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Guide for R&M welding engineers to re-understand
the solidification , cooling curves and phase diagrams
before attending Iron-Carbon phase diagram.
Presentation by Biranchi Narayan Biswal.
Regional Manager
Ador Fontech Ltd
Introduction - Components - Phase
• Components are pure metals and/or compounds of which
an alloy is composed. For example, in a copper–zinc brass,
the components are Cu and Zn.
• It refers to a independent chemical species. The
components of a system may be elements, ions or
compounds.
• A component can exist in many phases.
– Water exists as ice, liquid water, and water vapor.
– Carbon exists as graphite and diamond.
Prof. Naman M. Dave
Phases - Solution
• A solution (liquid or solid) is phase with more than one component;
a mixture is a material with more than one phase.
• Solute (minor component of two in a solution) does not change the
structural pattern of the solvent, and the composition of any
solution can be varied.
• In mixtures, there are different phases, each with its own atomic
arrangement. It is possible to have a mixture of two different
solutions!
• For many alloy systems and at some specific temperature, there is
a maximum concentration of solute atoms that may dissolve in the
solvent to form a solid solution; this is called a solubility limit.
• The addition of solute in excess of this solubility limit results in the
formation of another solid solution or compound that has a
distinctly different composition.
Solid solutions
Substitutional Solid Solution
Ordered Substitutional Solid Solution
Disordered Substitutional Solid Solution
Interstitial Solid Solution
Prof. Naman M. Dave
Equilibrium Phase Diagram
• Important information, useful in materials development and
selection, obtainable from a phase diagram.
• It shows phases present at different compositions and
temperatures under slow cooling (equilibrium) conditions.
• It indicates equilibrium solid solubility of one element /
compound in another.
• It suggests temperature at which an alloy starts to solidify
and the range of solidification.
• It signals the temperature at which different phases start to
melt.
• Amount of each phase in a two-phase mixture can be
obtained
Cooling Curves
COOLING CURVE FOR PURE METAL OR COMPOUND
COOLING CURVE FOR BINARY SOLID SOLUTIONS.
BINARY EUTECTIC COOLING CURVE
Cadmium (Cd) + Bismuth (Bi)
Cadmium (Cd) + Bismuth (Bi) Binary Eutectic diagram
140 C
Lead (Pb) + Tin (Sn) Eutectic phase diagram
Summery of Binary Eutectic Phase diagrams
1
2
3
Types of reactions in binary phase diagrams
Thank You for learning patiently.
Now you will 100% understand the
“Iron – iron carbide” phase diagram
easily in my next presentation.
My email :- bnbiswal@rediffmail.com

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PART-1 Learning phase diagram-BNB-audio-1.pptx

  • 1. Guide for R&M welding engineers to re-understand the solidification , cooling curves and phase diagrams before attending Iron-Carbon phase diagram. Presentation by Biranchi Narayan Biswal. Regional Manager Ador Fontech Ltd
  • 2. Introduction - Components - Phase • Components are pure metals and/or compounds of which an alloy is composed. For example, in a copper–zinc brass, the components are Cu and Zn. • It refers to a independent chemical species. The components of a system may be elements, ions or compounds. • A component can exist in many phases. – Water exists as ice, liquid water, and water vapor. – Carbon exists as graphite and diamond.
  • 3. Prof. Naman M. Dave Phases - Solution • A solution (liquid or solid) is phase with more than one component; a mixture is a material with more than one phase. • Solute (minor component of two in a solution) does not change the structural pattern of the solvent, and the composition of any solution can be varied. • In mixtures, there are different phases, each with its own atomic arrangement. It is possible to have a mixture of two different solutions! • For many alloy systems and at some specific temperature, there is a maximum concentration of solute atoms that may dissolve in the solvent to form a solid solution; this is called a solubility limit. • The addition of solute in excess of this solubility limit results in the formation of another solid solution or compound that has a distinctly different composition.
  • 4. Solid solutions Substitutional Solid Solution Ordered Substitutional Solid Solution Disordered Substitutional Solid Solution Interstitial Solid Solution
  • 5. Prof. Naman M. Dave Equilibrium Phase Diagram • Important information, useful in materials development and selection, obtainable from a phase diagram. • It shows phases present at different compositions and temperatures under slow cooling (equilibrium) conditions. • It indicates equilibrium solid solubility of one element / compound in another. • It suggests temperature at which an alloy starts to solidify and the range of solidification. • It signals the temperature at which different phases start to melt. • Amount of each phase in a two-phase mixture can be obtained
  • 7. COOLING CURVE FOR PURE METAL OR COMPOUND
  • 8. COOLING CURVE FOR BINARY SOLID SOLUTIONS.
  • 9.
  • 10.
  • 11. BINARY EUTECTIC COOLING CURVE Cadmium (Cd) + Bismuth (Bi)
  • 12.
  • 13. Cadmium (Cd) + Bismuth (Bi) Binary Eutectic diagram 140 C
  • 14. Lead (Pb) + Tin (Sn) Eutectic phase diagram
  • 15. Summery of Binary Eutectic Phase diagrams 1 2 3
  • 16. Types of reactions in binary phase diagrams
  • 17. Thank You for learning patiently. Now you will 100% understand the “Iron – iron carbide” phase diagram easily in my next presentation. My email :- bnbiswal@rediffmail.com