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OCSiAl Europe
Success Stories and Challenges
Christoph Siara, Director Sales & Marketing OCSiAl Europe
Super technologies
breakthroughs
Space elevator
Passenger Drone
Hyperloop
Wide adoption of
electric cars
Space X
02
Atmospheric satellite
SUPER MATERIALS
Single wall cnt
GRAPHENE
NANOTUBE
~ 4 µm
~ 2 nm
LENGTH
DIAMETER
1g = 150 million Km
GRAPHENE NANOTUBES
EXCEPTIONAL PROPERTIES
Thermal
stability Strength
Surface
area
Length to
diameter
ratio
Electrical
conductivity
103 - 106 Comparable with
cooper but
5 times
lighter
~ 1000 m2/g
stronger than steel
100 times
1000 °C
up to
* Ma, P. C., Siddiqui, N. A., Marom, G., & Kim, J. K. (2010). Dispersion and functionalization of carbon nanotubes for polymer-based nanocomposites:
a review. Composites Part A: Applied Science and Manufacturing, 41 (10), 1345-1367.
GRAPHENE
NANOTUBES
CARBON NANOFIBERSMICROPARTICLES
GRAPHENE NANOTUBES
EXCEPTIONAL PROPERTIES
CARBON BLACK
20–40%
To improve the target properties of materials, only ultra-low concentrations of graphene nanotubes are
needed. This leads to cost savings, without negative effects on viscosity, colour or other properties.
METAL
FILLERS
15–35%
CARBON
FIBERS
3–12%
GRAPHENE
1–6%
MWCNT
0.5–5% TUBALL
0.001–0.01%
ADDITIVES COMPARISON
THRESHOLD OF CHANGE
Lessons learned
POWDER IS NOT ENOUGH
Know-how H&S
FROM POWDER & READY TO USE PRODUCTS
MODIFIERS MATERIALSTUBALL™ SWCNT-BASED
END PRODUCTS
TUBALL™ MODIFIERS MATERIALS GRAPHENE
NANOTUBES-
BASED
END PRODUCTS
PRODUCED BY OCSIAL:
RUSSIA, LUXEMBOURG*
PRODUCED BY OCSIAL
AND PARTNERS:
WORLDWIDE
MIX-IN
*under construction
OCSiAl R&D TEAM
•18 21 40 >40
Patents &
patent application
ScientistsUndergraduates
at the department
of nanocomposite
materials NSU
PhD
PROTOTYPING CENTER:
WHERE NEW MATERIALS, PRODUCTS AND TECHNOLOGIES ARE BORN
300 ITEMS
OF EQUIPMENT
MORE THAN
110 EMPLOYEES
6 INDUSTRIAL
TECHONOLOGIESPR
OTOTYPED
> 20 PRODUCTS
DEVELOPED
REACH
(Registration, Evaluation, Authorisation
and Restriction of Chemicals)
First and only SWCNT completed
(29 September, 2016)
TUBALL™ is registered under the number
01-2120130006-75-0000
Allows to commercialize
up to 10 t/y in Europe
TUBALL™ nanotubes are certified to be widely used in a wide range of industries, including consumable products
EPA
(Environmental Protection Agency)
EPA consented
PMN number P-17-0257
Allows to commercialize
up to 25 t/y in USA
Success Stories
TUBALL™
APPLICIATIONS:
ONE ADDITIVE
FOR THOUSANDS
OF MATERIALS
Spintronics
Transparent
conductors
Field
emission
Transistors
and integrated
circuits
Memory devices
Optical
switches
Composites
Lightning
strike protection
EMI shielding
coatings
Anti-icing
coatings
Aircraft
braking
system
coatings
Flame-retardant
materials
Polymer
composites
EMI
shielding
coatings
Wind turbine
blade composites
Polystyrene
composites
Polymers
with EMI or RFI
shielding capabilities
Lithium-ion
batteries
Lead–acid
battery
Supercapacitors
Photovoltaics
Fuel cells
Biosensors
MRI contrast
agents
FRET
biosensors
Gene
delivery
Gas
separation
Chemical
and gas sensors
Radiation
sensors
Desalination
membranes
Sensor
materialsfor improving
IR detection
Medical device
coatings
Drug
delivery
Conductive
composites
Wound
healing
Wear-resistant
coatings
Thermal barrier
coatings
ESD, EMI andRFI
paintsEnergy
Automotive
Electronics
Composites
Biomedicine
Aerospace
& aviation
Sensors
& filtration
pre-dispersed concentrate of single
wall carbonnanotubes
Source: The Carbon Nanotubes, Graphene & 2D Materials Global Opportunity
Report www.futuremarketsinc.com
SUCCESS STORIES
Mobility Construction Oil & Gas
BODY INTERIOR BATTERY TIRES
INNOVATIONS: ACHIEVED & COMMERCIALIZED SO FAR
SMC conductive body parts,
Conductive coatings & paints,
Coloured & transparent
conductive gelcoats,
EMI Shielding.
Improved level of
confort: Local surface
heating,
Antistatic synthetic
leather, conductive
panels.
Energy density 300wh/kg,
Extended cycle life,
Improved discharge rates.
Optimised fuel efficiency,
Stronger grip,
Extended longevity,
Different color options.
KEY BENEFITS
• Abrasion resistance increased up to 15%
• Wet grip dramatically increased
• Electrical resistance to ground < 106
• ESD protection for user/motorcycle
More applications available in the PDF “Success Stories”
COMPANY
Mitas-Trelleborg Group, Slovenia
APPLICATION
Tyre tread compound processed with 1wt% MATRIX 603
PRODUCT
Tyre of electric two-wheeled vehicle
MOTORCYCLE TYRE TREAD
COMPANY
Büfa Composites, Germany
APPLICATION
UP-based system processed with 0,05wt% TUBALL™
instead of 8wt% conductive carbon black
PRODUCT
Antistatic gelcoat for molds used in automotive area
Winner of the AVK Innovation Awards 2018
KEY BENEFITS
• Provides surface resistivity of 105 Ω/sq
• Permanent, stable & homogenous resistivity
• No “hot spots” & no influence of humidity
• Brigth colours including white are possible
More applications available in the PDF “Success Stories”
ANTISTATIC GELCOAT
COMPANY
Orient Energy & Technologies, China
APPLICATION
NBR compounds processed with MATRIX 604-DOS
(loading level non disclosed)
PRODUCT
Screw drilling stator for oil & gas plants
KEY BENEFITS
• Tensile modulus improved by 30%
• Abrasion reduced by 20% (without rubber Mooney viscosity increase)
• Drilling speed increased by 20%
• Torque output increased by 30%
NBR SCREW DRILLING STATOR
ANTI-STATIC DIAGNOSTIC
POLYURETHANE PIGS
PRODUCT
Anti-static PU-based diagnostic pig`s discs for gas and oil
pipelines
REQUIREMENTS
• Resistivity <106 Ω·cm
• Permanent and stable level of resistivity
• Minimal impact on mechanical properties
TUBALL™ SOLUTION
0.4 wt.% of TUBALL™ MATRIX 202
KEY BENEFITS
• Stable 105 Ω·cm without “hot spots”
• Permanent anti-static properties independent on humidity
• Without negative influence on mechanical properties
• Without static interference with pipes cracks detection
equipment
ANTI-STATIC PRINTING ROLLERS
AND SLEEVES
PRODUCT
Anti-static PU-based rollers for ESA printing
REQUIREMENTS
• Resistivity <106 Ω·cm
• Permanent and stable level of resistivity
• Maintained mechanical properties
TUBALL™ SOLUTION
0.3 wt.% of TUBALL™ MATRIX 202
KEY BENEFITS
• Permanent and stable resistivity without “hot spots”
• Without negative influence on mechanical properties
• Resistivity is independent of humidity
LLDPE – ROTATIONAL MOLDING
PRODUCT
LLDPE with AS properties using 0.1 wt% TUBALL™ SWCNT
APPLICATIONS
Packaging for flammable and explosive solids, liquids, pallets
produced by rotational molding technology
KEY BENEFITS
• Effective at ultralow dosage
• Allow production of colored antistatic parts
• Permanent effect without compromising mechanical
properties
• Improved internal surface over incumbent solutions
0.07 wt.% TUBALL
106 Ω×cm
0.1 wt.% TUBALL
106 Ω×cm
ANTI-STATIC TEXTILE
PRODUCT
Anti-static PVC plastisol-based textile for ESD protection
REQUIREMENTS
Permanent resistivity <108 Ω/sq
TUBALL™ SOLUTION
0.5 wt.% of TUBALL™ PD 0302
KEY BENEFITS
• Permanent and stable level of resistivity without “hot spots”
• No negative influence on mechanical properties
• Resistivity is independent of humidity
Si/C
ANODES
HIGH-PERFORMANCE
CATHODES
CYCLE LIFE ENERGY DENSITY
Increase cycle–life of high–energy Si/C
anodes with only 0.05% of graphene
nanotubes, allowing their adoption in LIB
to reach 300 Wh/kg energy density
Maximise energy with only 0.06%
of graphene nanotubes: by using up to 99%
of active material in modern high-energy NCM
and other cathodes
SAFETY AND STABLE PERFORMANCE
Slower DCR growth, improved cycle life and c-
rate performance can be achieved with adding
as low as 0.01%
Joining forces with
industry leaders
PRODUCTION FACILITIES
2018
GRAPHETRON
50 tonnes/
year
2014
PRODUCTION FACILITIES
2022
GRAPHETRON
250 tonnes/
year
2018
COLUMBUS
LUXEMBOURG
MOSСOW
NOVOSIBIRSK
SEOUL
SHANGHAI
SHENZHEN
HONG KONGMUMBAI
ISRAEL
ITALY
TUNISIA
MALAYSIA
JAPAN
BRAZIL
CANADA
GERMANY
TURKEY
SINGAPORE
INDONESIA
VIETNAMTHAILAND
NORWAY
SWEDEN
FINLAND
DENMARK
GREECE
NAMIBIA
SOUTH AFRICA
MOROCCO
ALGERIA
SPAIN
AUSTRALIA
MAP OF REGIONAL OCSiAl REGIONAL OFFICES AND DISTRIBUTORS
MORE THAN
400EMPLOYEES
IN 12COUNTRIES
Michael enotiades   oc si-al

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Michael enotiades oc si-al

  • 1. OCSiAl Europe Success Stories and Challenges Christoph Siara, Director Sales & Marketing OCSiAl Europe
  • 2. Super technologies breakthroughs Space elevator Passenger Drone Hyperloop Wide adoption of electric cars Space X 02 Atmospheric satellite
  • 5. ~ 4 µm ~ 2 nm LENGTH DIAMETER 1g = 150 million Km
  • 6. GRAPHENE NANOTUBES EXCEPTIONAL PROPERTIES Thermal stability Strength Surface area Length to diameter ratio Electrical conductivity 103 - 106 Comparable with cooper but 5 times lighter ~ 1000 m2/g stronger than steel 100 times 1000 °C up to
  • 7. * Ma, P. C., Siddiqui, N. A., Marom, G., & Kim, J. K. (2010). Dispersion and functionalization of carbon nanotubes for polymer-based nanocomposites: a review. Composites Part A: Applied Science and Manufacturing, 41 (10), 1345-1367. GRAPHENE NANOTUBES CARBON NANOFIBERSMICROPARTICLES GRAPHENE NANOTUBES EXCEPTIONAL PROPERTIES
  • 8. CARBON BLACK 20–40% To improve the target properties of materials, only ultra-low concentrations of graphene nanotubes are needed. This leads to cost savings, without negative effects on viscosity, colour or other properties. METAL FILLERS 15–35% CARBON FIBERS 3–12% GRAPHENE 1–6% MWCNT 0.5–5% TUBALL 0.001–0.01% ADDITIVES COMPARISON THRESHOLD OF CHANGE
  • 10. POWDER IS NOT ENOUGH Know-how H&S
  • 11. FROM POWDER & READY TO USE PRODUCTS MODIFIERS MATERIALSTUBALL™ SWCNT-BASED END PRODUCTS TUBALL™ MODIFIERS MATERIALS GRAPHENE NANOTUBES- BASED END PRODUCTS PRODUCED BY OCSIAL: RUSSIA, LUXEMBOURG* PRODUCED BY OCSIAL AND PARTNERS: WORLDWIDE MIX-IN *under construction
  • 12. OCSiAl R&D TEAM •18 21 40 >40 Patents & patent application ScientistsUndergraduates at the department of nanocomposite materials NSU PhD
  • 13. PROTOTYPING CENTER: WHERE NEW MATERIALS, PRODUCTS AND TECHNOLOGIES ARE BORN 300 ITEMS OF EQUIPMENT MORE THAN 110 EMPLOYEES 6 INDUSTRIAL TECHONOLOGIESPR OTOTYPED > 20 PRODUCTS DEVELOPED
  • 14. REACH (Registration, Evaluation, Authorisation and Restriction of Chemicals) First and only SWCNT completed (29 September, 2016) TUBALL™ is registered under the number 01-2120130006-75-0000 Allows to commercialize up to 10 t/y in Europe TUBALL™ nanotubes are certified to be widely used in a wide range of industries, including consumable products EPA (Environmental Protection Agency) EPA consented PMN number P-17-0257 Allows to commercialize up to 25 t/y in USA
  • 16. TUBALL™ APPLICIATIONS: ONE ADDITIVE FOR THOUSANDS OF MATERIALS Spintronics Transparent conductors Field emission Transistors and integrated circuits Memory devices Optical switches Composites Lightning strike protection EMI shielding coatings Anti-icing coatings Aircraft braking system coatings Flame-retardant materials Polymer composites EMI shielding coatings Wind turbine blade composites Polystyrene composites Polymers with EMI or RFI shielding capabilities Lithium-ion batteries Lead–acid battery Supercapacitors Photovoltaics Fuel cells Biosensors MRI contrast agents FRET biosensors Gene delivery Gas separation Chemical and gas sensors Radiation sensors Desalination membranes Sensor materialsfor improving IR detection Medical device coatings Drug delivery Conductive composites Wound healing Wear-resistant coatings Thermal barrier coatings ESD, EMI andRFI paintsEnergy Automotive Electronics Composites Biomedicine Aerospace & aviation Sensors & filtration pre-dispersed concentrate of single wall carbonnanotubes Source: The Carbon Nanotubes, Graphene & 2D Materials Global Opportunity Report www.futuremarketsinc.com
  • 18. BODY INTERIOR BATTERY TIRES INNOVATIONS: ACHIEVED & COMMERCIALIZED SO FAR SMC conductive body parts, Conductive coatings & paints, Coloured & transparent conductive gelcoats, EMI Shielding. Improved level of confort: Local surface heating, Antistatic synthetic leather, conductive panels. Energy density 300wh/kg, Extended cycle life, Improved discharge rates. Optimised fuel efficiency, Stronger grip, Extended longevity, Different color options.
  • 19. KEY BENEFITS • Abrasion resistance increased up to 15% • Wet grip dramatically increased • Electrical resistance to ground < 106 • ESD protection for user/motorcycle More applications available in the PDF “Success Stories” COMPANY Mitas-Trelleborg Group, Slovenia APPLICATION Tyre tread compound processed with 1wt% MATRIX 603 PRODUCT Tyre of electric two-wheeled vehicle MOTORCYCLE TYRE TREAD
  • 20. COMPANY Büfa Composites, Germany APPLICATION UP-based system processed with 0,05wt% TUBALL™ instead of 8wt% conductive carbon black PRODUCT Antistatic gelcoat for molds used in automotive area Winner of the AVK Innovation Awards 2018 KEY BENEFITS • Provides surface resistivity of 105 Ω/sq • Permanent, stable & homogenous resistivity • No “hot spots” & no influence of humidity • Brigth colours including white are possible More applications available in the PDF “Success Stories” ANTISTATIC GELCOAT
  • 21. COMPANY Orient Energy & Technologies, China APPLICATION NBR compounds processed with MATRIX 604-DOS (loading level non disclosed) PRODUCT Screw drilling stator for oil & gas plants KEY BENEFITS • Tensile modulus improved by 30% • Abrasion reduced by 20% (without rubber Mooney viscosity increase) • Drilling speed increased by 20% • Torque output increased by 30% NBR SCREW DRILLING STATOR
  • 22. ANTI-STATIC DIAGNOSTIC POLYURETHANE PIGS PRODUCT Anti-static PU-based diagnostic pig`s discs for gas and oil pipelines REQUIREMENTS • Resistivity <106 Ω·cm • Permanent and stable level of resistivity • Minimal impact on mechanical properties TUBALL™ SOLUTION 0.4 wt.% of TUBALL™ MATRIX 202 KEY BENEFITS • Stable 105 Ω·cm without “hot spots” • Permanent anti-static properties independent on humidity • Without negative influence on mechanical properties • Without static interference with pipes cracks detection equipment
  • 23. ANTI-STATIC PRINTING ROLLERS AND SLEEVES PRODUCT Anti-static PU-based rollers for ESA printing REQUIREMENTS • Resistivity <106 Ω·cm • Permanent and stable level of resistivity • Maintained mechanical properties TUBALL™ SOLUTION 0.3 wt.% of TUBALL™ MATRIX 202 KEY BENEFITS • Permanent and stable resistivity without “hot spots” • Without negative influence on mechanical properties • Resistivity is independent of humidity
  • 24. LLDPE – ROTATIONAL MOLDING PRODUCT LLDPE with AS properties using 0.1 wt% TUBALL™ SWCNT APPLICATIONS Packaging for flammable and explosive solids, liquids, pallets produced by rotational molding technology KEY BENEFITS • Effective at ultralow dosage • Allow production of colored antistatic parts • Permanent effect without compromising mechanical properties • Improved internal surface over incumbent solutions 0.07 wt.% TUBALL 106 Ω×cm 0.1 wt.% TUBALL 106 Ω×cm
  • 25. ANTI-STATIC TEXTILE PRODUCT Anti-static PVC plastisol-based textile for ESD protection REQUIREMENTS Permanent resistivity <108 Ω/sq TUBALL™ SOLUTION 0.5 wt.% of TUBALL™ PD 0302 KEY BENEFITS • Permanent and stable level of resistivity without “hot spots” • No negative influence on mechanical properties • Resistivity is independent of humidity
  • 26. Si/C ANODES HIGH-PERFORMANCE CATHODES CYCLE LIFE ENERGY DENSITY Increase cycle–life of high–energy Si/C anodes with only 0.05% of graphene nanotubes, allowing their adoption in LIB to reach 300 Wh/kg energy density Maximise energy with only 0.06% of graphene nanotubes: by using up to 99% of active material in modern high-energy NCM and other cathodes SAFETY AND STABLE PERFORMANCE Slower DCR growth, improved cycle life and c- rate performance can be achieved with adding as low as 0.01%