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EXTENDING THE BATTERY PERFORMANCE LIMITS
THROUGH THE COMBINATION OF TECHNOLOGIES
August 2018
NEED FOR ENERGY STORAGE AND HARVESTING
2
No electric vehicles
possible without storage
No CO2 emission
reduction possible
without hybridizing ICE
No renewables possible
without storage
No smart grids possible
without storage
MOST IMPORTANT METRICS FOR ENERGY STORAGE
Units: $/Wh/cycle
or better “cost of
ownership”.
How fast we could use the
energy and how much of the
energy we lose due to an
imperfect system?
How far we could drive?
COST SAFETYPOWER /
EFFICIENCY
ENERGY
CHALLENGES FOR BATTERIES
▶  Low charge / discharge rate (not quick enough for frequency
regulation in grids, slow charge of EV battery)
▶  Safety concerns (fire hazard)
▶  Short lifetime (expensive to change)
▶  Low and high temperatures intolerance
▶  Low efficiency (heat generation requires expensive thermal
management systems)
Battery
Ultracapacitor
Battery
Ultracapacitor
Energy
Power
Cycle life
Temperature performance
Safety
BATTERY vs ULTRACAPACITOR
HOW TO CREATE A MÉLANGE OF LARGE ENERGY AND HIGH POWER?
Effect of low inner resistance of Yunasko ultracapacitor module (A)
as compared with the best competing devices (B):
1 – current flowing through battery; 2 – current flowing through ultracapacitor;
3 – total current
Yunasko UC effectively unloads the battery and enhances total current
(parallel connection with a battery)
ULTRACAPACITOR (UC) AND BATTERY COMBINATION
Parallel connection
(load leveling the battery)
40 mΩ 1 mΩ
UCBattery
M
O
T
O
R
DC
EDLC
(C-C supercapacitor, ultracapacitor)
AC Active carbon (AC)
AC Oxide/graphite
Oxide + ACOxide + AC
Asymmetric hybrid
(internal serial, LIC)
Symmetric hybrid
(parallel LIC (//LIC) or
enhanced LIB)
HYBRIDIZATION: TYPES OF CAPACITOR SYSTEMS
RESULT: energy storage system with battery-type charge-
discharge curve and energy density up to 40 Wh/kg
(also confirmed by tests in ITS, Davis, USA and VW Group,
Germany)
PARALLEL HYBRID SOLUTION
LITHIUM-ION CAPACITORS
OUR APPROACH: electrode level hybridization - both
positive and negative electrodes comprise Li-ion and
activated carbon components with thoroughly matched
potential ranges: “parallel hybrid” //LIC, patent pending
8
HIGH POWER Li-ion ULTRACAPACITOR YUNASKO //LIC
Power, kW/kg 1…3 10…50 3…5
Energy, Wh/kg 60…100 5…7 30…40
Charge / discharge
time
15…90
minutes
10…30
seconds
2…3
minutes
Cycle life <10,000 >1,000,000 >30,000
Temperature window -20 0C…+60 0C -40 0C…+85 0C -40 0C…+60 0C
HYBRIDIZATION RESULTS
=
HIGH SAFETY OF YUNASKO LIC
NO thermal runaway
Nail penetration test
the most effective
TECHNOLOGY COMPARISON
We can safely charge
energy of lead-acid
battery within 2 minutes
and discharge up to
150C* rate (~20s) with
efficiency >80%
* NOTE: C-Rate is a measure of the rate (time or current) at which a battery is charged or discharged relative to the capacity
of the battery. A 1C rate means that the discharge current will discharge the entire battery in 1 hour. 11
YUNASKO BACKGROUND AND DOMAIN
COMPANY MANUFACTURING PRODUCT TECHNOLOGY
▶  Founded in 2010, in
energy storage projects
since 1989
▶  40 people, 12 of them
in R&D, 6 PhD:
researchers &
engineers
▶  Ukraine: R&D, Design
Bureau and Pilot Plant
▶  London: financial and
IP harbour
▶  Pilot plant in the
West of Ukraine
▶  Ready to build large
scale manufacture
with the capacity
over 4 million large
cells / year
▶  Ultra high power heavy duty
ultracapacitor cells from
200F to 3,000F. 3-5 times
more power than
competitors.
▶  16V, 48V, 90V, 112V stack
and module building blocks
▶  Lithium capacitors with high
energy (up to 40 Wh/kg) and
power (up to 5 kW/kg)
▶  High temperature
ultracapacitors with -25oC…
+110oC operating
temperature range
▶  Carbon / carbon
ultracapacitors and lithium –
ion capacitors with organic
electrolytes and proprietary
design
▶  Proprietary dry electrode
manufacturing technology
▶  Power fusion foil (current
collector) treatment
technology
▶  8 patents granted and 8
patent applications filled
▶  Only commercially available,
low cost components
YUNASKO TRACTION
Materials
performance:
simplest
ultracapacitor
and lithium
capacitor
built to show
performance
Prototype
performance:
large cells
(>1 Wh) that
maps to
modules
Device performance:
pilot plant production
rate reached 200
large cells/year with
yield over 90%
Product performance:
ultracapacitor and
lithium capacitors cells
sold and tested by the
customers
Unit economics:
large scale production
STEPS
COMPLETED
2018-2019
2015-2017
2012-2014
2010-2012
2010
Idea
Seeking for a strategic
partner
Performance verified by independent experts:
Institute of Transportation Studies, Davis, USA; Wayne State University, Detroit,
USA; JME, Cleveland, USA.
and customers:
VW group, PSA group, Renault, BFFT - Audi, MTS Systems – Ferrari, SAFRAN,
Electro Standard Labs, US Navy, MOOG, US Air Force and others,
(reports available upon request)
13
Vadim UTKIN
CEO
+380 67 445 3713
vu@yunasko.com
yunasko.com

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Vadym utkin for_wef_2018_aug3

  • 1. EXTENDING THE BATTERY PERFORMANCE LIMITS THROUGH THE COMBINATION OF TECHNOLOGIES August 2018
  • 2. NEED FOR ENERGY STORAGE AND HARVESTING 2 No electric vehicles possible without storage No CO2 emission reduction possible without hybridizing ICE No renewables possible without storage No smart grids possible without storage
  • 3. MOST IMPORTANT METRICS FOR ENERGY STORAGE Units: $/Wh/cycle or better “cost of ownership”. How fast we could use the energy and how much of the energy we lose due to an imperfect system? How far we could drive? COST SAFETYPOWER / EFFICIENCY ENERGY
  • 4. CHALLENGES FOR BATTERIES ▶  Low charge / discharge rate (not quick enough for frequency regulation in grids, slow charge of EV battery) ▶  Safety concerns (fire hazard) ▶  Short lifetime (expensive to change) ▶  Low and high temperatures intolerance ▶  Low efficiency (heat generation requires expensive thermal management systems)
  • 5. Battery Ultracapacitor Battery Ultracapacitor Energy Power Cycle life Temperature performance Safety BATTERY vs ULTRACAPACITOR HOW TO CREATE A MÉLANGE OF LARGE ENERGY AND HIGH POWER?
  • 6. Effect of low inner resistance of Yunasko ultracapacitor module (A) as compared with the best competing devices (B): 1 – current flowing through battery; 2 – current flowing through ultracapacitor; 3 – total current Yunasko UC effectively unloads the battery and enhances total current (parallel connection with a battery) ULTRACAPACITOR (UC) AND BATTERY COMBINATION Parallel connection (load leveling the battery) 40 mΩ 1 mΩ UCBattery M O T O R DC
  • 7. EDLC (C-C supercapacitor, ultracapacitor) AC Active carbon (AC) AC Oxide/graphite Oxide + ACOxide + AC Asymmetric hybrid (internal serial, LIC) Symmetric hybrid (parallel LIC (//LIC) or enhanced LIB) HYBRIDIZATION: TYPES OF CAPACITOR SYSTEMS
  • 8. RESULT: energy storage system with battery-type charge- discharge curve and energy density up to 40 Wh/kg (also confirmed by tests in ITS, Davis, USA and VW Group, Germany) PARALLEL HYBRID SOLUTION LITHIUM-ION CAPACITORS OUR APPROACH: electrode level hybridization - both positive and negative electrodes comprise Li-ion and activated carbon components with thoroughly matched potential ranges: “parallel hybrid” //LIC, patent pending 8
  • 9. HIGH POWER Li-ion ULTRACAPACITOR YUNASKO //LIC Power, kW/kg 1…3 10…50 3…5 Energy, Wh/kg 60…100 5…7 30…40 Charge / discharge time 15…90 minutes 10…30 seconds 2…3 minutes Cycle life <10,000 >1,000,000 >30,000 Temperature window -20 0C…+60 0C -40 0C…+85 0C -40 0C…+60 0C HYBRIDIZATION RESULTS =
  • 10. HIGH SAFETY OF YUNASKO LIC NO thermal runaway Nail penetration test
  • 11. the most effective TECHNOLOGY COMPARISON We can safely charge energy of lead-acid battery within 2 minutes and discharge up to 150C* rate (~20s) with efficiency >80% * NOTE: C-Rate is a measure of the rate (time or current) at which a battery is charged or discharged relative to the capacity of the battery. A 1C rate means that the discharge current will discharge the entire battery in 1 hour. 11
  • 12. YUNASKO BACKGROUND AND DOMAIN COMPANY MANUFACTURING PRODUCT TECHNOLOGY ▶  Founded in 2010, in energy storage projects since 1989 ▶  40 people, 12 of them in R&D, 6 PhD: researchers & engineers ▶  Ukraine: R&D, Design Bureau and Pilot Plant ▶  London: financial and IP harbour ▶  Pilot plant in the West of Ukraine ▶  Ready to build large scale manufacture with the capacity over 4 million large cells / year ▶  Ultra high power heavy duty ultracapacitor cells from 200F to 3,000F. 3-5 times more power than competitors. ▶  16V, 48V, 90V, 112V stack and module building blocks ▶  Lithium capacitors with high energy (up to 40 Wh/kg) and power (up to 5 kW/kg) ▶  High temperature ultracapacitors with -25oC… +110oC operating temperature range ▶  Carbon / carbon ultracapacitors and lithium – ion capacitors with organic electrolytes and proprietary design ▶  Proprietary dry electrode manufacturing technology ▶  Power fusion foil (current collector) treatment technology ▶  8 patents granted and 8 patent applications filled ▶  Only commercially available, low cost components
  • 13. YUNASKO TRACTION Materials performance: simplest ultracapacitor and lithium capacitor built to show performance Prototype performance: large cells (>1 Wh) that maps to modules Device performance: pilot plant production rate reached 200 large cells/year with yield over 90% Product performance: ultracapacitor and lithium capacitors cells sold and tested by the customers Unit economics: large scale production STEPS COMPLETED 2018-2019 2015-2017 2012-2014 2010-2012 2010 Idea Seeking for a strategic partner Performance verified by independent experts: Institute of Transportation Studies, Davis, USA; Wayne State University, Detroit, USA; JME, Cleveland, USA. and customers: VW group, PSA group, Renault, BFFT - Audi, MTS Systems – Ferrari, SAFRAN, Electro Standard Labs, US Navy, MOOG, US Air Force and others, (reports available upon request) 13
  • 14. Vadim UTKIN CEO +380 67 445 3713 vu@yunasko.com yunasko.com