Semester - I B) Reactive Intermediates by Dr Pramod R Padolepramod padole
The document discusses various reactive intermediates in organic chemistry, focusing on carbocations and carbanions. It defines carbocations as organic ions with a positively charged carbon atom and carbanions as organic ions with a negatively charged carbon atom. It describes their structures, methods of generation, stability orders, and factors affecting stability such as inductive and resonance effects. Carbocations are more stable with electron-donating groups or resonance, while carbanions are more stable with electron-withdrawing groups or resonance. The document also provides examples and practice questions related to these reactive intermediates.
La metodología Carl Orff se basa en el uso del cuerpo como instrumento musical, el ritmo y la palabra, la escala pentatónica y la improvisación. El método enfatiza la participación activa del estudiante a través de la interpretación de ritmos, formas musicales como el eco y el ostinato, y la improvisación rítmica, melódica y armónica utilizando instrumentos sencillos.
This document summarizes key differences between aldehydes and ketones. Aldehydes contain a carbonyl group attached to one carbon, while ketones have the carbonyl between two carbons. Aldehydes are easily oxidized to carboxylic acids, while ketones require more vigorous oxidation. Both can undergo nucleophilic addition reactions to form alcohols. Common tests to distinguish the two include Tollen's reagent and Fehling's reagent.
Este documento describe los compuestos carbonílicos como aldehídos, cetonas, ácidos carboxílicos y sus derivados. Explica las propiedades químicas de estos compuestos, incluidas las adiciones nucleófilas y reacciones de oxidación y reducción. También analiza los mecanismos de toxicidad del formaldehído y el acetaldehído, y cómo estos compuestos se encuentran en el medio ambiente y los alimentos. El documento proporciona ejemplos de estos compuestos y cómo se
This document provides information on various heterocyclic compounds. It discusses aromatic 5-membered rings including pyrrole, furan, and thiophene which follow Hückel's rule of 4n+2 delocalized pi electrons. Pyrrole is described as a colorless liquid that polymerizes readily upon exposure to air. Its chemical properties include acidification and participation in Ullmann and Bromination reactions. Larger heterocycles such as pyridine and derivatives are also covered, including their structures, aromatic properties, and common biological roles in molecules like vitamins. The document concludes with discussions of purine bases important in nucleic acids and alkaloid stimulants like caffeine that are derived from them.
The document discusses the properties of d-block elements or transition elements. It describes their position in the periodic table, electronic configuration, and trends in various properties across the transition series. The key points are:
1) Transition elements have partially filled d orbitals and lie between the electropositive s-block and electronegative p-block elements in the periodic table.
2) Their electronic configurations follow the pattern [n-1]d1-10ns1-2 and there are three series of transition elements based on the d orbital - d-block, d-block and f-block.
3) Transition elements show variable oxidation states, high melting points, form colored compounds and alloys
Alkyl halides contain a halogen atom bonded to an alkyl group. They are named as substituents with prefixes like chloro, bromo or iodo. Aromatic compounds like benzene are important industrially. Substituents on benzene rings are named as ortho, meta, or para based on position. Ethers contain an oxygen atom between two alkyl groups. They are named by identifying the parent alkyl groups and noting the alkoxy substituent.
Semester - I B) Reactive Intermediates by Dr Pramod R Padolepramod padole
The document discusses various reactive intermediates in organic chemistry, focusing on carbocations and carbanions. It defines carbocations as organic ions with a positively charged carbon atom and carbanions as organic ions with a negatively charged carbon atom. It describes their structures, methods of generation, stability orders, and factors affecting stability such as inductive and resonance effects. Carbocations are more stable with electron-donating groups or resonance, while carbanions are more stable with electron-withdrawing groups or resonance. The document also provides examples and practice questions related to these reactive intermediates.
La metodología Carl Orff se basa en el uso del cuerpo como instrumento musical, el ritmo y la palabra, la escala pentatónica y la improvisación. El método enfatiza la participación activa del estudiante a través de la interpretación de ritmos, formas musicales como el eco y el ostinato, y la improvisación rítmica, melódica y armónica utilizando instrumentos sencillos.
This document summarizes key differences between aldehydes and ketones. Aldehydes contain a carbonyl group attached to one carbon, while ketones have the carbonyl between two carbons. Aldehydes are easily oxidized to carboxylic acids, while ketones require more vigorous oxidation. Both can undergo nucleophilic addition reactions to form alcohols. Common tests to distinguish the two include Tollen's reagent and Fehling's reagent.
Este documento describe los compuestos carbonílicos como aldehídos, cetonas, ácidos carboxílicos y sus derivados. Explica las propiedades químicas de estos compuestos, incluidas las adiciones nucleófilas y reacciones de oxidación y reducción. También analiza los mecanismos de toxicidad del formaldehído y el acetaldehído, y cómo estos compuestos se encuentran en el medio ambiente y los alimentos. El documento proporciona ejemplos de estos compuestos y cómo se
This document provides information on various heterocyclic compounds. It discusses aromatic 5-membered rings including pyrrole, furan, and thiophene which follow Hückel's rule of 4n+2 delocalized pi electrons. Pyrrole is described as a colorless liquid that polymerizes readily upon exposure to air. Its chemical properties include acidification and participation in Ullmann and Bromination reactions. Larger heterocycles such as pyridine and derivatives are also covered, including their structures, aromatic properties, and common biological roles in molecules like vitamins. The document concludes with discussions of purine bases important in nucleic acids and alkaloid stimulants like caffeine that are derived from them.
The document discusses the properties of d-block elements or transition elements. It describes their position in the periodic table, electronic configuration, and trends in various properties across the transition series. The key points are:
1) Transition elements have partially filled d orbitals and lie between the electropositive s-block and electronegative p-block elements in the periodic table.
2) Their electronic configurations follow the pattern [n-1]d1-10ns1-2 and there are three series of transition elements based on the d orbital - d-block, d-block and f-block.
3) Transition elements show variable oxidation states, high melting points, form colored compounds and alloys
Alkyl halides contain a halogen atom bonded to an alkyl group. They are named as substituents with prefixes like chloro, bromo or iodo. Aromatic compounds like benzene are important industrially. Substituents on benzene rings are named as ortho, meta, or para based on position. Ethers contain an oxygen atom between two alkyl groups. They are named by identifying the parent alkyl groups and noting the alkoxy substituent.
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This is a report about Aldehydes. The content of this slideshow are as follows: What is an aldehyde, How to name aldehydes with IUPAC Nomenclature and Common Names, The Physical Properties of Aldehydes, and the examples of aldehyde and its uses. The main objective of this report is to widen the knowledge of the readers/learners concerning of the stated topic so that they can further understand the concept of aldehydes.
Report made by: Students of Sogod National High School STEM 9-Newton
Kyla Krystelle Salva
Krishia Belle Cambalon
Marycris Felicilda
A project on the Mother plant of Petrochemical Industry.
110 MT per year production capacity of NCP plant at RIL- VMD. Detailed studies on Short residence time Furnaces, Distillation columns, Catalytic converters, heat exchangers etc. calculations made on process parameters and mechanical design aspects.
This document provides information about alcohols, including their structure, nomenclature, and classification. It begins by reviewing hydrocarbons and noting that alcohols differ in that they contain an OH (hydroxyl) functional group. Alcohols are classified as primary, secondary, or tertiary depending on whether the alcohol carbon is bonded to 1, 2, or 3 carbon atoms. Naming involves identifying the parent chain and lowest locant for the OH group. Examples of methanol, butanol, and isopropanol are provided to illustrate the nomenclature rules.
Aldehydes and ketones are carbonyl compounds that contain a carbon-oxygen double bond. Aldehydes contain a carbonyl group bonded to at least one hydrogen, while ketones do not contain any hydrogens bonded to the carbonyl carbon. Carbonyl compounds are more polar than alkanes due to the electronegative oxygen, allowing them to hydrogen bond. Common reactions of aldehydes and ketones include oxidation, reduction, and addition reactions. Oxidation of aldehydes forms carboxylic acids, while ketones cannot be oxidized further. Reduction adds hydrogen, converting aldehydes to primary alcohols and ketones to secondary alcohols. Addition reactions with alcoh
medicinal importance of all types of alkaloids.keshob ghosh
Claudius Galenus (130-200 AD) was an ancient Roman physician, surgeon and philosopher who is considered the father of pharmacy. He lived in Pergamon, Turkey and practiced medicine in Rome, Italy.
The document discusses the classification of alkaloids. It covers biosynthetic classification based on amino acid precursors, chemical classification, pharmacological classification based on mechanism of action and effects, and taxonomic classification based on the organisms that produce them. Examples of different types of alkaloids like morphine, caffeine, and pilocarpine are provided along with their properties and uses.
Toluene is an aromatic hydrocarbon that is a colorless, flammable liquid with a benzene-like odor. It is insoluble in water but soluble in organic solvents. Toluene's main uses are as a precursor to benzene in chemical production, as an octane booster in gasoline, and as an industrial solvent. It is emitted from facilities involved in crude oil and natural gas extraction and petroleum refining.
Chapter 12 aldehydes ketones and carboxylic_acidssuresh gdvm
This document contains sample questions and answers about aldehydes, ketones, and carboxylic acids from Class XII Chemistry Chapter 12. The questions cover defining and giving examples of reaction types, naming compounds using IUPAC nomenclature, drawing structures of derivatives, predicting reaction products, and converting between related compounds.
Alkanes are saturated hydrocarbons that contain only carbon and hydrogen. They have the general formula CnH2n+2 and contain single bonds between carbon atoms. Alkanes are highly stable due to weak polarization of carbon-hydrogen bonds. They undergo substitution reactions and reactions at high temperatures like halogenation and cracking. Alkanes can be synthesized by hydrogenation of alkenes/alkynes, reduction of alkyl halides, and Wurtz reaction.
The document discusses recent advances in 1,3-dipolar cycloadditions. It begins by introducing the [3+2] 1,3-dipolar cycloaddition reaction which combines a dipolarophile and 1,3-dipole to form a five-membered heterocycle. This reaction is widely used in natural product and pharmaceutical synthesis. It then describes different types of dipolarophiles and 1,3-dipoles that can be used. The reaction mechanisms, classification based on frontier molecular orbitals, effect of Lewis acids, and methods for asymmetric variants are also covered. Recent literature examples of this reaction in natural product synthesis and regioselectivity/stereoselectivity are summarized.
This document discusses aromatic compounds and benzene chemistry. It begins by introducing aromatic hydrocarbons and noting they have different properties than aliphatic hydrocarbons. Benzene, the simplest aromatic hydrocarbon, is described as having posed problems for early chemists to determine its structure. Kekulé proposed benzene has alternating single and double bonds, but this did not explain its chemical behavior. The resonance structure of benzene is able to account for its reactivity. The document continues discussing nomenclature of aromatic compounds with different numbers of substituents on the benzene ring. Characteristic reactions of benzene like halogenation and nitration are also covered. Phenols are introduced as aromatic compounds containing an -OH group
Este documento trata sobre los compuestos aromáticos y sus propiedades. Explica que los compuestos aromáticos contienen anillos cerrados de átomos de carbono que presentan gran estabilidad debido a su estructura resonante. Luego describe algunos compuestos aromáticos importantes como las hormonas, vitaminas y condimentos. Finalmente, analiza en mayor profundidad las propiedades y reacciones del benceno, un compuesto aromático clave.
Aldehydes are organic compounds containing a carbonyl group with the formula -CHO. They consist of a carbon double bonded to oxygen and single bonded to hydrogen and an R group. Common aldehydes include formaldehyde, acetaldehyde, and benzaldehyde. Aldehydes have medical uses as disinfectants and for treating cardiovascular disease. Industrially, they are used as food flavorings, solvents, and in perfumes. Breathing or contacting aldehydes can irritate lungs, skin, and eyes. Repeated exposure may cause damage to organs and cancer. Aldehydes are also formed endogenously during lipid peroxidation and metabolism.
El documento resume la evolución de la música en el cine desde los años 1908 hasta la actualidad. Se destaca que en 1908 surgió la primera banda sonora original para una película y que en 1914 se generalizaron las composiciones musicales originales con estudios contratando a sus propios compositores. La música en el cine ha ido profesionalizándose y perfeccionándose a lo largo de las décadas, con compositores emblemáticos en cada época y nuevas tecnologías como el sintetizador en los años 80.
Aldehydes and ketones contain the carbonyl group. Aldehydes are considered the most important functional group. Ketones A carbon double bonded to an oxygen is called a carbonyl group. Compounds in which the carbon of a carbonyl group is bonded to two other carbons
The document contains information about 5 students' matric numbers and a passage discussing alkyl halides. It defines alkyl halides and describes their classification, nomenclature, physical properties, synthesis from alcohols and alkenes, and reactions including nucleophilic substitution and elimination. Examples are provided to illustrate key concepts and reaction mechanisms.
Citral is an acyclic compound containing two double bonds and an aldehyde group. It exists as two cis-trans isomers that differ in the orientation of the aldehyde group relative to the double bond and methylene group. This isomerism is evidenced by citral forming two different semicarbazones and reducing to either geraniol or nerol depending on the isomer. NMR data also shows differences between the isomers due to magnetic shielding effects. The carbon skeleton of citral contains two isoprene units joined head to tail, which is revealed through its cyclization to p-cymene when heated.
This document discusses aldehydes, ketones, and carboxylic acids. It begins by stating the objectives of understanding the nomenclature, structures, properties, reactions and uses of these carbonyl compounds. It then defines aldehydes as containing a carbonyl group bonded to a carbon and hydrogen, ketones as bonded to two carbons, and carboxylic acids as bonded to an oxygen. The document provides examples of common and IUPAC names for some aldehydes and ketones. It notes that carbonyl compounds play important roles in biochemistry, adding flavors and fragrances to nature. They are also used in foods, pharmaceuticals, solvents, and materials like plastics and fabrics.
Presentation by
Primary Information Services
www.primaryinfo.com
mailto:primaryinfo@gmail.com
Download PDF Version at
https://www.slideshare.net/thorapadi/presentations
See You tube Channel
https://www.youtube.com/user/ch600091/videos?view_as=subscriber
This is a report about Aldehydes. The content of this slideshow are as follows: What is an aldehyde, How to name aldehydes with IUPAC Nomenclature and Common Names, The Physical Properties of Aldehydes, and the examples of aldehyde and its uses. The main objective of this report is to widen the knowledge of the readers/learners concerning of the stated topic so that they can further understand the concept of aldehydes.
Report made by: Students of Sogod National High School STEM 9-Newton
Kyla Krystelle Salva
Krishia Belle Cambalon
Marycris Felicilda
A project on the Mother plant of Petrochemical Industry.
110 MT per year production capacity of NCP plant at RIL- VMD. Detailed studies on Short residence time Furnaces, Distillation columns, Catalytic converters, heat exchangers etc. calculations made on process parameters and mechanical design aspects.
This document provides information about alcohols, including their structure, nomenclature, and classification. It begins by reviewing hydrocarbons and noting that alcohols differ in that they contain an OH (hydroxyl) functional group. Alcohols are classified as primary, secondary, or tertiary depending on whether the alcohol carbon is bonded to 1, 2, or 3 carbon atoms. Naming involves identifying the parent chain and lowest locant for the OH group. Examples of methanol, butanol, and isopropanol are provided to illustrate the nomenclature rules.
Aldehydes and ketones are carbonyl compounds that contain a carbon-oxygen double bond. Aldehydes contain a carbonyl group bonded to at least one hydrogen, while ketones do not contain any hydrogens bonded to the carbonyl carbon. Carbonyl compounds are more polar than alkanes due to the electronegative oxygen, allowing them to hydrogen bond. Common reactions of aldehydes and ketones include oxidation, reduction, and addition reactions. Oxidation of aldehydes forms carboxylic acids, while ketones cannot be oxidized further. Reduction adds hydrogen, converting aldehydes to primary alcohols and ketones to secondary alcohols. Addition reactions with alcoh
medicinal importance of all types of alkaloids.keshob ghosh
Claudius Galenus (130-200 AD) was an ancient Roman physician, surgeon and philosopher who is considered the father of pharmacy. He lived in Pergamon, Turkey and practiced medicine in Rome, Italy.
The document discusses the classification of alkaloids. It covers biosynthetic classification based on amino acid precursors, chemical classification, pharmacological classification based on mechanism of action and effects, and taxonomic classification based on the organisms that produce them. Examples of different types of alkaloids like morphine, caffeine, and pilocarpine are provided along with their properties and uses.
Toluene is an aromatic hydrocarbon that is a colorless, flammable liquid with a benzene-like odor. It is insoluble in water but soluble in organic solvents. Toluene's main uses are as a precursor to benzene in chemical production, as an octane booster in gasoline, and as an industrial solvent. It is emitted from facilities involved in crude oil and natural gas extraction and petroleum refining.
Chapter 12 aldehydes ketones and carboxylic_acidssuresh gdvm
This document contains sample questions and answers about aldehydes, ketones, and carboxylic acids from Class XII Chemistry Chapter 12. The questions cover defining and giving examples of reaction types, naming compounds using IUPAC nomenclature, drawing structures of derivatives, predicting reaction products, and converting between related compounds.
Alkanes are saturated hydrocarbons that contain only carbon and hydrogen. They have the general formula CnH2n+2 and contain single bonds between carbon atoms. Alkanes are highly stable due to weak polarization of carbon-hydrogen bonds. They undergo substitution reactions and reactions at high temperatures like halogenation and cracking. Alkanes can be synthesized by hydrogenation of alkenes/alkynes, reduction of alkyl halides, and Wurtz reaction.
The document discusses recent advances in 1,3-dipolar cycloadditions. It begins by introducing the [3+2] 1,3-dipolar cycloaddition reaction which combines a dipolarophile and 1,3-dipole to form a five-membered heterocycle. This reaction is widely used in natural product and pharmaceutical synthesis. It then describes different types of dipolarophiles and 1,3-dipoles that can be used. The reaction mechanisms, classification based on frontier molecular orbitals, effect of Lewis acids, and methods for asymmetric variants are also covered. Recent literature examples of this reaction in natural product synthesis and regioselectivity/stereoselectivity are summarized.
This document discusses aromatic compounds and benzene chemistry. It begins by introducing aromatic hydrocarbons and noting they have different properties than aliphatic hydrocarbons. Benzene, the simplest aromatic hydrocarbon, is described as having posed problems for early chemists to determine its structure. Kekulé proposed benzene has alternating single and double bonds, but this did not explain its chemical behavior. The resonance structure of benzene is able to account for its reactivity. The document continues discussing nomenclature of aromatic compounds with different numbers of substituents on the benzene ring. Characteristic reactions of benzene like halogenation and nitration are also covered. Phenols are introduced as aromatic compounds containing an -OH group
Este documento trata sobre los compuestos aromáticos y sus propiedades. Explica que los compuestos aromáticos contienen anillos cerrados de átomos de carbono que presentan gran estabilidad debido a su estructura resonante. Luego describe algunos compuestos aromáticos importantes como las hormonas, vitaminas y condimentos. Finalmente, analiza en mayor profundidad las propiedades y reacciones del benceno, un compuesto aromático clave.
Aldehydes are organic compounds containing a carbonyl group with the formula -CHO. They consist of a carbon double bonded to oxygen and single bonded to hydrogen and an R group. Common aldehydes include formaldehyde, acetaldehyde, and benzaldehyde. Aldehydes have medical uses as disinfectants and for treating cardiovascular disease. Industrially, they are used as food flavorings, solvents, and in perfumes. Breathing or contacting aldehydes can irritate lungs, skin, and eyes. Repeated exposure may cause damage to organs and cancer. Aldehydes are also formed endogenously during lipid peroxidation and metabolism.
El documento resume la evolución de la música en el cine desde los años 1908 hasta la actualidad. Se destaca que en 1908 surgió la primera banda sonora original para una película y que en 1914 se generalizaron las composiciones musicales originales con estudios contratando a sus propios compositores. La música en el cine ha ido profesionalizándose y perfeccionándose a lo largo de las décadas, con compositores emblemáticos en cada época y nuevas tecnologías como el sintetizador en los años 80.
Aldehydes and ketones contain the carbonyl group. Aldehydes are considered the most important functional group. Ketones A carbon double bonded to an oxygen is called a carbonyl group. Compounds in which the carbon of a carbonyl group is bonded to two other carbons
The document contains information about 5 students' matric numbers and a passage discussing alkyl halides. It defines alkyl halides and describes their classification, nomenclature, physical properties, synthesis from alcohols and alkenes, and reactions including nucleophilic substitution and elimination. Examples are provided to illustrate key concepts and reaction mechanisms.
Citral is an acyclic compound containing two double bonds and an aldehyde group. It exists as two cis-trans isomers that differ in the orientation of the aldehyde group relative to the double bond and methylene group. This isomerism is evidenced by citral forming two different semicarbazones and reducing to either geraniol or nerol depending on the isomer. NMR data also shows differences between the isomers due to magnetic shielding effects. The carbon skeleton of citral contains two isoprene units joined head to tail, which is revealed through its cyclization to p-cymene when heated.
This document discusses aldehydes, ketones, and carboxylic acids. It begins by stating the objectives of understanding the nomenclature, structures, properties, reactions and uses of these carbonyl compounds. It then defines aldehydes as containing a carbonyl group bonded to a carbon and hydrogen, ketones as bonded to two carbons, and carboxylic acids as bonded to an oxygen. The document provides examples of common and IUPAC names for some aldehydes and ketones. It notes that carbonyl compounds play important roles in biochemistry, adding flavors and fragrances to nature. They are also used in foods, pharmaceuticals, solvents, and materials like plastics and fabrics.
2. jsou
to organické sloučeniny
obsahující karbonylovou skupinu
mají ke karbonylové skupině připojeny
dva uhlovodíkové zbytky
3. Triviální
systematické, které se tvoří příponou -on. Ta
se přidává k názvu uhlovodíku
1. Název základního uhlovodíku je propan.
2. Připojíme k názvu uhlovodíku příponu -on.
3. propan + -on = propanon
nebo
je uhlovodíkový zbytek methanu, který se
nazývá methyl. Methyly jsou tam dva, takže
je to dimethyl + keton = dimethylketon
(triviální název - aceton)
4. Obr.č.1
Vlastnosti:
Je to bezbarvá, hořlavá a
jedovatá kapalina
charakteristického zápachu,
neomezeně mísitelná s vodou.
Jeho páry tvoří se vzduchem
výbušnou směs.
5. Použití:
Je to výborné rozpouštědlo
nátěrových hmot a laků na
nehty. Používá se k výrobě
umělého hedvábí, plastů a
barviv a jeho bromové a
chlorové deriváty mají silné
slzotvorné účinky.
Obr.č.2
6. V lidském organismu vzniká aceton v malém
množství spontánní dekarboxylací acetacetátu, látky,
která vzniká v játrech při zpracování mastných kyselin
(z tuků). Acetacetát je tzv. ketolátka, která slouží jako
alternativní zdroj energie (místo glukózy) pro buňky
během hladovění. Aceton je vydýcháván v plicích. Při
DIABETU se tvoří zvýšené množství ketolátek, proto
je dech diabetiků cítit po acetonu.
7. Aceton je základní surovinou chemického průmyslu.
Methylester kyseliny akrylové je základní stavební
prvek polymeru známého jako plexisklo. Aceton se
také využívá na výrobu podpatků a podrážek a jiných
gumových dílů obuvi.