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Nuclear Radiation
Radioactivity
 This is the process by which unstable isotopes
emit material.
 The instability in the atom is the result of an
unstable nucleus trying to become more stable.
 A radioisotope is defines as the nuclei of an
unstable isotope
 Example: C-14 radioactive dating process
Radiation
Is defined as the material and/ or energy that
are emitted from an unstable isotope.
Examples:
Alpha – this is a Helium ion He 4
2a
Beta – changes a neutron into a proton or a
proton into a neutron. 0
-1b
Gamma – is not a particle – it is energy (ray)
0
0g
Energy
In terms of the energy associated with each
type of radiation:
Increasing energy
a b g
Good news…………………………Bad news
Penetrating Ability
Depending upon its energy, different types of radiation
are stopped by different materials
a b g
Good News………………………Bad news
Radioactive Decay
The next step in the process of
becoming more stable
Nuclear Chemistry deals with the nuclei of
atoms breaking apart. Atoms are continually
undergoing decay. When studying nuclear
chemistry, there is a typical format used to
represent specific isotopes.
Copyright © Cengage Learning. All rights reserved 7
The nuclear reactions that we will cover in chemistry class
can be categorized as either an emission reaction or a
bombardment reaction.
Emission reactions: These are decay
reactions, in which an unstable isotope
decays into another element/isotope and
releases a particle. The particles we will
covering include:
 4
2a Alpha particle – helium nucleus
 0
-1b Beta particle – electron
 0
0g Gamma emission
1
1p Proton
1
0n Neutron
Copyright © Cengage Learning. All rights reserved 8
Copyright © Cengage Learning. All rights reserved 9
First type of Radioactive Decay –
Alpha Particle Production
 Alpha particle – helium nucleus
 Examples
 Net effect is loss of 4 in mass number and
loss of 2 in atomic number.
Where A is the parent isotope (the atom being
broken apart) B is the daughter isotope or the
isotope formed.
When an element is broken down in alpha decay it
loses two neutrons and two (2) protons. This means
that the name of the element will change as well,
moving back two (2) places on the periodic table.
Copyright © Cengage Learning. All rights reserved 10
Nuclear equations are typically written in the
format shown below.
Alpha decay follows the form:
Copyright © Cengage Learning. All rights reserved 11
Alpha decay is not very penetrating
because the He atoms capture electrons
before traveling very far. However it is very
damaging because the alpha particles can
knock atoms off of molecules.
Alpha decay is the most common in
elements with an atomic number greater
than 83.
Copyright © Cengage Learning. All rights reserved 13
Second type of Radioactive Decay –
Beta Particle Production
 Beta particle – electron
 Examples
 Net effect is to change a neutron to a
proton.
Beta negative decay
follows the form:
The beta emission
increases the atomic
number by one (1) by
adding one (1) proton. At
the same time, one (1)
neutron is lost so the mass
of the daughter isotope is
the same as the parent
isotope.
Copyright © Cengage Learning. All rights reserved 14
 Beta negative decay is more penetrating than
alpha decay because the particles are smaller,
but less penetrating than gamma decay.
 Beta electrons can penetrate through about one
(1) cm of flesh before they are brought to a halt
because of electrostatic forces.
 Beta decay is most common in elements with a
high neutron to proton ratio.
Gamma emission

Am
Z A 0
0g + A
Z B

(Isotopes are moving from an excited state
(m) to ground state)
Copyright © Cengage Learning. All rights reserved 16
Third type of Radioactive Decay –
Gamma Production
Gamma decay follows the form:
 In gamma emission, neither the atomic number or the
mass number is changed. A high energy gamma ray
is given off when the parent isotope falls into a lower
energy state.
 Gamma radiation is the most penetrating of all. These
photons can pass through the body and cause
damage by ionizing all the molecules in their way
Copyright © Cengage Learning. All rights reserved 17
Copyright © Cengage Learning. All rights reserved 18
Fourth type of Radioactive Decay –
Positron Production
 Positron – particle with same mass
as an electron but with a positive
charge
 Example
 Net effect is to change a proton to a
neutron.
Positron emission (also called Beta
positive decay) follows the form:
Copyright © Cengage Learning. All rights reserved 19
 In this reaction a positron is emitted.
 A positron is exactly like an electron in mass and
charge force except with a positive charge.
 It is formed when a proton breaks into a neutron with
mass and no charge and this positron with no mass
and the positive charge.
 Positron emission is most common in lighter
elements with a low neutron to proton ratio.
20
Fifth type of Radioactive Decay –
Electron Capture
 Process in which one of the inner-
orbital electrons is captured by the
nucleus.
Electron capture follows the form:
21
In this reaction a nucleus captures one (1) of
its own atom's inner shell electrons which
reduces the atomic number by one.
This captured electron joins with a proton in
the nucleus to form a neutron.
Electron capture is common in larger
elements with a low neutron to proton ratio.
Transuranium Elements
 Elements with atomic numbers greater
than 92 which have been synthesized.
Bombardment reactions
These are reactions that result from the
addition of a particle to an isotope, which
results in the formation of a new
element/isotope and occasionally another
particle. Isotopes can be bombarded with
any of the following particles:
 4
2a 0
-1b 0
0g 1
1p 1
0n
23
Bombardment reactions
 Alpha bombardment
 A
Z X + 4
2a A+4
Z+2 Y
 Beta bombardment
 A
Z X + 0
-1b A
Z-1 Y
 Gamma bombardment
 A
Z X + 0
0g Am
Z X
 Proton bombardment
 A
Z X + 1
1p A+1
Z+1 Y
 Neutron bombardment
 A
Z X + 1
0n A+1
Z X
24
25
Concept Check Transformation
If the bombardment of Am-243 with alpha
particles leads to the emission of a neutron, which
nuclide is formed in this nuclear transformation
process?
247
97
247
96
248
96
246
97
a) Bk
b) Cm
c) Cm
d) Bk The correct answer is d. Since a neutron is
emitted, the mass number goes up by 3
(not 4) and the atomic number goes up by
2 (from 95 to 97).

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Nuclear PP.ppt

  • 2. Radioactivity  This is the process by which unstable isotopes emit material.  The instability in the atom is the result of an unstable nucleus trying to become more stable.  A radioisotope is defines as the nuclei of an unstable isotope  Example: C-14 radioactive dating process
  • 3. Radiation Is defined as the material and/ or energy that are emitted from an unstable isotope. Examples: Alpha – this is a Helium ion He 4 2a Beta – changes a neutron into a proton or a proton into a neutron. 0 -1b Gamma – is not a particle – it is energy (ray) 0 0g
  • 4. Energy In terms of the energy associated with each type of radiation: Increasing energy a b g Good news…………………………Bad news
  • 5. Penetrating Ability Depending upon its energy, different types of radiation are stopped by different materials a b g Good News………………………Bad news
  • 6. Radioactive Decay The next step in the process of becoming more stable
  • 7. Nuclear Chemistry deals with the nuclei of atoms breaking apart. Atoms are continually undergoing decay. When studying nuclear chemistry, there is a typical format used to represent specific isotopes. Copyright © Cengage Learning. All rights reserved 7
  • 8. The nuclear reactions that we will cover in chemistry class can be categorized as either an emission reaction or a bombardment reaction. Emission reactions: These are decay reactions, in which an unstable isotope decays into another element/isotope and releases a particle. The particles we will covering include:  4 2a Alpha particle – helium nucleus  0 -1b Beta particle – electron  0 0g Gamma emission 1 1p Proton 1 0n Neutron Copyright © Cengage Learning. All rights reserved 8
  • 9. Copyright © Cengage Learning. All rights reserved 9 First type of Radioactive Decay – Alpha Particle Production  Alpha particle – helium nucleus  Examples  Net effect is loss of 4 in mass number and loss of 2 in atomic number.
  • 10. Where A is the parent isotope (the atom being broken apart) B is the daughter isotope or the isotope formed. When an element is broken down in alpha decay it loses two neutrons and two (2) protons. This means that the name of the element will change as well, moving back two (2) places on the periodic table. Copyright © Cengage Learning. All rights reserved 10
  • 11. Nuclear equations are typically written in the format shown below. Alpha decay follows the form: Copyright © Cengage Learning. All rights reserved 11
  • 12. Alpha decay is not very penetrating because the He atoms capture electrons before traveling very far. However it is very damaging because the alpha particles can knock atoms off of molecules. Alpha decay is the most common in elements with an atomic number greater than 83.
  • 13. Copyright © Cengage Learning. All rights reserved 13 Second type of Radioactive Decay – Beta Particle Production  Beta particle – electron  Examples  Net effect is to change a neutron to a proton.
  • 14. Beta negative decay follows the form: The beta emission increases the atomic number by one (1) by adding one (1) proton. At the same time, one (1) neutron is lost so the mass of the daughter isotope is the same as the parent isotope. Copyright © Cengage Learning. All rights reserved 14
  • 15.  Beta negative decay is more penetrating than alpha decay because the particles are smaller, but less penetrating than gamma decay.  Beta electrons can penetrate through about one (1) cm of flesh before they are brought to a halt because of electrostatic forces.  Beta decay is most common in elements with a high neutron to proton ratio.
  • 16. Gamma emission  Am Z A 0 0g + A Z B  (Isotopes are moving from an excited state (m) to ground state) Copyright © Cengage Learning. All rights reserved 16 Third type of Radioactive Decay – Gamma Production
  • 17. Gamma decay follows the form:  In gamma emission, neither the atomic number or the mass number is changed. A high energy gamma ray is given off when the parent isotope falls into a lower energy state.  Gamma radiation is the most penetrating of all. These photons can pass through the body and cause damage by ionizing all the molecules in their way Copyright © Cengage Learning. All rights reserved 17
  • 18. Copyright © Cengage Learning. All rights reserved 18 Fourth type of Radioactive Decay – Positron Production  Positron – particle with same mass as an electron but with a positive charge  Example  Net effect is to change a proton to a neutron.
  • 19. Positron emission (also called Beta positive decay) follows the form: Copyright © Cengage Learning. All rights reserved 19  In this reaction a positron is emitted.  A positron is exactly like an electron in mass and charge force except with a positive charge.  It is formed when a proton breaks into a neutron with mass and no charge and this positron with no mass and the positive charge.  Positron emission is most common in lighter elements with a low neutron to proton ratio.
  • 20. 20 Fifth type of Radioactive Decay – Electron Capture  Process in which one of the inner- orbital electrons is captured by the nucleus.
  • 21. Electron capture follows the form: 21 In this reaction a nucleus captures one (1) of its own atom's inner shell electrons which reduces the atomic number by one. This captured electron joins with a proton in the nucleus to form a neutron. Electron capture is common in larger elements with a low neutron to proton ratio.
  • 22. Transuranium Elements  Elements with atomic numbers greater than 92 which have been synthesized.
  • 23. Bombardment reactions These are reactions that result from the addition of a particle to an isotope, which results in the formation of a new element/isotope and occasionally another particle. Isotopes can be bombarded with any of the following particles:  4 2a 0 -1b 0 0g 1 1p 1 0n 23
  • 24. Bombardment reactions  Alpha bombardment  A Z X + 4 2a A+4 Z+2 Y  Beta bombardment  A Z X + 0 -1b A Z-1 Y  Gamma bombardment  A Z X + 0 0g Am Z X  Proton bombardment  A Z X + 1 1p A+1 Z+1 Y  Neutron bombardment  A Z X + 1 0n A+1 Z X 24
  • 25. 25 Concept Check Transformation If the bombardment of Am-243 with alpha particles leads to the emission of a neutron, which nuclide is formed in this nuclear transformation process? 247 97 247 96 248 96 246 97 a) Bk b) Cm c) Cm d) Bk The correct answer is d. Since a neutron is emitted, the mass number goes up by 3 (not 4) and the atomic number goes up by 2 (from 95 to 97).