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On the perspectives of supercapacitor
technology
On the perspectives of supercapacitor technology
2
3
On the perspectives of supercapacitor technology
Batteries SC Flywheels
Specific energy stored, W.h/kg 30… 150 3… 6 4… 9
Specific power (@ 95% eff.), kW/kg 0.1… 1 1… 10* 2… 4
Supercapacitors are NOT energy devices, they are POWER devices!
Key SC applications are related with covering the peaks of power, load
leveling the batteries, kinetic energy recovery, etc.
4
On the perspectives of supercapacitor technology
* YUNASKO value only
5
On the perspectives of supercapacitor technology
Rin
= ʃI2Rindt
~ U2 / Rin
On the perspectives of supercapacitor technology
Eff =
RLoad
RLoad + Rin
6
Y. Maletin et al. Carbon Based Electrochemical Double Layer Capacitors
of Low Internal Resistance. Energy&Environment Research, 2013, vol
3, # 2, pp.156-165.
http://www.ccsenet.org/journal/index.php/eer/issue/current
On the perspectives of supercapacitor technology
7
Yunasko SC cells and combined modules
(Li-ion battery and SC stack in parallel)
Module: 14 V
Max.current: 1200 A
Mass: 2.8 kg
Single cells:
480 F
1200 F
1500 F
On the perspectives of supercapacitor technology
8
48 V, 165 F:
DC resistance: <4 mΩ
Mass: 13 kg
equipped with a proprietary
voltage balancing system
and temperature sensor
On the perspectives of supercapacitor technology
9
16 V, 200 F:
DC resistance: <1 mΩ
Mass: 2.5 kg
equipped with a proprietary
voltage balancing system
and temperature sensor
On the perspectives of supercapacitor technology
10
Continuous cycling the 16V module over 8 hours
basic city duty cycle
ΔT:
cells in the centre
cells at the edge
Time, s
V
A, charge
A, discharge
On the perspectives of supercapacitor technology
11
“During the recent ECCAP Symposium at AABC-2013 in Strasbourg
(June 24-26) a recognised specialist in the field of supercapacitor
research – Dr. John Miller from JME Inc. revealed testing results for
the six key ultracapacitor producers, including a market leader –
Maxwell Technologies. The results showed substantial advantage
of YUNASKO technology over the closest analogues.”
(http://us1.campaign-archive1.com/?u=84cc935cd75c22a368d1cd12e&id=31a3699821&e=193f657ac6)
On the perspectives of supercapacitor technology
12
On the perspectives of supercapacitor technology
NOTE: 2.7V  3.5V results in:
• E & P increase in ~70% per a single cell, or
• 14 cells in 48V module instead of 18
13
•
•
•
On the perspectives of supercapacitor technology
14
NOTE: test results for JM Energy
hybrid were also obtained at ITS
and added here for comparison
100 1000 10000
0
5
10
15
20
25
30
35
40
Yunasko hybrid 6000F
Yunasko AC/AC 1200F
JME AC/Graphite 1100F
Specificenergy,Wh/g
Specific power, W/kg
On the perspectives of supercapacitor technology
15
-40 -20 0 20 40 60
0
20
40
60
80
100
50 0
C25 0
C
Dischargecapacity,%
t, 0
C
1 C
20 C
50 C
-30 0
C
On the perspectives of supercapacitor technology
16
On the perspectives of supercapacitor technology
17
On the perspectives of supercapacitor technology
18
On the perspectives of supercapacitor technology
19
On the perspectives of supercapacitor technology
20
Capacitance,
F
Internal
resistance,
mΩ
Time
constant,
s
Spec.
energy
(CU2
/2),
W.h/kg
Spec.
power
(95% eff.),
kW/kg
Max.
spec.
power,
kW/kg
SC power cells (2.7V)
480a
0.20 0.10 4.9 10.2 91
1200a,b
0.10 0.12 5.3 8.9 79
1500b
0.09 0.14 6.1 9.1 81
Hybrid cells (2.8 V)
6000a
1.0 6.0 37 4.5 NA
16 V module (6 “power” cells of 1200F in series)
200c,d
0.6 0.12 2.8 4.8 43
48 V module (18 “energy” cells of 3000F in series)
165d
4.0 0.65 4.4 1.4 12
a) Also tested in ITS, UC Davis, CA; b) Also tested in JME, Cleveland, OH;
c) Also tested in Wayne State University, Detroit, MI;
d) Equipped with a proprietary voltage balancing system (patent pending).
On the perspectives of supercapacitor technology
21
22
On the perspectives of supercapacitor technology
On the perspectives of supercapacitor technology
23
Maletin AABC 2014

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Maletin AABC 2014

  • 1. On the perspectives of supercapacitor technology
  • 2. On the perspectives of supercapacitor technology 2
  • 3. 3 On the perspectives of supercapacitor technology
  • 4. Batteries SC Flywheels Specific energy stored, W.h/kg 30… 150 3… 6 4… 9 Specific power (@ 95% eff.), kW/kg 0.1… 1 1… 10* 2… 4 Supercapacitors are NOT energy devices, they are POWER devices! Key SC applications are related with covering the peaks of power, load leveling the batteries, kinetic energy recovery, etc. 4 On the perspectives of supercapacitor technology * YUNASKO value only
  • 5. 5 On the perspectives of supercapacitor technology
  • 6. Rin = ʃI2Rindt ~ U2 / Rin On the perspectives of supercapacitor technology Eff = RLoad RLoad + Rin 6
  • 7. Y. Maletin et al. Carbon Based Electrochemical Double Layer Capacitors of Low Internal Resistance. Energy&Environment Research, 2013, vol 3, # 2, pp.156-165. http://www.ccsenet.org/journal/index.php/eer/issue/current On the perspectives of supercapacitor technology 7
  • 8. Yunasko SC cells and combined modules (Li-ion battery and SC stack in parallel) Module: 14 V Max.current: 1200 A Mass: 2.8 kg Single cells: 480 F 1200 F 1500 F On the perspectives of supercapacitor technology 8
  • 9. 48 V, 165 F: DC resistance: <4 mΩ Mass: 13 kg equipped with a proprietary voltage balancing system and temperature sensor On the perspectives of supercapacitor technology 9
  • 10. 16 V, 200 F: DC resistance: <1 mΩ Mass: 2.5 kg equipped with a proprietary voltage balancing system and temperature sensor On the perspectives of supercapacitor technology 10
  • 11. Continuous cycling the 16V module over 8 hours basic city duty cycle ΔT: cells in the centre cells at the edge Time, s V A, charge A, discharge On the perspectives of supercapacitor technology 11
  • 12. “During the recent ECCAP Symposium at AABC-2013 in Strasbourg (June 24-26) a recognised specialist in the field of supercapacitor research – Dr. John Miller from JME Inc. revealed testing results for the six key ultracapacitor producers, including a market leader – Maxwell Technologies. The results showed substantial advantage of YUNASKO technology over the closest analogues.” (http://us1.campaign-archive1.com/?u=84cc935cd75c22a368d1cd12e&id=31a3699821&e=193f657ac6) On the perspectives of supercapacitor technology 12
  • 13. On the perspectives of supercapacitor technology NOTE: 2.7V  3.5V results in: • E & P increase in ~70% per a single cell, or • 14 cells in 48V module instead of 18 13
  • 14. • • • On the perspectives of supercapacitor technology 14
  • 15. NOTE: test results for JM Energy hybrid were also obtained at ITS and added here for comparison 100 1000 10000 0 5 10 15 20 25 30 35 40 Yunasko hybrid 6000F Yunasko AC/AC 1200F JME AC/Graphite 1100F Specificenergy,Wh/g Specific power, W/kg On the perspectives of supercapacitor technology 15
  • 16. -40 -20 0 20 40 60 0 20 40 60 80 100 50 0 C25 0 C Dischargecapacity,% t, 0 C 1 C 20 C 50 C -30 0 C On the perspectives of supercapacitor technology 16
  • 17. On the perspectives of supercapacitor technology 17
  • 18. On the perspectives of supercapacitor technology 18
  • 19. On the perspectives of supercapacitor technology 19
  • 20. On the perspectives of supercapacitor technology 20
  • 21. Capacitance, F Internal resistance, mΩ Time constant, s Spec. energy (CU2 /2), W.h/kg Spec. power (95% eff.), kW/kg Max. spec. power, kW/kg SC power cells (2.7V) 480a 0.20 0.10 4.9 10.2 91 1200a,b 0.10 0.12 5.3 8.9 79 1500b 0.09 0.14 6.1 9.1 81 Hybrid cells (2.8 V) 6000a 1.0 6.0 37 4.5 NA 16 V module (6 “power” cells of 1200F in series) 200c,d 0.6 0.12 2.8 4.8 43 48 V module (18 “energy” cells of 3000F in series) 165d 4.0 0.65 4.4 1.4 12 a) Also tested in ITS, UC Davis, CA; b) Also tested in JME, Cleveland, OH; c) Also tested in Wayne State University, Detroit, MI; d) Equipped with a proprietary voltage balancing system (patent pending). On the perspectives of supercapacitor technology 21
  • 22. 22 On the perspectives of supercapacitor technology
  • 23. On the perspectives of supercapacitor technology 23