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FINDINGS #19, JANUARY 2015
CATALYST-BASED NON-CHEMICAL
WATER TREATMENT
GSA Public Buildings Service
Catalyst-Based Device Reduces Calcite
Buildup, Requires Minimal Maintenance
According to the US Geological Survey, more than 85 percent
of the United States has hard water.1
In plumbing, hard water
leaves calcite deposits that restrict water flow by occluding
pipes. In water heaters, calcite coats heating elements, causing
them to overheat and eventually fail. Standard approaches to
calcite mitigation rely on chemicals, which must be replenished
frequently, or ultra-fine-membrane filtering, which uses large
amounts of water and energy. GSA’s Green Proving Ground
(GPG) program commissioned Oak Ridge National Laboratory
(ORNL) to assess the effectiveness of a catalytic insert that
alters the chemistry of hard water to prevent calcite buildup.
Researchers assessing the technology at the Frank E. Moss
Federal Court House in Salt Lake City, Utah, found that the
catalyst-based non-chemical water treatment (NCWT) system
dramatically reduced calcite buildup and had immediate payback
when compared to a chemical (salt-based) system. Payback at
other locations will depend on the ongoing remediation costs of
calcite buildup. Catalyst-based NCWT should be considered for
deployment in any heating system that is subject to calcification,
including hydronic heating systems and boilers, condensing
boilers, and gas and electric water heaters.
The Green Proving Ground program leverages GSA’s real estate portfolio to evaluate innovative
sustainable building technologies. The program aims to drive innovation in environmental performance
in federal buildings and help lead market transformation through deployment of new technologies.
Green Proving Ground Program www.gsa.gov/gpg gpg@gsa.gov 2
What is This Technology?
PIPE WITH HELICAL INSERT REDUCES CALCITE PLATING
The NCWT technology assessed in this measurement and verification (M&V)
process consists of a length of pipe containing a single fixed helical insert. The
insert is made from a proprietary catalytic alloy and is installed directly into the
system’s water delivery pipe. As water flows over the metallic alloy, calcium
and carbon form flushable crystals of the inert mineral aragonite rather than
calcite. The technology is installed by removing a section of the cold-water and
recirculating line and replacing it with the pipe containing the helical insert. Unit
sizing, which corresponds to pipe diameter, ranges from 3
⁄8 of an inch to 16 inches
and is determined by the flow rate of water to be treated. Once installed, the
system operates as a stand-alone device, requiring minimal maintenance and no
chemicals or energy over its 15-year life span.
What We Did
RESEARCHERS ASSESSED NCWT IMPACT ON SYSTEM CALCIFICATION
IN HIGH HARD WATER CONDITIONS
Researchers from ORNL tested the catalyst-based technology in an electric
domestic water heater. The water heater provided an ideal test-bed because it
is located in an area of high groundwater hardness and had no installed calcite
control technology. Over the course of 18 months, ORNL conducted pre- and post-
installation assessments of calcite formation on water system heating elements
and documented energy use, incidence of element failure, and labor and material
costs. Researchers also conducted a preliminary economic analysis of installed
cost and potential savings on the courthouse’s cooling tower.
INTRODUCTION
“Before we installed the
catalytic insert, our hot
water heating elements
failed every six weeks
because our water is so
hard. With the inserts in
place, regular inspections
show there is essentially
no scale build up at all.
—Daniel Wang
	 Property Manager
	 Frank E. Moss Federal Courthouse
	 Salt Lake City, Utah
	 Great Lakes Region
	 U.S. General Services Administration
Before NCWT
Before NCWT
Calcite buildup after two months of
untreated operation caused heating
elements to overheat and fail.
After NCWT
New heating elements 18 months after
installation of NCWT show no significant
signs of calcite buildup or overheating.
Pipe with helical insert installed in
cold-water and recirculating line
Green Proving Ground Program www.gsa.gov/gpg gpg@gsa.gov 3
CALCITE BUILDUP DRAMATICALLY REDUCED Before installation of the catalytic-based technology, and in
the absence of any kind of water treatment, commercial-grade heating elements had such significant calcite
buildup that they overheated and failed after only two months of operation. After installation, elements had
little visible calcite buildup even after eighteen months of operation.
PAYBACK WILL BE SITE-SPECIFIC The catalyst-based system had minimal operational costs beyond
the initial installed cost of $1,692. At the Moss Federal courthouse, simple payback was less than two
years, when compared to the cost of replacing failed heating elements. When compared to the cost of a
conventional salt-based system, payback is immediate. The harder the water, the more likeley NCWT will be
cost-effective.
MINIMAL OPERATIONS AND MAINTENANCE Little training is needed for site personnel, as there are no
moving parts or chemicals added. In installations where there is high iron content, the catalytic device may
require periodic cleaning. In systems without a drain, calcite can form a soft sludge in the bottom of the tank
which should be removed either manually or with a wet & dry vacuum every 18-24 months.
DEPLOY WHERE THERE IS HIGH WATER HARDNESS Catalyst-based NCWT technology should be
considered for any GSA facility with calcification issues. Remote locations, where access to power, chemicals,
and labor makes conventional water softening impractical and expensive, may benefit particularly from
this technology.
FINDINGS
NCWT vs. Salt-Based System in Salt Lake City
Payback for NCWT is immediate compared to a salt-based system
Salt-Based System NCWT
Equipment Cost $2,600 $1,192— (3
⁄4” diameter pipe) Unit pricing ranges between $798
for a 3
⁄8” pipe and $96,360 for a 16” pipe
Installation
Cost
$600 $500 —(10 hours @ $50/hr) Installation for new construction is
$0, as it incurs no additional costs over baseline
Maintenance
Costs/year
$1,850 $350 chemicals,
$1,500 labor
$100—Systems without a drain require biannual tank cleaning
Simple Payback Immediate
Green Proving Ground Program www.gsa.gov/gpg gpg@gsa.gov 4
What We Concluded
TECHNOLOGY PREVENTS CALCITE BUILDUP AND SAVES ENERGY
At the Moss Federal Courthouse, the catalyst-based non-chemical water
treatment prevented calcite buildup with minimal O&M costs. The technology
should be considered for any heating system with calcification issues, including
hydronic heating systems and boilers, condensing boilers, and gas and electric
water heaters. The harder the water, the more likely NCWT will be cost-effective.
As a next step, GPG will evaluate the technology in cooling tower applications,
following preliminary modeling that found it to be life-cycle cost-effective.
Lessons Learned
Device sizing key to effective performance Initially, calcite buildup and
overheating continued because the device was sized based on design flow rather
than measured water flow. A flow test using ultrasonic meters should be used to
determine appropriate device sizing.
Appropriate element capacity yields maximum effectiveness Electric
heating elements should match appliance specifications. The heating elements
originally installed in the courthouse’s water heater were designed for residential
use. Because they did not meet commercial capacity or building system
specifications, they failed every six weeks, far more frequently than commercial-
grade elements, which would have failed approximately every six months under
similar conditions.
Barriers to Adoption
Technology relatively new to U.S. Developed in Europe in 1973, the technology
is deployed in 40 countries, with more than one million installations. It was first
marketed in the U.S. in 2010, and certified by the National Sanitation Foundation in
2013. Currently, there are approximately ten thousand U.S. installations.
Higher First Costs The technology can have higher first costs than some other
water treatment systems, though substantial savings are still possible because it
uses no energy or chemicals and has minimal O&M costs.
Reference to any specific commercial product, process or service does not constitute or imply
its endorsement, recommendation or favoring by the United States Government or any agency
thereof.
CONCLUSIONS
These Findings are based
on the report, “Catalyst-
Based Non-Chemical Water
Treatment System, Frank E.
Moss U.S. Courthouse, Salt
Lake City, Utah,” which is
available from the GPG
program website,
www.gsa.gov/gpg
For more information,
contact
Green Proving Ground
gpg@gsa.gov
Footnotes
1
	USGS, http://water.usgs.gov/owq/
hardness-alkalinity.html (>60 mg/liter)

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GPG Findings 19 - NCWT (2) (1)

  • 1. FINDINGS #19, JANUARY 2015 CATALYST-BASED NON-CHEMICAL WATER TREATMENT GSA Public Buildings Service Catalyst-Based Device Reduces Calcite Buildup, Requires Minimal Maintenance According to the US Geological Survey, more than 85 percent of the United States has hard water.1 In plumbing, hard water leaves calcite deposits that restrict water flow by occluding pipes. In water heaters, calcite coats heating elements, causing them to overheat and eventually fail. Standard approaches to calcite mitigation rely on chemicals, which must be replenished frequently, or ultra-fine-membrane filtering, which uses large amounts of water and energy. GSA’s Green Proving Ground (GPG) program commissioned Oak Ridge National Laboratory (ORNL) to assess the effectiveness of a catalytic insert that alters the chemistry of hard water to prevent calcite buildup. Researchers assessing the technology at the Frank E. Moss Federal Court House in Salt Lake City, Utah, found that the catalyst-based non-chemical water treatment (NCWT) system dramatically reduced calcite buildup and had immediate payback when compared to a chemical (salt-based) system. Payback at other locations will depend on the ongoing remediation costs of calcite buildup. Catalyst-based NCWT should be considered for deployment in any heating system that is subject to calcification, including hydronic heating systems and boilers, condensing boilers, and gas and electric water heaters. The Green Proving Ground program leverages GSA’s real estate portfolio to evaluate innovative sustainable building technologies. The program aims to drive innovation in environmental performance in federal buildings and help lead market transformation through deployment of new technologies.
  • 2. Green Proving Ground Program www.gsa.gov/gpg gpg@gsa.gov 2 What is This Technology? PIPE WITH HELICAL INSERT REDUCES CALCITE PLATING The NCWT technology assessed in this measurement and verification (M&V) process consists of a length of pipe containing a single fixed helical insert. The insert is made from a proprietary catalytic alloy and is installed directly into the system’s water delivery pipe. As water flows over the metallic alloy, calcium and carbon form flushable crystals of the inert mineral aragonite rather than calcite. The technology is installed by removing a section of the cold-water and recirculating line and replacing it with the pipe containing the helical insert. Unit sizing, which corresponds to pipe diameter, ranges from 3 ⁄8 of an inch to 16 inches and is determined by the flow rate of water to be treated. Once installed, the system operates as a stand-alone device, requiring minimal maintenance and no chemicals or energy over its 15-year life span. What We Did RESEARCHERS ASSESSED NCWT IMPACT ON SYSTEM CALCIFICATION IN HIGH HARD WATER CONDITIONS Researchers from ORNL tested the catalyst-based technology in an electric domestic water heater. The water heater provided an ideal test-bed because it is located in an area of high groundwater hardness and had no installed calcite control technology. Over the course of 18 months, ORNL conducted pre- and post- installation assessments of calcite formation on water system heating elements and documented energy use, incidence of element failure, and labor and material costs. Researchers also conducted a preliminary economic analysis of installed cost and potential savings on the courthouse’s cooling tower. INTRODUCTION “Before we installed the catalytic insert, our hot water heating elements failed every six weeks because our water is so hard. With the inserts in place, regular inspections show there is essentially no scale build up at all. —Daniel Wang Property Manager Frank E. Moss Federal Courthouse Salt Lake City, Utah Great Lakes Region U.S. General Services Administration Before NCWT Before NCWT Calcite buildup after two months of untreated operation caused heating elements to overheat and fail. After NCWT New heating elements 18 months after installation of NCWT show no significant signs of calcite buildup or overheating. Pipe with helical insert installed in cold-water and recirculating line
  • 3. Green Proving Ground Program www.gsa.gov/gpg gpg@gsa.gov 3 CALCITE BUILDUP DRAMATICALLY REDUCED Before installation of the catalytic-based technology, and in the absence of any kind of water treatment, commercial-grade heating elements had such significant calcite buildup that they overheated and failed after only two months of operation. After installation, elements had little visible calcite buildup even after eighteen months of operation. PAYBACK WILL BE SITE-SPECIFIC The catalyst-based system had minimal operational costs beyond the initial installed cost of $1,692. At the Moss Federal courthouse, simple payback was less than two years, when compared to the cost of replacing failed heating elements. When compared to the cost of a conventional salt-based system, payback is immediate. The harder the water, the more likeley NCWT will be cost-effective. MINIMAL OPERATIONS AND MAINTENANCE Little training is needed for site personnel, as there are no moving parts or chemicals added. In installations where there is high iron content, the catalytic device may require periodic cleaning. In systems without a drain, calcite can form a soft sludge in the bottom of the tank which should be removed either manually or with a wet & dry vacuum every 18-24 months. DEPLOY WHERE THERE IS HIGH WATER HARDNESS Catalyst-based NCWT technology should be considered for any GSA facility with calcification issues. Remote locations, where access to power, chemicals, and labor makes conventional water softening impractical and expensive, may benefit particularly from this technology. FINDINGS NCWT vs. Salt-Based System in Salt Lake City Payback for NCWT is immediate compared to a salt-based system Salt-Based System NCWT Equipment Cost $2,600 $1,192— (3 ⁄4” diameter pipe) Unit pricing ranges between $798 for a 3 ⁄8” pipe and $96,360 for a 16” pipe Installation Cost $600 $500 —(10 hours @ $50/hr) Installation for new construction is $0, as it incurs no additional costs over baseline Maintenance Costs/year $1,850 $350 chemicals, $1,500 labor $100—Systems without a drain require biannual tank cleaning Simple Payback Immediate
  • 4. Green Proving Ground Program www.gsa.gov/gpg gpg@gsa.gov 4 What We Concluded TECHNOLOGY PREVENTS CALCITE BUILDUP AND SAVES ENERGY At the Moss Federal Courthouse, the catalyst-based non-chemical water treatment prevented calcite buildup with minimal O&M costs. The technology should be considered for any heating system with calcification issues, including hydronic heating systems and boilers, condensing boilers, and gas and electric water heaters. The harder the water, the more likely NCWT will be cost-effective. As a next step, GPG will evaluate the technology in cooling tower applications, following preliminary modeling that found it to be life-cycle cost-effective. Lessons Learned Device sizing key to effective performance Initially, calcite buildup and overheating continued because the device was sized based on design flow rather than measured water flow. A flow test using ultrasonic meters should be used to determine appropriate device sizing. Appropriate element capacity yields maximum effectiveness Electric heating elements should match appliance specifications. The heating elements originally installed in the courthouse’s water heater were designed for residential use. Because they did not meet commercial capacity or building system specifications, they failed every six weeks, far more frequently than commercial- grade elements, which would have failed approximately every six months under similar conditions. Barriers to Adoption Technology relatively new to U.S. Developed in Europe in 1973, the technology is deployed in 40 countries, with more than one million installations. It was first marketed in the U.S. in 2010, and certified by the National Sanitation Foundation in 2013. Currently, there are approximately ten thousand U.S. installations. Higher First Costs The technology can have higher first costs than some other water treatment systems, though substantial savings are still possible because it uses no energy or chemicals and has minimal O&M costs. Reference to any specific commercial product, process or service does not constitute or imply its endorsement, recommendation or favoring by the United States Government or any agency thereof. CONCLUSIONS These Findings are based on the report, “Catalyst- Based Non-Chemical Water Treatment System, Frank E. Moss U.S. Courthouse, Salt Lake City, Utah,” which is available from the GPG program website, www.gsa.gov/gpg For more information, contact Green Proving Ground gpg@gsa.gov Footnotes 1 USGS, http://water.usgs.gov/owq/ hardness-alkalinity.html (>60 mg/liter)