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SERVICES and PRODUCTS
„WE MAKE NANOFIBERS“
PARDAM – what do we do??
CENTRIFUGAL SPINNINGELECTROSPINNING
PRODUCTION DEVELOPMENT OTHER SERVICES
SOLUTION SPINNING
R&D
&
O N L Y small production
of ~ 100nm fibers
CUSTOM MADE - INORGANIC NANOFIBERS
CUSTOM MADE - POLYMERIC NANOFIBERS
CONTRACTUAL
PRODUCTION
PRODUCTS &
APPLICATIONS
XRD
SEM
BET
RESEARCH STUDIES
SOLUTION
SPINNING
Fibers ~ 400-800nm
MELT
SPINNING
Fibers ~ 400-800nm
TECHNOLOGY
Inorganic nanofibers (POWDER like materials / COTTON like materials NEW)
Inorganic nanofibers are special function materials in the form of thin fibers, which posses very high
accessibility of its surface enhanced many times by the inner porosity of fiber material.
Its benefit in batteries, catalyst, abrasives or composite material is ultra-high surface accessible for gas,
liquid or solid material.
The benefit over nanoparticles is that nanoparticles are not porous, they have different morphology so they
can settle down and do not allow the medium to contact with the surface and they are very difficult to fix in
defined place.
NEW COTTON LIKE structure enable better handling and utilization for many applications over
POWDERS
▪ Li-ion batteries anode or cathode,
▪ Li-ion battery/Fuel cell separator,
▪ Catalyst, Catalyst support,
▪ Photo catalyst, Gas sensors,
▪ Thermal insulators,
▪ Metal or Ceramics nano-composites,
▪ Dehumidifiers,
▪ Abrasives,
▪ Thermal barrier coatings,
▪ Filtration etc.
NnF CERAM®
Polymer nanofibers (MEMBRANES / COTTON like structures NEW)
Fibrous materials with submicron dimensions can be made as membranes deposited on a supporting
substrate or as self standing membranes or in the form of 3D-Cotton like structure. For its unique
properties polymeric nanofibers can be used for separation/sorption/decontamination or any other
materials. Pardam has developed unique technology for lamination of the membranes into sandwich too.
PUR, PA6, PVB, PVA, PAN, PVDF, PCL, PET, composite PA6/PUR
Modification
- doping with nanoparticles and other functional substances
Filtration
Air, water, wastewater, other liquids and gasses..
Submicron fiber thickness allows much thinner pores of filter
with ultra high flux of filtered media
The ultra–high fiber surface allows to capture very small particles
as well as bacteria. The structure of nonwoven polymer nanofiber layer
is very breathable resulting of very high permeability of membrane.
Function textiles
Main effect is the non-liquid permeability consequently with
very high breathability for air and vapor.
Medicine
The main issue for wound dressing and tissue scaffold is the softness
of nanofibers with the combination of breathability and bacteria barrier.
Industrial production of Inorganic nanofibers – powders and cotton like structures
TiO2, SiO2, ZrO2, CeZrO2, WO3, LTO,
BTO, SBTO, Al2O3, CeO2, …
Industrial production of Polymer nanofibers - membranes and cotton like structures
PA6, PUR, PVB, PCL, PAN, PVDF, PVA, special polymers…
SERVICES _ Production _ Centrifugal Spinning Technology
We are partners in 7FP program
| MATFLEXEND – developing nanofibrous materials for ANODE of Li-Ion batteries
and
piezoelectric cells
Partners: Fraunhofer Berlin, VARTA, …
Czech government R&D project – ALFA
| SiO2 nanofibrous sorbent
Partner: University Pardubice
Developing new applications
| Li-ion battery separators
| Water purification filters
| Biomedical products
……………..
WE CAN BE YOUR PARTNER IN YOUR PROJECT
Developing new nanofibrous materials from novel precursors or polymers
SERVICES _ R&D _ materials / applications / products
SURE WE CAN MAKE IT!!
NANOFIBROUS APPLICATIONS AND PRODUCTS DEVELOPED BY PARDAM
4 PATENT PENDING APPLICATIONS
• 2014 - Inorganic nanofibers for catalytic reactions
• 2015 – Inorganic nanofiber for peptide analyses
• 2015 – Electrically conductive nanofibrous membrane
• 2015 – SiO2 nanofibrous sorbent
4 COMMERCIAL PRODUCTS in 2015
• NnF MBRANE - PET nanofibrous sandwich membrane for swimming pool water purification
• NnF MBRANE – PA6 nanofibrous sandwich membrane for food products purification
• NnF CERAM - SiO2 novel ceramic Li-Ion battery separator
• NnF CERAM - ZrO2 new analytical tips for peptide analyses
| LTO nanofibers
| TiN nanofibers
| LTO nanofibers - modified with TiN surface (conducive)
| BTO and SBTO nanofibers
| Hybrid polymer nanofibers PVDF/PUR/PA6 with BTO nanofibers incorporated
| Dielectric PVDF nanofibrous membranes
| Material analyses SEM/BET/XRD/XPS
New flexible, durable and solution-processable ink materials
for energy harvesting integrating mechanical-to-electrical
energy conversion and storage in single device
FP7 project co-funded by EC
| Development of new solutions based on TEOS precursor.
| Optimization of centrifugal force spinning process for mass production.
| Optimization of calcination process to obtain very high specific surface area (up to
1000m2/g)
| Patent application PS4039CZ
Production technique of advanced nanostructured SiO2 nanofibers
Technology Agency of the Czech Republic project nr. TA04011557
NnF CERAM for CERAMIC SEPARATOR FOR 3D LI-ION BATTERY
Unique and patented solution of the ceramic separator for 3D Li-Ion battery
Partner: HE3DA
SAFETY - stable up to 500°C
WETTABILITY
Better saturation with electrolyte improves ionic conductivity between
electrodes
ROBUST CONSTRUCTION
Ceramic separators do not allow dendrites growing and prevent
shortage creation inside accumulators
STABILITY – ceramic separators keep its structure and shape
CONSTANT DIMENSIONS
Thanks to nanofibrous materials – specific surface of the separators
is in hundreds of m2/g hence constant dimensions of the material in
the volume of the separator is reached
LOWER FARADAY LOSESS
Nanofibrous structure enables faster diffusion of Lithium Ions through
separator which decreases faraday loses in the accumulator
3 Working prototypes 1kW Li-ion battery
were introduced in 2015
NnF CERAM for SELECTIVE AND EFFICIENT ENRICHMENT OF PHOSPHOPEPTIDES
Partner: Institute of Analytical Chemistry, Brno, Czech Republic
• Columns packed with nanofibers show significantly higher
permeability in comparison to the particle packed column
• Efficient enrichment of single and multiphosphorylated peptide
from tryptic digests achieved
• Fabrication of new types of nanofibers such as SnO2, Ga2O3
and HfO2 in progress
• Further evaluation of the nanofibers materials by “real”
proteomic samples needed - collaborators welcomed
phosphorylated peptides
non-phosphorylated peptides
1000 1500 2000 2500 3000 3500
Mass (m/z)
307.8
0
10
20
30
40
50
60
70
80
90
100
%Intensity
4700 Reflector Spec #1 MC[BP = 3468.7,308]
*
*
NnF MBRANE for SWIMMING POOL WATER PURIFICATION
New generation of Nanofiber swimming pool filters available on the market in April 2016
PARDAM in cooperation with LEITAT and SACOPA developed and successfully up scaled
the production of nanofibrous materials for this unique product (see video)
More information on our
Materials, Services and Products
can be found at our web
www.pardam.cz
Please feel free to contact us
for farther information
because
WE MAKE NANOFIBERS!
Production Facility:
Žižkova 2494
413 01 Roudnice nad Labem
Czech Republic
Head Office:
Jahnova 8
530 02 Pardubice
Czech Republic
info@pardam.cz
production@pardam.cz

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PARDAM 2016 PRODUCTS AND SERVICES

  • 1. SERVICES and PRODUCTS „WE MAKE NANOFIBERS“
  • 2. PARDAM – what do we do?? CENTRIFUGAL SPINNINGELECTROSPINNING PRODUCTION DEVELOPMENT OTHER SERVICES SOLUTION SPINNING R&D & O N L Y small production of ~ 100nm fibers CUSTOM MADE - INORGANIC NANOFIBERS CUSTOM MADE - POLYMERIC NANOFIBERS CONTRACTUAL PRODUCTION PRODUCTS & APPLICATIONS XRD SEM BET RESEARCH STUDIES SOLUTION SPINNING Fibers ~ 400-800nm MELT SPINNING Fibers ~ 400-800nm TECHNOLOGY
  • 3. Inorganic nanofibers (POWDER like materials / COTTON like materials NEW) Inorganic nanofibers are special function materials in the form of thin fibers, which posses very high accessibility of its surface enhanced many times by the inner porosity of fiber material. Its benefit in batteries, catalyst, abrasives or composite material is ultra-high surface accessible for gas, liquid or solid material. The benefit over nanoparticles is that nanoparticles are not porous, they have different morphology so they can settle down and do not allow the medium to contact with the surface and they are very difficult to fix in defined place. NEW COTTON LIKE structure enable better handling and utilization for many applications over POWDERS ▪ Li-ion batteries anode or cathode, ▪ Li-ion battery/Fuel cell separator, ▪ Catalyst, Catalyst support, ▪ Photo catalyst, Gas sensors, ▪ Thermal insulators, ▪ Metal or Ceramics nano-composites, ▪ Dehumidifiers, ▪ Abrasives, ▪ Thermal barrier coatings, ▪ Filtration etc. NnF CERAM®
  • 4. Polymer nanofibers (MEMBRANES / COTTON like structures NEW) Fibrous materials with submicron dimensions can be made as membranes deposited on a supporting substrate or as self standing membranes or in the form of 3D-Cotton like structure. For its unique properties polymeric nanofibers can be used for separation/sorption/decontamination or any other materials. Pardam has developed unique technology for lamination of the membranes into sandwich too. PUR, PA6, PVB, PVA, PAN, PVDF, PCL, PET, composite PA6/PUR Modification - doping with nanoparticles and other functional substances Filtration Air, water, wastewater, other liquids and gasses.. Submicron fiber thickness allows much thinner pores of filter with ultra high flux of filtered media The ultra–high fiber surface allows to capture very small particles as well as bacteria. The structure of nonwoven polymer nanofiber layer is very breathable resulting of very high permeability of membrane. Function textiles Main effect is the non-liquid permeability consequently with very high breathability for air and vapor. Medicine The main issue for wound dressing and tissue scaffold is the softness of nanofibers with the combination of breathability and bacteria barrier.
  • 5. Industrial production of Inorganic nanofibers – powders and cotton like structures TiO2, SiO2, ZrO2, CeZrO2, WO3, LTO, BTO, SBTO, Al2O3, CeO2, … Industrial production of Polymer nanofibers - membranes and cotton like structures PA6, PUR, PVB, PCL, PAN, PVDF, PVA, special polymers… SERVICES _ Production _ Centrifugal Spinning Technology
  • 6. We are partners in 7FP program | MATFLEXEND – developing nanofibrous materials for ANODE of Li-Ion batteries and piezoelectric cells Partners: Fraunhofer Berlin, VARTA, … Czech government R&D project – ALFA | SiO2 nanofibrous sorbent Partner: University Pardubice Developing new applications | Li-ion battery separators | Water purification filters | Biomedical products …………….. WE CAN BE YOUR PARTNER IN YOUR PROJECT Developing new nanofibrous materials from novel precursors or polymers SERVICES _ R&D _ materials / applications / products
  • 7. SURE WE CAN MAKE IT!! NANOFIBROUS APPLICATIONS AND PRODUCTS DEVELOPED BY PARDAM 4 PATENT PENDING APPLICATIONS • 2014 - Inorganic nanofibers for catalytic reactions • 2015 – Inorganic nanofiber for peptide analyses • 2015 – Electrically conductive nanofibrous membrane • 2015 – SiO2 nanofibrous sorbent 4 COMMERCIAL PRODUCTS in 2015 • NnF MBRANE - PET nanofibrous sandwich membrane for swimming pool water purification • NnF MBRANE – PA6 nanofibrous sandwich membrane for food products purification • NnF CERAM - SiO2 novel ceramic Li-Ion battery separator • NnF CERAM - ZrO2 new analytical tips for peptide analyses
  • 8. | LTO nanofibers | TiN nanofibers | LTO nanofibers - modified with TiN surface (conducive) | BTO and SBTO nanofibers | Hybrid polymer nanofibers PVDF/PUR/PA6 with BTO nanofibers incorporated | Dielectric PVDF nanofibrous membranes | Material analyses SEM/BET/XRD/XPS New flexible, durable and solution-processable ink materials for energy harvesting integrating mechanical-to-electrical energy conversion and storage in single device FP7 project co-funded by EC
  • 9. | Development of new solutions based on TEOS precursor. | Optimization of centrifugal force spinning process for mass production. | Optimization of calcination process to obtain very high specific surface area (up to 1000m2/g) | Patent application PS4039CZ Production technique of advanced nanostructured SiO2 nanofibers Technology Agency of the Czech Republic project nr. TA04011557
  • 10. NnF CERAM for CERAMIC SEPARATOR FOR 3D LI-ION BATTERY Unique and patented solution of the ceramic separator for 3D Li-Ion battery Partner: HE3DA SAFETY - stable up to 500°C WETTABILITY Better saturation with electrolyte improves ionic conductivity between electrodes ROBUST CONSTRUCTION Ceramic separators do not allow dendrites growing and prevent shortage creation inside accumulators STABILITY – ceramic separators keep its structure and shape CONSTANT DIMENSIONS Thanks to nanofibrous materials – specific surface of the separators is in hundreds of m2/g hence constant dimensions of the material in the volume of the separator is reached LOWER FARADAY LOSESS Nanofibrous structure enables faster diffusion of Lithium Ions through separator which decreases faraday loses in the accumulator 3 Working prototypes 1kW Li-ion battery were introduced in 2015
  • 11. NnF CERAM for SELECTIVE AND EFFICIENT ENRICHMENT OF PHOSPHOPEPTIDES Partner: Institute of Analytical Chemistry, Brno, Czech Republic • Columns packed with nanofibers show significantly higher permeability in comparison to the particle packed column • Efficient enrichment of single and multiphosphorylated peptide from tryptic digests achieved • Fabrication of new types of nanofibers such as SnO2, Ga2O3 and HfO2 in progress • Further evaluation of the nanofibers materials by “real” proteomic samples needed - collaborators welcomed phosphorylated peptides non-phosphorylated peptides 1000 1500 2000 2500 3000 3500 Mass (m/z) 307.8 0 10 20 30 40 50 60 70 80 90 100 %Intensity 4700 Reflector Spec #1 MC[BP = 3468.7,308] * *
  • 12. NnF MBRANE for SWIMMING POOL WATER PURIFICATION New generation of Nanofiber swimming pool filters available on the market in April 2016 PARDAM in cooperation with LEITAT and SACOPA developed and successfully up scaled the production of nanofibrous materials for this unique product (see video)
  • 13. More information on our Materials, Services and Products can be found at our web www.pardam.cz Please feel free to contact us for farther information because WE MAKE NANOFIBERS! Production Facility: Žižkova 2494 413 01 Roudnice nad Labem Czech Republic Head Office: Jahnova 8 530 02 Pardubice Czech Republic info@pardam.cz production@pardam.cz