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Chillers Data Centers Hospitals Water Efficiency and You
The Data on Water 
• 
As data centers get larger, they are getting thirstier as well. The enormous volume of water required to cool high-density cloud computing server farms is making water management a growing priority for data center operators. A 15-megawatt data center can use up to 360,000 gallons of water a day, according to James Hamilton, a data center designer and researcher at Amazon.com.
The Data on Water 
• 
Hospitals on average use 136,000 gallons of water / year / bed for cooling
Chiller Facts 
This article has been published in Maintenance Technology and Hotel Engineer Magazines. 
• 
Chillers are the single largest energy-using component in most facilities, and can typically consume over 50% of the electrical usage. 
• 
Chillers use approximately 20% of the total electrical power generated in North America 
• 
U.S. Department of Energy estimates that chillers expend up to 30% in additional energy through inefficiency. 
• 
With over 100,000 chillers in the United States alone, inefficiency costs industry billions of dollars in energy annually. 
• 
Chillers running inefficiently also result in decreased equipment reliability, increased maintenance intervals and shortened lifespan. The slightest decrease in chiller performance can have a major impact on efficiency. 
• 
For instance, every 1°F increase in condenser water temperature above full load design can decrease chiller efficiency by 1% to 2%. 
• 
A failing or neglected water treatment program can reduce efficiency 10% to 35% or more in extreme cases.
Cities That Could Run Out of H2 
1. 
San Antonio 
2. 
Miami 
3. 
Lincoln NE 
4. 
San Jose 
5. 
San Diego 
6. 
LA /Long Beach/Santa Anna 
7. 
Salt Lake 
8. 
Riverside 
9. 
Mission Viejo 
10. 
El Paso
Measuring 
• 
The metric for water usage in the data center is defined at a high level as Water Usage Effectiveness or WUE 
Annual Water Usage 
IT Equipment Energy 
•The units of WUE are liters/kilowatt-hour (L/kWh). 
•IT Equipment Energy. This includes the load associated with all of the IT equipment, including computer, storage, and network equipment, along with supplemental equipment such as KVM switches, monitors, and workstations/laptops used to monitor or otherwise control the data center 
•“We think that 0.22 L/kWh is a great result, but it should be noted that the WUE concept is fairly new and, to our knowledge, no one else has publicly reported WUE yet,” writes Facebook’s Daniel Lee. “
Definitions 
• 
1 ppm 
– 
1 Lb. of something / 1,000,000 Lbs. of something 
– 
Ex 1 pounds antiscale / 1,000,000 Lbs water 
– 
10 pounds antiscale / 1,000,000 Lbs water 
– 
Our Dose of antiscale 
• 
100 – 200 pounds antiscale / 1,000,000 Lbs water 
• 
10 – 20 / 100,000 
• 
1 - 2/ 10,000 
• 
2 – 4 / 20,000 Find 2 guys at an average a’s game 
• 
Q or Heat Flux = BTU / Sq. Ft. / Hr 
• 
1 Tn Refrigeration = 12,000 BTU / Hr rejected 
• 
Cycles = How many times a feed water is concentrated up 
• 
Bleed = water removed from the system to control cycles
Definitions 
• 
Heat exchangers were initially developed to use plain (or smooth) heat transfer surfaces. 
– 
An Enhanced heat transfer surface has a special surface geometry that provides a higher thermal performance, per unit base surface area than a plain surface. 
Internal Enhancement 
External Enhancement
Chillers 
• 
What is a Chiller? 
– 
A chiller is a water-cooled air conditioning system that cools inside air, creating a more comfortable and productive environment. 
– 
Chillers are also used in the manufacturing environment to provide "process" cooling to equipment in an effort to maximize productivity. 
• 
With large facilities, such as commercial buildings, hospitals, universities, government facilities and theme parks, the cost of energy to generate cooling in excess of 50 tons is cost prohibitive with air-cooled units. 
• 
Water-cooled chillers produce higher tonnage at lower costs per ton, creating greater energy efficiency. 
• 
Typical Home 
– 
has 3-5 tons of cooling capacity. 
• 
Typical Data Center 
– 
has 300 – 1000 + tns cooling 
– 
Older = smaller 
– 
Newer = larger 
• 
Typical Hospital 
– 
has 2 – 5 tns / bed
Chillers 
• 
How a Complete Chiller System Works 
– 
Chillers circulate chilled water to air-handlers in order to transfer heat from air to water. 
– 
This water then returns to the evaporator side of the chiller where the heat is passed from the water to a liquid refrigerant (freon). 
– 
The refrigerant leaves the evaporator as a cold vapor and enters the compressor where it is compressed into a hot vapor. 
– 
Upon leaving the compressor, the vapor enters the condenser side of the chiller where heat is transferred from the refrigerant to the water side of the condenser where it is circulated to an open cooling tower for the final removal of heat via evaporation in the cooling tower. 
Closed Chilled Water Loop 
Open Tower Water Loop 
Potential Fouling Points On Water Side
Fouling 
• 
240 ton chiller 
– 
Greg Bush Regional Services Lead for Americas 
• 
SAP GFM Data Center Services 
• 
Regional Energy Manager for Americas 
– 
In the case of SAP at $0.15 kWH 
– 
$5,600.00 a year in wasted electricity per degree approach fowling. This is a meter verified number. 
• 
Chiller in study has efficiency of .65 Kw per ton annualized. 
EPA statement said a 1000 ton chiller at $0.11 per kWH is $10,000.00 a year of wasted energy per degree fouling
Chiller Efficiency 
• 
Chiller efficiency is the amount of energy (electricity) it takes to produce a "ton" of cooling. It is expressed as kw/ton. 
– 
All chillers have a designed kw/ton efficiency that was established when the chiller was commissioned. 
– 
Plant design, water treatment, maintenance practices, chiller age, cooling tower design, cooling load and plant operations dramatically effect chiller operating efficiency and operating costs. 
•A chiller "operator" is known by several titles, including Stationary Engineer, HVAC Engineer and Service Technician. 
–Operation and maintenance includes collecting and logging data from various gauges, controls and meters located on or near the chiller. 
•There are essentially three types of maintenance performed on chillers; 
–Water chemistry is maintained to keep proper balance and minimize the effects of scale, corrosion and micro-biological / debris fouling. 
–Mechanical maintenance includes proper lubrication, adequate liquid refrigerant, oil levels and pump curve tests. 
–Operational procedures include eddy-current tests, oil analysis, calibration of gauges and meters and other various tests.
Improving Chiller Efficiency 
• 
The best way to provide precise data, obtain concrete results and minimize problems 
is to verify flow rates to the chiller for tonnage measurements and other 
calculations to determine efficiency. 
Four methods for determining flow are 
inline flow meter, external flow meter, delta pressure and delta temperature. 
• 
The use of delta temperature along with a flow meter or delta pressure gauge creates a powerful diagnostic tool that can detect problems affecting efficiency in the chiller system. 
• 
Increase the Chill Water Temperature and Lower the Entering Condenser Water Temperature For constant speed chillers, every 1°F increase in chill water temperature can increase chiller energy efficiency 1 to 2%. For variable speed chillers, every 1°F increase in chill water temperature can result in a 2 to 4% efficiency increase. 
• 
Take advantage of wet bulb conditions in the cooling tower system to lower the chiller's entering condenser water temperature. This can result in a 1 to 1.5% efficiency improvement for every 1°F below the chiller full load design.
Improving Chiller Efficiency 
• 
A good water treatment program is a necessity for efficiency. Maintaining the proper water treatment will prevent costly problems. 
– 
If a problem(s) already exists, take the necessary steps to correct it immediately. 
• 
Biocide and Scale/Corrosion Protection 
– 
A water treatment program provides a biocide program that minimizes microbiological growth along with excellent scale/corrosion protection. 
– 
Microbes, if not properly controlled, can cause numerous problems, such as forming sticky slime deposits in the tube bundle of a chiller, possibly reducing heat transfer efficiency 15% or more. 
– 
The situation can be compounded by the formation of permanent scale or iron deposits on the sticky site. If this occurs, an additional 10 to 20% loss in heat transfer efficiency may result.
Typical Problems Encountered 
• 
Tower Basin 
– 
Calcium deposits 
– 
Corrosion Tubercle 
• 
Tubercle removed 
• 
Under Deposit Corrosion 
• 
Corrosion Perforation 
– 
Under Deposit Corrosion
Pitting 
• 
All forms of corrosion, with the exception of some types of high- temperature corrosion, occur through the action of the electrochemical cell. 
• 
The elements that are common to all corrosion cells are: 
– 
An anode where oxidation and metal loss occur, 
– 
A cathode where reduction and protective effects occur, 
– 
Metallic and electrolytic ( system water ) paths between the anode and cathode through which electronic and ionic current flows, 
– 
A potential difference that drives the cell. 
• 
The driving potential may be the result of differences between the characteristics of dissimilar metals, surface conditions, and the environment, including chemical concentrations.
Pitting 
• 
Pitting corrosion is a localized form of corrosion by which cavities or "holes" are produced in the material. 
• 
Pitting is considered to be more dangerous than uniform corrosion damage because it is more difficult to detect, predict and design against. 
• 
Corrosion products often cover the pits. 
– 
A small, narrow pit with minimal overall metal loss can lead to the failure of an entire engineering system. 
– 
Pitting corrosion, which, for example, is almost a common denominator of all types of localized corrosion attack, may assume different shapes. 
• 
Pitting is initiated by: 
– 
Localized chemical or mechanical damage to the protective oxide film; water chemistry factors which can cause breakdown of a passive film are acidity, low dissolved oxygen concentrations (which tend to render a protective oxide film less stable) and high concentrations of chloride (as in seawater) 
– 
Localized damage to, or poor application of, a protective coating 
– 
The presence of non-uniformities in the metal structure of the component, e.g. nonmetallic inclusions. 
• 
Theoretically, a local cell that leads to the initiation of a pit can be caused by 
– 
an abnormal anodic site ( under a deposit ) surrounded by normal surface which acts as a cathode, 
– 
or by the presence of an abnormal cathodic site surrounded by a normal surface in which a pit will have disappeared due to corrosion.
Theory 
• 
Water Chemistry 
– 
Lack of proper water treatment chemistry allows deposits to occur 
– 
Ca, Mg, Fe 
– 
Deposits cause corrosion 
– 
Corrosion products cause more deposits / corrosion with out proper treatment
Observations 
• 
Corrosion 
• 
Corrosion Products 
• 
Corrosion products covered with scale 
• 
Scale is chips off and anode is formed 
• 
Small anode 
• 
Combined with large cathode 
•Pitting is expected
Alternatives 
• 
Do Nothing 
• 
Dolphin and or Magnets 
– 
Relies on Low Cycles 
• 
Wastes Water 
• 
Deposits 
• 
Corrosion 
• 
Softeners 
– 
Improper water chemistry results in corrosion 
• 
Other Water Treatment Companies 
– 
Low degree of monitoring 
– 
Disincentive to provide service
Traditional Water Treatment 
• 
Monitored 
– 
Conductivity 
– 
pH 
• 
Controlled 
– 
pH 
– 
Conductivity 
– 
Antiscale pump on and off
Dolphin 
• 
Controls nothing 
• 
Tower is bled to keep 
– 
Cycles Low 
– 
Water Use High 
• 
Essentially once through cooling
Softeners 
Softeners are not recommended for galvanized towers 
• 
Historically, maximum service life was obtained by maintaining the chemistry of the circulating water at an essentially neutral state (pH of 6.5 to 9.0) and allowing the natural formation of a protective, light crystalline film on the zinc surface which retarded the formation of white rust. 
• 
While there is still some disagreement on the actual cause of the recent increase in reported cases of "white rust", various water treatment experts are concluding that some of the newer, higher alkaline, treatment chemistries actually inhibit the formation of protective films on the galvanized surface and thus allow the development of white rust. 
• 
There are also indications that soft water (less than 30 ppm total hardness), when combined with these high pH conditions, can exacerbate the problem.
We Use Water More Effectively
Nereus On Line Chemistry 
• 
Conductivity 
– 
Controls cycles of concentration 
• 
pH 
– 
Controls alkalinity / LSI / Scale 
• 
ORP 
– 
Controls biocide feed 
– 
Biological control 
• 
Antiscalant 
– 
Controls scale 
• 
Ca 
• 
Si 
• 
Fe
Nereus On Line Meters 
• 
Make Up 
– 
Water Use and cost 
• 
Bleed 
– 
Sewer discharge and cost 
• 
Recirculation 
– 
Supply to Heat Exchangers 
• 
Temperature 
– 
Air Dry 
– 
Air Wet bulb 
– 
Heat exchanger supply water 
– 
Heat exchanger return water 
– 
Refrigerant condensing temperature 
• 
Chemical inventory levels 
• 
Chemical feed rate
Nereus Auxilary 
• 
Corrosion coupons 
– 
System metallurgy 
• 
Biological Testing 
– 
Total Aerobic Count 
– 
Sulfate Reducing Bacteria 
– 
Mold 
– 
Fungus
Nereus Calculations 
• 
Tower 
– 
Efficiency and efficiency vs design 
– 
Approach and approach vs design 
– 
Delta T and delta T vs design 
• 
Heat Exchanger 
– 
Approach and approach vs design 
– 
Heat Flux in BTU / Sq. Ft. / Hr. and Heat flux vs design 
– 
$ lost due to fouling 
• 
Today / this Month / YTD 
• 
Yr over Yr 
• 
Water 
– 
$ / Day, Month, Yr 
– 
$ vs budget Day / Month / Yr 
– 
Yr over Yr 
• 
Sewer 
– 
$ / Day, Month, Yr 
– 
$ vs budget Day / Month / Yr 
– 
Yr over Yr 
• 
Chemical 
– 
% Tank level 
– 
$ / Day, Month, Yr 
– 
$ vs budget Day / Month / Yr 
– 
Yr over Yr
Nereus Calculations 
• 
Refrigeration tns on line 
• 
Refrigeration as a % of design max 
• 
Cost / Tn of refrigeration for 
– 
Water actual / actual vs budget / Yr vs Yr 
– 
Sewer actual / actual vs budget / Yr vs Yr 
– 
Chemical actual / actual vs budget / Yr vs Yr 
– 
Power actual / actual vs budget / Yr vs Yr 
• 
Refrigeration Efficiency 
– 
Kw / Tn refrigeration actual / actual vs budget / Yr vs Yr
Nereus vs Old School
Cooling Inhibitor 1140 D ( Die Traced ) Contains 
– 
BZT 
• 
BZT is a corrosion inhibitor and/or yellow metal deactivator based on 1,2,3- benzotrizole. 
– 
BZT prevents corrosion of yellow metals such as copper, copper alloys, bronze, and other metals. 
– 
BZT inhibits the corrosion of steel, cast iron, cadmium and nickel alloys under certain conditions. 
– 
BZT reduces the corrosive influence of copper ions on various metals. 
– 
HEDP 
• 
HEDP is an organophosphoric acid corrosion / scale inhibitor. 
– 
HEDP can chelate with Fe, Cu, and Zn ions to form stable chelating compounds. 
– 
HEDP shows excellent scale and corrosion inhibition effects under temperature 250℃. 
– 
HEDP has good chemical stability under high pH value, hard to be hydrolyzed, and hard to be decomposed under ordinary light and heat conditions. 
– 
HEDP acid/alkali and chlorine oxidation tolerance are better than that of other organophosphoric acids (salt). 
– 
HEDP can react with metal ions in water systems to form hexa-element chelating complex, with calcium ion in particular. 
– 
PBTC 
• 
PBTC acts as a crystal modifying agent and threshold inhibitor for calcium and other metal salts. 
– 
PBTC is widely used in industry as a sequestering agent and calcium carbonate scale inhibitor. 
– 
In systems that utilize oxidizing microbiocides, such as bromine, PBTC exhibits superior stability under oxidizing conditions compared to other organophosphonate compounds. 
– 
Silica Control Polymer 
• 
ACUMER 5000 is a proprietary multifunctional polymer with a molecular weight of 5000 that provides outstanding silica and magnesium silicate scale inhibition. 
– 
ACUMER 5000 prevents silica-based scale formation by dispersing colloidal silica and by preventing magnesium silicate scale formation at heat transfer surfaces
Condensafe 100% safe acid replacement 
0 
0 
0 
Condensafe II
We Use Water More Effectively
Getting Started 
• 
No Cost to Client 
– 
Water Samples provided to SWS LLC 
• 
City & Tower 
– 
System Information 
• 
Cost 
– 
Water, Sewer, Power, Descaling 
– 
Tns total system design 
– 
% Load On Line 
» 
Fall, Winter, Spring, Summer 
» 
Days in each season 
• 
Output with in 2 weeks 
– 
Savings available, Cap Ex, Op Ex 
• 
Process guarantee 
– 
$ savings will be delivered 
– 
System will operate with less scale than is currently the case 
– 
System will operate with less corrosion than is currently the case 
– 
System will operate with less energy than is currently the case

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Nereus for cooling - Sustainable Water Solutions, LLC

  • 1. Chillers Data Centers Hospitals Water Efficiency and You
  • 2. The Data on Water • As data centers get larger, they are getting thirstier as well. The enormous volume of water required to cool high-density cloud computing server farms is making water management a growing priority for data center operators. A 15-megawatt data center can use up to 360,000 gallons of water a day, according to James Hamilton, a data center designer and researcher at Amazon.com.
  • 3. The Data on Water • Hospitals on average use 136,000 gallons of water / year / bed for cooling
  • 4. Chiller Facts This article has been published in Maintenance Technology and Hotel Engineer Magazines. • Chillers are the single largest energy-using component in most facilities, and can typically consume over 50% of the electrical usage. • Chillers use approximately 20% of the total electrical power generated in North America • U.S. Department of Energy estimates that chillers expend up to 30% in additional energy through inefficiency. • With over 100,000 chillers in the United States alone, inefficiency costs industry billions of dollars in energy annually. • Chillers running inefficiently also result in decreased equipment reliability, increased maintenance intervals and shortened lifespan. The slightest decrease in chiller performance can have a major impact on efficiency. • For instance, every 1°F increase in condenser water temperature above full load design can decrease chiller efficiency by 1% to 2%. • A failing or neglected water treatment program can reduce efficiency 10% to 35% or more in extreme cases.
  • 5. Cities That Could Run Out of H2 1. San Antonio 2. Miami 3. Lincoln NE 4. San Jose 5. San Diego 6. LA /Long Beach/Santa Anna 7. Salt Lake 8. Riverside 9. Mission Viejo 10. El Paso
  • 6. Measuring • The metric for water usage in the data center is defined at a high level as Water Usage Effectiveness or WUE Annual Water Usage IT Equipment Energy •The units of WUE are liters/kilowatt-hour (L/kWh). •IT Equipment Energy. This includes the load associated with all of the IT equipment, including computer, storage, and network equipment, along with supplemental equipment such as KVM switches, monitors, and workstations/laptops used to monitor or otherwise control the data center •“We think that 0.22 L/kWh is a great result, but it should be noted that the WUE concept is fairly new and, to our knowledge, no one else has publicly reported WUE yet,” writes Facebook’s Daniel Lee. “
  • 7. Definitions • 1 ppm – 1 Lb. of something / 1,000,000 Lbs. of something – Ex 1 pounds antiscale / 1,000,000 Lbs water – 10 pounds antiscale / 1,000,000 Lbs water – Our Dose of antiscale • 100 – 200 pounds antiscale / 1,000,000 Lbs water • 10 – 20 / 100,000 • 1 - 2/ 10,000 • 2 – 4 / 20,000 Find 2 guys at an average a’s game • Q or Heat Flux = BTU / Sq. Ft. / Hr • 1 Tn Refrigeration = 12,000 BTU / Hr rejected • Cycles = How many times a feed water is concentrated up • Bleed = water removed from the system to control cycles
  • 8. Definitions • Heat exchangers were initially developed to use plain (or smooth) heat transfer surfaces. – An Enhanced heat transfer surface has a special surface geometry that provides a higher thermal performance, per unit base surface area than a plain surface. Internal Enhancement External Enhancement
  • 9. Chillers • What is a Chiller? – A chiller is a water-cooled air conditioning system that cools inside air, creating a more comfortable and productive environment. – Chillers are also used in the manufacturing environment to provide "process" cooling to equipment in an effort to maximize productivity. • With large facilities, such as commercial buildings, hospitals, universities, government facilities and theme parks, the cost of energy to generate cooling in excess of 50 tons is cost prohibitive with air-cooled units. • Water-cooled chillers produce higher tonnage at lower costs per ton, creating greater energy efficiency. • Typical Home – has 3-5 tons of cooling capacity. • Typical Data Center – has 300 – 1000 + tns cooling – Older = smaller – Newer = larger • Typical Hospital – has 2 – 5 tns / bed
  • 10. Chillers • How a Complete Chiller System Works – Chillers circulate chilled water to air-handlers in order to transfer heat from air to water. – This water then returns to the evaporator side of the chiller where the heat is passed from the water to a liquid refrigerant (freon). – The refrigerant leaves the evaporator as a cold vapor and enters the compressor where it is compressed into a hot vapor. – Upon leaving the compressor, the vapor enters the condenser side of the chiller where heat is transferred from the refrigerant to the water side of the condenser where it is circulated to an open cooling tower for the final removal of heat via evaporation in the cooling tower. Closed Chilled Water Loop Open Tower Water Loop Potential Fouling Points On Water Side
  • 11. Fouling • 240 ton chiller – Greg Bush Regional Services Lead for Americas • SAP GFM Data Center Services • Regional Energy Manager for Americas – In the case of SAP at $0.15 kWH – $5,600.00 a year in wasted electricity per degree approach fowling. This is a meter verified number. • Chiller in study has efficiency of .65 Kw per ton annualized. EPA statement said a 1000 ton chiller at $0.11 per kWH is $10,000.00 a year of wasted energy per degree fouling
  • 12. Chiller Efficiency • Chiller efficiency is the amount of energy (electricity) it takes to produce a "ton" of cooling. It is expressed as kw/ton. – All chillers have a designed kw/ton efficiency that was established when the chiller was commissioned. – Plant design, water treatment, maintenance practices, chiller age, cooling tower design, cooling load and plant operations dramatically effect chiller operating efficiency and operating costs. •A chiller "operator" is known by several titles, including Stationary Engineer, HVAC Engineer and Service Technician. –Operation and maintenance includes collecting and logging data from various gauges, controls and meters located on or near the chiller. •There are essentially three types of maintenance performed on chillers; –Water chemistry is maintained to keep proper balance and minimize the effects of scale, corrosion and micro-biological / debris fouling. –Mechanical maintenance includes proper lubrication, adequate liquid refrigerant, oil levels and pump curve tests. –Operational procedures include eddy-current tests, oil analysis, calibration of gauges and meters and other various tests.
  • 13. Improving Chiller Efficiency • The best way to provide precise data, obtain concrete results and minimize problems is to verify flow rates to the chiller for tonnage measurements and other calculations to determine efficiency. Four methods for determining flow are inline flow meter, external flow meter, delta pressure and delta temperature. • The use of delta temperature along with a flow meter or delta pressure gauge creates a powerful diagnostic tool that can detect problems affecting efficiency in the chiller system. • Increase the Chill Water Temperature and Lower the Entering Condenser Water Temperature For constant speed chillers, every 1°F increase in chill water temperature can increase chiller energy efficiency 1 to 2%. For variable speed chillers, every 1°F increase in chill water temperature can result in a 2 to 4% efficiency increase. • Take advantage of wet bulb conditions in the cooling tower system to lower the chiller's entering condenser water temperature. This can result in a 1 to 1.5% efficiency improvement for every 1°F below the chiller full load design.
  • 14. Improving Chiller Efficiency • A good water treatment program is a necessity for efficiency. Maintaining the proper water treatment will prevent costly problems. – If a problem(s) already exists, take the necessary steps to correct it immediately. • Biocide and Scale/Corrosion Protection – A water treatment program provides a biocide program that minimizes microbiological growth along with excellent scale/corrosion protection. – Microbes, if not properly controlled, can cause numerous problems, such as forming sticky slime deposits in the tube bundle of a chiller, possibly reducing heat transfer efficiency 15% or more. – The situation can be compounded by the formation of permanent scale or iron deposits on the sticky site. If this occurs, an additional 10 to 20% loss in heat transfer efficiency may result.
  • 15. Typical Problems Encountered • Tower Basin – Calcium deposits – Corrosion Tubercle • Tubercle removed • Under Deposit Corrosion • Corrosion Perforation – Under Deposit Corrosion
  • 16. Pitting • All forms of corrosion, with the exception of some types of high- temperature corrosion, occur through the action of the electrochemical cell. • The elements that are common to all corrosion cells are: – An anode where oxidation and metal loss occur, – A cathode where reduction and protective effects occur, – Metallic and electrolytic ( system water ) paths between the anode and cathode through which electronic and ionic current flows, – A potential difference that drives the cell. • The driving potential may be the result of differences between the characteristics of dissimilar metals, surface conditions, and the environment, including chemical concentrations.
  • 17. Pitting • Pitting corrosion is a localized form of corrosion by which cavities or "holes" are produced in the material. • Pitting is considered to be more dangerous than uniform corrosion damage because it is more difficult to detect, predict and design against. • Corrosion products often cover the pits. – A small, narrow pit with minimal overall metal loss can lead to the failure of an entire engineering system. – Pitting corrosion, which, for example, is almost a common denominator of all types of localized corrosion attack, may assume different shapes. • Pitting is initiated by: – Localized chemical or mechanical damage to the protective oxide film; water chemistry factors which can cause breakdown of a passive film are acidity, low dissolved oxygen concentrations (which tend to render a protective oxide film less stable) and high concentrations of chloride (as in seawater) – Localized damage to, or poor application of, a protective coating – The presence of non-uniformities in the metal structure of the component, e.g. nonmetallic inclusions. • Theoretically, a local cell that leads to the initiation of a pit can be caused by – an abnormal anodic site ( under a deposit ) surrounded by normal surface which acts as a cathode, – or by the presence of an abnormal cathodic site surrounded by a normal surface in which a pit will have disappeared due to corrosion.
  • 18. Theory • Water Chemistry – Lack of proper water treatment chemistry allows deposits to occur – Ca, Mg, Fe – Deposits cause corrosion – Corrosion products cause more deposits / corrosion with out proper treatment
  • 19. Observations • Corrosion • Corrosion Products • Corrosion products covered with scale • Scale is chips off and anode is formed • Small anode • Combined with large cathode •Pitting is expected
  • 20. Alternatives • Do Nothing • Dolphin and or Magnets – Relies on Low Cycles • Wastes Water • Deposits • Corrosion • Softeners – Improper water chemistry results in corrosion • Other Water Treatment Companies – Low degree of monitoring – Disincentive to provide service
  • 21. Traditional Water Treatment • Monitored – Conductivity – pH • Controlled – pH – Conductivity – Antiscale pump on and off
  • 22. Dolphin • Controls nothing • Tower is bled to keep – Cycles Low – Water Use High • Essentially once through cooling
  • 23. Softeners Softeners are not recommended for galvanized towers • Historically, maximum service life was obtained by maintaining the chemistry of the circulating water at an essentially neutral state (pH of 6.5 to 9.0) and allowing the natural formation of a protective, light crystalline film on the zinc surface which retarded the formation of white rust. • While there is still some disagreement on the actual cause of the recent increase in reported cases of "white rust", various water treatment experts are concluding that some of the newer, higher alkaline, treatment chemistries actually inhibit the formation of protective films on the galvanized surface and thus allow the development of white rust. • There are also indications that soft water (less than 30 ppm total hardness), when combined with these high pH conditions, can exacerbate the problem.
  • 24. We Use Water More Effectively
  • 25.
  • 26. Nereus On Line Chemistry • Conductivity – Controls cycles of concentration • pH – Controls alkalinity / LSI / Scale • ORP – Controls biocide feed – Biological control • Antiscalant – Controls scale • Ca • Si • Fe
  • 27. Nereus On Line Meters • Make Up – Water Use and cost • Bleed – Sewer discharge and cost • Recirculation – Supply to Heat Exchangers • Temperature – Air Dry – Air Wet bulb – Heat exchanger supply water – Heat exchanger return water – Refrigerant condensing temperature • Chemical inventory levels • Chemical feed rate
  • 28. Nereus Auxilary • Corrosion coupons – System metallurgy • Biological Testing – Total Aerobic Count – Sulfate Reducing Bacteria – Mold – Fungus
  • 29. Nereus Calculations • Tower – Efficiency and efficiency vs design – Approach and approach vs design – Delta T and delta T vs design • Heat Exchanger – Approach and approach vs design – Heat Flux in BTU / Sq. Ft. / Hr. and Heat flux vs design – $ lost due to fouling • Today / this Month / YTD • Yr over Yr • Water – $ / Day, Month, Yr – $ vs budget Day / Month / Yr – Yr over Yr • Sewer – $ / Day, Month, Yr – $ vs budget Day / Month / Yr – Yr over Yr • Chemical – % Tank level – $ / Day, Month, Yr – $ vs budget Day / Month / Yr – Yr over Yr
  • 30. Nereus Calculations • Refrigeration tns on line • Refrigeration as a % of design max • Cost / Tn of refrigeration for – Water actual / actual vs budget / Yr vs Yr – Sewer actual / actual vs budget / Yr vs Yr – Chemical actual / actual vs budget / Yr vs Yr – Power actual / actual vs budget / Yr vs Yr • Refrigeration Efficiency – Kw / Tn refrigeration actual / actual vs budget / Yr vs Yr
  • 31. Nereus vs Old School
  • 32. Cooling Inhibitor 1140 D ( Die Traced ) Contains – BZT • BZT is a corrosion inhibitor and/or yellow metal deactivator based on 1,2,3- benzotrizole. – BZT prevents corrosion of yellow metals such as copper, copper alloys, bronze, and other metals. – BZT inhibits the corrosion of steel, cast iron, cadmium and nickel alloys under certain conditions. – BZT reduces the corrosive influence of copper ions on various metals. – HEDP • HEDP is an organophosphoric acid corrosion / scale inhibitor. – HEDP can chelate with Fe, Cu, and Zn ions to form stable chelating compounds. – HEDP shows excellent scale and corrosion inhibition effects under temperature 250℃. – HEDP has good chemical stability under high pH value, hard to be hydrolyzed, and hard to be decomposed under ordinary light and heat conditions. – HEDP acid/alkali and chlorine oxidation tolerance are better than that of other organophosphoric acids (salt). – HEDP can react with metal ions in water systems to form hexa-element chelating complex, with calcium ion in particular. – PBTC • PBTC acts as a crystal modifying agent and threshold inhibitor for calcium and other metal salts. – PBTC is widely used in industry as a sequestering agent and calcium carbonate scale inhibitor. – In systems that utilize oxidizing microbiocides, such as bromine, PBTC exhibits superior stability under oxidizing conditions compared to other organophosphonate compounds. – Silica Control Polymer • ACUMER 5000 is a proprietary multifunctional polymer with a molecular weight of 5000 that provides outstanding silica and magnesium silicate scale inhibition. – ACUMER 5000 prevents silica-based scale formation by dispersing colloidal silica and by preventing magnesium silicate scale formation at heat transfer surfaces
  • 33. Condensafe 100% safe acid replacement 0 0 0 Condensafe II
  • 34.
  • 35. We Use Water More Effectively
  • 36. Getting Started • No Cost to Client – Water Samples provided to SWS LLC • City & Tower – System Information • Cost – Water, Sewer, Power, Descaling – Tns total system design – % Load On Line » Fall, Winter, Spring, Summer » Days in each season • Output with in 2 weeks – Savings available, Cap Ex, Op Ex • Process guarantee – $ savings will be delivered – System will operate with less scale than is currently the case – System will operate with less corrosion than is currently the case – System will operate with less energy than is currently the case