also determined by its ability to remove oxygen from metal oxide.  If HYDROGEN is MORE REACTIVE than the metal, HYDROGEN WILL REMOVE OXYGEN from the METAL OXIDE.  HYDROGEN POSITION OF HYDROGEN IN THE REACTIVITY SERIES
  • 39. APPARATUS SET-UP TO DETERMINE THE POSITION OF HYDROGEN IN THE REACTIVITY SERIES OF METALS
  • 41. Aluminium Oxide + Hydrogen NO REACTION Zinc Oxide + Hydrogen  NO REACTION Iron oxide + Hydrogen  IRON + WATER Copper oxide + Hydrogen COPPER + WATER WORD EQUATIONS
  • 42.  Most metals in metal ores exist in the form of metal oxides, metal sulphides and metal carbonates  Extraction of metals involve in the reducing of metal ores to metal or obtaining metal from their ores  Position of metals in the reactivity series will determine the suitable method for the extraction of metals  Carbon is widely used to extract iron, tin, zinc and lead from their ores because carbon is more reactive than these metals.  CARBON IS KNOWN AS REDUCING AGENT EXTRACTION OF METALS FROM THEIR ORES
  • 43.  THANK YOU AND GOOD LUCK  IF YOU HAVE DONE YOUR VERY BEST, YOUR BEST IS ENOUGH!  TCER P