Over time, the fields of energetic materials, low energy nuclear reactions (LENRs), and battery technologies are gradually converging as they pursue ways to create products with vastly improved performance through utilizing processes at the micron and nanoscale.
This convergence is driven by the quest for higher energy densities in applications like portable electronics and electric vehicles. Emerging technologies like LENRs may enable revolutionary leaps in energy density beyond what is possible through chemical means alone.
The document discusses how LENRs could interact with and benefit battery technologies, presenting opportunities for both increased safety and new high-performance power sources in the future. Japanese companies are exploring using LENRs to replace internal combustion
Lattice Energy LLC - Many body collective magnetic mechanism creates ultrahig...Lewis Larsen
“The main reason why the origin of cosmic rays(CRs) is still unknown, one century after their discovery, is that they are charged nuclei isotropized by the turbulent magnetic field in the Galaxy to such a high degree that their observed flux is essentially identical in all directions, with no sources or decisive hot spots identified in any region the sky …” - Etienne Parizot (Univ. of Paris-Diderot), Nuclear Physics B (2014)
In 2008 (arXiv) and 2010 (Pramana), we derived and published approximate, rule-of-thumb formulas for calculating estimated one-shot, mean center-of-mass acceleration energies for charged particles present in plasma-filled magnetic flux tubes (also called “coronal loops”) for two cases: (1) steady-state and (2) explosive destruction of an unstable flux tube (this second case is subset of “magnetic reconnection” processes).
Our simple equations for magnetic flux tubes are robust and scale-independent. They consequently have broad applicability from exploding wires (which in early stages of explosion comprise dense dusty plasmas), lightning, to solar flux tubes and other astrophysical environments that are characterized by vastly higher magnetic fields; these include many other types of stars besides the Sun, neutron stars, magnetars, and regions located near black holes and active galactic nuclei.
Herein we show how plasma-filled magnetic flux tubes likely occur in many different astrophysical systems from relatively small objects (neutron stars and magnetars) to relatively large objects (accretion disks and jet bases of supermassive black holes). When these ordered magnetic structures explode (reconnection, flares), enormous amounts of magnetic energy are converted into kinetic energy of charged particles present inside exploding flux tubes. Using reasonable parametric assumptions, we calculate one-shot, center-of-mass acceleration energies for protons in collapsing protoneutron stars (5.5 x 1018 eV), two cases for BH accretion disks (2.2 x 1017 eV and 0.9 x 1019 eV), and finally for the jet base of a supermassive black hole (2.2 x 1021eV).
What all these numbers suggest, including those for the Sun, is that W-L-S particle acceleration mechanism for magnetic flux tubes can create cosmic ray particles at energies that span the entire cosmic-ray energy spectrum from top to bottom. This argues that commonplace flux tubes may well play a significant role in generating the observed cosmic ray energy spectrum and would be consistent with apparent overall anisotropy of sources at all but the very highest particle energies. That said, we think a number of different acceleration mechanisms likely contribute to entire spectrum, including shock acceleration and perhaps exotic mechanisms such as evaporation of gaseous winds from neutron stars (Widom et al. arXiv:1410.6498v2 -2015).
Lattice Energy LLC - Mystery of Nagaokas 1920s Gold Experiments - Why Did Wor...Lewis Larsen
In a recorded interview with fellow physicist Prof. John Wheeler in 1962, Nobel prize-winning Japanese physicist Hideki Yukawa said that his colleague Hantaro Nagaoka in the 1930s was (quoting directly), “…“I think Professor Nagaoka was all powerful then among scientists … he had some very deep insight, although he did not work himself [at that point in his career] … Nagaoka was [the] President of Osaka University when I moved from Kyoto to Osaka. But he was at the same time President of the Academy; he was the greatest boss among all the scientists in Japan.”
Between September 1924 and June 1925, Nagaoka and his co-workers at RIKEN in Japan conducted some 200 experiments with high-current electric arc discharges between Tungsten electrodes immersed in liquid hydrocarbon transformer oil in which they detected successful transmutation of Tungsten into macroscopic, visible flecks of Gold and Platinum. In June 1925, Nagaoka went a world tour in which he spoke to scientific and lay audiences about their transmutation experiments in Japan and handed-out samples comprising small pieces of porcelain reactor vessels with tiny bits of adhering Gold that had been created therein. In July 1925, “Nature” published his Letter to the Editors in which he reported on their results and encouraged other scientists to try to repeat their provocative experiments.
Amazingly, as far as we can tell no one ever tried to repeat Nagaoka et al.’s landmark experiments. Even more incredibly, the entire area of inquiry involving electric discharge-triggered transmutations of elements essentially died-out worldwide by 1930 (Chadwick discovered the neutron in 1932 and transmutation via neutron-capture was first elucidated by Taylor in 1935). In this document, we explore some of the possible underlying reasons that may have caused this totally unexpected historical twist.
In 2004, Cirillo & Iorio (Italy) transmuted Tungsten into Rhenium, Osmium, and Gold in a modern, roughly equivalent version of Nagaoka’s electric arc discharge experiments. In 2012 at an American Nuclear Society meeting, using a very different type of gaseous D2 thin-film permeation experimental method it had pioneered in back 2002, Mitsubishi Heavy Industries reported transmutation of implanted Tungsten targets into Osmium and Platinum.
Widom & Larsen theory of neutron-catalyzed low energy nuclear reactions (as published in the “European Physical Journal C – Particles and Fields” - 2006 and in “Pramana – Journal of Physics” – 2010) both predicts and explains all of this earlier experimental transmutation data with Tungsten targets.
If a modern repetition of Nagaoka et al.’s 1920s experiments produced encouraging results, commercial transmutation of Gold might not be very far in the future. That said, as in many cases--- time will tell --- and as they say in Russia, “We shall live and we shall see.”
Lattice Energy LLC - Strategic importance of accelerating commercialization o...Lewis Larsen
Prospects for commercialization of LENRs have radically improved. New Lattice report “Strategic importance of accelerating commercialization of LENRs for green radiation-free nuclear power and propulsion” aims at a broad audience and outlines strategic case for greatly increasing R&D funding to accelerate development of ultralow energy neutron reactions (LENRs) for CO2-free power generation. Recent Japanese government-funded NEDO project solved previously intractable problems with rational device design & fabrication, experimental repeatability, and erratic, limited thermal output that bedeviled researchers worldwide since 1989-90.
Given spectacular Japanese progress, it appears very likely that LENRs will be commercialized, probably sooner rather than later. Today, Japan is by far the experimental leader along that path; heavily involved companies include Mitsubishi Heavy industries, Toyota, and Nissan..
Lattice Energy LLC - 1994 conference paper - Prof John Dash reported producti...Lewis Larsen
Synopsis: In a ‘lost’ conference paper published 23 years ago, Prof. John Dash et al. correctly concluded that “slow neutrons” were responsible for creating Gold and Silver transmutation products that were clearly observed in electrochemical cells that had been electrolyzed for 400 hours. However, they mistakenly thought that such neutrons were produced by a nuclear fusion process.
More recently, Mitsubishi Heavy Industries (MHI) has used a proprietary gas permeation method for LENR transmutation of Tungsten to Osmium and finally to Platinum. However, MHI’s ultralow energy neutron fluxes in Deuterium gas permeation cleanroom systems were not quite high enough to proceed all the way down the neutron-catalyzed LENR transmutation pathway to reach Gold like Dash et al.
Mitsubishi is presently pushing aggressively to increase LENR transmutation rates and product yields in laboratory devices. In a recent company technical bulletin, the company revealed that transmutation product yields had been increased by nearly 3 orders of magnitude in 3 years by shifting from gas to electrochemical permeation through a thin-film metal-oxide sandwich structure (see slides #34 - 36). Interestingly, to achieve this increase in yields, MHI unknowingly followed guidelines that were already spelled-out in a Widom-Larsen theory rate calculation paper published back in 2007 (slide #33).
Since MHI is also using semiconductor-like fabrication methods, cleanrooms, and some nanotech to build devices and increase transmutation product yields, it begs the question of whether there are any parallels between today’s primitive LENR devices and the historical development of transistors in the semiconductor industry. Well, there are.
Slides #37 – 43 explain how --- in certain ways --- LENR active sites really do resemble electronic transistors used in microchips. I also discuss what this unexpected similarity may mean for future development and commercialization of LENRs for power generation. Amazingly, some aspects of future transistors and LENR device technology will probably converge and perhaps even strongly overlap.
Lattice Energy LLC - Neutron production and nucleosynthesis in electric disch...Lewis Larsen
LENR transmutations can occur all around us. Neutrons can be created when Hydrogen atoms (protons) are present within many different types of electric discharges that can include among diverse other things: atmospheric lightning on earth and other planets, arcs between electrodes in air, water, hydrocarbons, as well as in nano-arcs (internal shorts) that can occur in electrochemical batteries.
Lattice Energy LLC- Technical Discussion-Oct 1 Tesla Motors Model S Battery T...Lewis Larsen
On October 1, 2013, in Kent, WA USA while traveling down a 4-lane state highway during morning rush-hour, a Tesla Model S sedan experienced a battery thermal runaway and ensuing fire with 6-foot high flames that destroyed the front hood area of the vehicle.
To explain why its much-heralded battery safety systems were unable to prevent the occurrence of a potentially dangerous battery thermal runaway and fire that disabled and destroyed key parts of a full-sized vehicle within a span of several minutes, Tesla proposed a theory for the event. It explains the runaway as having been caused by the car’s driver accidentally running over piece of road debris - “large metallic object” - that had been lying on the highway surface. In Tesla’s theory, this hypothetical metal object somehow rotated upwards, slammed into the car’s armored underbody with 25 tons of force, and then pierced a module in the car’s battery pack, which triggered a thermal runaway and fire.
Lattice’s alternative theory for the October 1 model S runaway incident posits that: field-failure internal electrical short (whatever its proximate cause might truly be) occurred in a single 18650 cell that was located somewhere in first front module of vehicle’s battery pack. This field-failure-triggered event caused catastrophic overheating of the affected cell, creating huge local temperature increase within a few seconds that eventually wreaked havoc within the immediate module.
Importantly, propagation of field-failure-induced super-hot runaway conditions into adjacent cells (“thermal fratricide”) within same battery pack module was slowed rather significantly by Tesla’s multi-tier, very sophisticated battery safety system engineering discussed herein. The consequent retardation of thermal propagation between cells by safety features built into the battery pack lengthened the runaway event timeline by > 2 - 3 minutes, which was observed on Oct. 1.
In this incident, Lattice believes that the Model S battery pack encountered something very different from “garden variety” thermal runaways (see Appendix 1 in this presentation for definitions and details) that Tesla’s otherwise brilliant system safety engineering was designed to thwart.
What probably occurred on Oct. 1 was very likely a much rarer, deadlier type of thermal runaway called a ‘field-failure” (again, see Appendix 1). What distinguishes field-failures from ‘ordinary’ thermal runaways are vastly higher peak temperatures in conjunction with electric arc discharges. The best that can be hoped-for under such circumstances is that a battery fails relatively ‘gracefully’ without detonating, as happened on Oct. 1, 2013.
Lattice Energy LLC - LENR transmutation of Carbon better energy strategy than...Lewis Larsen
While Obama’s new clean power plan is certainly very well-intentioned, it implicitly throws the fossil fuel industry “under the bus,” naively assumes that wind and solar power will take up the slack at reasonable cost, and does not really attempt to develop radical new sources of low-cost energy.
Rather than eventually replacing fossil fuels with solar, wind, and renewable energy sources over time, LENR technology instead enables oil, gas, and coal producers to convert fossil fuels into cleaner, more valuable form of CO2-free LENR energy --- energy producers, energy consumers, and Mother Earth all win.
While solar PV and wind are CO2-free and extremely biosafe, their intrinsic energy densities are much lower than today’s fossil fuels and inherently intermittent --- not continuous --- sources of electrical and thermal power. Solar and wind renewables therefore simply cannot 100% replace fossil energy sources without enormous economic disruption and gigantic increases in energy costs.
LENRs are the only primary energy technology on foreseeable horizon that could provide the world with affordable dense green energy, connect the unconnected, and empower billions of now powerless, energy-poor people
Lattice’s strategy for replacing today’s combustion with LENR transmutation of Carbon saves the fossil fuel industry yet is highly synergistic with renewables, enables sustainable economic growth, and helps to ameliorate CO2-driven climate change.
Lattice Energy LLC - Many body collective magnetic mechanism creates ultrahig...Lewis Larsen
“The main reason why the origin of cosmic rays(CRs) is still unknown, one century after their discovery, is that they are charged nuclei isotropized by the turbulent magnetic field in the Galaxy to such a high degree that their observed flux is essentially identical in all directions, with no sources or decisive hot spots identified in any region the sky …” - Etienne Parizot (Univ. of Paris-Diderot), Nuclear Physics B (2014)
In 2008 (arXiv) and 2010 (Pramana), we derived and published approximate, rule-of-thumb formulas for calculating estimated one-shot, mean center-of-mass acceleration energies for charged particles present in plasma-filled magnetic flux tubes (also called “coronal loops”) for two cases: (1) steady-state and (2) explosive destruction of an unstable flux tube (this second case is subset of “magnetic reconnection” processes).
Our simple equations for magnetic flux tubes are robust and scale-independent. They consequently have broad applicability from exploding wires (which in early stages of explosion comprise dense dusty plasmas), lightning, to solar flux tubes and other astrophysical environments that are characterized by vastly higher magnetic fields; these include many other types of stars besides the Sun, neutron stars, magnetars, and regions located near black holes and active galactic nuclei.
Herein we show how plasma-filled magnetic flux tubes likely occur in many different astrophysical systems from relatively small objects (neutron stars and magnetars) to relatively large objects (accretion disks and jet bases of supermassive black holes). When these ordered magnetic structures explode (reconnection, flares), enormous amounts of magnetic energy are converted into kinetic energy of charged particles present inside exploding flux tubes. Using reasonable parametric assumptions, we calculate one-shot, center-of-mass acceleration energies for protons in collapsing protoneutron stars (5.5 x 1018 eV), two cases for BH accretion disks (2.2 x 1017 eV and 0.9 x 1019 eV), and finally for the jet base of a supermassive black hole (2.2 x 1021eV).
What all these numbers suggest, including those for the Sun, is that W-L-S particle acceleration mechanism for magnetic flux tubes can create cosmic ray particles at energies that span the entire cosmic-ray energy spectrum from top to bottom. This argues that commonplace flux tubes may well play a significant role in generating the observed cosmic ray energy spectrum and would be consistent with apparent overall anisotropy of sources at all but the very highest particle energies. That said, we think a number of different acceleration mechanisms likely contribute to entire spectrum, including shock acceleration and perhaps exotic mechanisms such as evaporation of gaseous winds from neutron stars (Widom et al. arXiv:1410.6498v2 -2015).
Lattice Energy LLC - Mystery of Nagaokas 1920s Gold Experiments - Why Did Wor...Lewis Larsen
In a recorded interview with fellow physicist Prof. John Wheeler in 1962, Nobel prize-winning Japanese physicist Hideki Yukawa said that his colleague Hantaro Nagaoka in the 1930s was (quoting directly), “…“I think Professor Nagaoka was all powerful then among scientists … he had some very deep insight, although he did not work himself [at that point in his career] … Nagaoka was [the] President of Osaka University when I moved from Kyoto to Osaka. But he was at the same time President of the Academy; he was the greatest boss among all the scientists in Japan.”
Between September 1924 and June 1925, Nagaoka and his co-workers at RIKEN in Japan conducted some 200 experiments with high-current electric arc discharges between Tungsten electrodes immersed in liquid hydrocarbon transformer oil in which they detected successful transmutation of Tungsten into macroscopic, visible flecks of Gold and Platinum. In June 1925, Nagaoka went a world tour in which he spoke to scientific and lay audiences about their transmutation experiments in Japan and handed-out samples comprising small pieces of porcelain reactor vessels with tiny bits of adhering Gold that had been created therein. In July 1925, “Nature” published his Letter to the Editors in which he reported on their results and encouraged other scientists to try to repeat their provocative experiments.
Amazingly, as far as we can tell no one ever tried to repeat Nagaoka et al.’s landmark experiments. Even more incredibly, the entire area of inquiry involving electric discharge-triggered transmutations of elements essentially died-out worldwide by 1930 (Chadwick discovered the neutron in 1932 and transmutation via neutron-capture was first elucidated by Taylor in 1935). In this document, we explore some of the possible underlying reasons that may have caused this totally unexpected historical twist.
In 2004, Cirillo & Iorio (Italy) transmuted Tungsten into Rhenium, Osmium, and Gold in a modern, roughly equivalent version of Nagaoka’s electric arc discharge experiments. In 2012 at an American Nuclear Society meeting, using a very different type of gaseous D2 thin-film permeation experimental method it had pioneered in back 2002, Mitsubishi Heavy Industries reported transmutation of implanted Tungsten targets into Osmium and Platinum.
Widom & Larsen theory of neutron-catalyzed low energy nuclear reactions (as published in the “European Physical Journal C – Particles and Fields” - 2006 and in “Pramana – Journal of Physics” – 2010) both predicts and explains all of this earlier experimental transmutation data with Tungsten targets.
If a modern repetition of Nagaoka et al.’s 1920s experiments produced encouraging results, commercial transmutation of Gold might not be very far in the future. That said, as in many cases--- time will tell --- and as they say in Russia, “We shall live and we shall see.”
Lattice Energy LLC - Strategic importance of accelerating commercialization o...Lewis Larsen
Prospects for commercialization of LENRs have radically improved. New Lattice report “Strategic importance of accelerating commercialization of LENRs for green radiation-free nuclear power and propulsion” aims at a broad audience and outlines strategic case for greatly increasing R&D funding to accelerate development of ultralow energy neutron reactions (LENRs) for CO2-free power generation. Recent Japanese government-funded NEDO project solved previously intractable problems with rational device design & fabrication, experimental repeatability, and erratic, limited thermal output that bedeviled researchers worldwide since 1989-90.
Given spectacular Japanese progress, it appears very likely that LENRs will be commercialized, probably sooner rather than later. Today, Japan is by far the experimental leader along that path; heavily involved companies include Mitsubishi Heavy industries, Toyota, and Nissan..
Lattice Energy LLC - 1994 conference paper - Prof John Dash reported producti...Lewis Larsen
Synopsis: In a ‘lost’ conference paper published 23 years ago, Prof. John Dash et al. correctly concluded that “slow neutrons” were responsible for creating Gold and Silver transmutation products that were clearly observed in electrochemical cells that had been electrolyzed for 400 hours. However, they mistakenly thought that such neutrons were produced by a nuclear fusion process.
More recently, Mitsubishi Heavy Industries (MHI) has used a proprietary gas permeation method for LENR transmutation of Tungsten to Osmium and finally to Platinum. However, MHI’s ultralow energy neutron fluxes in Deuterium gas permeation cleanroom systems were not quite high enough to proceed all the way down the neutron-catalyzed LENR transmutation pathway to reach Gold like Dash et al.
Mitsubishi is presently pushing aggressively to increase LENR transmutation rates and product yields in laboratory devices. In a recent company technical bulletin, the company revealed that transmutation product yields had been increased by nearly 3 orders of magnitude in 3 years by shifting from gas to electrochemical permeation through a thin-film metal-oxide sandwich structure (see slides #34 - 36). Interestingly, to achieve this increase in yields, MHI unknowingly followed guidelines that were already spelled-out in a Widom-Larsen theory rate calculation paper published back in 2007 (slide #33).
Since MHI is also using semiconductor-like fabrication methods, cleanrooms, and some nanotech to build devices and increase transmutation product yields, it begs the question of whether there are any parallels between today’s primitive LENR devices and the historical development of transistors in the semiconductor industry. Well, there are.
Slides #37 – 43 explain how --- in certain ways --- LENR active sites really do resemble electronic transistors used in microchips. I also discuss what this unexpected similarity may mean for future development and commercialization of LENRs for power generation. Amazingly, some aspects of future transistors and LENR device technology will probably converge and perhaps even strongly overlap.
Lattice Energy LLC - Neutron production and nucleosynthesis in electric disch...Lewis Larsen
LENR transmutations can occur all around us. Neutrons can be created when Hydrogen atoms (protons) are present within many different types of electric discharges that can include among diverse other things: atmospheric lightning on earth and other planets, arcs between electrodes in air, water, hydrocarbons, as well as in nano-arcs (internal shorts) that can occur in electrochemical batteries.
Lattice Energy LLC- Technical Discussion-Oct 1 Tesla Motors Model S Battery T...Lewis Larsen
On October 1, 2013, in Kent, WA USA while traveling down a 4-lane state highway during morning rush-hour, a Tesla Model S sedan experienced a battery thermal runaway and ensuing fire with 6-foot high flames that destroyed the front hood area of the vehicle.
To explain why its much-heralded battery safety systems were unable to prevent the occurrence of a potentially dangerous battery thermal runaway and fire that disabled and destroyed key parts of a full-sized vehicle within a span of several minutes, Tesla proposed a theory for the event. It explains the runaway as having been caused by the car’s driver accidentally running over piece of road debris - “large metallic object” - that had been lying on the highway surface. In Tesla’s theory, this hypothetical metal object somehow rotated upwards, slammed into the car’s armored underbody with 25 tons of force, and then pierced a module in the car’s battery pack, which triggered a thermal runaway and fire.
Lattice’s alternative theory for the October 1 model S runaway incident posits that: field-failure internal electrical short (whatever its proximate cause might truly be) occurred in a single 18650 cell that was located somewhere in first front module of vehicle’s battery pack. This field-failure-triggered event caused catastrophic overheating of the affected cell, creating huge local temperature increase within a few seconds that eventually wreaked havoc within the immediate module.
Importantly, propagation of field-failure-induced super-hot runaway conditions into adjacent cells (“thermal fratricide”) within same battery pack module was slowed rather significantly by Tesla’s multi-tier, very sophisticated battery safety system engineering discussed herein. The consequent retardation of thermal propagation between cells by safety features built into the battery pack lengthened the runaway event timeline by > 2 - 3 minutes, which was observed on Oct. 1.
In this incident, Lattice believes that the Model S battery pack encountered something very different from “garden variety” thermal runaways (see Appendix 1 in this presentation for definitions and details) that Tesla’s otherwise brilliant system safety engineering was designed to thwart.
What probably occurred on Oct. 1 was very likely a much rarer, deadlier type of thermal runaway called a ‘field-failure” (again, see Appendix 1). What distinguishes field-failures from ‘ordinary’ thermal runaways are vastly higher peak temperatures in conjunction with electric arc discharges. The best that can be hoped-for under such circumstances is that a battery fails relatively ‘gracefully’ without detonating, as happened on Oct. 1, 2013.
Lattice Energy LLC - LENR transmutation of Carbon better energy strategy than...Lewis Larsen
While Obama’s new clean power plan is certainly very well-intentioned, it implicitly throws the fossil fuel industry “under the bus,” naively assumes that wind and solar power will take up the slack at reasonable cost, and does not really attempt to develop radical new sources of low-cost energy.
Rather than eventually replacing fossil fuels with solar, wind, and renewable energy sources over time, LENR technology instead enables oil, gas, and coal producers to convert fossil fuels into cleaner, more valuable form of CO2-free LENR energy --- energy producers, energy consumers, and Mother Earth all win.
While solar PV and wind are CO2-free and extremely biosafe, their intrinsic energy densities are much lower than today’s fossil fuels and inherently intermittent --- not continuous --- sources of electrical and thermal power. Solar and wind renewables therefore simply cannot 100% replace fossil energy sources without enormous economic disruption and gigantic increases in energy costs.
LENRs are the only primary energy technology on foreseeable horizon that could provide the world with affordable dense green energy, connect the unconnected, and empower billions of now powerless, energy-poor people
Lattice’s strategy for replacing today’s combustion with LENR transmutation of Carbon saves the fossil fuel industry yet is highly synergistic with renewables, enables sustainable economic growth, and helps to ameliorate CO2-driven climate change.
Lattice Energy LLC - LENRs are revolutionary disruptive energy technology for...Lewis Larsen
Safe, radiation-free ultralow energy neutron reactions (LENRs) expand use of nuclear power & propulsion into huge range of land vehicles, aircraft, watercraft, and spacecraft. Scales downward from large fission reactors used in nuclear naval aircraft carriers and submarines. Enormous energy densities of LENR-based power & propulsion technology could confer decisive combat systems advantages on near-future battlefields.
Lattice Energy LLC - Production of Gold via LENR transmutation of Platinum in...Lewis Larsen
Presently, unbeknownst to unsuspecting drivers worldwide, green LENR transmutation processes are occurring at very low rates during operation of three-way catalytic converters installed in over a billion cars and trucks.
Radiation-free nuclear transmutation of chemical elements by LENRs inside catalytic converters is strongly indicated by the presence of anomalous Gold, excess radiogenic Osmium, and shifts toward heavier isotopes that have been reported in Platinum and Palladium found in micron-scale nanoparticles that are emitted from vehicle exhaust pipes.
Extensive sampling and chemical analysis of certain roadway dust and roadside soils by environmental scientists have revealed that in scattered locations nanoparticulate Gold emitted from motor vehicle exhaust has accumulated to the point where local concentrations of this precious metal nearing key minimum threshold of 0.5 ppm needed for economic Gold ore.
This surprising nuclear activity in ubiquitous catalytic converters and absence of deleterious consequences for drivers or Earth’s environment argue that world is already safely coexisting with LENRs. This supports idea that LENRs could potentially be a very attractive future source of green nuclear energy if the technology is successfully commercialized.
Lattice Energy LLC- Containment of Lithium-based Battery Fires-A Fools Paradi...Lewis Larsen
Focus is on thermal runaways in primary and secondary lithium-based batteries; includes:
• High-level historical overview: battery chemistries and increased energy density
• Peak temperatures that can possibly be reached during thermal runaway events
• Scaling-up electrical storage capacities can cause increases in safety-related risks
• Different causes of thermal runaways
• Examples of runaways involving portable devices and various mobile platforms
• Runaways in advanced Boeing 787 aircraft
• Incident examples: worst-of-the-worst
• Analysis and commentary on Boeing 787 Dreamliner’s battery containment system
The transportation industry continues to adopt more supercapacitors into their designs each year. Advantages in power density, cold temperature performance, and lifetime make them suitable for accompanying or replacing a battery bank.
This presentation introduces what a supercapacitor is (it isn't just a big capacitor!), some characteristics to consider, and two applications of ELDCs.
This paper was presented by KEMET at the 2015 Applied Power Electronic Conference in Charlotte, NC.
Lattice Energy LLC - Widom-Larsen theory reveals surprising similarities and ...Lewis Larsen
Widom-Larsen theory unveils additional surprising similarities and connections between LENRs and chemical catalysis.
Synopsis: recent extensions of the Widom-Larsen theory of LENRs have for the first time revealed additional striking and unexpected similarities between electroweak nuclear catalysis --- collective many-body en + pn reaction in condensed matter --- and enzymatic catalysis, inorganic chemical catalysis, plasmon-mediated chemical photocatalysis with “hot” charge carriers, as well as widely published nanotechnology concept of heterometallic plasmonic antenna-reactor nanoparticles for photocatalysis. Among a number of surprising commonalities between LENRs and chemical catalytic processes, many-body collective quantum effects and high local electric fields > 1010 V/m enable many chemical reactions and LENRs to proceed with substantial rates at vastly lower working temperatures and pressures. Existence of all these unexpected parallels suggests that valuable engineering insights can be obtained by data mining state-of-the art technical knowledge about nanotech and chemical catalysis and then applying and leveraging new insights derived therefrom to help accelerate future development of LENRs for power generation.
Lattice Energy LLC - Scalability of LENR power generation systems - Nov 29 2015Lewis Larsen
Lattice shows how LENR power generation systems could someday scale-up from today’s primitive milliwatt thermal devices to kwh and megawatts of electrical output.
In this PowerPoint presentation, we outline how substantial scale-up of LENR (safe ultralow energy neutron reactions) power generation systems from today’s primitive milliwatt thermal devices to kwh and megawatts is a feasible goal in the near-future. LENR reactors would be vastly smaller and less expensive than equivalent fission counterparts with comparable thermal output.
D-T fusion reactors like ITER and other similar Tokamaks mainly create heat by harvesting the kinetic energy of deadly 14.1 MeV neutrons. Consequently, they require massive shielding and containment systems for safe operation and unsurprisingly have enormous costs and unavoidably huge physical size. Given that the radiation-free Lithium LENR fuel cycle releases nearly 27 MeV versus a total Q-value of 17.6 MeV for the D-T fusion reaction, it is hard to imagine a sound economic argument for spending 100s of billions on commercial fusion reactors if LENR technology is successfully developed and scaled-up as we have outlined herein.
Lack of hard radiation and radioactive wastes permit downward scalability that could enable future development of revolutionary, compact battery-like portable LENR power sources that can compete directly on $ price/kwh with chemical batteries in many applications including power tools, tablets, and smartphones.
Lattice Energy LLC - LENRs are revolutionary disruptive energy technology for...Lewis Larsen
Safe, radiation-free ultralow energy neutron reactions (LENRs) expand use of nuclear power & propulsion into huge range of land vehicles, aircraft, watercraft, and spacecraft. Scales downward from large fission reactors used in nuclear naval aircraft carriers and submarines. Enormous energy densities of LENR-based power & propulsion technology could confer decisive combat systems advantages on near-future battlefields.
Lattice Energy LLC - Production of Gold via LENR transmutation of Platinum in...Lewis Larsen
Presently, unbeknownst to unsuspecting drivers worldwide, green LENR transmutation processes are occurring at very low rates during operation of three-way catalytic converters installed in over a billion cars and trucks.
Radiation-free nuclear transmutation of chemical elements by LENRs inside catalytic converters is strongly indicated by the presence of anomalous Gold, excess radiogenic Osmium, and shifts toward heavier isotopes that have been reported in Platinum and Palladium found in micron-scale nanoparticles that are emitted from vehicle exhaust pipes.
Extensive sampling and chemical analysis of certain roadway dust and roadside soils by environmental scientists have revealed that in scattered locations nanoparticulate Gold emitted from motor vehicle exhaust has accumulated to the point where local concentrations of this precious metal nearing key minimum threshold of 0.5 ppm needed for economic Gold ore.
This surprising nuclear activity in ubiquitous catalytic converters and absence of deleterious consequences for drivers or Earth’s environment argue that world is already safely coexisting with LENRs. This supports idea that LENRs could potentially be a very attractive future source of green nuclear energy if the technology is successfully commercialized.
Lattice Energy LLC- Containment of Lithium-based Battery Fires-A Fools Paradi...Lewis Larsen
Focus is on thermal runaways in primary and secondary lithium-based batteries; includes:
• High-level historical overview: battery chemistries and increased energy density
• Peak temperatures that can possibly be reached during thermal runaway events
• Scaling-up electrical storage capacities can cause increases in safety-related risks
• Different causes of thermal runaways
• Examples of runaways involving portable devices and various mobile platforms
• Runaways in advanced Boeing 787 aircraft
• Incident examples: worst-of-the-worst
• Analysis and commentary on Boeing 787 Dreamliner’s battery containment system
The transportation industry continues to adopt more supercapacitors into their designs each year. Advantages in power density, cold temperature performance, and lifetime make them suitable for accompanying or replacing a battery bank.
This presentation introduces what a supercapacitor is (it isn't just a big capacitor!), some characteristics to consider, and two applications of ELDCs.
This paper was presented by KEMET at the 2015 Applied Power Electronic Conference in Charlotte, NC.
Lattice Energy LLC - Widom-Larsen theory reveals surprising similarities and ...Lewis Larsen
Widom-Larsen theory unveils additional surprising similarities and connections between LENRs and chemical catalysis.
Synopsis: recent extensions of the Widom-Larsen theory of LENRs have for the first time revealed additional striking and unexpected similarities between electroweak nuclear catalysis --- collective many-body en + pn reaction in condensed matter --- and enzymatic catalysis, inorganic chemical catalysis, plasmon-mediated chemical photocatalysis with “hot” charge carriers, as well as widely published nanotechnology concept of heterometallic plasmonic antenna-reactor nanoparticles for photocatalysis. Among a number of surprising commonalities between LENRs and chemical catalytic processes, many-body collective quantum effects and high local electric fields > 1010 V/m enable many chemical reactions and LENRs to proceed with substantial rates at vastly lower working temperatures and pressures. Existence of all these unexpected parallels suggests that valuable engineering insights can be obtained by data mining state-of-the art technical knowledge about nanotech and chemical catalysis and then applying and leveraging new insights derived therefrom to help accelerate future development of LENRs for power generation.
Lattice Energy LLC - Scalability of LENR power generation systems - Nov 29 2015Lewis Larsen
Lattice shows how LENR power generation systems could someday scale-up from today’s primitive milliwatt thermal devices to kwh and megawatts of electrical output.
In this PowerPoint presentation, we outline how substantial scale-up of LENR (safe ultralow energy neutron reactions) power generation systems from today’s primitive milliwatt thermal devices to kwh and megawatts is a feasible goal in the near-future. LENR reactors would be vastly smaller and less expensive than equivalent fission counterparts with comparable thermal output.
D-T fusion reactors like ITER and other similar Tokamaks mainly create heat by harvesting the kinetic energy of deadly 14.1 MeV neutrons. Consequently, they require massive shielding and containment systems for safe operation and unsurprisingly have enormous costs and unavoidably huge physical size. Given that the radiation-free Lithium LENR fuel cycle releases nearly 27 MeV versus a total Q-value of 17.6 MeV for the D-T fusion reaction, it is hard to imagine a sound economic argument for spending 100s of billions on commercial fusion reactors if LENR technology is successfully developed and scaled-up as we have outlined herein.
Lack of hard radiation and radioactive wastes permit downward scalability that could enable future development of revolutionary, compact battery-like portable LENR power sources that can compete directly on $ price/kwh with chemical batteries in many applications including power tools, tablets, and smartphones.
Lattice Energy LLC - Japanese NEDO LENR project reported reasonably reproduci...Lewis Larsen
Japan’s NEDO industry-academia-government R&D program’s recent experimental results technically validated potential for LENRs to become major future energy source.
Excess heat was produced in ~ 80% of project’s reported LENR experiments. Whenever excess heat was created, it is most often at Watt-levels or better at reactor operating temperatures of 200 - 300 degrees C. Duration of excess heat production ranged up to weeks, which is non-trivial. Such LENR device behavior represents excellent reproducibility for complex early-stage technology. With respect to reproducibility of device fabrication methods and heat production, these are best-ever experimental results reported to date in field of LENRs.
Watt-level excess heat was produced in Hydrogen (H)- and Deuterium (D)-loaded experimental systems. No deadly energetic (MeV-energy) gamma or neutron radiation was detected during heat production in any project experimental runs. Such observations are consistent with and predicted by the Widom-Larsen theory of LENRs which posits production and capture of ultralow energy neutrons on ‘fuel’ atoms which drive hard-radiation-free nuclear transmutation reactions and decays that release nuclear binding energy in form of copious heat.
In Lattice’s opinion, NEDO project’s outstanding experimental results change LENRs’ Technology Readiness Level (TRL) from TRL-3 to TRL-4 (European Commission definitions). This is an important step in commercialization of LENRs for power generation applications.
Lattice Energy LLC Company Vision-September 11 2011Lewis Larsen
Lattice Energy LLC's company vision of commercializing Low Energy Nuclear Reactions (LENRs): what key milestones remain and why are we doing this? It's not just about money.
Lattice Energy LLC - LENR technology could help justify 2 trillion valuation ...Lewis Larsen
LENR technology could help justify Crown Prince Mohammed bin Salman’s proposed US$ 2 trillion valuation for Saudi Aramco in planned 2018 company IPO.
Some outsiders and company insiders believe IPO valuation of US$ 400 billion up to maximum of 1.5 trillion are more realistic numbers. To the contrary, announcing major new R&D program in LENR technology by Aramco prior to IPO could boost valuation by increasing perceived future growth prospects and potentially enabling future production and sale of new types of revolutionary nanoparticulate CO2-free fuels derived from oil. These aromatic Carbon LENR fuels for transportation and power generation applications would have over 5,000x the energy density of gasoline.
Lattice Energy LLC - Green hard-radiation-free len rs could provide game-chan...Lewis Larsen
Green hard-radiation-free ultralow energy neutron reactions (LENRs) could provide game-changing nuclear power for military combat systems ranging from aircraft to individual warfighters. LENRs are the only energy technology on the foreseeable horizon that could provide a quantum-leap in military power generation and propulsion capabilities in the 2030 - 2050 time-frame.
Lattice Energy LLC - Revolutionary LENRs for power generation - accelerating ...Lewis Larsen
Commercialization of radiation-free ultralow energy neutron reactions (LENRs) for power generation could potentially occur with surprising speed. In just 2.5 years, Japanese government NEDO-funded LENR device fabrication and testing project achieved TRL-4 (refuting the skeptics) and validated application of Widom-Larsen theory, materials science, and nanotech to help accelerate commercialization pathway from present developmental level of TRL-4 to future commercial LENR-based products at TRL-9.
Lattice Energy LLC - LENR technologys compelling value proposition for oil an...Lewis Larsen
LENRs offer a compelling future value proposition for oil & gas companies. Technology of ultralow energy neutron reactions (LENRs) could enable conversion of aromatics derived from crude oil and natural gas into nanoparticulate LENR fuels with energy densities that are 5,000x greater than gasoline.
Achievement of this unprecedented capability could vastly increase performance of customers’ power generation systems as well as enable the rapid future development of many types of revolutionary products suitable for array of key consumer and military markets.
LENR technology could also stretch useful economic lifetimes of today’s remaining in-ground supplies of oil & gas from British Petroleum's 2016 estimate of < 53 years out to at least another 25,000 years further into far future.
Lattice Energy LLC - Compelling Economics of Transmutation vs Combustion of C...Lewis Larsen
Revolutionary LENR technology can potentially transform oil and coal into ‘green’ CO2-free LENR fuels that possess >5,000x the energy density (Watt*hours/kg) of unleaded gasoline.
In LENR fuels derived from extraction and processing of aromatic fractions found in oil and coal, generation of thermal heat energy occurs via clean radiation-free, neutron-catalyzed transmutation of Carbon into Nitrogen and Oxygen rather than chemical combustion with O2.
Herein we show how applied LENR technology can potentially increase the economic value of natural fossil Carbonaceous energy sources by at least 500x; much of this increase in energetic economic value comes from enormous energy densities and BTUs produced by nuclear processes as compared to purely chemical energy processes such as combustion.
In British Petroleum's 63rd annual Statistical Review of World Energy (2014) they estimated that oil will run-out in ~53 years and coal in ~113 years. Given at least 500x increase in the energetic economic value of LENR fuel, commercialization of LENRs on aromatic molecules would extend useful economic lifetime of fossil Carbon sources out to at least 25,000 years.
Commercialization of LENRs occurring on aromatic rings would eliminate the so-called “Carbon Bubble” and fossil fuel “stranded asset” problems that during the past few years have begun to concern certain financial players that even include the Bank of England.
Lattice Energy LLC - March 2 Technova seminar in Tokyo released more info re ...Lewis Larsen
Japan’s NEDO-sponsored LENR device project released additional technical details at Technova seminar held in Tokyo on March 2, 2018. Japanese government is targeting commercialization of LENRs as a revolutionary, radiation-free nuclear technology for use in power generation and propulsion applications. NEDO project results to date have demonstrated Watt-level reproducibility of excess heat in small nanocomposite LENR devices. Assuming substantial scale-up of device heat output is possible, NEDO project’s technical achievement validates future potential for LENRs to someday become an important source of green CO2-free energy.
Lattice Energy LLC - Battery energy density - product safety - thermal runawa...Lewis Larsen
Global quest to improve performance drives battery R&D toward ever-higher energy densities. High gravimetric energy density rewards battery users with lighter portable or mobile power sources and longer operating times between recharges. Product safety & reliability could be the hidden costs --- higher energy density is a two-edged sword that cuts both ways. Internal electrical shorts, hot sparks, and catastrophic electric arcs are reducing durability and causing thermal runaways, fires, and even explosions in Lithium-ion batteries. Ultralow energy neutron reactions (LENRs) may be causing some of these extreme events; engineering for LENR effects could potentially help improve future battery safety and durability.
Lattice Energy LLC - Russia announces nuclear fission-powered cruise missile ...Lewis Larsen
In globally televised speech on March 1, President Vladimir Putin claimed that Russia has successfully developed and tested a nuclear-powered cruise missile with unprecedented performance capabilities. If real (which appears likely), this advanced weapon system is probably powered by an unshielded Uranium fission reactor. Such a propulsion system would almost certainly produce large emissions of deadly energetic neutron/gamma radiation and release radioactive waste particulates into reactor exhaust plumes that would be rather dangerous to exposed people and the environment.
Radiation-free ultralow energy neutron reactions (LENRs) --- which involve neither fission nor fusion --- now under development by Lattice, Mitsubishi Heavy Industries, Toyota, and Nissan are a truly safe, green nuclear technology. Importantly, LENRs can potentially be scaled-up and might someday be able to safely propel future missiles, manned aircraft/UAVs, manned submarines/UUVs, and everyday motor vehicles.
Lattice Energy LLC-Game changing LENRs - What are they and amazing things the...Lewis Larsen
Lacking production of deadly radiation or hazardous long-lived radioactive wastes, LENR power systems would not require any expensive and massive shielding, containment, or waste clean-up. Coupled with intrinsic multiway scalability, these unique attributes could enable development of highly competitive commercial products with outputs ranging from milliwatts to megawatts suitable for portable, stationary, vehicular, and aerospace power markets. End-user price per BTU or kWh for LENR-based power systems could be substantially lower than prices for competing batteries or fuel cells, combustion, and present fission and fusion technologies.
Lattice Energy LLC - Japanese NEDO industry-academia-government project - nan...Lewis Larsen
Nanocomposite LENR devices in Japanese NEDO industry-academia-government R&D project produced enough cumulative excess heat to boil a cup of tea.
Since 1989, production of calorimetrically measured excess heat during vast majority of experiments with purpose-fabricated LENR devices was a hit-or-miss proposition. When excess heat produced, was typically < 1 Watt for periods ranging from few hours to several days. NEDO greatly improved device fabrication, reproducibility, longevity, and excess heat performance.
For years skeptics summarily dismissed LENRs as a potential new energy source because experiments were unable to produce enough excess heat to even “boil a cup of tea.” Thanks to results of NEDO project, not any more.
NEDO project has demonstrated that LENRs can produce non-trivial, Watt-level amounts of excess heat from nanocomposite multi-metal devices without emission of deadly fluxes of energetic neutron or gamma radiation --- it is safe, radiation-free nuclear technology.
Lattice White Paper-LENRs: Cutting Energy's Gordian Knot-April 12 2010 Lewis Larsen
EXCERPT from Lattice Energy LLC - White Paper - Commercializing Low Energy Nuclear Reactions -LENRs: Cutting Energy's Gordian Knot- A Grand Challenge for Science and Energy- April 12, 2010
Lattice Energy LLC-Widom-Larsen Theory Explains Data Presented in New Mitsubi...Lewis Larsen
Widom-Larsen theory of LENRs can successfully explain the various experimental data that was presented and discussed in the recently published, LENR-related US patent application filed June 8, 2012, by Mitsubishi Heavy Industries, Ltd. (Japan), US 2012/0269309 A2.
Readers are encouraged to download copies and compare various details of Lattice’s fundamental patent US # 7,893,414 (issued by the USPTO on February 22, 2011) with Mitsubishi’s above-noted, recently published US application.
Mitsubishi uses their EINR model published in 1998 to explain their experimental data; however, it is strictly a conceptual phenomenological model and does not explain physics of exactly how LENR catalytic neutrons are formed and why copious energetic neutron radiation is not observed; neither does it explain why prompt and delayed MeV gamma radiation is not emitted during neutron captures on various isotopes.
Widom-Larsen theory of LENRs, as published in 2006 and 2010, fully explains the physics of ultra-low momentum neutron production, as well as the absence of deadly fluxes of energetic neutrons and ‘hard’ MeV-energy gamma radiation; Widom-Larsen theory’s deep insights in detailed device physics enables meaningful engineering of useful LENR devices for controlled production of thermal energy and/or purposeful transmutation of elements to accomplish a variety of objectives.
Conclusions: the Widom-Larsen theory of LENRs can successfully explain the various experimental data that was presented and discussed in the recently published, LENR-related US patent application filed June 8, 2012, by Mitsubishi Heavy Industries, Ltd. (Japan), US 2012/0269309 A2.
As a parting thought, please note that a number of large Japanese companies now have ongoing LENR R&D programs --- Mitsubishi Heavy Industries, Toyota Central Research, and Toyota Motors, among others. That being the case, it is highly likely that one or more companies, somewhere, sometime in the not-too-distant future, will eventually succeed in commercializing LENRs.
Lattice Energy LLC - Japanese NEDO LENR project reported good progress in exc...Lewis Larsen
Japan now funding R&D in LENR technology for use in power generation applications. Quietly threw down the gauntlet to global oil industry.
January 2018: terse project report summarizing progress in Japanese government NEDO-funded R&D in LENRs for period of Oct. 2015 through Oct. 2017 was released by Technova Inc. on ResearchGate. Herein we will review and discuss NEDO project’s reported progress.
Project scientists reported significant R&D progress toward developing LENR devices that serve as powerful heat sources. Reproducibility of device fabrication techniques and excess heat output were improved. Certain nanocomposite, multi-metal LENR test devices with mass <140 grams cumulatively produced up to ~85 megajoules (MJ) of excess heat per mole (MJ/mol) of absorbed Hydrogen (H) or Deuterium (D); some: duration of heat > 1 month. By contrast, complete combustion of Hydrogen releases ~0.286 MJ/mol of H. Chemical processes cannot explain these results.
Japan, Inc. appears to be developing LENR technology to someday replace the internal combustion engine.
Lattice Energy LLC- Field Failures and LENRs in Lithium-based Batteries-Jan 2...Lewis Larsen
LENRs are potentially another mechanism for producing so-called field failures that can trigger catastrophic thermal runaways in Lithium-based batteries; may sometimes, but not always, be associated with internal electrical shorts.
Energy storage for vehicles: when will they become economically feasibleJeffrey Funk
these slides summarize the technology trends for energy storage technologies in vehicles. Energy and power storage densities are important dimensions of performance for these energy storage vehicles and trends in these variables help us understand if and when these new energy storage technologies might become economically feasible. This is done for batteries, capacitors, and flywheels. the slides conclude with a discussion of how electrical energy storage might be implemented.
Lattice Energy LLC - LENRs enable green radiation-free nuclear power and prop...Lewis Larsen
If commercialized, LENRs could become one of the world’s preeminent energy technologies. At system electrical power outputs of just 5 - 10 kwh, modular LENR-based distributed power generation systems providing combined heat and electricity (CHP) could satisfy energy requirements of a majority of urban and rural households as well as smaller businesses worldwide. Much lower-output, revolutionary portable LENR power sources could displace chemical batteries in applications where ultrahigh performance and longevity are needed.
At electrical outputs of 60 - 200 kwh, LENR-based integrated power generation systems would be able to power vehicles, drones, as well as smaller aircraft and watercraft. This would break oil-based fuels’ 150-year stranglehold on internal combustion engines and decisively decarbonize the entire transportation sector. High-performance LENR thermal sources could also provide high-quality heat for many types of industrial processes.
Although they could very likely be designed and built, development of megawatt-output LENR systems is not mandatory to disrupt the world of energy for the better. If wide deployment of small-scale, low-cost LENR CHP distributed generation could be achieved, large numbers of fossil-fired and/or fission power plants would not have to be built to supply competitively priced, uninterruptible electricity to regional grids serving urbanized areas. Under that scenario, centralized grid power generation would be gradually displaced by vast numbers of smaller, price-competitive distributed LENR power systems inside homes and businesses.
Lewis Larsen - DJIA approaches previous all-time record high close of 26828 -...Lewis Larsen
Dow-Jones Industrial Average (DJIA) is approaching previous all-time record high close of 26,828 - what happens next? If U.S. economy speeds-up by 3Q 2019 and/or good China-US trade deal is completed, DJIA could hit new all-time highs and increase by 3,000 to 6,000 points during next 6 - 18 months.
Lattice Energy LLC - Microbial radiation resistance transmutation of elements...Lewis Larsen
Microbial radiation resistance, possible transmutation of elements, and the dawn of life on Earth
Multi-species communities of microorganisms will expend energy to assimilate and process heavy elements like Cesium, Gold, and Uranium that -- now -- play no obvious roles in growth or metabolism. Credible experimental data suggests some bacteria are shifting isotope ratios and possibly even transmuting certain elements. How and why are microbes doing this? LENRs may explain how, but why?
Although credible experimental data suggests some microbes can transmute certain elements via LENRs, much more experimentation will be required to decisively demonstrate that microorganisms can truly transmute chemical elements at will and determine which species of microbes have such capabilities. LENRs may not be all that uncommon out in Nature; if so, there will be major implications for geochemistry, isotope geology, and nuclear waste remediation.
LENRs can mimic isotopic effects of mass-dependent and mass-independent chemical fractionation. Elements and isotopes conserve their mass-balances in purely chemical systems; that is not necessarily true if LENRs are also occurring in same systems. Accurate measurement of total mass balances for all chemical species may be needed to discriminate between chemical and nuclear processes.
ULE neutron-catalyzed transmutation is not energetically practical for more-abundant chemical elements found in living systems such as Carbon. However, transmutation could potentially be an energetically feasible and advantageous capability that could enable some fortunate microbes to produce life-critical, low-abundance catalytic active site metals that are unavailable in local environments.
Japanese government-funded project with Mitsubishi Heavy Industries, Toyota, Nissan, and four universities is developing abiotic LENRs for power generation. Recently reported outstanding heat production results at working temperatures and pressures far lower than those found in many undersea hydrothermal vents.
Lattice Energy LLC - Korean scientists use bacteria to reduce concentration o...Lewis Larsen
Korean scientists used experimental laboratory mixtures of bacteria to reduce concentration of radioactive Cesium-137 (as indicated by gamma emissions) present in aqueous growth solutions irradiated with light at 12-hour intervals, shaken, and incubated at 25o C.
During experiments, and compared to controls, measured gamma radiation for flasks containing bacteria decreased at vastly higher rates than would be expected for ‘normal’ rate of Cs-137 β-decay. Is radioactive Cesium actually being transmuted into heavier Cs isotopes and other elements by living bacteria?
Lattice energy LLC - Chinese chemists report photochemical triggering of LENR...Lewis Larsen
Experiments reported in 2017 by Prof. Gong-xuan Lu et al. at Lanzhou Institute of Chemical Physics, in Lanzhou, China showed photocatalytic triggering of ultralow energy neutron reactions (LENRs) at NTP with visible light. Experimental results reported in “Journal of Molecular Catalysis” (China) in 2017 claimed production of Deuterium and Helium as well as nuclear transmutation of Potassium to Calcium. Very significant discovery if experimental claims can be independently confirmed by other researchers using same methods. If Lu et al.’s claims are confirmed, their work has important implications. For chemical catalysis, it suggests that LENR transmutations can occur at very low rates in parallel with ordinary chemical reactions; LENRs can coexist and interoperate at NTP. Also implies total mass-balances for chemical elements comprising reactants and products might not necessarily be conserved. For astrophysics and cosmochemistry, it means that nucleosynthesis can occur on surfaces of Hydrogen- and metal-rich dust grains irradiated by starlight.
Lattice Energy LLC - LENR experiment conducted by The Aerospace Corporation r...Lewis Larsen
LENR experiment conducted independently in 2017 by The Aerospace Corporation (non-profit company that operates a FFRDC) effectively repeated excess heat results reported by the Japanese government-funded NEDO LENR fabrication and testing project. Experimental data from this confirmatory experiment was reported by Dr. Edward Beiting, a physicist and Senior Scientist at The Aerospace Corporation, in a presentation that occurred on June 5, 2018 at the ICCF-21 conference held at Colorado State University in Ft. Collins, Colorado.
Lewis Larsen - Dow-Jones Industrial Average reaches 26000 - what happens next...Lewis Larsen
Dow-Jones Industrial Average (DJIA) has just gone above 26,000 for first time ever. What happens next? Boom or bust?
Short pithy answer: “We ain’t seen nothin’ yet”; quoted from Barron’s article published in February 1988
Slightly longer answer: We are presently in an era of low-inflation economic growth and explosion of new technologies. Therefore, a continued global financial and economic boom subject to episodic, healthy market price corrections is much more likely to occur than a fearsome bust like the near-collapse of U.S. financial markets in 2008 and subsequent Great Recession from which world financial markets and many national economies are just beginning to fully recover. Herein we present key reasons why this bullish scenario should transpire as events unfold.
Lattice Energy LLC - Polar vortex cold wave in USA has potential for lower te...Lewis Larsen
Today, the United States is gripped in jaws of a Polar Vortex extreme cold weather event in Midwest and Northeast. On December 27, 2017 the nighttime low temperature in Duluth, Minnesota hit bone-chilling 41 degrees below zero F. This severe cold snap is predicted to persist through January 5 – 7, 2018. How will wind & solar renewable energy sources and commercial natural gas pipelines perform during this latest Polar Vortex event in U.S.? It will be interesting to see what happens between today and mid-January 2018.
Lattice Energy LLC - Fossil fuels and nuclear vs renewables for powering elec...Lewis Larsen
Enormous potential future value for diversified portfolios of renewable, fossil-fueled, and nuclear power generation --- enable grids to have resilience against extreme weather events related to climate change and “Black Swan” volcanic eruptions.
Proverb: “In the first place … an ounce of prevention is worth a pound of cure.” Benjamin Franklin (1735). Fukushima lessons: mitigate improbable extreme events if not too expensive; $200 million was thought too costly to fix backup generators in 2006 but the ‘cure’ for the 2011 nuclear disaster now costs $189 billion and could take 30 - 40 years.
What may appear ‘greener’ and less $$$ in myopic short-term decision-making about grids could end-up being extremely $$$ expensive or catastrophic in longer-term. Data suggests that is it too risky for society to put all its energy “eggs” into a single renewable basket. Lattice therefore believes balanced diversity of different types of grid power sources is best strategy for insuring 99+% future reliability and excellent resiliency of electricity grids facing onslaughts of extreme weather events and low but non-zero probability for catastrophic Black Swan volcanic eruptions.
Since high % of renewable energy sources on electricity grids is a new phenomenon and unexplored territory, there aren’t preexisting road maps to guide government regulation and critical implementation by industry. Private sector companies by nature are concerned with short-term bottom line profitability and have more narrowly focused interests; by contrast, government is responsible for insuring national energy security over much longer time-frames and broader range of grid-threatening events.
Rick Perry/DOE’s controversial NOPR to FERC in September created an important opportunity for U.S. government and industry to begin productive dialogue about how to enhance the U.S. electricity grid’s ability to maintain present reliability and adapt to climate change.
Lattice Energy LLC - US Secretary of Energy Rick Perry-DOE suggestions to FER...Lewis Larsen
U.S. Secretary of Energy Rick Perry-DOE suggestions to FERC re improving future grid resiliency are reasonable
U.S. Secretary of Energy Rick Perry has been heavily criticized for controversial DOE letter to FERC that proposed changes to compensation rules involving coal and nuclear power generation. Letter suggested that coal and nuclear operators should be compensated somehow for special value to grid resiliency provided by providing uninterruptible power during extreme weather events. Rick Perry-DOE further suggested that another requirement for receiving such compensation would be that eligible grid-connected dispatchable generation assets must be able to store enough fuel onsite to permit 90 days of uninterrupted electric power generation.
Ongoing climate change appears to be increasing the probability of extreme polar vortex cold snaps like what occurred in U.S. in winter of 2014; lowest temperatures during that episode only lasted for several days. Since then, there have been additional occurrences of weather extremes that drastically reduced renewable power output and lasted much longer than several days.
During 2015 there was a severe wind drought in Western United States lasting nearly six months. During December 2016 and January 2017 Germany and Western Europe experienced several protracted periods --- lasting up to one month --- during which there was little or no sun nor any wind. On January 24, power shortfall with renewables got so bad that Germany came within one dispatchable coal-fired power plant of experiencing a national power blackout. That was eerily similar to what nearly happened in Northeastern U.S. during worst of 2014 polar vortex and revealed limited resilience of Germany's Energiewende.
Given that extreme weather events can clearly cause substantial, protracted power shortfalls with renewables and natural gas plants, Rick Perry/DOE’s deep concerns about fuel security and suggestions to FERC are reasonable.
Lattice Energy LLC - Japanese confirm Lattice hypotheses re importance of ads...Lewis Larsen
Survival of 40% of world’s population heavily depends on higher food production enabled by Ammonia fertilizer produced in large plants via Haber-Bosch process as commercialized in 1909.
Progress is being made with new catalyst technology that could potentially reduce capital and operating costs of future Ammonia plants which would be cost-effective in much smaller sizes that enable distributed production.
Recent Japanese papers confirm Lattice’s hypotheses about importance of adsorbed protons and high
local electric fields for boosting reaction rates on some types of metallic catalyst surfaces.
Manabe et al. achieved high yield Haber-Bosch-like synthesis of Ammonia by applying DC electric fields
along with N2, H2, Cs/Ru catalyst and SrZrO3 support at just room temperature and ~1 atmosphere pressure versus ~450o C and ~200 atm in commercial NH3 plant.
Widom-Larsen theory of LENRs predicts deep causal connection between many-body collective physics of electroweak nuclear catalysis and chemical catalysis: very high local electric fields ≥ 1010 V/m and mobile surface patches of Q-M entangled protons. In LENRs these enable: electron + proton --> neutron + neutrino.
Lattice Energy LLC - Unclassified 2010 US Defense Threat reduction Agency Pow...Lewis Larsen
U.S. Defense Threat Reduction Agency (DTRA) favorably evaluated Widom-Larsen theory of LENRs in official contract report originally published back in March 2010. Unclassified document very recently became publicly available on the U.S. Dept. of Homeland Security’s digital library website. Quoting from DTRA report’s conclusions: “Could the W-L theory be the breakthrough needed to position LENR as a major source of carbon-free, environmentally clean source of source of low-cost nuclear energy??”
Lattice Energy LLC - Adequate reasonably priced dispatchable power generation...Lewis Larsen
Adequate reasonably priced dispatchable power generation is critical for every country’s energy security.
Renewable energy sources sometimes unable to fill total national demand for electric power because they are intermittent. Unusual European weather in December 2016 demonstrated that Germany’s Energiewende (energy transition) as idealistically envisioned by its many supporters may be impractical.
“One cannot simultaneously rely on massive amounts of wind and sunshine, dispense with nuclear power plants, significantly lower the supply of fossil energy, and nevertheless tell people that electricity will definitely be available in the future.” Quoted from article by Heiner Flassbeck, a prominent German economist, that was published on January 10, 2017
It is thus apparent that national energy security, 99+ % grid uptime availability, and reasonably priced electricity for retail consumers could be jeopardized in countries that don’t have adequate dispatchable power generation capacity.
Electricity shortfalls from renewable wind and solar energy sources are today covered by dispatchable fossil fuel and fission power plants --- if fossil fuels and fission are then phased-out, then what will replace them?
Radiation-free ultralow energy neutron reactions (LENRs) could potentially provide an alternative nuclear technology to fission and fusion. While LENRs do use safe ultralow energy neutrons to trigger release of nuclear binding energy (heat) from an enormous array of stable element target fuels, they are radically different from Uranium and Thorium fission reactors that require criticality to operate properly. Unlike fission, LENRs don’t involve multiplicative chain reactions with fuels that in turn release multiple neutrons which then explosively accelerate neutron production --- nuclear runaways are not a risk with LENRs.
D-T fusion reactors like ITER and other similar Tokamaks mainly produce heat by harvesting the kinetic energy of deadly 14.1 MeV energetic neutrons. Consequently, they require massive shielding and containment systems for safe operation and unsurprisingly have enormous costs and unavoidably huge physical size. Given that the Lithium LENR fuel cycle releases nearly 27 MeV versus a total Q-value of 17.6 MeV for the D-T fusion reaction, it is hard to imagine a sound economic argument for spending 100s of billions on commercial fusion reactors if LENR technology were successfully developed and scaled-up as outlined herein.
Lack of hard radiation and radioactive wastes permit downward scalability that could enable future development of revolutionary, compact battery-like portable LENR power sources that can compete directly on $ price/kwh with chemical batteries in many applications including power tools, tablets, and smartphones.
Lattice Energy LLC - Synopsis of book titled Fusion Fiasco by Steven Krivit p...Lewis Larsen
Synopsis of Steve Krivit’s book “Fusion Fiasco” in context of the Widom-Larsen theory of LENRs:
By late October 1989 Dr. Edward Teller, ‘father’ of the first Hydrogen bomb, was apparently convinced Pons & Fleischmann had discovered a little-understood nuclear process that could operate in ordinary electrochemical cells. Bizarre absence of deadly hard radiation indicated to him that P&F’s puzzling results probably weren’t caused by a fusion process. After seeing all the ERAB panel’s data, he further speculated that the underlying process was very likely nuclear and possibly catalyzed by “neutral particle of small mass and marginal stability” that was somewhat akin to a neutron. Krivit reveals how his prescient insights were ignored by the DOE ERAB panel and then effectively buried for 27 years.
Lattice Energy LLC - Liu et al increase effective electron masses in ZrTe5 by...Lewis Larsen
In Nature Communications Liu et al. reported detectible increases in the effective mass of electrons in ZrTe5 with application of an extremely high magnetic field. Their ZrTe5 experimental system operates similarly to the Widom-Larsen theory of ultra-low momentum neutron reactions (LENRs) in condensed matter wherein many-body collective effects create surface plasmon electrons with substantially larger effective masses. Quoting from press release about Liu et al.’s paper, “An international team of researchers has for the first time discovered that in a very high magnetic field an electron with no mass can acquire a mass. Understanding why elementary particles -- e.g. electrons, photons, neutrinos -- have a mass is a fundamental question in physics and an area of intense debate.”
State of ICS and IoT Cyber Threat Landscape Report 2024 previewPrayukth K V
The IoT and OT threat landscape report has been prepared by the Threat Research Team at Sectrio using data from Sectrio, cyber threat intelligence farming facilities spread across over 85 cities around the world. In addition, Sectrio also runs AI-based advanced threat and payload engagement facilities that serve as sinks to attract and engage sophisticated threat actors, and newer malware including new variants and latent threats that are at an earlier stage of development.
The latest edition of the OT/ICS and IoT security Threat Landscape Report 2024 also covers:
State of global ICS asset and network exposure
Sectoral targets and attacks as well as the cost of ransom
Global APT activity, AI usage, actor and tactic profiles, and implications
Rise in volumes of AI-powered cyberattacks
Major cyber events in 2024
Malware and malicious payload trends
Cyberattack types and targets
Vulnerability exploit attempts on CVEs
Attacks on counties – USA
Expansion of bot farms – how, where, and why
In-depth analysis of the cyber threat landscape across North America, South America, Europe, APAC, and the Middle East
Why are attacks on smart factories rising?
Cyber risk predictions
Axis of attacks – Europe
Systemic attacks in the Middle East
Download the full report from here:
https://sectrio.com/resources/ot-threat-landscape-reports/sectrio-releases-ot-ics-and-iot-security-threat-landscape-report-2024/
Epistemic Interaction - tuning interfaces to provide information for AI supportAlan Dix
Paper presented at SYNERGY workshop at AVI 2024, Genoa, Italy. 3rd June 2024
https://alandix.com/academic/papers/synergy2024-epistemic/
As machine learning integrates deeper into human-computer interactions, the concept of epistemic interaction emerges, aiming to refine these interactions to enhance system adaptability. This approach encourages minor, intentional adjustments in user behaviour to enrich the data available for system learning. This paper introduces epistemic interaction within the context of human-system communication, illustrating how deliberate interaction design can improve system understanding and adaptation. Through concrete examples, we demonstrate the potential of epistemic interaction to significantly advance human-computer interaction by leveraging intuitive human communication strategies to inform system design and functionality, offering a novel pathway for enriching user-system engagements.
UiPath Test Automation using UiPath Test Suite series, part 3DianaGray10
Welcome to UiPath Test Automation using UiPath Test Suite series part 3. In this session, we will cover desktop automation along with UI automation.
Topics covered:
UI automation Introduction,
UI automation Sample
Desktop automation flow
Pradeep Chinnala, Senior Consultant Automation Developer @WonderBotz and UiPath MVP
Deepak Rai, Automation Practice Lead, Boundaryless Group and UiPath MVP
Transcript: Selling digital books in 2024: Insights from industry leaders - T...BookNet Canada
The publishing industry has been selling digital audiobooks and ebooks for over a decade and has found its groove. What’s changed? What has stayed the same? Where do we go from here? Join a group of leading sales peers from across the industry for a conversation about the lessons learned since the popularization of digital books, best practices, digital book supply chain management, and more.
Link to video recording: https://bnctechforum.ca/sessions/selling-digital-books-in-2024-insights-from-industry-leaders/
Presented by BookNet Canada on May 28, 2024, with support from the Department of Canadian Heritage.
Encryption in Microsoft 365 - ExpertsLive Netherlands 2024Albert Hoitingh
In this session I delve into the encryption technology used in Microsoft 365 and Microsoft Purview. Including the concepts of Customer Key and Double Key Encryption.
Key Trends Shaping the Future of Infrastructure.pdfCheryl Hung
Keynote at DIGIT West Expo, Glasgow on 29 May 2024.
Cheryl Hung, ochery.com
Sr Director, Infrastructure Ecosystem, Arm.
The key trends across hardware, cloud and open-source; exploring how these areas are likely to mature and develop over the short and long-term, and then considering how organisations can position themselves to adapt and thrive.
Elevating Tactical DDD Patterns Through Object CalisthenicsDorra BARTAGUIZ
After immersing yourself in the blue book and its red counterpart, attending DDD-focused conferences, and applying tactical patterns, you're left with a crucial question: How do I ensure my design is effective? Tactical patterns within Domain-Driven Design (DDD) serve as guiding principles for creating clear and manageable domain models. However, achieving success with these patterns requires additional guidance. Interestingly, we've observed that a set of constraints initially designed for training purposes remarkably aligns with effective pattern implementation, offering a more ‘mechanical’ approach. Let's explore together how Object Calisthenics can elevate the design of your tactical DDD patterns, offering concrete help for those venturing into DDD for the first time!
UiPath Test Automation using UiPath Test Suite series, part 4DianaGray10
Welcome to UiPath Test Automation using UiPath Test Suite series part 4. In this session, we will cover Test Manager overview along with SAP heatmap.
The UiPath Test Manager overview with SAP heatmap webinar offers a concise yet comprehensive exploration of the role of a Test Manager within SAP environments, coupled with the utilization of heatmaps for effective testing strategies.
Participants will gain insights into the responsibilities, challenges, and best practices associated with test management in SAP projects. Additionally, the webinar delves into the significance of heatmaps as a visual aid for identifying testing priorities, areas of risk, and resource allocation within SAP landscapes. Through this session, attendees can expect to enhance their understanding of test management principles while learning practical approaches to optimize testing processes in SAP environments using heatmap visualization techniques
What will you get from this session?
1. Insights into SAP testing best practices
2. Heatmap utilization for testing
3. Optimization of testing processes
4. Demo
Topics covered:
Execution from the test manager
Orchestrator execution result
Defect reporting
SAP heatmap example with demo
Speaker:
Deepak Rai, Automation Practice Lead, Boundaryless Group and UiPath MVP
Securing your Kubernetes cluster_ a step-by-step guide to success !KatiaHIMEUR1
Today, after several years of existence, an extremely active community and an ultra-dynamic ecosystem, Kubernetes has established itself as the de facto standard in container orchestration. Thanks to a wide range of managed services, it has never been so easy to set up a ready-to-use Kubernetes cluster.
However, this ease of use means that the subject of security in Kubernetes is often left for later, or even neglected. This exposes companies to significant risks.
In this talk, I'll show you step-by-step how to secure your Kubernetes cluster for greater peace of mind and reliability.
Smart TV Buyer Insights Survey 2024 by 91mobiles.pdf91mobiles
91mobiles recently conducted a Smart TV Buyer Insights Survey in which we asked over 3,000 respondents about the TV they own, aspects they look at on a new TV, and their TV buying preferences.
Slack (or Teams) Automation for Bonterra Impact Management (fka Social Soluti...Jeffrey Haguewood
Sidekick Solutions uses Bonterra Impact Management (fka Social Solutions Apricot) and automation solutions to integrate data for business workflows.
We believe integration and automation are essential to user experience and the promise of efficient work through technology. Automation is the critical ingredient to realizing that full vision. We develop integration products and services for Bonterra Case Management software to support the deployment of automations for a variety of use cases.
This video focuses on the notifications, alerts, and approval requests using Slack for Bonterra Impact Management. The solutions covered in this webinar can also be deployed for Microsoft Teams.
Interested in deploying notification automations for Bonterra Impact Management? Contact us at sales@sidekicksolutionsllc.com to discuss next steps.
Builder.ai Founder Sachin Dev Duggal's Strategic Approach to Create an Innova...Ramesh Iyer
In today's fast-changing business world, Companies that adapt and embrace new ideas often need help to keep up with the competition. However, fostering a culture of innovation takes much work. It takes vision, leadership and willingness to take risks in the right proportion. Sachin Dev Duggal, co-founder of Builder.ai, has perfected the art of this balance, creating a company culture where creativity and growth are nurtured at each stage.
Lattice Energy LLC- Increased Energy Densities Drive Convergence of Batteries and LENRs-Sept 6 2013
1. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 1
Weiji today g Jihui tomorrow
Lewis Larsen
President and CEO
Lattice Energy LLC
September 6, 2013
Contact: 1-312-861-0115
lewisglarsen@gmail.com
http://www.slideshare.net/lewisglarsen
Large increases in device energy densities
Drive convergence between energetic materials, LENRs and batteries
LENRs can sometimes create thermal problems in high-energy-density batteries
Battery manufacturers can potentially turn today’s LENR issues into greater profitability in future
LENRs a nano energetic materials
Critical point a for a strategy shift?
Release bonding or binding energy
Chinese characters: wei ji
“I have learned to use the word ‘impossible’ with the greatest caution.”
Wernher von Braun
Sept. 15, 2014: added Slides #86 - 89 re unexpected pullback in Lithium-air battery R&D by two major players, IBM and JCESR
2. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 2
Convergence of energetic materials, LENRs and batteries
September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 2
3. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 3
Source: http://www.estquality.com/technology Note: superimposed S-curve and dates were added by Lattice Batteries maturing and approaching technological limits
Energy density increases and related cost reductions are slowing down
1859
1899
1991
1996
2014
Next 10 -15 years
Lithium-based batteries became dominant in portable electronics and new EVs because they have much higher energy densities than other battery chemistries
Energy density in Wh/L
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Source: C. Zu & H. Li, Energy & Environmental Science 4 pp. 2614 - 2624 (2011)
LENRs could be great leap forward in energy density
Lithium-ion technology nearing energy-density limits for that chemistry
Energy density in Wh/kg
5. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 5
Source: http://www.popsci.com/node/30347
So-called “thermite reactions” burning at thousands of degrees have much in common
with absolute worst case field- failure thermal runaways
in chemical batteries
Certain chemical reactions release
enough heat to actually melt metals
Over time, energetic materials, LENRs, and advanced battery technologies are all gradually converging and overlapping with each other; it is a very persistent trend
This is happening because future R&D paths to create vastly improved commercial products in these domains must all necessarily utilize micron- to nm-scale objects and energetic processes occurring on surfaces/interfaces
Achieving such ambitious future goals with regard to system-level product performance and energy density will require using optimized combinations of co-existing chemical, electromagnetic, and … thanks to insights provided by Widom-Larsen … green radiation-free nano- nuclear processes with huge intrinsic energy densities
Synergistic interaction and interdisciplinary cross- fertilization between these three domains of technology will create many opportunities for revolutionary change
6. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 6
Japanese companies understand convergence of LENRs and batteries: Mitsubishi Heavy industries, Toyota Central Research, Toyota Motor Corp., and other unnamed large Japanese companies all now have LENR R&D programs; Lattice believes their goal is to eventually replace the internal combustion engine with CO2-free LENRs
Battery manufacturers should begin factoring LENRs into product safety risk mitigation strategies - weiji. Ideally, they would also embrace LENRs, viewing it as strategic opportunity to increase battery safety in the near-term, and in longer-term to gradually move toward a new, higher-performance future portable power technology whose energy density surpasses anything that is possible in the chemical realm - jihui
Lattice would welcome a major battery manufacturer as a strategic business partner
Based on proprietary technical knowledge, Lattice believes achievable thermal energy densities in commercial LENR devices could be substantially greater than 0.1% of Lattice’s estimated theoretical maximum of 57,500,000 Wh/kg. At a conservative 0.1% of maximum, still equates to extraordinary thermal energy density of ~57,500 Wh/kg.
Assuming a value of 20% for heat-to-rotational power conversion efficiency translates into an estimated effective LENR net energy density of ~11,500 Wh/kg, which is equivalent to 100% efficient chemical combustion of gasoline with Oxygen and ≅ to Lithium-oxygen battery’s estimated theoretical maximum density of 11,680 Wh/kg
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Overview of three technology domains …………………………….…………….. 9 - 12
Technology convergence is length-scale-related ..………………..……….…... 13 - 19
What was thought impossible becomes possible at nm ……………………… 20 - 23
Widom-Larsen theory explains LENRs …..…………………….………….......... 24 - 36
Battery industry is already encountering LENRs …………..………….…….... 37 - 51
Thermal runaways: batteries behaving badly …………………………………... 52 - 60
Example of a battery that had a thermal runaway …………………………….. 61 - 66
Parallels between LENRs and Lithium-based batteries ……………….….….. 67 - 71
High thermal runaway temps create energetic materials …………………….. 72 - 77
Increased battery energy density drives convergence …………………..…….78 - 89
8. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 8
Energy density scale-up can increase safety risks …………………………..... 90 - 96
Japanese companies understand the convergence …………….……………... 97 - 100
If you can’t beat ‘em, join ‘em ..……………………....…………..…….………… 101 - 107
Working with Lattice: we think we know the way…..……..….……………...... 108 - 110
Additional reading for the technically inclined ……………..……….…….…... 111 - 112
Parting thoughts ……………………………………………………………….……. 113
Quote regarding revolutions: Eric Hoffer (1967)……….…..…….…..…..114
Closing slide: Jihui - the future .……………………..….………….……… 115
9. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 9
Convergence of energetic materials, LENRs and batteries
Revolution in nuclear technology
September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 9
Widom-Larsen theory of LENRs
10. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 10
Three different technologies now converging on nanoscale
Each domain is being driven by a quest for higher energy densities
Chemical batteries: devices used for reversibly storing electrical input energy (charging) in chemical bonds and controllably releasing clean electricity (discharging) on demand. Rise of portable electronic consumer products has driven vast, meteoric growth in both primary and secondary battery markets for more than 40 years
Energetic materials: chemical compounds that can be triggered to irreversibly release very large amounts of chemical bonding energy via extremely fast reactions; are typically quite uncontrollable after being triggered
Low energy neutron reactions (LENRs): unlike more familiar fission or fusion processes mainly driven by the strong interaction, these are truly eco-green nuclear processes wherein key steps depend instead on weak interactions; importantly, while LENRs can be designed to controllably release extremely large amounts of CO2- free thermal energy, they do not emit any dangerous fluxes of deadly energetic neutron or gamma radiation
Credit: J. Le Perchec, Europhysics Letters (2010)
Coherent cavity mode high-E-field hot spots
11. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 11
Three domains of technology all involve energy releases Differ in main purpose, source, energy-scale of reactions, and rates
Technology domain
Main
purpose
Source of energy
Energy- scale
Typical rates of reactions
Temps in Centigrade
Representative examples
Electro- chemical batteries
Store electrical energy reversibly in chemical bonds
Chemical bonds
Electron Volts
(eV)
Slow to moderate; typically diffusion rate-limited at various types of interfaces found inside batteries
Batteries can generally be operated safely only at temperatures < 200o C
Large variety of different chemistries: lead-acid, alkaline, NiMH, Nickel-cadmium, Lithium-ion, LiFePO4, Lithium-oxygen, etc.
Energetic materials
Thermal igniters, explosives, propellants
Chemical bonds
eVs
Fast combustion processes w. O2, e.g., deflagration and detonation
Macroscopic peak temps max-out at ~5,000o C
Thermite reactions (burning of metals), dinitro-chloro-azido benzene, RDX, etc.
Low energy neutron reactions (LENRs)
Produce large amounts of CO2-free thermal energy from decay particles’ kinetic energies
and gamma conversion to infrared
Nuclear binding energy stored inside atomic nuclei
Mega- electron Volts
(MeVs)
one MeV is equal to a million eVs
Nuclear reactions themselves are super-fast, i.e., picosecond and faster; decays of any resulting unstable isotopes can range from very slow on order of millions of years to fast, i.e., nanoseconds
Peak temperatures in micron- scale, short- lived LENR hotspot regions on surfaces and at interfaces typically reach ~3,700o to 5,700o C
Neutron captures on various elements and isotopes; for example, LENR neutron capture processes starting with Lithium as base fuel target can release ~27 MeV in short sequence of nuclear reactions that do not release any energetic neutron or gamma radiation
12. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 12
September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 12
LENRs are a paradigm-shifting nuclear technology
No deadly gamma radiation …
No dangerous energetic neutron fluxes and
Insignificant production of radioisotopes
Truly revolutionary and environmentally safe
13. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 13
Convergence of energetic materials, LENRs and batteries
September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 13
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September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 14
LENRs and nanotechnology are intimately connected
Large length scales
Huge array of new technological capabilities and opportunities open-up at micron to nanometer length-scales
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Huge decrease in distances separating battery anodes from cathodes
centimeter (1.0 cm) millimeter-scale (.01 cm) micron-scale (.001mm)
Baghdad battery ~ 250 BCE? 20th century lead-acid starter battery Contemporary lithium-ion battery
Technology convergence is length-scale related Jelly roll
16. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 16
Technology convergence is length-scale related All paths lead toward using micron- to nm-scale objects and processes
Credit: the Thomann Group at Rice University
Credit: Scientific Reports 3 paper #2335 (Aug. 2013)
High-E-field nm-scale hot spots near interfaces
Battery performance is diffusion-rate-limited through intervening materials and across interfaces; to improve this parameter and increase overall energy density of battery cells, manufacturers invented the “jelly roll” architecture and shrank thicknesses of dielectric plastic separators between anode and cathode from centimeters to microns (thousand-fold decrease); to further increase performance and energy density parameters, they are increasingly utilizing nanotechnology and developing new types advanced battery chemistries, e.g., Lithium-Oxygen technology
Independently, technologists working to improve energy density and performance metrics of energetic chemical materials used in thermal igniters, propellants, and certain types of explosives are increasingly utilizing much of the same nanotechnology --- this relatively new area of R&D is called “nano-energetic materials”
Paradigm-shifting Widom-Larsen theory explains the key role of nanoplasmonics in LENRs, why they are intrinsically μm- to nm- scale surface and interfacial phenomena, and illuminates an R&D pathway that incorporates existing nanotechnology to design and fabricate commercial versions of LENR heat sources at low cost
Conclusion: energetic materials, battery and LENR technologies are converging by utilizing μm-to nm-scale objects and processes
17. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 17
Technology convergence is length-scale related
All R&D paths lead to nm-scale processes/objects at surfaces/interfaces
Eco-green ultra- high performance energy storage and power generation systems for key portable, stationary, and mobile applications
Very energetic materials
Nanotech/plasmonics
Advanced batteries
Materials science
LENRs
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“… eventually there comes a time when neither component replacement nor structural deepening [of the older, dominant technological paradigm] add much to performance. If further advancement is sought, a [new] novel principle is needed.” pp. 138 “Origination is not just a new way of doing things, but a new way of seeing things … And the new threatens … to make the old expertise obsolete. Often in fact, some version of the new principle [paradigm] has been already touted or already exists and has been dismissed by standard practitioners, not necessarily because lack of imagination. But because it creates a cognitive dissonance, an emotional mismatch, between the potential of the new and the security of the old.” pp. 139 W. Brian Arthur, “The Nature of Technology - What it is and how it evolves” Free Press (2009)
Technology convergence is length-scale-related Will trigger revolutionary change in many synergistic technologies
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September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 19
jihui
wei ji
Thermal runaways Tomorrow
Chemical-only
processes
LENRs + chemical processes coexist
Widom-Larsen paradigm shift
Dominant paradigm today
20. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 20 Convergence of batteries, LENRs, and energetic materials
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“Hot electrons do the impossible: plasmon- induced dissociation of H2 on Au” S. Mukherjee et al. NANO Letters 13 pp. 240 - 247 (2013) http://pubs.acs.org/doi/pdf/10.1021/nl303940z
ABSTRACT: “Heterogeneous catalysis is of paramount importance in chemistry and energy applications. Catalysts that couple light energy into chemical reactions in a directed, orbital-specific manner would greatly reduce the energy input requirements of chemical transformations, revolutionizing catalysis- driven chemistry. Here we report the room temperature dissociation of H2 on gold nanoparticles using visible light. Surface plasmons excited in the Au nanoparticle decay into hot electrons with energies between the vacuum level and the work function of the metal. In this transient state, hot electrons can transfer into a Feshbach resonance of an H2 molecule adsorbed on the Au nanoparticle surface, triggering dissociation. We probe this process by detecting the formation of HD molecules from the dissociations of H2 and D2 and investigate the effect of Au nanoparticle size and wavelength of incident light on the rate of HD formation. This work opens a new pathway for controlling chemical reactions on metallic catalysts.”
What was thought impossible becomes possible at nm
Example: first experimental evidence for room temp. dissociation of H2
22. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 22
What was thought impossible becomes possible at nm
Example: essentially room temp. splitting of water H2O molecules
“An autonomous photosynthetic device in which all charge carriers derive from surface plasmons” S. Mubeen et al. Nature Nanotechnology 8 pp. 247 - 251 (2013) http://www.nature.com/nnano/journal/v8/n4/full/nnano.2013.18.html
ABSTRACT: “Solar conversion to electricity or to fuels based on electron– hole pair production in semiconductors is a highly evolved scientific and commercial enterprise. Recently, it has been posited that charge carriers either directly transferred from the plasmonic structure to a neighboring semiconductor (such as TiO2) or to a photocatalyst, or induced by energy transfer in a neighboring medium, could augment photoconversion processes, potentially leading to an entire new paradigm in harvesting photons for practical use. The strong dependence of the wavelength at which the local surface plasmon can be excited on the nanostructure makes it possible, in principle, to design plasmonic devices that can harvest photons over the entire solar spectrum and beyond. So far, however, most such systems show rather small photocatalytic activity in the visible as compared with the ultraviolet. Here, we report an efficient, autonomous solar water-splitting device based on a gold nanorod array in which essentially all charge carriers involved in the oxidation and reduction steps arise from the hot electrons resulting from the excitation of surface plasmons in the nanostructured gold. Each nanorod functions without external wiring, producing 5 × 1013 H2 molecules per cm2 per s under 1 sun illumination (AM 1.5 and 100 mW cm−2), with unprecedented long-term operational stability.”
Until now, besides $ expensive aqueous electrolysis at <100o C, many water-splitting technologies have often involved various types of high temperature processes; e.g.:
“Efficient generation of H2 by splitting water with an isothermal redox cycle”
C. Muhich et al., Science 341 pp. 540 - 542 (2013) http://www.sciencemag.org/content/341/6145/540.abstract
Quoting from Muhich et al.:
“We show that these temperature swings are unnecessary and that isothermal water splitting (ITWS) at 1350°C using the ‘hercynite cycle’ exhibits H2 production capacity >3 and >12 times that of hercynite and ceria, respectively, per mass of active material when reduced at 1350°C and reoxidized at 1000°C.”
23. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 23
What was thought impossible becomes possible at nm
Example: essentially room temp. splitting of water H2O molecules
Fig. 1 (a) in S. Mubeen et al., Nature Nanotechnology (2013)
In story titled, “Gold replaces semiconductor for solar energy conversion,” by Kate Prengaman (Materials Research Society, Materials 360 Online, published March 11, 2013 - http://www.materials360online.com/newsDetails/38540); she interviewed Prof. Martin Moskovits (Univ. California-Santa Barbara), one of the co-authors of the Nature Nanotechnology paper by Muhich et al. In describing the Moskovits interview she wrote: “ ‘The sunlight excites electrons on the surface of the gold so that they temporarily oscillate in unison’, says Martin Moskovits, one of the paper’s authors. He likens the process, known as a surface plasmon, to a flash mob dance - a sudden coordinated motion replaces the usual random motion for a brief display. ‘We knew that they could suck up an enormous amount of energy from the sun. We knew that the light would send their electrons quivering,’ Moskovits says. ‘The electrons come away with additional energy, and it’s that energy we want to grab to make hydrogen and oxygen’.” What Moscovits is in fact describing in vivid informal terms are many- body collective effects with surface plasmon electrons. These same physics ‘aikido’ effects in W-L theory, in conjunction with analogous many-body collective quantum effects that occur with protons or deuterons and local breakdown of Born-Oppenheimer approximation on surfaces and at interfaces, are exactly what enable weak- interaction nuclear processes to occur in condensed matter at relatively low macroscopic temperatures, i.e., stars not required to trigger nucleosynthetic reactions in the laboratory and in Nature.
24. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 24 Convergence of energetic materials, LENRs and batteries
September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 24
25. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 25
Low energy neutron reactions (LENRs) are a uniquely green nuclear technology: no deadly energetic gamma or neutron radiation and no production of long-lived radioactive wastes
LENRs are neither fission nor fusion but something wonderfully different
September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 25
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Widom-Larsen theory explains LENRs
Many-body collective effects and Q-M entanglement enable aikido
Table shows the key attributes of W-L many-body LENR-active surface patches
Type of particle in LENR- active patch
Are particles in patch charged?
Dimensionality
Do particles collectively oscillate?
Are particles Q-M entangled?
Comments
Widom- Larsen surface patch
Sizes vary randomly - diameters can range from several nm to perhaps up to ~100 microns
Surface plasmon electrons (fermions)
Decidedly many-body
Yes, -
~2-D to 3-D
somewhat reduced
Yes
Yes
Q-M wave functions are very delocalized within a patch
Very high nuclear-strength electric fields > 2 x 1011 V/m present within an energized patch; this increases local SP electron masses, allowing some of them to directly react with protons in e + p n + ν
Surface protons (hydrogen) (fermions)
Decidedly many-body
Yes, +
~2-D to 3-D
somewhat reduced
Yes
Yes
Q-M wave functions are very delocalized within a patch
Very high nuclear-strength electric fields > 2 x 1011 V/m present within an energized patch thanks to E-M coupling and breakdown of the Born- Oppenheimer approximation
Substrate material
Mostly neutral atoms except for interstitial absorbed hydrogenous ions that occupy material-specific sites in substrate bulk lattice
No
charge-neutral for the most part
Essentially 3-D
i.e., bulk material
No
No
When protons are loaded into a hydride-forming lattice, they occupy specific interstitial sites. After site occupancies > ~0.80 , protons start leaking back onto surface, forming collectively oscillating, Q-M entangled, ~2-D monolayer pools of protons that E-M couple locally to surface plasmon electrons
29. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 29
30. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 30
31. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 31
Widom-Larsen theory explains LENRs Collective many-body physics and SP electrons enable interconnection
Nuclear Chemical
32. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 32
Widom-Larsen theory explains LENRs
Many-body collective neutron production requires input energy
Input energy is required: to create non-equilibrium conditions that enable nuclear-strength local E-fields which produce populations of heavy-mass e-* electrons that react with many- body surface patches of p+, d+, or t+ to produce neutrons via e-* + p+ 1 n or e-* + d+ 2 n, etc. (cost = 0.78 MeV/neutron for H; 0.39 for D; 0.26 for T); includes (can be combined):
Electrical currents - i.e., an electron beam of one sort or another can serve as input source
Ion currents - across the interface on which SP electrons reside (i.e., an ion beam that can be comprised of protons, deuterons, tritons, and/or other types of charged ions); one method used to input energy is ion flux caused by imposing a pressure gradient (Iwamura et al. 2002)
Incoherent and coherent E-M photon fluxes - can be incoherent E-M radiation found in resonant electromagnetic cavities; with proper coupling, SP electrons can also be directly energized with coherent laser beams emitting photons at appropriate resonant wavelengths
Organized magnetic fields with cylindrical geometries - mainly at very high electron currents; includes organized, non-ideal so-called “dusty plasmas” - scales way-up to stellar flux tubes
Key feature of complex multi-step LENR transmutation networks: large numbers of viable network pathways can release more net nuclear binding energy that arises from a combination of neutron captures (with direct conversion of resulting prompt and delayed gammas into IR per W-L theory) and nuclear decays (e.g., α, β, etc.) vs. input energy that is required to produce total numbers of neutrons required for network pathway(s) to operate
33. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 33
Widom-Larsen theory explains LENRs
Below are the basic requirements for successfully triggering LENRs
Substantial quantities of Hydrogen isotopes must be brought into intimate contact with fully-loaded metallic hydride-forming metals (or non-metals like Se); e.g., Palladium, Platinum, Rhodium, Nickel, Titanium , Tungsten, etc. Please note that collectively oscillating, 2-D surface plasmon (SP) electrons are intrinsically present and cover the surfaces of such metals. At “full loading” of H, many-body, collectively oscillating island-like patches of protons (p+), deuterons (d+), or tritons (t+) will form spontaneously at random locations scattered across such surfaces
Or, delocalized collectively oscillating π electrons that comprise the outer covering surfaces of fullerenes, graphene, benzene, and polycyclic aromatic hydrocarbon (PAH) molecules behave very similarly to SPs; when such molecules are hydrogenated, they can create many-body, collectively oscillating, entangled quantum systems that, per W-L theory, are functionally equivalent analogues of loaded metallic hydrides (trigger LENRs on aromatic rings)
Born-Oppenheimer approximation breaks down in tiny surface patches of contiguous collections of collectively oscillating p+, d+, and/or t+ ions; enables E-M coupling between nearby SP or π electrons and hydrogen ions at these locations; creates nuclear-strength local electric fields > 2 x 1011 V/m; effective masses of electrons in that field are then increased to a multiple of an electron at rest (e → e*) - determined by required ~simultaneous energy input(s)
System must be subjected to external non-equilibrium fluxes of charged particles or E-M photons that are able to transfer input energy directly to many-body SP or π electron surface films. Examples of such external energy sources include (they may be used in combination): electric currents (i.e., electron beams); E-M photons (e.g., emitted from lasers, IR-resonant E-M cavity walls, etc.); pressure gradients of p+, d+, and/or t+ ions imposed across surfaces; currents of other ions crossing the SP electrons on surface in either direction (ion beams); etc. Such sources can provide additional input energy required to surpass certain minimum H-isotope-specific electron-mass thresholds that allow production of ULM neutron fluxes via e* + p+, e* + d+, or e* + t+ weak interactions
N.B.: please note again that surface plasmons are collective, many-body electronic phenomena closely associated with interfaces. For example, they can exist at gas/metal interfaces or metal/oxide interfaces. Thus, surface plasmon oscillations will almost certainly also be present at contact points between purely metallic surfaces and adsorbed so-called target nanoparticles composed of metallic oxides, e.g., PdO, NiO, or TiO2, etc., or vice-versa
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Widom-Larsen theory explains LENRs
In 2009 we hypothesized surface plasmons on polycyclic aromatics
Our conjecture was recently confirmed by A. Manjavacas et al. (March 2013)
ABSTRACT: “We show that chemically synthesized polycyclic aromatic hydrocarbons (PAHs) exhibit molecular plasmon resonances that are remarkably sensitive to the net charge state of the molecule and the atomic structure of the edges. These molecules can be regarded as nanometer-sized forms of graphene, from which they inherit their high electrical tunability. Specifically, the addition or removal of a single electron switches on/off these molecular plasmons. Our first- principles time-dependent density-functional theory (TDDFT) calculations are in good agreement with a simpler tight- binding approach that can be easily extended to much larger systems. These fundamental insights enable the development of novel plasmonic devices based upon chemically available molecules, which, unlike colloidal or lithographic nanostructures, are free from structural imperfections. We further show a strong interaction between plasmons in neighboring molecules, quantified in significant energy shifts and field enhancement, and enabling molecular-based plasmonic designs. Our findings suggest new paradigms for electro-optical modulation and switching, single-electron detection, and sensing using individual molecules.”
“Tunable molecular plasmons in polycyclic aromatic hydrocarbons” A. Manjavacas et al. ACS Nano 7 pp. 3635 - 3643 (2013) http://pubs.acs.org/doi/abs/10.1021/nn4006297
“Technical Overview - PAHs and LENRs” L. Larsen, Lattice Energy LLC November 25, 2009 (61 slides) http://www.slideshare.net/lewisglarsen/lattice-energy-llctechnical-overviewpahs- and-lenrsnov-25-2009
Synopsis: Widom-Larsen predicts that under proper conditions, energy can be inputted to hydrogenated PAH rings such that ultra low momentum neutrons are created from ring hydrogens (protons) via weak interaction; produced neutrons then capture on nearby ring carbon atoms, causing nuclear transmutation
See Slides # 42 – 45 in:
35. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 35
Widom-Larsen theory explains LENRs
Nuclear and non-nuclear chemical processes coexist on LENR-active surfaces
LENR hot spots create intense local heating and variety of readily noticeable surface features such as craters: over time, LENR-active surfaces inevitably experience major micron-scale changes in local nanostructures and elemental/isotopic compositions. On LENR-active substrate surfaces, there are a myriad of different complex, nanometer-to micron-scale electromagnetic, chemical, and nuclear processes that operate in conjunction with and simultaneously with each other. LENRs involve interactions between surface plasmon electrons, E-M fields, and many different types of nanostructures with varied geometries, surface locations relative to each other, different-strength local E-M fields, and varied chemical/isotopic compositions; chemical and nuclear realms interoperate
To varying degrees, many of these complex, time-varying surface interactions are electromagnetically coupled on many different physical length-scales: thus, mutual E-M resonances can be very important in such systems. In addition to optical frequencies, SP and π electrons in condensed matter often also have some absorption and emission bands in infrared (IR) and UV portions of E-M spectrum. Well, walls of gas-phase metallic or glass LENR reaction vessels can emit various wavelengths of E-M photon energy into the interior space; glass tubes with inside surfaces coated with complex phosphors can function as resonant E-M cavities. Target nanostructures, nanoparticles, and/or molecules located inside such cavities can absorb IR, UV, or visible photons radiated from vessel walls if their absorption bands happen (or are engineered) to fall into same spectral range as E-M cavity wall radiation emission; complex two-way E-M interactions between targets and walls occurs (imagine interior of a reaction vessel as arrays of E-M nanoantennas with walls and targets having two-way send/receive channels)
Wide variety of complex, interrelated E-M, nuclear, and chemical processes may be occurring simultaneously, side-by-side in adjacent nm to μ-scale local regions on LENR-active surfaces: for example, some regions on a given surface may be absorbing E-M energy locally, while others nearby can be emitting energy (e.g., as energetic electrons, photons, other charged particles, etc.). At same time, energy can be transferred laterally from regions of resonant absorption or capture to other regions in which emission or consumption is taking place: e.g., photon or electron emission, and/or LENRs in which: [E-M field energy] + e- → e-* + p+ → nulm + ν
36. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 36
Solves several
unexplained
astronomical mysteries
Energetic particles (GeVs),
gamma-ray bursts (GRBs)
and ultra-high energy
cosmic rays (TeVs)
Active galactic
nuclei in vicinity
of compact,
massive objects
(black holes)
Up to
several AU
(distance
from earth
to sun)
Solves mysteries of
heating of solar corona
and radioactive isotopes
in stellar atmospheres
Transmutations, large
fluxes of energetic
particles (to GeVs), limited
gamma shielding, X-rays
Dusty plasmas: high
mega-currents and
very large-scale, highly
organized magnetic
fields
Outer layers and
atmospheres of
stars (flux tubes)
Many
Meters to
Kilometers
This regime is useful for
large-scale commercial
power generation
Transmutations, ‘leakier’
gamma shielding, heat; X-rays
up to 10 keV, larger
energetic particle fluxes
Dusty plasmas: mixed
high-current and high
local magnetic fields
Exploding wires,
planetary
lightning
Microns to
Many
Meters
This regime is useful for
small-scale commercial
power generation
Transmutations, high level
gamma shielding, heat,
some energetic particles
Very high, short-range
electric fields on solid
substrates
Hydrogen
isotopes on
metallic surfaces
Microns
Obtain unavailable trace
elements; survive deadly
gamma/X-ray radiation
Transmutations, high
level gamma shielding
Very short-range
electric or magnetic
fields
Certain earthly
bacteria and
fungi
Submicron
Comment
Collective LENR
Phenomena
Electromagnetic
Regime
Type
of System
Length
Scale
Note: mass renormalization of electrons by high local E-fields not a key factor in magnetically dominated regimes at large length scales
Green nuclear regime
Widom-Larsen theory explains LENRs
LENRs in condensed matter only occur in nm- to micron-sized regions
Green LENR processes are intrinsically micron-to-nanometer-scale phenomena
Magnetically
dominated regime
W-L theory’s many-body collective E-M effects extend from microcosm to macrocosm
Aikido physics
37. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 37
Convergence of energetic materials, LENRs and batteries
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38. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 38
Battery industry is already encountering LENRs
LENR experiments in electrolytic cells are similar to charging batteries
Example 1: Heavy-water P&F-type electrolytic cell Electric current provides necessary input energy
Example 2: Light-water P&F-type electrolytic cell Electric current provides necessary input energy for LENRs
For over 20 years, LENR researchers have been reporting credible experimental data providing evidence for nuclear transmutations in electrolytic chemical cells. Some such experiments, e.g. Miley et al. (1996) have produced outstanding results
Source: html version is http://newenergytimes.com/v2/reports/Index-of-LENR-Experimental-Methodologies.shtml pdf: http://www.slideshare.net/StevenKrivit/lenr-methodsdistributioncopyrightnewenergytimes20130522-21707257
39. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 39
Battery industry is already encountering LENRs
LENR-active hotspots in electrolytic cells / batteries hit 3,700 - 5,700o C
Conditions conducive to initiation of LENRs occur in microscopic, micron-scale regions in random scattered locations on dendrites and other types of growing nanostructures and nanoparticles inside lithium-based batteries and electrolytic cells
Although radiation-free, LENRs involving neutron captures on stable lithium isotopes are extremely energetic nuclear processes – can release up to 27 million times more heat than even the most exothermic types of electrochemical reactions
Microscopic 100 micron LENR hotspot can release 5+ Watts of heat in less than 400 nanoseconds; nuclear processes raise local hotspot temps to 3,700 - 5,700o C
Batteries: micron-scale LENR-active sites that happen to be located close to a plastic battery anode/cathode separator (with or without a ceramic layer) will vaporize and flash-ionize a local region of separator which can in turn trigger an internal electrical short discharge at that particular location ; similarly, an LENR patch occurring on surface of a Lithium cobalt oxide cathode or carbon anode can potentially directly trigger irreversible combustion of an affected electrode In rare events, LENRs can either induce internal electric arcs and/or directly trigger catastrophic thermal runaways in advanced batteries of many different chemistries
40. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 40
Battery industry is already encountering LENRs
Mechanism for triggering microscopic LENR-active hotspots Dr. Andre Anders of Lawrence Berkeley National Lab has a model: Steps 1 - 4 below describe his “arc spot ignition” model as follows: High local electric field, enhanced by:
Protrusion (e.g. roughness, previous arcing) [dendrites on surfaces] or
Charged dielectrics (e.g. dust particles, flakes) [surface nanoparticles]
1.Higher field leads to locally greater e-emission
2.Joule heating enhances temperature of emission site
3.Higher temperature amplifies e-emission non-linearly
4.Runaway electric arc discharge To which Lattice would add, based on Widom-Larsen theory:
5.LENRs --- if other necessary preconditions are also fulfilled, as we have previously outlined in this document
Positive thermal feedback loop
Figure credit: B. Jüttner, Berlin
LENR hotspot crater being created
Timeline
+
41. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 41
Anders’ SEM images vs. selected images of post-experiment surfaces in LENR experiments:
LENR Pd surface post-experiment: P. Boss et al.
Anders cathodic arc: post-experiment surface feature
Please note what appears to be a somewhat common morphological difference between LENR craters and those produced by prosaic cathodic arcs as discussed by Anders. Many central craters in LENR SEM images often appear to have more sharply defined, crisper interior walls and greater depths (relative to the surface area) compared to arc discharges without LENRs (i.e., a much higher aspect-ratio); this may be indicative of much more rapid, higher levels of heating than those envisioned by Anders
LENR craters - U.S. Navy SPAWAR
Cathodic arcs also produce surface craters
Battery industry is already encountering LENRs
Morphological similarities: cathodic arc damage and LENR craters
42. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 42
Excerpted and quoted directly from: “Ultrafast laser patterning of OLEDs on flexible substrate for solid-state lighting” D. Karnakis, A. Kearsley, and M. Knowles Journal of Laser Micro/Nanoengineering 4 pp. 218 - 223 (2009) http://www.jlps.gr.jp/jlmn/upload/25e2c628adb23db70b26356271d20180.pdf
Fig. 6 from Karnakis et al. (2009)
LENR Pd surface post-experiment: P. Boss et al.
US Navy - SPAWAR
Quoting from Karnakis et al.: “Laser irradiation at fluences between 137-360 mJ/cm2 removed the cathode layer only, resulting in a uniform flat floor and an intact LEP surface, allowing a relatively wide process window for cathode removal. A typical example of such laser patterned Ba/Al cathode layer on the OLED stack is shown in Figure 6. The average fluence was 230 mJ/cm2 irradiated with an estimated spot diameter at 1/e2 of 35 μm. This resulted in a crater diameter of 21.5 μm.”
Battery industry is already encountering LENRs
LENR craters have high aspect ratio just like laser ablation of surfaces
Note microspheres formed at lips of craters
Evidence for explosive boiling of metals:
43. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 43
Excerpted and quoted directly from: “Multiplicity and contiguity of ablation mechanisms in laser-assisted analytical micro-sampling”, D. Bleiner and A. Bogaerts Spectrochimica Acta Part B: Atomic Spectroscopy 61 pp. 421 - 432 (2006) http://www.sciencedirect.com/science/article/pii/S0584854706000437
Fig. 1. Phase stability diagram of a liquid metal near the critical point. For fast heating, as obtained during ns laser ablation, the melt can be pushed close to critical conditions (superheating), which favors the realization of explosive boiling
Fig. 2. Schematic visualization of the hydrodynamic evolution of a fluid system under and impulse stress (here milk). Note the non-deterministic formation of jets at the sides and their break-up into droplets. From Ref. [58].
Battery industry is already encountering LENRs
Phase explosions (explosive boiling) of metals creates microspheres
Note similarities to U.S. Navy SEM images of craters
Phase stability diagram
44. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 44
Battery industry is already encountering LENRs
Dynamic infrared (IR) imaging of LENR hotspots by U.S. Navy SPAWAR
2005 - U.S. Navy SPAWAR San Diego LENR Research Lab: Infrared Measurements
Jan 13, 2009 - 2 min - Uploaded by Steven Krivit
http://www.youtube.com/watch?v=Pb9V_qFKf2M&feature=player_embedded Readers are urged to view USN SPAWAR’s (P. Boss et al.) fascinating short video clip: it is very reminiscent of high-speed flickering of thousands of tiny fireflies in a dark field at night Tiny, rapidly flickering hotspots during Pd co- deposition LENR experiment
45. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 45
Battery industry is already encountering LENRs
Piezoelectric detection of nano-explosions on LENR electrode surface
Copy of PowerPoint slides presented at Tenth International Conference on Cold Fusion (ICCF-10) held in Cambridge, MA (2003); this document may differ from the accompanying paper that was published by World Scientific, Inc. in official conference Proceedings (2003) http://lenr-canr.org/acrobat/SzpakSpolarizedda.pdf
Quoting directly: “The flashes observed in the IR experiments suggest ‘mini-explosions’ so we designed an experimental set-up to see if we could record these events using a piezoelectric sensor. Again, the co- deposition approach made this possible. A piezoelectric transducer was coated with epoxy as an insulation layer except for approximately 1 sq. cm on the front on which an electrically conducting material (Ag) was deposited. This became the cathode onto which Pd was co-deposited from the PdCl in a deuterated water solution. The experimental setup and instrumentation is shown.”
Lattice comment: U.S. Navy SPAWAR researchers observed acoustic events in parallel with thermal imaging of transient LENR hot spots on electrodes
46. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 46
A. Anders: Spot Type 1 - “contaminated” surface
LENR surface shown to right, which started-out smooth at the beginning of the experiment, appears to be much rougher in texture than the cathodic arc
Zhang and Dash (2007) --- Fig. 10. SEM picture of region #2 in Fig. 4(b). SEM No.WS060424Pd-H-CC-i2-150X
A. Anders “Cathodic Arcs, and related phenomena” (2010)
Free copy of Zhang and Dash paper at:
http://www.lenr- canr.org/acrobat/ZhangWSexcessheat.pdf
Cathodic arc craters
LENR craters
Fig. 11. Characteristic X-ray spectrum of spot #1 in Fig. 10.
Quoting from discussion of Fig. 10: “Ni was listed as “not detected” in the chemical analysis provided by the vendor of the Pd foil. It is very unlikely to have resulted from the cold rolling process or from electrodeposition because it is highly localized near one corner of the cathode. If it is the result of either contamination from the rolling mill or from electroplating it should not be highly localized on only one corner of the cathode. It could not have resulted from SEM systems because the stainless steel components of the SEM chamber also contain Fe and Cr. Fe and/or Cr are not present in any of the spectra. The SEM does not have components made of pure Ni. Therefore, the origin of the Ni is not known.”.
Nickel (Ni) anomalies observed on surface
Anders’ SEM images vs. images of post-experiment surfaces in LENR experiments
Battery industry is already encountering LENRs
LENR experiments: craters associated w. elemental/isotopic anomalies
47. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 47
Battery industry is already encountering LENRs
Zhang & Dash triggered nuclear transmutations in electrolytic cells
Selected images of post-experiment surfaces in LENR experiments by Zhang and Dash
LENRs: Zhang and Dash (2007) - Fig. 9
Fig. 9. SEM picture of crater at another time. SEM
No.WS060607Pd-H-CC-i2-2kX
Zhang and Dash: Table IX. Relative atomic percent concentrations of silver (Ag) in area and spots shown in Fig. 9
Spot # wa* area** +1 +2 +3 +4 +5
Ag/(Pd+Ag) 1.2 +/- 0.5 5.6 +/- 0.4 6.8 +/- 0.4 5.6 +/- 0.3 6.3 +/- 0.4 3.6 +/- 0.6 1.2 +/- 0.5
*wa = whole entire area comprising image in Fig. 9
** area = delimited by the white square outlined in Fig. 9
Following likely took place in these experiments:
Pd + n → unstable n-rich Pd isotope → Ag isotopes
neutron capture beta decay
Palladium Cathode
Note: Pd surface b.p. = 2,970o C
Palladium Cathode
LENRs: Zhang and Dash (2007) - Fig. 8
Free copy of
Zhang & Dash
paper at:
http://www.lenr-canr.
org/acrobat/
ZhangWSexcess
heat.pdf
Quoting: “The most common
finding is that silver occurs in
craters, such as those shown in Fig.
8. These craters with rims almost
certainly formed during electrolysis.
Pt deposition was concentrated on
these protruding rims.”
48. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 48
Please note that as little as a single blazing hot LENR-active site measuring only 30 microns in diameter --- if it happens to occur in vulnerable physical location deep inside a battery cell and adjacent to the surface of a plastic separator only 25 microns thick --- can effectively vaporize a tiny local region of the separator, almost instantly turning it into a dense, micron-sized ball of highly conductive plasma. This would in turn create an electrical short between anode and cathode at that location, triggering a large inrush of electrical arc current through the breach in the separator dam. Intense local Joule heating would ensue from the arc current, further enlarging the breach and spatially expanding the superheated region inside a given battery cell. Depending on many complex, event-specific details, such a conflagration may or may not grow to engulf an entire cell; thus rare LENR events do not inevitably cause catastrophic heat runaways.
Under just the right conditions, a single microscopic LENR site can trigger a chain of energetic electrical (Joule heating) and chemical (exothermic reactions) processes that together create spatially autocatalytic, very macroscopic thermal runaway events that destroy battery cells billions of times larger than volumes of LENR site(s). In course of such runaways, 99.9+% of total energy released is non- nuclear; hot spark LENRs are just an effective triggering mechanism. Also note that internal electrical shorts - whatever their cause - can also trigger runaways.
Battery industry is already encountering LENRs
Detailed description of LENR processes in batteries
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Within as little as milliseconds after the creation of an electric arc or LENR-active site, nm- to cm-scale local regions of a battery cell at or near such locations can become a super-hot, fiendishly complicated chemical “witches’ brew” consisting of many different types of old and newly created compounds, expected thermal decomposition products, various ionized species, and many mutually competing chemical reaction pathways
Positive thermal (heat) feedback loop: the hotter a given region gets, the faster local chemical reactions accelerate therein and the more widely the conflagration spreads into previously unaffected regions of a given battery cell --- this is causative root of thermal runaway effect and “thermal fratricide” that can occur between many cells
Evolution of such complex chemical systems is very rapid and incompletely understood - quite unpredictable with respect to final results: outcomes can range from minor thermal damage to single cell; to combustion of flammable electrolytes and charring of materials inside case and outside via venting; and at worst, to complete combustion of all materials located inside of and including cell casings -- - even all contents of surrounding multi-cell enclosures; worst-case Armageddon scenarios involve thermite-like, violent super-fast-reacting pyrotechnic processes
Battery industry is already encountering LENRs
Detailed description of LENR processes in batteries
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Battery industry is already encountering LENRs
Lithium-ion battery cells have relatively small safe operating window
~325o C
~325o C
Thermal runaway + feedback loop
Voltage/temp safe operating window only occupies small portion of entire battery parameter space
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Although there are differences, there is a degree of morphological similarity in SEM images of post- experiment cathodic arc surfaces (e.g., crater-like structures and related droplets) compared to those observed after LENR-related experiments
To the extent that such morphologies are highly indicative of very rapid heating and quenching in small areas of cathode surfaces, it implies that temperatures reached in electric arc and LENR-active hot spots or patches are briefly high enough to melt and even boil and vaporize substrate metals, e.g., Palladium (Pd) boiling point = 2,970o C or other transition metals, including refractory ones and even Tungsten
Widom-Larsen theory predicts that if necessary preconditions are met, LENRs can be triggered in high- local-current arcs and high-EM-field electrical phenomena that include field emission and breakdown on surfaces, adjacent nanoparticles, and dendrite tips
Variety of different nuclear transmutation products observed by a large number of LENR researchers in and around surface structures such as craters suggests that LENRs probably occurred at non-negligible rates in and around such active regions
Micron-scale LENR-active sites that happen to be located close to a plastic battery separator (with or without a ceramic layer) will vaporize and flash-ionize a local region of separator which can in turn trigger an internal electrical short right there; similarly, an LENR patch occurring on surface of a Lithium cobalt oxide cathode or carbon anode can potentially trigger the irreversible combustion of an electrode
With or without the help of LENRs, electric arcs (internal shorts) are capable of triggering catastrophic thermal runaways in batteries of many varied chemistries
Battery industry is already encountering LENRs
LENRs or electric arcs force batteries out of safe operating window
LENRs and/or electric arcs can trigger battery thermal runaways and fires
52. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 52 Convergence of energetic materials, LENRs and batteries
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53. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 53
Market success of lithium-based batteries and large increases in cell energy densities have encouraged battery technologists familiar with relatively small- scale applications to scale-up into physically larger lithium-based cells and huge arrays of cells that can address vastly larger electrical energy storage requirements of stationary back-up power systems and mobile platforms, e.g., hybrid and all-electric plug-in vehicles, as well as new aircraft such as the Boeing Dreamliner. Unfortunately, this scale-up has led to unforeseen safety issues that were either simply not readily apparent to anyone or irrelevant risk factors in smaller-scale system applications
There is really no such thing as a real-world Lithium battery chemistry that is 100% immune to danger of thermal runaways and/or catastrophic field-failures. From risk management perspective, various lithium chemistries only differ in their relative probabilities; some are more or less problem-prone than others
Thermal runaways: batteries behaving badly No Lithium-based battery chemistry is 100% immune to runaway risks
Credit: Image by Jiangang Zhu and Jingyang Gan/WUSTL
High-Q microresonators on a silicon wafer - class of devices called whispering-gallery-mode resonators
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Thermal runaways: batteries behaving badly Thermal runaway fires sometimes occur in portable electronic devices
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Typically well-controlled electrochemical reactions in batteries ordinarily generate a certain amount of unavoidable process heat which is then dissipated harmlessly simply by emitting invisible infra-red radiation from the battery case out into the local environment; during normal operation, contents of battery cells still remain well-within proscribed boundaries of designed range of optimal thermochemical operating temperatures
On rare occasions, for a variety of different reasons, a battery cell’s electrochemical reactions can suddenly start running at greatly elevated rates that create more process heat than a battery’s normal thermal dissipative mechanisms can easily handle, which then starts raising the temperature of battery cell contents out beyond their ideal safe operating range; threshold for out-of-control danger has not yet been crossed At key point --- call it the Rubicon River for a failing battery cell --- a very dangerous positive (+) feedback loop is created: whereby, increasing cell temperatures further accelerate electrochemical reactions in cells which produces even more heat, boosting local cell temperatures even higher, etc. Thermal runaways are thus born: only question is how bad they get before destroying enough of a battery to stop + feedback-accelerated reactions
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Thermal runaways: batteries behaving badly Start when reactions enter a temperature-driven positive feedback loop
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Thermal runaways: batteries behaving badly Good news: thermal runaway events are statistically rare
Bad news: when they do happen they can cause catastrophic effects
By any reasonable standard, lithium-based batteries are a pretty safe technology: garden variety thermal runaways only occur at frequencies of one such event per several millions of battery cells
The very worst, least understood type of thermal runaway, which goes under innocuous-sounding sobriquet of “field-failure,” occurs at a rate of one such event per ~ 4 - 5 million lithium-based battery cells right off the production line and regardless of their chemistry or primary vs. secondary, according to statistics collected by a major Japanese manufacturer of lithium-ion consumer batteries
There’s one more issue: although it’s hard to quantitatively specify, probability of thermal runaways seems to increase significantly as batteries age and go thru a great many charge-discharge cycles
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‘Garden variety’ thermal runaways:
Field-failure thermal runaways can also include electric arc shorting:
Temps: ~300o C up to 600o C (Lattice’s criteria)
Reasonably well understood failure events
Triggered by substantial over-charging or excessively deep discharges of Li batteries
Often triggered by external mechanical damage to battery cells, e.g., crushing, punctures; growth of internal dendrites pierces plastic separators
Temps: > 600o C - can go up to thousands of o C with arcs
Much rarer and comparatively poorly understood
Many believe triggered and/or accompanied by electrical arc discharges (internal shorts); what causes initial micro-arcs?
Much higher peak temperatures vs. garden variety events
Lattice suggests: super-hot low energy nuclear reactions (LENRs) could well be initial triggers for some % of them
Thermal runaways: batteries behaving badly Two main types of damaging events: ‘garden variety’ and field-failures
58. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 58
Garden variety single-cell thermal runaways: can be as little as a battery that just heats-up a bit and simply stops functioning … or a battery’s case can bulge significantly from internally generated heat without designed venting and releasing of contents from the inside before it stops functioning and then starts cooling down on its own
A slightly worse variant of a garden variety thermal runaway results in just a single cell venting or rupturing, but (in cases of flammable electrolytes) there are no hot, flaming battery contents spewed-out that could potentially ignite local combustibles and adjacent cells
In worst-case garden variety runaway, hot flaming electrolyte erupts from a ruptured battery cell, which may ignite nearby materials and cells; in this event variant (that is still not the worst-of-the-worst), internal peak temperatures usually not yet hot-enough to melt metals
Thermal runaways: batteries behaving badly Thermal runaways can have greatly varying degrees of severity
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59. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 59
Thermal runaways: batteries behaving badly Field-failures are truly catastrophic events in chemical batteries
Accepted battery industry definition of a field-failure thermal runaway event
Source: “Batteries for Sustainability – Selected Entries from the Encyclopedia of Sustainability in Science and Technology,” Ralph J. Brodd, Ed., Chapter 9 by B. Barnett et al., “Lithium-ion Batteries, Safety” Springer ISBN 978-1-4614-5791-6 (2012)
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Field-failure category of thermal runaways can reach extremely high peak temperatures of thousands of degrees Centigrade along with big electric arcs
Such temperatures are hot-enough to melt metallic structures inside batteries and combust almost anything and everything located within a battery case
If initiating spark is hot-enough, battery materials containing chemically bound oxygen will release it as O2; by creating its own oxygen supply, combustion process becomes self-sustaining, self-propagating flame front that consumes all burnable battery materials. Progressive thermal fratricide between cells can reduce batteries to unrecognizable debris; such fires could burn in a vacuum In absolutely worst-case events, even METALS can start burning in very fast, thermite-like reactions that can boost temps up to ~ 4,000o C; this is nightmare scenario wherein even deadly explosions with shrapnel can potentially occur
Thermal runaways: batteries behaving badly
Absolute worst-case Armageddon runaways involve burning metals
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Separators: polyethylene (M.P. ~125o C) or polypropylene (M.P. ~155o C)
Very thin separators: microporous insulating plastic films that allow Li+ ions to freely migrate through them, but still prevents anode and cathode from coming into direct physical contact with each other and shorting-out via hot electric arcs; these plastic films are only 25 μm thick
Anode
Cathode
Carbon
Lithium cobalt dioxide
Lithium transport salt in electrolyte = LiPF6
Electrolyte = diethyl carbonate or perhaps dimethoxyethane
Could be polyethylene or polypropylene or mix
SEI layer
Example of a battery that had a thermal runaway
GS-Yuasa Lithium battery: Boeing 787 Dreamliner - Logan Airport (2013)
63. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 63
separator
separator
Al
Cu
Carbon-based material
Not to scale
Carbon-based material
Source: figure adapted from Slide #13 in NTSB PowerPoint slideshow presented by Deborah Hersman at news conference on January 24, 2013
Copy of source document: http://www.ntsb.gov/investigations/2013/boeing_787/JAL_B-787_1-24-13.pdfs
Anode
Cathode
Cu and Al current collectors
Example of a battery that had a thermal runaway
GS-Yuasa Lithium battery: Boeing 787 Dreamliner - Logan Airport (2013)
64. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 64
Example of a battery that had a thermal runaway
Source: NTSB report: CT scan image
Source: GS Yuasa - prismatic cell a la 787 Dreamliner battery
Source: SONY “jelly roll” cell - commodity Lithium-ion battery
Source: USPTO – sample patent drawing for prismatic battery cell
Source: NTSB #13-013 February 19, 2013
GS-Yuasa Lithium battery: Boeing 787 Dreamliner - Logan Airport (2013)
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Perfect microspheres suggest there was μ-scale stainless steel phase-explosion
Presence of many perfect stainless steel microspheres in battery debris suggests that local temperatures were > 3,000o C
Perfect stainless steel microspheres are created by condensation of droplets from a vapor phase; similarities to laser ablation
NTSB Report No. 13-013:
NTSB Report No. 13-013:
Breakdown of surface
Figure courtesy of B. Jüttner, Berlin
LENR crater being formed; note creation of ~spherical droplets
LENRs: Pd surface post-experiment SEM P. Boss et al. , U.S. Navy – SPAWAR:
LENRs: Pd surface post-experiment SEM P. Boss et al. , U.S. Navy - SPAWAR
Example of a battery that had a thermal runaway
GS-Yuasa Lithium battery: Boeing 787 Dreamliner - Logan Airport (2013)
66. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 66
When NTSB scientists investigated charred debris found inside the ruined Logan GS Yuasa battery cells with a scanning electron microscope (SEM), near locations where electric arcs (internal short circuits) had obviously occurred they discovered notable numbers of perfect (microscopic) stainless steel microspheres lying amongst the disorganized rubble of variously damaged battery materials
What most technical people following the NTSB’s investigation may not have fully appreciated was that these beautiful little metallic microspheres are smoking gun evidence for vaporization and condensation of stainless steel comprising the battery cell casing in local hotspots created by high-current, low voltage electric arcs, i.e., one or more internal shorts likely occurred inside GS Yuasa battery cell #5
This experimental data implies that the local temperature of the battery casing’s Type 304 stainless steel hotspots directly exposed to the internal short’s arc plasma didn’t just get to the melting point of such steel (~1,482 degrees C) --- instead these local areas got all the way up past the boiling point of stainless (> 3,000 degrees Centigrade), were turned into a gaseous vapor (expanding in volume by >50,000 x in the process of vaporizing); solid steel then recondensed from hot metallic vapor in the form of perfect nanoscale steel spheres as portions of the super-hot metallic Fe- alloy vapor quench-cooled. This flash-boiling of metal is called a phase explosion
Perfect microspheres suggest there was μ-scale stainless steel phase-explosion
Example of a battery that had a thermal runaway
GS-Yuasa Lithium battery: Boeing 787 Dreamliner - Logan Airport (2013)
67. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 67 Convergence of energetic materials, LENRs and batteries
September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 67
68. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 68
Parallels between LENRs and Lithium-based batteries
LENR experiments with electrolytic cells resemble charging batteries Electrical current provides the input energy needed to produce neutrons per W-L
Heavy-water P&F-type cell Light-water P&F-type cell
Majority of LENR experiments with electrolytic cells had Lithium somehow present in the electrolyte; forms intimate alloys on surfaces of metallic cathodes. In classic Pons & Fleischmann-type experiments with Pd cathodes, ultra-low-momentum neutron captures on Lithium and Palladium produced most excess thermal energy measured with calorimetry LENR electrolytic cell with associated apparatus Courtesy: T. Mizuno et al., Hokkaido Univ. (Japan)
69. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 69
Parallels between LENRs and Lithium-based batteries
Neutron captures on Li release 27 million x more energy vs. chemical
Widom-Larsen theory posits following Lithium-target fuel LENR network cycle
“Ultra low momentum neutron catalyzed nuclear reactions on metallic
hydride surfaces” A. Widom and L. Larsen
European Physical Journal C – Particles and Fields 46 pp. 107-111 (2006)
ULMN-catalyzed LENR Lithium network cycle – from Eqs. 30 - 32
6Li + n 7Li
3 3
7Li + n 8Li
3 3
8Li 8Be + e- 3 4 e
8Be 4He + 4He
4 2 2
4He + n 5He
2 2
5He + n 6He
2 2
6He 6Li + e- 2 3 e
He is a
reactant in
this region;
captures
neutrons
ULM neutron
captures on
Lithium
Qv~16 MeV
Qv~92 keV
Low
energy
α-decay
Begin
Return cycle
8Li β-decay is largest single energy release in LENR Li cycle
End
Lithium-6 + 2 ULM neutrons g 2 Helium-4 + beta LENR neutron-catalyzed Lithium fuel cycle
particle + 2 neutrinos + Q-value = ~26.9 MeV
This particular cyclical LENR pathway can release about the
same amount of energy as the D-T fusion reaction without
creating any MeV-energy energetic neutrons, hard gamma
radiation, or radioactive isotopes. Although a portion of the
26.9 MeV in excess nuclear binding energy released is lost
(“haircut”) with emitted neutrinos, much of it still remains in
the kinetic energy of the two helium atoms (which are low-energy
alpha particles), and much more energetic beta
particle.
In this particular case, local solid matter is heated-up by the
scattering of low-energy alpha and much-higher-energy beta
particles; heavy-mass electrons also present in LENR-active
patches convert any locally produced hard gammas or X-rays
(from whatever process) directly into infrared heat.
70. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 70
Lattice Energy LLC has developed multiple alternative types of system embodiments for use in planned commercial versions of future LENR systems. Unfortunately, virtually all of them are highly proprietary, and cannot be discussed in a document such as this. That having been said, there is a generic type of LENR heat-producing device that can be discussed conceptually without disclosing sensitive engineering-related information
A major difference between chemical batteries and LENR technologies is that with batteries the on-demand conversion from stored chemical energy into electrical power output is intrinsically automatic and built-in. In the case of LENR-based heat- producing devices, the principal product of nuclear reaction pathways triggered by neutron absorption is mostly raw infrared heat, which must then be converted into electricity by separate, integrated heat-to-electricity or heat-to-shaft-rotation energy conversion subsystems. For example, in an integrated LENR-based power generation system solid-state thermoelectric devices could convert raw heat directly into high quality DC electrical power; steam engines could also be built
The chart on the next slide compares and contrasts selected aspects of a generic conceptualization of an LENR-based heat-producing device to a present-day advanced Lithium-based battery. It illustrates commonalities between various aspects of LENR-based systems and advanced Lithium-based battery technologies
Parallels between LENRs and Lithium-based batteries Advanced batteries and LENR devices have commonalities and overlaps
71. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 71
Parallels between LENRs and Lithium-based batteries
Advanced batteries and LENR devices have commonalities and overlaps
Aspect or characteristic
Advanced Lithium-ion polymer electrolyte batteries
Conceptualized LENR-based heat-producing eco-green nuclear device
Comments
Comments
Main purpose of device
Reversibly store electricity in chemical bonds
Power generation: release nuclear binding energy in form of IR heat
Anode
yes
Graphite (Carbon)
effectively
Nickel, Titanium, etc.
Cathode
yes
Li-iron phosphate
effectively
Nickel, Titanium, etc.
Electrolyte
yes
Carbon-H polymer
equivalent
Aqueous fluid with dissolved metal salts; H2 gas
Hydrogen isotopes (H) in some chemical form
yes
H in Carbon-H polymer (Cn-Hn)
yes
Either H or deuterium (D) in H2O/D2O or ionized gas – need H or D to make Widom-Larsen ULM neutrons
Key chemical element
Lithium
shuttles electrons at eV energies
Used as an electron carrier ion found in a chemical compound, e.g., LICoO2 or Li2FePO4
Lithium or alternative target release MeV nuclear binding energy
Can be ‘burned’ as target nuclear fuel source– present in electrolyte - Lithium –seed LENR network releases 27 MeV in nuclear binding energy
‘Fuel’
Electrochemical
electrons
Charge-up from electrical power source (e.g., grid); then discharge
SP and π electrons, + protons + Li and/or
Nickel, Titanium, or any target fuel element or isotope that can capture catalytic neutrons
Reactants ‘burned’ as nuclear fuels – in anode, cathode, and/or electrolyte – having no electrical charge, neutrons are promiscuous nuclear particles that can readily be captured by almost any element or isotope, which then triggers release of nuclear binding energy
Typical energy-scale of reactions
eVs
Simply chemical electronic energies
MeVs
Nuclear binding energies – Lithium (Li) target: its nuclear reactions release ~27 MeV; other elements release much less binding energy than Li
Principal output
Electricity
Voltages depend on chemistry
Thermal IR heat
Subsystem must convert into usable electricity
Uses nanotech?
yes
e.g., fabrication
yes
e.g., fabrication, materials, preparation of fuel target nanoparticles
Thermal mgmt. circuitry
yes
Prevent thermal failure events
yes
Prevent extreme overheating and thermal failure
Microprocessor controlled?
yes
Uses sensors to control power
yes
Uses sensors to manage and control power output
Eco-green?
yes
Safe disposal in landfills
yes
No radiation or ‘hot’ radioactive waste – OK landfills
72. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 72 Convergence of energetic materials, LENRs and batteries
September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 72
73. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 73
“Burn ‘em all --- let God sort ‘em out.” 1.
“You can run, but you can’t hide.” 2.
1.. Underlying motto unofficially adopted by various military groups; originally, was modernized from Latin, "Caedite eos. Novit enim Dominus qui sunt eius" which literally translated means “Kill them all. God will recognize His own." Quote attributed to Arnaud, Abbot of Citeaux, in reply to question asking how one might tell Cathar heretics from orthodox Catholics during siege of Beziers in Albigensian Crusade (July, 1209)
2. Threat made to Mad Max by a murderous character named “Wez” in Mel Gibson‘s cult-classic film, “The Road Warrior” (1981)
Adapted from a U.S. military motto:
Popularized by U.S. special operations forces during the 1960s Vietnam war
High thermal runaway temps create energetic materials
Leave domain of stable electrochemistry when batteries heat-up enough
LENRs are themselves energetic materials; can create many other energetic materials
Batteries cannot withstand star-like local temperatures created by electric arc discharges or LENRS and remain stable; LENR-based power systems can be designed to handle this, e.g. dusty plasmas
Creation of nightmarish local “witches’ brew” cauldrons of inter- reacting compounds and ions in some regions of failing batteries; very fast, hyper-accelerated reaction rates in superheated zones
Witches’ cauldrons can generate their own supplies of Oxygen to support combustion processes that propagate spatially within and between battery cells via fast-moving, autocatalytic flame-fronts coupled with intense emission of thermal infrared and UV radiation
Arc- and/or LENR-heated regions’ behavior is almost more akin to chemistry of stellar atmospheres than everyday electrochemistry
74. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 74
Causative agent that can trigger thermal runaways
Regime or
requirements
Physical dimensions
Key details
Temperature range in o C
Comments
Electric discharges: that is,
arcs or sparks; alternative names for internal electrical short circuits that can occur inside battery cells
Outer edges of tubular arc plasma sheath
Arc lengths can range in length from 2 nm between metallic nanoparticles all the way up to as long as several centimeters (cm) between larger structures
Chemical and nuclear reactions can occur within; dep. on current
~2,727 up to ~4,727
Heat radiation is mainly created via Joule heating by electrons and ions found in arc discharge plasma; very damaging to materials; can even breach battery cell case
Innermost core of arc plasma’s tubular sheath-like structure
~9,726 up to ~19,726
LENR-active hotspots: can occur on metallic surfaces or at oxide- metal interfaces anywhere inside battery where be: e-, p+ and metals
Require local presence of hydrogen (protons), metals, and surface plasmon or π electrons
2 nanometers (nm) to as large as ~100+ microns (μ) in diameter; roughly circular in shape
MeV-energy nuclear reactions occur within
~3,700 up to ~5,700
Directly radiate infrared heat photon energy; ionizes nearby molecules, materials, destroys μ-scale nanostructures
Formation of LiF releases one of the highest known energy per mass of reactants, only second to that of BeO
High thermal runaway temps create energetic materials
Formation of Lithium fluoride releases an enormous amounts of heat B787 GS Yuasa battery definitely contained LiPF6 - Lithium hexafluorophosphate
Identified in NTSB report as being detected during post-Logan incident materials analysis; at right - ionic molecular structure
Chosen for ferrying Li+ ions between anode and cathode because highly soluble in non-aqueous, nonpolar electrolyte solvents such as diethyl carbonate and dimethoxyethane
Melts at ~194o C; thermal decomposition begins 262- 284o C then decomposes into LiF and PF5
75. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 75
Source: “Chemical Principles” S. Zumdahl, pp. 608 in 6th edition, Houghton Mifflin (2009)
Figure 13.9 in Zumdahl
High thermal runaway temps create energetic materials
Leave domain of stable electrochemistry when high local temps occur
Once battery materials are locally heated to thousands of degrees and begin to intermix, the types of chemical as well as LENR reactions that are possible suddenly change radically and quite unpredictably. This confluence of mutually interacting and reinforcing processes creates what Prof. Michel Armand (Univ. Picardie, Paris) calls a fearsome “witches’ brew”
76. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 76
High thermal runaway temps create energetic materials
Al + HF reaction below releases ~6x as much thermal energy as TNT Curse of the pyrotechnics and thermites
Note: many thanks to J. Bruce Popp of FedEx for sending Lattice down this fruitful line of inquiry
Note: Al, Fe, Cu, and O are all available somewhere inside many types of batteries; potential to form various energetic materials in or near witches’ brew cauldron areas
Can potentially synthesize explosive nano pyrotechnic mixtures in localized regions
Examples of two classic very exothermic thermite reactions: Fe2O3 + 2 Al g 2 Fe + Al2O3 3 CuO + 2 Al g 3 Cu + Al2O3
Please recall that LiF can be formed in some battery cells; when it is heated enough beyond its B.P. (1,681o C) in witches’ cauldrons it can decompose to form HF, which can then enable the following: 2 Al(s) + 6 HF(g) 2 AlF3(s) + 3 H2(g)
Highest-temperature regions in and around localized witches’ cauldrons (almost star-like in many ways) can be hot enough to liberate metal ions which can then react with Oxygen to effectively create burning metals, which is often a high-temperature process:
Cobalt metal burns in air at ~2,760o C; Aluminum at ~3,827o C; Iron at ~870o C; etc. --- bottom line: burning metals spells big trouble
400 - 600oC
AlF3 rf Ho (solid) = - 1510.4 kJ/mol.
Al2O3 rf Ho (solid) = - 780 kJ/mol.
Al + HF is 2x CuO + Al and ~6x TNT
77. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 77
High thermal runaway temps create energetic materials
LENR-active surface sites can flash-vaporize refractory metals
“Phase explosion and Marangoni flow effects during laser micromachining of thin metal films”
http://lyle.smu.edu/~mhendija/index_files/Hendijanifard%20SPIE2008.pdf
Their most recently published work alone this line of inquiry is:
“Nanosecond time-resolved measurements of transient hole opening during laser micromachining of an Aluminum film”
M. Hendijanifard and D. Willis
Journal of Heat Transfer 35 article #091201 (2013)
Hendijanifard & Willis
Intense heating by nuclear processes during short lifetimes of micron-scale LENR-active sites on metallic substrates can result in local flash-boiling of metals in what is also known as a phase explosion. In such events, a local region of metal is vaporized; depending on which metal, heated material expands by 40,000 to 70,000 times its previous volume as a solid. Vapor cloud can cool and condense into tiny droplets, creating microspheres seen in SEM images Curse of the metallic phase explosions
78. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 78 Convergence of energetic materials, LENRs and batteries
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79. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 79
Lithium-based batteries come in many different chemistries
LiSOCl2
LiAg2CrO4
LiAg2V4O11
LiBi2Pb2O5
LiCuO
LiCuCl2
Li(CF)x
LiI2
LiCu4O(PO4)2
LiPbCuS
LiFeS2
Li-Cu4O(PO4)2
LiSO2Cl2
LiPbCuS
LiBi2O3
Li/AlMnO2
LiFeS
Li4Ti5O12
Li22Si4
80. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 80
1859
1989
1899
1991
1996
Increased battery energy density drives convergence Large uptick in past 25 years; lithium-air promises even higher density
2013
1859
1899
1989
1991
1996
Future: lithium-air?
2013
Lithium-based batteries became extremely dominant in portable electronics because they have much higher energy densities than other battery chemistries
Adapted from source: http://liteplusbattery.com/lifepo4-energy-density/
81. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 81
Increased battery energy density drives convergence Comparison of present Lithium-ion vs. future Lithium-air technology
Li-air battery reduces volume/weight by getting electron acceptor (O) from air
Source: http://www.longtailpipe.com/2013/03/toyota-research-into-lithium-air-and.html
82. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 82
Increased battery energy density drives convergence Lithium-air = Lithium-oxygen: practical density much > than Li-ion
Fig. 1 from: “Challenges and opportunities of nanostructured materials for aprotic rechargeable lithium-air batteries” J. Wang, Y. Li, and X. Sun, Nano Energy 2 pp. 443 - 467 (2013)
83. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 83
Source: http://www.extremetech.com/computing/126745-ibm-creates-breathing-high-density-light-weight-lithium-air-battery
Increased battery energy density drives convergence
IBM’s Lithium-air concept ca. 2012: an air-breathing advanced battery
Also see: http://www.ibm.com/smarterplanet/us/en/smart_grid/article/battery500.html
Credit: ca. 2012
84. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 84
Credit: ca. 2012
Increased battery energy density drives convergence IBM’s Lithium-air concept ca. 2012: an air-breathing advanced battery
Electron flow
How it works
Lithium-air batteries are air breathing. During discharge (driving), oxygen from the air reacts with lithium ions, forming lithium peroxide on a carbon matrix. Upon recharge, the oxygen is given back to the atmosphere and the lithium goes back onto the anode.
Oxygen
Oxygen
Carbon
Lithium ion
Lithium peroxide (Li2O2)
Oxygen
Lithium anode
Electrolyte
Li+
+
-
85. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 85
Increased battery energy density drives convergence Frequency of LENR issues in batteries might be even higher in future
“A critical review of Li/air batteries” J. Christensen et al. Journal of the Electrochemical Society, 159 pp. R1 - R30 (2012) http://www.eosenergystorage.com/documents/2012_JES_Christensen_Kojic_Critical_Review_Li-air.pdf “The pursuit of rechargeable solid-state Li-air batteries” F. Li et al. Energy & Environmental Science 6 pp. 2302 - 2311 (2013) http://pubs.rsc.org/en/content/articlelanding/2013/ee/c3ee40702k/unauth#!divAbstract
Excellent Li-air review papers:
Trends toward greatly increased energy densities in lithium-based batteries and expanding use of nanotech will probably continue; many researchers believe Li-air is most promising new battery chemistry/technology
Two papers cited to right provide comprehensive overviews of the present state-of-the-art with Li-air; after reading them, it appears that after several decades of R&D, Li-air battery technology is still in a state of considerable technical flux with many key, yet- to-be-answered questions. That being the case, it appears that large-scale commercial production of Li- air batteries is very probably 5 - 10 years in the future
Recognizing that many key technical details of Li-air batteries have yet to be worked-out, but given what has happened so far with lithium-based battery chemistries, there is no reason to believe a priori that such batteries would be immune to the risk of thermal runaways. Given much greater energy densities, one could argue that LENRs might be more likely in Li-air
86. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 86
Increased battery energy density drives convergence Since Sept. 2013 two major Li-air players have downgraded R&D effort
Source: http://qz.com/214969/two-big-labs-most-promising-next-generation-battery-electric-car/
“Two big labs step back from the most promising next-generation battery”
Steve Levine in Quartz May 30, 2014
“In a sign of more gloom in the struggle for a better battery, two major US labs have quietly downgraded research on a technology until now widely believed to be the most promising path to a competitive electric car.” “IBM and the US-funded Joint Center for Energy Storage Research (JCESR) have ratcheted down or outright abandoned their work on the lithium-air battery, a concept in which oxygen would react with lithium to create electricity.” “In a little-remarked-upon article in March, Nature magazine reported that IBM’s Winfried Wilcke, director of the Battery 500 Project, had a ‘change of heart’ about lithium-air and had turned his favor to a technology featuring sodium. In an electric car, a sodium-air battery, he said, stood a better chance of meeting the economics needed to compete with conventional cars. It was a dramatic move, with the most bullish player in lithium-air --- Wilcke himself --- calling it a day.”
87. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 87
Increased battery energy density drives convergence Since Sept. 2013 two major Li-air players have downgraded R&D effort
Source: http://qz.com/214969/two-big-labs-most-promising-next-generation-battery-electric-car/
“Two big labs step back from the most promising next-generation battery”
Steve Levine in Quartz May 30, 2014
“Wilcke did not respond to emails. An IBM spokesman told Quartz that the Nature report is accurate but said that the company is now working on both lithium-air and sodium.”
“About the same time, JCESR dropped its lithium-air project entirely. Like IBM, JCESR did not announce the decision publicly. Kevin Gallagher, a JCESR manager, said it concluded that the challenges were too overwhelming to resolve any time soon. ‘The penalty of using gaseous reactions overwhelmed any advantage,’ he told Quartz.”
“Lithium-air is not being abandoned everywhere. At Argonne, Michael Thackeray is directing work on a novel hybrid battery combining lithium-ion and lithium-air. The result is the potential for a battery with specific density of 500 watt hours per kilogram, two-and-a-half times greater than today’s best commercial lithium-ion cell.”
88. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 88
Increased battery energy density drives convergence Since Sept. 2013 two major Li-air players have downgraded R&D effort
Richard Van Noorden in Nature 507 pp. 26 - 28 March 5, 2014
Source: http://www.nature.com/polopoly_fs/1.14815!/menu/main/topColumns/topLeftColumn/pdf/507026a.pdf
“The rechargeable revolution: A better battery Chemists are reinventing rechargeable cells to drive down costs and boost capacity.”
“Modern Li-ion batteries hold more than twice as much energy by weight as the first commercial versions sold by Sony in 1991 --- and are ten times cheaper. But they are nearing their limit. Most researchers think that improvements to Li-ion cells can squeeze in at most 30% more energy by weight (see 'Powering up').” “Five years ago, Wilcke, who heads IBM's nanoscience and technology division in San Jose, California, launched a project to develop a car battery with an 800- kilometre range. At the start, he focused on the theoretical ultimate in energy-dense electrochemical storage: the oxidation of lithium with oxygen drawn from the air. Such 'breathing' batteries have a huge weight advantage over other types, because they do not have to carry around one of their main ingredients. A lithium-oxygen (Li- O) battery can, in theory, store energy as densely as a petrol engine --- more than ten times better than today's car battery packs.”
89. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 89
Increased battery energy density drives convergence Since Sept. 2013 two major Li-air players have downgraded R&D effort
Source: http://www.nature.com/polopoly_fs/1.14815!/menu/main/topColumns/topLeftColumn/pdf/507026a.pdf
“The rechargeable revolution: A better battery Chemists are reinventing rechargeable cells to drive down costs and boost capacity.”
“But after driving more than 22,000 kilometres in his [Tesla] electric roadster, Wilcke is happy with the 400-kilometre range that its battery already provides. The real problem, he says, is money: battery packs for electric cars cost more than $500 kWh−1. ‘What's holding back the mass acceptance of electric cars is really the price rather than the energy density,’ he says. So Wilcke now favours a cheaper breathing battery based on sodium. Theory predicts that sodium-oxygen (Na-O) batteries could provide only half the energy density of Li-O, but that is still five times better than Li-ion batteries. And sodium is cheaper than lithium, so Na-O might, Wilcke hopes, get closer to the $100- kWh−1goal that the JCESR and others have set for affordability.” “Wilcke's change of heart was undoubtedly influenced by the fact that many have given up hope on Li-O … ‘The bottom line is that Li-O has zero chance for vehicles,” says Stanley Whittingham … who invented the concept of Li-ion batteries in the 1970s …”
Richard Van Noorden in Nature 507 pp. 26 - 28 March 5, 2014
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91. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 91
Energy density scale-up can increase safety risks
High capacity applications for lithium-based batteries in autos/aircraft
Accidents with fires and explosions have been widely publicized on the Internet
“There are known knowns; there are things we know that we know. There are known unknowns; that is to say, there are things that we now know we don't know. But there are also unknown unknowns – there are things we do not know we don't know.” Donald Rumsfeld U.S. Secretary of Defense Press conference (2002)
92. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 92
Energy density scale-up can increase safety risks
High capacity applications for lithium-based batteries in autos/aircraft
Accidents with fires and explosions have been widely publicized on the Internet
Within the past several years, Lithium-based batteries have caused:
Incinerations of hybrid and all-electric consumer vehicles
Houses burned to the ground (EVs, laptop computers)
Cargo aircraft destroyed in flight with multiple crew fatalities
Thermal runaways on new passenger aircraft (Boeing 787)
Bizarre explosion of a Lithium-ion battery recycling plant
Unexplained destruction of US Navy ASDS all-electric minisub
And a myriad of other battery-related mishaps involving virtually every type of Lithium chemistry have been reported
93. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 93
Unfortunately, safer lead-acid batteries are impractical for all-electric vehicles and e-aircraft --- their energy densities are simply too low
Lead-acid batteries have been used safely in the U.S. for 150 years, nickel-cadmium for 67 years, consumer alkaline for 54 years; those chemistries are tried-and-true and well known to be relatively safe
By contrast, battery industry has had less than 25 years of experience with high-energy density Lithium-based batteries; most of that was in consumer portable electronics applications where power demand/storage was measured in Watt-hours, not kilowatt-hours
Energy density scale-up can increase safety risks
High capacity applications for lithium-based batteries in autos/aircraft
Accidents with fires and explosions have been widely publicized on the Internet
Scale-up of any technology involves a certain level of inescapable intrinsic risks, some of which are known, and some which are not, e.g. Rumsfeld’s “unknown unknowns”
94. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 94
Thermal runaway event inside single-cell, lithium-based button battery might ruin a small electronic device, but it probably won’t set anything else on fire or hurt any nearby person or persons seriously
Runaway inside smartphone’s multi-cell battery might start a woman’s handbag smoking or burn a hole through a man’s pants pocket, or make someone drop it, but it generally wouldn’t cause serious skin burns or ignite a large portion of someone’s clothing
Catastrophic runaways inside significantly larger, multi-cell laptop computer batteries have inflicted serious burns on people’s legs and in several documented cases, have even burned-down entire homes
Runaways involving large to extremely large many-cell secondary batteries on stationary (onsite back-up power) and mobile platforms such as hybrid or all-electric vehicles and passenger or cargo aircraft are very serious matters; can cause multiple fatalities and up to many millions of $ in physical damage to equipment and/or local facilities
Risks can increase with scale-up
Energy density scale-up can increase safety risks
Very large form-factor Lithium batteries can do vastly more damage
95. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 95
Energy density scale-up can increase safety risks Thermal runaways become more likely if heat dissipation is impaired
Surface area vs. volume decreases with increased size
Positive system-level thermal feedback loops leading to runaways become easier in larger sizes For exothermic electrochemical reactions that normally occur inside operating battery cells, total cell heat production scales with the cube of the size of the battery cell (V ∝ r³), but a cell’s heat transfer capability scales with square of the size (A ∝ r²), so that rate of heat production-to- area ratio scales with the size (V/A ∝ r) End-result of this immutable scaling relationship between volumetric generation of heat within a given mass of reactants in a cell versus its area- related ability to dissipate produced heat is that chemistries that may well operate very safely in small cells are potentially dangerous and quite thermally unstable in considerably larger ones Consequence: scale-up of the internal energy densities, electrical capacity, and sheer physical size of battery systems can lead to much larger, vastly more dangerous thermal runaway events
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Since 1991: improved battery energy densities enabled by Lithium-ion chemistry mutually reinforced and supported meteoric increases in global unit sales of portable electronic devices including laptop computers and cellphones and more recently, tablet computers and a myriad of different smartphones from many manufacturers
Using various different chemistries, next logical step for battery technologists was to scale-up arrays of batteries so that their total electrical storage capacity was enough for effective use in hybrid/all-electric vehicles (EVs) and even larger-scale applications
Persistently high gasoline prices encouraged CY 2000 global launch of first mass- produced, highly successful gasoline-electric hybrid car, the Toyota Prius. Market success of Prius along with continuing high gas prices and improvements in Li-ion technology encouraged development and sale of all-electric, plug-in vehicles by several new start-ups, notably Tesla (Roadster, 2008) and Fisker (Karma, 2012). Large established auto manufacturers now rising to meet upstarts’ competitive challenge
Also driven by high jet fuel prices, parallel developments also occurred in aircraft technology which encouraged adoption of much lighter-weight airframes (carbon-fiber composite vs. older tried-and-true aluminum) and more weight-efficient all-electric (vs. older hydraulic) critical aircraft systems; this led to utilization of high-energy-density batteries for onboard electric power. These new technological thrusts were embodied in Boeing Dreamliner (2012), Cessna Citation (2013), and Chinese Yuneec e430 (2013)
Energy density scale-up can increase safety risks Relatively high energy densities drove market success of Lithium
97. September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 97 Convergence of energetic materials, LENRs and batteries
September 6, 2013 Lattice Energy LLC, Copyright 2013 All rights reserved 97