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International Journal of Civil Engineering and Technology (IJCIET)
Volume 10, Issue 01, January 2019, pp. 1862-1869, Article ID: IJCIET_10_01_172
Available online at http://www.iaeme.com/ijciet/issues.asp?JType=IJCIET&VType=10&IType=01
ISSN Print: 0976-6308 and ISSN Online: 0976-6316
© IAEME Publication Scopus Indexed
MATHEMATICAL COMPUTATION OF WATER
QUALITY INDEX FOR THE ASSESSMENT OF
AL-HILLA RIVER ECOSYSTEM
I. A. Al-Ani
Civil Engineering Department, Al-Farabi University College, Baghdad, Iraq
ABSTRACT
Al-Hilla River has a great importance to the people in the vicinity which serves as
a main drinking and irrigation source. The aim of the current study is to estimate the
Water Quality Index (WQI) of Al-Hilla River, southern Baghdad using the weighted
arithmetic water quality index method. Water samples were collected from 7 stations
in March in which eight water quality parameters were analyzed: Turbidity, total
dissolved solids, dissolved oxygen, concentration of hydrogen ion, electrical
conductivity, chlorides, alkalinity and biological oxygen demand. The calculated WQI
of Al-Hilla River indicates that the river water is unsuitable for drinking which is
majorly attributed to the total dissolved solids and turbidity. This interprets the
condition of the river which can help the local authority in taking action by identifying
the sources of pollution and improving the water quality and stakeholders should be
involved in the decision making and mitigation alternatives.
Key words: WQI, Al-Hilla River, Euphrates River, Iraq
Cite this Article: I. A. Al-Ani, Mathematical Computation of Water Quality Index for
the Assessment of Al-Hilla River Ecosystem, International Journal of Civil Engineering
and Technology, 10(01), 2019, pp. 1862–1869
http://www.iaeme.com/IJCIET/issues.asp?JType=IJCIET&VType=10&IType=01
1. INTRODUCTION
The two dominating surface water sources in Iraq are Tigris and Euphrates and their tributaries.
Besides the surface water, ground water and springs can be considered as supporting sources
[1]. Nowadays, Iraq facing a real water crisis as the discharge in both of Tigris and Euphrates
goes down to a remarkable values which affects the drinking, irrigation and other uses in the
country. This is due to the building of many dams on both of the rivers in the riparian countries,
climate change and the severe decrease in annual precipitation which reduces Iraqi share of
water [2]. With the available quantity of water, the quality is highly recommended to be
investigated. According to the Ministry of Water Resources, 32 percentages of Iraqis has an
access to clean drinking water and only 19 percentages has an access to an acceptable sewage
I. A. Al-Ani
http://www.iaeme.com/IJCIET/index.asp 1863 editor@iaeme.com
system [3 and 4]. There are varieties of pollutants being disposed into both rivers from the non-
point sources (i.e. runoff) and point sources (like industrial wastes, agricultural and sewage)
[5]. This necessitates more studies on water quality in Iraqi rivers in order to identify the major
sources of pollution and mitigation alternatives.
[6] Assessed the Water Quality Index (WQI) of 11 streams and the receiving UM- Al Naaj
marshland at Misan governorate, Iraq using five water quality parameters in which it is
indicated that the quality of water ranging from good to excellent. [2] Assesses the drinking
water quality of Al-Kufa River for a duration of 12 months using the WQI and the Geographic
Information System (GIS) in which it is indicated that the quality of Al-Kufa River is classified
as very poor. This is due to the human activities along the river banks. [7] Evaluated the water
quality via WQI of Al-Gharraf River, branch of Tigris River in the southern parts of Iraq in
which samples were collected from five stations for duration of one year and eleven water
quality parameters were considered. Results showed different index for different stations in
which the water is poor in stations 1,2,3 and 4 whereas showed very poor quality in station 5.
Another study was performed in Iraq in which ten water quality parameters were adopted to
estimate the WQI in Dokanlake in northern parts of the country. Results showed that the quality
of water is deteriorating which was good in years 1978, 1979, 1980, 1999, 2000 and 2008 to
be a poor quality in 2009 and it is recommended the continuous monitoring of the water quality
in the lake for proper management and action [8].
The objectives of the current work is to apply the water quality index (WQI) for Al-Hilla
River based on the monitored water quality parameters and to help the local authority
concerning proper organization of water resources. Furthermore, is to shape a base data which
will help in future water supervision and protection preparations.
2. MATERIALS AND METHODS
2.1. Study Area
The study area is located in Al-Hilla city, Babylon, south of the capital Baghdad. Euphrates
River enters Babylon and divided into two rivers; the first one goes to Karbalaa and the second
one enter to Al-Hilla city and supply the water to the city. Figure 1 depicts the study area.
Figure 1 Location of the study area
Location
of
Mathematical Computation of Water Quality Index for the Assessment of Al-Hilla River
Ecosystem
http://www.iaeme.com/IJCIET/index.asp 1864 editor@iaeme.com
2.2. Data Collection
Data collection includes water quality samplings that have been collected from seven stations
in which each station consists of three locations (i.e. left, middle and right of
Figure 2 Water quality sampling stations
Table 1 Coordinates of water sampling
No. Location Latitude Longitude
1 Left 32.4592 44.4426
2 Middle 32.4591 44.4422
3 Right 32.4592 44.4419
4 Left 32.4584 44.4422
5 Middle 32.4583 44.4424
6 Right 32.4582 44.4420
7 Left 32.4569 44.4431
8 Middle 32.4568 44.4428
9 Right 32.4567 44.4424
10 Left 32.4560 44.4434
11 Middle 32.4561 44.4430
12 Right 32.4559 44.4425
13 Left 32.4551 44.4437
14 Middle 32.4549 44.4433
15 Right 32.4546 44.4430
16 Left 32.4535 44.4444
17 Middle 32.4534 44.4439
18 Right 32.4532 44.4436
19 Left 32.4515 44.4435
20 Middle 32.4513 44.4449
21 Right 32.4508 44.4449
I. A. Al-Ani
http://www.iaeme.com/IJCIET/index.asp 1865 editor@iaeme.com
Water samples were collected in March. Samples were analyzed according to American
Public Health Association (AHPA) standard methods [9]. Table 2 presents the monitored water
quality parameters.
Table 2 Water quality parameters
No. Parameter Unit Site
1 Turbidity NTU Laboratory
2 TDS mg/l Laboratory
3 DO mg/l In situ
4 pH pH units In situ
5 Electrical Conductivity µS/cm In situ
6 Chlorides mg/l Laboratory
7 Alkalinity mg/l Laboratory
8 BOD mg/l Laboratory
2.3. Water Quality Index Calculation
The water quality index for the river was calculated based on weighted arithmetic index method
for eight parameters namely: pH, turbidity, TDS, BOD, DO, alkalinity, chlorides and electrical
conductivity for seven stations in which each station got three sampling points (i.e. left side,
middle and right side of the river) as indicated in Figure 2. The weighted arithmetic water
quality index method was applied [10] in which the water quality parameters were multiplied
by a weighting factor and are then aggregated using a simple arithmetic mean using the
following equations:
Qi =
Mi − Li
Si − Li
x 100
Wi =
K
Si
WQI = ∑
∑
Where, Qi is the sub index of the ith parameter, Wi is the unit weightage of the ith
parameter, n is the number of parameters included, Mi is the monitored value of the parameter,
Li is the ideal value, Si is the standard value of the ith parameter.
According to [11], the quality of water regarding the WQI classification is given in Table
3
Table 3 Water Quality Index Classification
Range Quality
0-25 Excellent
26-50 Good
51-75 Poor
76-100 Very poor
>100 Unsuitable for drinking
Mathematical Computation of Water Quality Index for the Assessment of Al-Hilla River
Ecosystem
http://www.iaeme.com/IJCIET/index.asp 1866 editor@iaeme.com
3. RESULTS AND DISCUSSIONS
Based on the equations listed above, the WQI for the seven stations in Al-Hilla River was
calculated using the weighted arithmetic index method for the eight parameters mentioned
earlier in this study. The results of water quality monitoring for the seven stations are presented
in Table 4. In each station, three samples are collected (left side, middle and right side of the
river) and then average values for each station were adopted. Based on the results of monitoring
in the river, there are some differences in water quality parameters within the seven stations.
WQI calculations denoted that the quality of the water is decreasing as moving downstream.
This can be attributed to the multiple discharge points (i.e. sewage from multiple sources) along
the river which introduces various pollutants. The Iraqi water crises caused by building of dams
in Turkey, limited rain and the old irrigation system (produces high losses) which subsequently
results in fluctuations in water level and hence encouraged the drainage of groundwater into
the river water body [12]. This fluctuation in water level affects the quality of water especially
in summer when the water from reservoirs (full of organic materials and sediments) is
discharged into the water body to compensate the reduction in water level [13]. Furthermore,
soil erosion caused by runoff has dramatic impact as it introduces large quantities of sediments
and suspended solids to the water body [14].
Table 6 illustrates the results of WQI for the stations of one to seven which are 474.95,
505.97, 510.86, 480.34, 447.7, 526.21 and 501.43 respectively in which the water quality in all
stations is classified as unsuitable for drinking (refer to Table 3).
In Al-Hilla River, each of the monitored water quality parameters give different value for
different stations due to the reasons highlighted earlier as illustrated in Table 4. For the
turbidity, it is considered as an essential water quality parameter since it affects the water via
suspended particles and affects other parameters like DO and BOD [15]. It is clear that the
turbidity values for all the stations are much higher than the standard value < 5 NTU specified
by WHO [3]. The turbidity values play an important role in deteriorating the WQI for the seven
stations. For the TDS values, it is clear also that some of the monitored values are higher than
the standard value specified by WHO [3] is 1000 mg/l. According to Table 4, the TDS values
in stations 1, 2, 4, 5, 6 and 7 are exceeding the standard value except station 3 which is below
the recommended level.
Table 4 Monitored values of water quality parameters
Parameter Station 1 Station 2 Station 3 Station 4 Station 5 Station 6 Station 7
Turbidity 80 85 87 79 73 88 81
TDS 1009.8 1012.95 617.85 1037.7 1011.15 1011.15 1019.25
DO 7.2 6.8 6.6 6.5 7.1 7.3 7.5
pH 6.69 6.69 7.06 6.68 6.75 6.85 6.87
EC 1122 1125.5 980 1153 1123.5 1123.5 1132.5
Cl 150 163 188 197 211 199 201
Alkalinity 245 220.5 140.5 273 204 236 252
BOD 2 2.61 3.2 3.56 4.3 4.7 7.3
The DO is an important water quality parameter in evaluating the quality of water since it
is essential in bacterial actions in breaking down the organic matter available in water [16].
The DO values monitored in the river are higher than the standard value 5 mg/l. concerning the
pH values; they are different between stations in an acceptable level with a standard value of
7.5
I. A. Al-Ani
http://www.iaeme.com/IJCIET/index.asp 1867 editor@iaeme.com
The values of electrical conductivity (EC) monitored in the river for all the stations show
very high level as compared with the standard value of 250 µS/cm set by WHO [3]. The values
of chlorides were acceptable in which they are below the standard set by WHO. For the
alkalinity, only station 3 is below the standard < 200 mg/l as CaCo3 whereas other stations
recorded higher values.
Eventually, the BOD values for the stations of one to six recorded lower values than the
standard value of 5 mg/l except station 7 which recorded a value of 7.3 mg/l.
The ideal values and standard values for the eight water quality parameters are presented
in Table 5 below:
Table 5 Standard and ideal values of water quality parameters
Parameter Standard value Ideal value
Turbidity 5 0
TDS 1000 0
DO 5 14.6
pH 7.5 7
EC 250 0
Cl 350 0
Alkalinity 200 0
BOD 5 0
The estimated water quality index values for the seven stations are presented in Table 6
below.
Table 6 Water quality index for the seven stations
Station WQI Quality
1 474.95 Unsuitable for drinking
2 505.97 Unsuitable for drinking
3 510.863 Unsuitable for drinking
4 480.34 Unsuitable for drinking
5 447.703 Unsuitable for drinking
6 526.216 Unsuitable for drinking
7 501.433 Unsuitable for drinking
As highlighted in Table 6 above, the WQI index values for all the stations show that the
water is unsuitable for drinking. This is attributed majorly to the high turbidity and TDS values
that exceed the standard values specified by the WHO [3]. The original WQI values and the
WQI (excluding turbidity and TDS) were presented in Table 7 below.
Table 7 Comparison between the original WQI and the WQI without turbidity and TDS
Station WQI Quality
WQI (Excluding TDS and
Turbidity)
Quality
1 474.95 Unsuitable for drinking 62.754 Poor
2 505.97 Unsuitable for drinking 68.67 Poor
3 510.863 Unsuitable for drinking 60.784 Poor
4 480.34 Unsuitable for drinking 77.66 Very poor
5 447.703 Unsuitable for drinking 76.98 Very poor
6 526.216 Unsuitable for drinking 74.393 Poor
7 501.433 Unsuitable for drinking 91.866 Very poor
Mathematical Computation of Water Quality Index for the Assessment of Al-Hilla River
Ecosystem
http://www.iaeme.com/IJCIET/index.asp 1868 editor@iaeme.com
As illustrated in Table 7, the original water quality index for all the stations indicates that
the water is unsuitable for drinking but when the TDS and turbidity were excluded, the WQI
values were changed in which the water quality is poor in stations 1, 2, 3 and 6 whereas the
quality is very poor in stations 4, 5 and 7. Based on that, the water quality can be improved by
reducing the TDS and turbidity values to desirable limits. The TDS values can be minimized
by treating the sewage water prior to their direct disposal into the river and reducing human
activities that have a direct impact to the water body [17]. For the turbidity values, it is highly
recommended that erosion control measures are installed along the river banks so as to
minimize the erosion of soil at source [18]; [19]; [20]. Furthermore, sediment control measures
that capture the sediments before being washed into the water [14]. Drainage control measures
can also be installed to capture and minimize the runoff water [21]; [22].
4. CONCLUSIONS AND RECOMMENDATIONS
Al-Hilla River has a great importance to the people in the region for drinking and irrigation
purposes. This study aimed to assess the water quality of Al-Hilla River via estimating the WQI
of the river based on eight parameters. Based on the monitored water quality parameters for
seven stations, the WQI values were very high which expresses water quality "unsuitable for
drinking". This is attributed to the disposal of drainage of irrigation water, untreated sewage
and runoff of water to the water body. It is noticed that the turbidity and TDS values were
higher than the standard values in remarkable values. The WQI for the seven stations were re-
calculated excluding the turbidity and TDS to get a real evaluation of the water quality. For
some of the stations the quality were altered to polluted and for the rest of stations altered to
very polluted. Even with the exclusion of turbidity and TDS the water is not suitable yet for
drinking. Thus, this is emphasis on adopting control measures (erosion, sediment and drainage
controls) to improve runoff quality. Furthermore, it is recommended to take more samples
during different months of the year to give a better representation of the data and involving
more parameters. Eventually, stakeholders must be involved in the decision making and
mitigation alternatives.
5. ACKNOWLEDGEMENTS
The author would like to express his gratitude towards people who helped in making this work
happen and would like to thank Al-Farabi University College for giving him the opportunity
to publish this research.
REFERENCES
[1] Space Study Program, Tigris Euphrates and the global water crisis. International Space
University, 2011.
[2] Alanbari, M.A., Alqizweeni S.S., Abdalwahab, R.A., Assessing of Water Quality of Al-
Kufa River for Drinking Water using WQI and GIS. International Journal of Current
Engineering and Technology,7(4), 2017, pp. 2347-5161.
[3] World Health Organization. Guidelines for drinking water quality, 4th edition, 2011.
Available online via internet website
http://apps.who.int/iris/bitstream/handle/10665/44584/9789241548151_eng.pdf;jsessionid
=C72F0D7AF841D3E104D7259D6C200FF9?sequence=1. Accessed on January, 14th,
2019.
[4] Ahmed, H.H. A., Study the effect of evaporation on water quality to the Iraq reservoirs.
Journal of Babylon University/Engineering Science, 3, 2015, pp.638-649.
[5] Ahuja, S., Monitoring water quality pollution assessment, analysis and remediation.
Elseveir, Amsterdam, Netherlands, 2003, pp. 375.
I. A. Al-Ani
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[6] Alsaad, M., Water quality index of 11 streams pouring into Um-Alnaaj Marsh. Nahrain
University, College of Engineering Journal, 17(1), 2014, pp. 67-82.
[7] Ewaid, S. H. and Abed, S.A., Water quality index for Al-Gharraf River, southern Iraq.
Egyptian Journal of Aquatic Research,2017. Article in Press.
[8] Alobaidy, A.M.J., Abid, H.S., Maulood, B.K.,Application of water quality index for
assessment of Dokan Lake ecosystem, Kurdistan Region, Iraq. Journal of Water Resource
and Protection 2, 2010, pp. 792-798.
[9] American Public Health Association (AHPA), Standard methods for the examination of
water and wastewater, 27th ED. Washington, DC, 2012.
[10] Cude, C., Oregon water quality index: A tool for evaluating water quality management
effectiveness. Journal of the American Water Association, 37, 2001, pp. 125-137.
[11] Shweta, T., Bhavtosh, S., Prashant, S., Rajendra, D., Water quality assessment in terms of
water quality index. American Journal of Water Resources 1(3), 2013, pp. 34-38.
[12] Al-Muqdadi, S.W., Omer, M.F., Abo, R., Naghshineh, A., Dispute over water resource
management-Iraq and Turkey. Journal of Environmental Protection 7, 2016, pp. 1096-
1103.
[13] University of Baghdad, Tigris and Euphrates Sampling. Consulting Engineering Bureau,
College of Engineering, 2011.
[14] Al-Ani, I.A.R., Urbanization and sediment control using intelligent system. International
Journal of Energy and Environment, 9(4), 2018, pp. 373-384.
[15] Kale, V.S., Consequence of temperature, pH, turbidity and dissolved oxygen water quality
parameters. International Advanced Research Journal in Science, Engineering and
Technology, 3(8), 2007, pp. 186-190.
[16] Radwan, M., Willems, P., El-Sadek, A., Berlamont, J., Modelling of dissolved oxygen
demand in river water using a detailed and simplified model. Int. J. River Management,
1(2), 2003, pp. 97-103.
[17] Jabbar, W. T., Effect of domestic sewage on water quality of Al-Gharraf River in Al-Haay
city. Master Thesis. College of Science, Baghdad University, 2013.
[18] Alam, M., Ecological and economic indicators for measuring erosion control services
provided by ecosystems. Ecological Indicators, 95, 2018, pp. 695-701.
[19] Golosov, V. and Belyaev, V., The history and assessment of effectiveness of soil erosion
control measures deployed in Russia. International Soil and Water Conservation Research,
1(2), 2013, pp. 26-35.
[20] Dai, C., Liu, Y., Wang, T., Li, Z., Zhou, Y., Exploring optimal measures to reduce soil
erosion and nutrient losses in southern China. Agricultural Water Management, 210, 2018,
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[21] Sofia, G., Ragazzi, F., Giandon, P., Fontana, G. D., Tarolli, P., On the linkage between
runoff generation, land drainage, soil properties, and temporal patterns of precipitation in
agricultural floodplains. Advances in Water Resources, 2018. Article in Press.
[22] Al-Ani, I. A. R., Mohtar, W. H. M. W., Basri, N. E. A., Sidek, L. M., Development of a
hybrid expert system-multi criteria analysis on erosion and sediment control in construction
industry. KSCE Journal of Civil Engineering, 20(7), 2016, pp. 3045-3056.
[23] Vipin Kumar Swaroop, N.B. Singh and Apoorv Verma, Assessment of Groundwater
Quality Using Water Quality Index in Unnao District, Uttar Pradesh, India. International
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[24] Sridhar K, Lakshman A and Sree Lakshmi V, Assessment of Water Quality Index for the
Groundwater in Vaddeswaram, Andhra Pradesh. International Journal of Civil Engineering
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Ijciet 10 01_172

  • 1. http://www.iaeme.com/IJCIET/index.asp 1862 editor@iaeme.com International Journal of Civil Engineering and Technology (IJCIET) Volume 10, Issue 01, January 2019, pp. 1862-1869, Article ID: IJCIET_10_01_172 Available online at http://www.iaeme.com/ijciet/issues.asp?JType=IJCIET&VType=10&IType=01 ISSN Print: 0976-6308 and ISSN Online: 0976-6316 © IAEME Publication Scopus Indexed MATHEMATICAL COMPUTATION OF WATER QUALITY INDEX FOR THE ASSESSMENT OF AL-HILLA RIVER ECOSYSTEM I. A. Al-Ani Civil Engineering Department, Al-Farabi University College, Baghdad, Iraq ABSTRACT Al-Hilla River has a great importance to the people in the vicinity which serves as a main drinking and irrigation source. The aim of the current study is to estimate the Water Quality Index (WQI) of Al-Hilla River, southern Baghdad using the weighted arithmetic water quality index method. Water samples were collected from 7 stations in March in which eight water quality parameters were analyzed: Turbidity, total dissolved solids, dissolved oxygen, concentration of hydrogen ion, electrical conductivity, chlorides, alkalinity and biological oxygen demand. The calculated WQI of Al-Hilla River indicates that the river water is unsuitable for drinking which is majorly attributed to the total dissolved solids and turbidity. This interprets the condition of the river which can help the local authority in taking action by identifying the sources of pollution and improving the water quality and stakeholders should be involved in the decision making and mitigation alternatives. Key words: WQI, Al-Hilla River, Euphrates River, Iraq Cite this Article: I. A. Al-Ani, Mathematical Computation of Water Quality Index for the Assessment of Al-Hilla River Ecosystem, International Journal of Civil Engineering and Technology, 10(01), 2019, pp. 1862–1869 http://www.iaeme.com/IJCIET/issues.asp?JType=IJCIET&VType=10&IType=01 1. INTRODUCTION The two dominating surface water sources in Iraq are Tigris and Euphrates and their tributaries. Besides the surface water, ground water and springs can be considered as supporting sources [1]. Nowadays, Iraq facing a real water crisis as the discharge in both of Tigris and Euphrates goes down to a remarkable values which affects the drinking, irrigation and other uses in the country. This is due to the building of many dams on both of the rivers in the riparian countries, climate change and the severe decrease in annual precipitation which reduces Iraqi share of water [2]. With the available quantity of water, the quality is highly recommended to be investigated. According to the Ministry of Water Resources, 32 percentages of Iraqis has an access to clean drinking water and only 19 percentages has an access to an acceptable sewage
  • 2. I. A. Al-Ani http://www.iaeme.com/IJCIET/index.asp 1863 editor@iaeme.com system [3 and 4]. There are varieties of pollutants being disposed into both rivers from the non- point sources (i.e. runoff) and point sources (like industrial wastes, agricultural and sewage) [5]. This necessitates more studies on water quality in Iraqi rivers in order to identify the major sources of pollution and mitigation alternatives. [6] Assessed the Water Quality Index (WQI) of 11 streams and the receiving UM- Al Naaj marshland at Misan governorate, Iraq using five water quality parameters in which it is indicated that the quality of water ranging from good to excellent. [2] Assesses the drinking water quality of Al-Kufa River for a duration of 12 months using the WQI and the Geographic Information System (GIS) in which it is indicated that the quality of Al-Kufa River is classified as very poor. This is due to the human activities along the river banks. [7] Evaluated the water quality via WQI of Al-Gharraf River, branch of Tigris River in the southern parts of Iraq in which samples were collected from five stations for duration of one year and eleven water quality parameters were considered. Results showed different index for different stations in which the water is poor in stations 1,2,3 and 4 whereas showed very poor quality in station 5. Another study was performed in Iraq in which ten water quality parameters were adopted to estimate the WQI in Dokanlake in northern parts of the country. Results showed that the quality of water is deteriorating which was good in years 1978, 1979, 1980, 1999, 2000 and 2008 to be a poor quality in 2009 and it is recommended the continuous monitoring of the water quality in the lake for proper management and action [8]. The objectives of the current work is to apply the water quality index (WQI) for Al-Hilla River based on the monitored water quality parameters and to help the local authority concerning proper organization of water resources. Furthermore, is to shape a base data which will help in future water supervision and protection preparations. 2. MATERIALS AND METHODS 2.1. Study Area The study area is located in Al-Hilla city, Babylon, south of the capital Baghdad. Euphrates River enters Babylon and divided into two rivers; the first one goes to Karbalaa and the second one enter to Al-Hilla city and supply the water to the city. Figure 1 depicts the study area. Figure 1 Location of the study area Location of
  • 3. Mathematical Computation of Water Quality Index for the Assessment of Al-Hilla River Ecosystem http://www.iaeme.com/IJCIET/index.asp 1864 editor@iaeme.com 2.2. Data Collection Data collection includes water quality samplings that have been collected from seven stations in which each station consists of three locations (i.e. left, middle and right of Figure 2 Water quality sampling stations Table 1 Coordinates of water sampling No. Location Latitude Longitude 1 Left 32.4592 44.4426 2 Middle 32.4591 44.4422 3 Right 32.4592 44.4419 4 Left 32.4584 44.4422 5 Middle 32.4583 44.4424 6 Right 32.4582 44.4420 7 Left 32.4569 44.4431 8 Middle 32.4568 44.4428 9 Right 32.4567 44.4424 10 Left 32.4560 44.4434 11 Middle 32.4561 44.4430 12 Right 32.4559 44.4425 13 Left 32.4551 44.4437 14 Middle 32.4549 44.4433 15 Right 32.4546 44.4430 16 Left 32.4535 44.4444 17 Middle 32.4534 44.4439 18 Right 32.4532 44.4436 19 Left 32.4515 44.4435 20 Middle 32.4513 44.4449 21 Right 32.4508 44.4449
  • 4. I. A. Al-Ani http://www.iaeme.com/IJCIET/index.asp 1865 editor@iaeme.com Water samples were collected in March. Samples were analyzed according to American Public Health Association (AHPA) standard methods [9]. Table 2 presents the monitored water quality parameters. Table 2 Water quality parameters No. Parameter Unit Site 1 Turbidity NTU Laboratory 2 TDS mg/l Laboratory 3 DO mg/l In situ 4 pH pH units In situ 5 Electrical Conductivity µS/cm In situ 6 Chlorides mg/l Laboratory 7 Alkalinity mg/l Laboratory 8 BOD mg/l Laboratory 2.3. Water Quality Index Calculation The water quality index for the river was calculated based on weighted arithmetic index method for eight parameters namely: pH, turbidity, TDS, BOD, DO, alkalinity, chlorides and electrical conductivity for seven stations in which each station got three sampling points (i.e. left side, middle and right side of the river) as indicated in Figure 2. The weighted arithmetic water quality index method was applied [10] in which the water quality parameters were multiplied by a weighting factor and are then aggregated using a simple arithmetic mean using the following equations: Qi = Mi − Li Si − Li x 100 Wi = K Si WQI = ∑ ∑ Where, Qi is the sub index of the ith parameter, Wi is the unit weightage of the ith parameter, n is the number of parameters included, Mi is the monitored value of the parameter, Li is the ideal value, Si is the standard value of the ith parameter. According to [11], the quality of water regarding the WQI classification is given in Table 3 Table 3 Water Quality Index Classification Range Quality 0-25 Excellent 26-50 Good 51-75 Poor 76-100 Very poor >100 Unsuitable for drinking
  • 5. Mathematical Computation of Water Quality Index for the Assessment of Al-Hilla River Ecosystem http://www.iaeme.com/IJCIET/index.asp 1866 editor@iaeme.com 3. RESULTS AND DISCUSSIONS Based on the equations listed above, the WQI for the seven stations in Al-Hilla River was calculated using the weighted arithmetic index method for the eight parameters mentioned earlier in this study. The results of water quality monitoring for the seven stations are presented in Table 4. In each station, three samples are collected (left side, middle and right side of the river) and then average values for each station were adopted. Based on the results of monitoring in the river, there are some differences in water quality parameters within the seven stations. WQI calculations denoted that the quality of the water is decreasing as moving downstream. This can be attributed to the multiple discharge points (i.e. sewage from multiple sources) along the river which introduces various pollutants. The Iraqi water crises caused by building of dams in Turkey, limited rain and the old irrigation system (produces high losses) which subsequently results in fluctuations in water level and hence encouraged the drainage of groundwater into the river water body [12]. This fluctuation in water level affects the quality of water especially in summer when the water from reservoirs (full of organic materials and sediments) is discharged into the water body to compensate the reduction in water level [13]. Furthermore, soil erosion caused by runoff has dramatic impact as it introduces large quantities of sediments and suspended solids to the water body [14]. Table 6 illustrates the results of WQI for the stations of one to seven which are 474.95, 505.97, 510.86, 480.34, 447.7, 526.21 and 501.43 respectively in which the water quality in all stations is classified as unsuitable for drinking (refer to Table 3). In Al-Hilla River, each of the monitored water quality parameters give different value for different stations due to the reasons highlighted earlier as illustrated in Table 4. For the turbidity, it is considered as an essential water quality parameter since it affects the water via suspended particles and affects other parameters like DO and BOD [15]. It is clear that the turbidity values for all the stations are much higher than the standard value < 5 NTU specified by WHO [3]. The turbidity values play an important role in deteriorating the WQI for the seven stations. For the TDS values, it is clear also that some of the monitored values are higher than the standard value specified by WHO [3] is 1000 mg/l. According to Table 4, the TDS values in stations 1, 2, 4, 5, 6 and 7 are exceeding the standard value except station 3 which is below the recommended level. Table 4 Monitored values of water quality parameters Parameter Station 1 Station 2 Station 3 Station 4 Station 5 Station 6 Station 7 Turbidity 80 85 87 79 73 88 81 TDS 1009.8 1012.95 617.85 1037.7 1011.15 1011.15 1019.25 DO 7.2 6.8 6.6 6.5 7.1 7.3 7.5 pH 6.69 6.69 7.06 6.68 6.75 6.85 6.87 EC 1122 1125.5 980 1153 1123.5 1123.5 1132.5 Cl 150 163 188 197 211 199 201 Alkalinity 245 220.5 140.5 273 204 236 252 BOD 2 2.61 3.2 3.56 4.3 4.7 7.3 The DO is an important water quality parameter in evaluating the quality of water since it is essential in bacterial actions in breaking down the organic matter available in water [16]. The DO values monitored in the river are higher than the standard value 5 mg/l. concerning the pH values; they are different between stations in an acceptable level with a standard value of 7.5
  • 6. I. A. Al-Ani http://www.iaeme.com/IJCIET/index.asp 1867 editor@iaeme.com The values of electrical conductivity (EC) monitored in the river for all the stations show very high level as compared with the standard value of 250 µS/cm set by WHO [3]. The values of chlorides were acceptable in which they are below the standard set by WHO. For the alkalinity, only station 3 is below the standard < 200 mg/l as CaCo3 whereas other stations recorded higher values. Eventually, the BOD values for the stations of one to six recorded lower values than the standard value of 5 mg/l except station 7 which recorded a value of 7.3 mg/l. The ideal values and standard values for the eight water quality parameters are presented in Table 5 below: Table 5 Standard and ideal values of water quality parameters Parameter Standard value Ideal value Turbidity 5 0 TDS 1000 0 DO 5 14.6 pH 7.5 7 EC 250 0 Cl 350 0 Alkalinity 200 0 BOD 5 0 The estimated water quality index values for the seven stations are presented in Table 6 below. Table 6 Water quality index for the seven stations Station WQI Quality 1 474.95 Unsuitable for drinking 2 505.97 Unsuitable for drinking 3 510.863 Unsuitable for drinking 4 480.34 Unsuitable for drinking 5 447.703 Unsuitable for drinking 6 526.216 Unsuitable for drinking 7 501.433 Unsuitable for drinking As highlighted in Table 6 above, the WQI index values for all the stations show that the water is unsuitable for drinking. This is attributed majorly to the high turbidity and TDS values that exceed the standard values specified by the WHO [3]. The original WQI values and the WQI (excluding turbidity and TDS) were presented in Table 7 below. Table 7 Comparison between the original WQI and the WQI without turbidity and TDS Station WQI Quality WQI (Excluding TDS and Turbidity) Quality 1 474.95 Unsuitable for drinking 62.754 Poor 2 505.97 Unsuitable for drinking 68.67 Poor 3 510.863 Unsuitable for drinking 60.784 Poor 4 480.34 Unsuitable for drinking 77.66 Very poor 5 447.703 Unsuitable for drinking 76.98 Very poor 6 526.216 Unsuitable for drinking 74.393 Poor 7 501.433 Unsuitable for drinking 91.866 Very poor
  • 7. Mathematical Computation of Water Quality Index for the Assessment of Al-Hilla River Ecosystem http://www.iaeme.com/IJCIET/index.asp 1868 editor@iaeme.com As illustrated in Table 7, the original water quality index for all the stations indicates that the water is unsuitable for drinking but when the TDS and turbidity were excluded, the WQI values were changed in which the water quality is poor in stations 1, 2, 3 and 6 whereas the quality is very poor in stations 4, 5 and 7. Based on that, the water quality can be improved by reducing the TDS and turbidity values to desirable limits. The TDS values can be minimized by treating the sewage water prior to their direct disposal into the river and reducing human activities that have a direct impact to the water body [17]. For the turbidity values, it is highly recommended that erosion control measures are installed along the river banks so as to minimize the erosion of soil at source [18]; [19]; [20]. Furthermore, sediment control measures that capture the sediments before being washed into the water [14]. Drainage control measures can also be installed to capture and minimize the runoff water [21]; [22]. 4. CONCLUSIONS AND RECOMMENDATIONS Al-Hilla River has a great importance to the people in the region for drinking and irrigation purposes. This study aimed to assess the water quality of Al-Hilla River via estimating the WQI of the river based on eight parameters. Based on the monitored water quality parameters for seven stations, the WQI values were very high which expresses water quality "unsuitable for drinking". This is attributed to the disposal of drainage of irrigation water, untreated sewage and runoff of water to the water body. It is noticed that the turbidity and TDS values were higher than the standard values in remarkable values. The WQI for the seven stations were re- calculated excluding the turbidity and TDS to get a real evaluation of the water quality. For some of the stations the quality were altered to polluted and for the rest of stations altered to very polluted. Even with the exclusion of turbidity and TDS the water is not suitable yet for drinking. Thus, this is emphasis on adopting control measures (erosion, sediment and drainage controls) to improve runoff quality. Furthermore, it is recommended to take more samples during different months of the year to give a better representation of the data and involving more parameters. Eventually, stakeholders must be involved in the decision making and mitigation alternatives. 5. ACKNOWLEDGEMENTS The author would like to express his gratitude towards people who helped in making this work happen and would like to thank Al-Farabi University College for giving him the opportunity to publish this research. REFERENCES [1] Space Study Program, Tigris Euphrates and the global water crisis. International Space University, 2011. [2] Alanbari, M.A., Alqizweeni S.S., Abdalwahab, R.A., Assessing of Water Quality of Al- Kufa River for Drinking Water using WQI and GIS. International Journal of Current Engineering and Technology,7(4), 2017, pp. 2347-5161. [3] World Health Organization. Guidelines for drinking water quality, 4th edition, 2011. Available online via internet website http://apps.who.int/iris/bitstream/handle/10665/44584/9789241548151_eng.pdf;jsessionid =C72F0D7AF841D3E104D7259D6C200FF9?sequence=1. Accessed on January, 14th, 2019. [4] Ahmed, H.H. A., Study the effect of evaporation on water quality to the Iraq reservoirs. Journal of Babylon University/Engineering Science, 3, 2015, pp.638-649. [5] Ahuja, S., Monitoring water quality pollution assessment, analysis and remediation. Elseveir, Amsterdam, Netherlands, 2003, pp. 375.
  • 8. I. A. Al-Ani http://www.iaeme.com/IJCIET/index.asp 1869 editor@iaeme.com [6] Alsaad, M., Water quality index of 11 streams pouring into Um-Alnaaj Marsh. Nahrain University, College of Engineering Journal, 17(1), 2014, pp. 67-82. [7] Ewaid, S. H. and Abed, S.A., Water quality index for Al-Gharraf River, southern Iraq. Egyptian Journal of Aquatic Research,2017. Article in Press. [8] Alobaidy, A.M.J., Abid, H.S., Maulood, B.K.,Application of water quality index for assessment of Dokan Lake ecosystem, Kurdistan Region, Iraq. Journal of Water Resource and Protection 2, 2010, pp. 792-798. [9] American Public Health Association (AHPA), Standard methods for the examination of water and wastewater, 27th ED. Washington, DC, 2012. [10] Cude, C., Oregon water quality index: A tool for evaluating water quality management effectiveness. Journal of the American Water Association, 37, 2001, pp. 125-137. [11] Shweta, T., Bhavtosh, S., Prashant, S., Rajendra, D., Water quality assessment in terms of water quality index. American Journal of Water Resources 1(3), 2013, pp. 34-38. [12] Al-Muqdadi, S.W., Omer, M.F., Abo, R., Naghshineh, A., Dispute over water resource management-Iraq and Turkey. Journal of Environmental Protection 7, 2016, pp. 1096- 1103. [13] University of Baghdad, Tigris and Euphrates Sampling. Consulting Engineering Bureau, College of Engineering, 2011. [14] Al-Ani, I.A.R., Urbanization and sediment control using intelligent system. International Journal of Energy and Environment, 9(4), 2018, pp. 373-384. [15] Kale, V.S., Consequence of temperature, pH, turbidity and dissolved oxygen water quality parameters. International Advanced Research Journal in Science, Engineering and Technology, 3(8), 2007, pp. 186-190. [16] Radwan, M., Willems, P., El-Sadek, A., Berlamont, J., Modelling of dissolved oxygen demand in river water using a detailed and simplified model. Int. J. River Management, 1(2), 2003, pp. 97-103. [17] Jabbar, W. T., Effect of domestic sewage on water quality of Al-Gharraf River in Al-Haay city. Master Thesis. College of Science, Baghdad University, 2013. [18] Alam, M., Ecological and economic indicators for measuring erosion control services provided by ecosystems. Ecological Indicators, 95, 2018, pp. 695-701. [19] Golosov, V. and Belyaev, V., The history and assessment of effectiveness of soil erosion control measures deployed in Russia. International Soil and Water Conservation Research, 1(2), 2013, pp. 26-35. [20] Dai, C., Liu, Y., Wang, T., Li, Z., Zhou, Y., Exploring optimal measures to reduce soil erosion and nutrient losses in southern China. Agricultural Water Management, 210, 2018, pp. 41-48. [21] Sofia, G., Ragazzi, F., Giandon, P., Fontana, G. D., Tarolli, P., On the linkage between runoff generation, land drainage, soil properties, and temporal patterns of precipitation in agricultural floodplains. Advances in Water Resources, 2018. Article in Press. [22] Al-Ani, I. A. R., Mohtar, W. H. M. W., Basri, N. E. A., Sidek, L. M., Development of a hybrid expert system-multi criteria analysis on erosion and sediment control in construction industry. KSCE Journal of Civil Engineering, 20(7), 2016, pp. 3045-3056. [23] Vipin Kumar Swaroop, N.B. Singh and Apoorv Verma, Assessment of Groundwater Quality Using Water Quality Index in Unnao District, Uttar Pradesh, India. International Journal of Civil Engineering and Technology, 9(8), 2018, pp. 155- 165. [24] Sridhar K, Lakshman A and Sree Lakshmi V, Assessment of Water Quality Index for the Groundwater in Vaddeswaram, Andhra Pradesh. International Journal of Civil Engineering and Technology, 8(4), 2017, pp. 1614–1620