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Heat and thermodynamics
Muhammad Imtiaz
Cs, year 2
Namal College, Mianwali
Thermodynamics
 Heat:
 Heat is a form of energy.
 Thermodynamics:
 A branch of physics which deals with the energy and transformation of heat due to
matter into other forms of energy.
Kinetic theory of gases
 A finite volume of gas contain large numbers of atoms and molecules.
 The size of molecule is much smaller than the separation between molecules.
 Gas molecules are in random position and may change their direction after every
collision.
 Molecules do not exert force on each other except collision.
 The collision of molecules with themselves and with the wall of cylinder is perfectly
elastic.
Effect of pressure and temperature
 When gas molecules collide, they exert pressure on each other. In other words they
increase their Kinetic energy. So we can say that
 P K.E
 Also it increases temperature as well. so,
 T K.E
First law of thermodynamics
 Statement:
 In any thermodynamics process, when heat Q is added to the system this energy appears
as an increase in internal energy stored in the system plus work done by the system on
its surroundings.
 Q = ∆U + W
 Example:
 Bicycle pump
 Human metabolism
Isothermal and adiabatic process
 Isothermal process:
 A process in which temperature remains constant.
 Thus first law of thermodynamics:
 ∆U = 0 because temperature remains constant. i.e ∆T = 0
 Q = W
 Adiabatic process:
 The process in which no heat enters or leaves the system.
 i.e. Q = 0
 So, 1st law of thermodynamics will be
 Q = - ∆U
Molar specific heat of Gas
 Definition:
 The heat required to raise the temperature of one mole of gas, Called molar specific
heat of gas.
 Molar specific heat of gas at constant Volume:
 The heat required to raise the temperature of one mole of gas at constant volume
through 1K.
 Molar specific heat of gas at constant pressure:
 The heat required to raise the temperature of one mole of gas at constant pressure
through 1K.
 Relation:
 C 𝒑 − C 𝒗 = R
Second law of thermodynamics
 Statement:
It is impossible to devise a process or system which may convert heat entirely into work
without leaving any change in the working system.
Entropy
 Definition:
 The change in state of the system under natural process is termed as Entropy.
 Formula:
 ∆S = ∆Q / T
Thank you

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Presentation chapter 11

  • 1. Heat and thermodynamics Muhammad Imtiaz Cs, year 2 Namal College, Mianwali
  • 2. Thermodynamics  Heat:  Heat is a form of energy.  Thermodynamics:  A branch of physics which deals with the energy and transformation of heat due to matter into other forms of energy.
  • 3. Kinetic theory of gases  A finite volume of gas contain large numbers of atoms and molecules.  The size of molecule is much smaller than the separation between molecules.  Gas molecules are in random position and may change their direction after every collision.  Molecules do not exert force on each other except collision.  The collision of molecules with themselves and with the wall of cylinder is perfectly elastic.
  • 4. Effect of pressure and temperature  When gas molecules collide, they exert pressure on each other. In other words they increase their Kinetic energy. So we can say that  P K.E  Also it increases temperature as well. so,  T K.E
  • 5. First law of thermodynamics  Statement:  In any thermodynamics process, when heat Q is added to the system this energy appears as an increase in internal energy stored in the system plus work done by the system on its surroundings.  Q = ∆U + W  Example:  Bicycle pump  Human metabolism
  • 6. Isothermal and adiabatic process  Isothermal process:  A process in which temperature remains constant.  Thus first law of thermodynamics:  ∆U = 0 because temperature remains constant. i.e ∆T = 0  Q = W  Adiabatic process:  The process in which no heat enters or leaves the system.  i.e. Q = 0  So, 1st law of thermodynamics will be  Q = - ∆U
  • 7. Molar specific heat of Gas  Definition:  The heat required to raise the temperature of one mole of gas, Called molar specific heat of gas.  Molar specific heat of gas at constant Volume:  The heat required to raise the temperature of one mole of gas at constant volume through 1K.  Molar specific heat of gas at constant pressure:  The heat required to raise the temperature of one mole of gas at constant pressure through 1K.  Relation:  C 𝒑 − C 𝒗 = R
  • 8. Second law of thermodynamics  Statement: It is impossible to devise a process or system which may convert heat entirely into work without leaving any change in the working system.
  • 9. Entropy  Definition:  The change in state of the system under natural process is termed as Entropy.  Formula:  ∆S = ∆Q / T