Alkalinity in water is measured by titrating a water sample with sulfuric acid and monitoring the pH. Alkalinity is caused by hydroxides, carbonates, and bicarbonates and is expressed in units of mg/L of calcium carbonate. The amount of acid needed to reduce the pH to 8.3 measures phenolphthalein alkalinity, while the amount to reduce to 4.5 measures total alkalinity. Different combinations of hydroxides, carbonates, and bicarbonates can be present depending on the initial pH. Alkalinity data provides information useful for water treatment processes like coagulation, softening, and corrosion control.
Determination of hardness and alkalinity of waste waterAakash Deep
This power point presentation illustrates the principles and methods of estimation of hardness and alkalinity of waste water.
I have included the principle, titration method, formulas and some sample problems based on them.
Determination of hardness and alkalinity of waste waterAakash Deep
This power point presentation illustrates the principles and methods of estimation of hardness and alkalinity of waste water.
I have included the principle, titration method, formulas and some sample problems based on them.
Generally soaps create foam in water, but in present of some materials the foam creation is reduced and need more soap for producing foam, and this condition of water is called water hardness.
The presence of Calcium, Magnesium salt i.e. bicarbonates, sulphates, chloride in water is called causes of hardness of water. The water which contains these salts is called hard water. Hard water does not easily form lather with soap as the salt of Calcium and Magnesium react with soap to form insoluble organic salts.
Lab 4 alkalinity –acidity and determination of alkalinity in waterAnas Maghayreh
Environmental lab
Lab 4 alkalinity –acidity and determination of alkalinity in water
experiment at JORDAN UNIVERSITY OF SCIENCE AND TECHNOLOGY
by: ANAS MAGHAYREH
Generally hardness of water is defined as the measure of capacity of water to precipitate soap i.e., the capacity of the water to form lather with soap.
Hard water contains dissolved minerals such as Ca2+, Mg2+, Fe3+, SO4 2- ,etc.,
The degree of hardness is measured in Parts Per Million(ppm) or Grams per Gallon(GPG).
Hard water is better for drinking because it contains minerals.
Soft water is better for cleaning because it doesn’t form scum with soap.
Hardness of water is a measure of the total concentration of the calcium and magnesium ions expressed as calcium carbonate.
There are two types of hardness
1. Temporary hardness
Temporary Hardness is due to the presence of bicarbonates of calcium and magnesium. It can be easily removed by boiling.
Ca (HCO3 ) CaCO3 +CO2 +H2O
2. Permanent hardness
Permanent Hardness is due to the presence of chlorides and sulphates of calcium and magnesium. This type of hardness cannot be removed by boiling.
wholesomeness, Requirements for Domestic Use. Impurities in Water. Objects & purpose of Water Analysis.Collection of Samples. Classification of Analysis of Water: Physical,
Chemical & Biological Examination of Water.
Slides giving an overview on pH and its measurement.
Contains information about pH meters, its calibration, maintenance , types of ph electrode and modern definition of pH
Generally soaps create foam in water, but in present of some materials the foam creation is reduced and need more soap for producing foam, and this condition of water is called water hardness.
The presence of Calcium, Magnesium salt i.e. bicarbonates, sulphates, chloride in water is called causes of hardness of water. The water which contains these salts is called hard water. Hard water does not easily form lather with soap as the salt of Calcium and Magnesium react with soap to form insoluble organic salts.
Lab 4 alkalinity –acidity and determination of alkalinity in waterAnas Maghayreh
Environmental lab
Lab 4 alkalinity –acidity and determination of alkalinity in water
experiment at JORDAN UNIVERSITY OF SCIENCE AND TECHNOLOGY
by: ANAS MAGHAYREH
Generally hardness of water is defined as the measure of capacity of water to precipitate soap i.e., the capacity of the water to form lather with soap.
Hard water contains dissolved minerals such as Ca2+, Mg2+, Fe3+, SO4 2- ,etc.,
The degree of hardness is measured in Parts Per Million(ppm) or Grams per Gallon(GPG).
Hard water is better for drinking because it contains minerals.
Soft water is better for cleaning because it doesn’t form scum with soap.
Hardness of water is a measure of the total concentration of the calcium and magnesium ions expressed as calcium carbonate.
There are two types of hardness
1. Temporary hardness
Temporary Hardness is due to the presence of bicarbonates of calcium and magnesium. It can be easily removed by boiling.
Ca (HCO3 ) CaCO3 +CO2 +H2O
2. Permanent hardness
Permanent Hardness is due to the presence of chlorides and sulphates of calcium and magnesium. This type of hardness cannot be removed by boiling.
wholesomeness, Requirements for Domestic Use. Impurities in Water. Objects & purpose of Water Analysis.Collection of Samples. Classification of Analysis of Water: Physical,
Chemical & Biological Examination of Water.
Slides giving an overview on pH and its measurement.
Contains information about pH meters, its calibration, maintenance , types of ph electrode and modern definition of pH
Table Top Hydrazine Meter,Microprocessor Based Hydrazine Meter,Bench-top Hydrazine Sensor, Quality Benchtop Hydrazine Moniters,Portable Table Top Hydrazine Sensor,Weiber Hydrazine Analytical Instruments For More Information Please Logon http://cutt.us/Bjy1
Environmental Engineering Practical Series - Alkalinity Test of WaterSuyash Awasthi
Alkalinity of water is essential parameter to be found before its consumption. Following is a self explanatory presentation of why it is important and how to find the same in any sample of water.
pH is a measure of how acidic or alkaline a solution is. In pure water at room temperature, a small fraction (about two out of every billion) of the water molecules (H 2 O, or really, H-O-H) splits, or dissociates , spontaneously, into one positively charged hydrogen ion (H + ) and one negatively charged hydroxide ion (OH - ) each.For more information please log on http://cutt.us/4ObJ
Non- aqueous titrations are those in which the titrations of too weakly acidic or basic substances are carried out using non-aqueous solvents so as to get sharp end point.
Such titrations can also be used for the titration of the substances not soluble in water.
The speed, precision and accuracy of the non-aqueous method are close to those of classical acidimetric and alkalimetric titrations.
First reported successful quantitative titration of organic acid and base in non-aqueous solvent: 1910.
To an understanding of non-aqueous acid base titrimetry the theories of acid and base is very important. The theories are:
Acids are hydrogen containing compounds that dissociates to yield hydrogen ions (H+) when dissolved in water.
Bases are compounds that dissociates to yield hydroxide/hydroxyl ions (OH-) when dissolved in water.
A STUDY ON OCEAN ACIDIFICATION DUE TO CARBON DIOXIDE ALONG THE COAST OF VISAK...Soma Sekhar Sriadibhatla
Extensive Data Analytics on samples to understand Ocean Acidification process, a serious damage to ecosystem, increase in production of Carbon dioxide.
Artificial Reefs by Kuddle Life Foundation - May 2024punit537210
Situated in Pondicherry, India, Kuddle Life Foundation is a charitable, non-profit and non-governmental organization (NGO) dedicated to improving the living standards of coastal communities and simultaneously placing a strong emphasis on the protection of marine ecosystems.
One of the key areas we work in is Artificial Reefs. This presentation captures our journey so far and our learnings. We hope you get as excited about marine conservation and artificial reefs as we are.
Please visit our website: https://kuddlelife.org
Our Instagram channel:
@kuddlelifefoundation
Our Linkedin Page:
https://www.linkedin.com/company/kuddlelifefoundation/
and write to us if you have any questions:
info@kuddlelife.org
Micro RNA genes and their likely influence in rice (Oryza sativa L.) dynamic ...Open Access Research Paper
Micro RNAs (miRNAs) are small non-coding RNAs molecules having approximately 18-25 nucleotides, they are present in both plants and animals genomes. MiRNAs have diverse spatial expression patterns and regulate various developmental metabolisms, stress responses and other physiological processes. The dynamic gene expression playing major roles in phenotypic differences in organisms are believed to be controlled by miRNAs. Mutations in regions of regulatory factors, such as miRNA genes or transcription factors (TF) necessitated by dynamic environmental factors or pathogen infections, have tremendous effects on structure and expression of genes. The resultant novel gene products presents potential explanations for constant evolving desirable traits that have long been bred using conventional means, biotechnology or genetic engineering. Rice grain quality, yield, disease tolerance, climate-resilience and palatability properties are not exceptional to miRN Asmutations effects. There are new insights courtesy of high-throughput sequencing and improved proteomic techniques that organisms’ complexity and adaptations are highly contributed by miRNAs containing regulatory networks. This article aims to expound on how rice miRNAs could be driving evolution of traits and highlight the latest miRNA research progress. Moreover, the review accentuates miRNAs grey areas to be addressed and gives recommendations for further studies.
Diabetes is a rapidly and serious health problem in Pakistan. This chronic condition is associated with serious long-term complications, including higher risk of heart disease and stroke. Aggressive treatment of hypertension and hyperlipideamia can result in a substantial reduction in cardiovascular events in patients with diabetes 1. Consequently pharmacist-led diabetes cardiovascular risk (DCVR) clinics have been established in both primary and secondary care sites in NHS Lothian during the past five years. An audit of the pharmaceutical care delivery at the clinics was conducted in order to evaluate practice and to standardize the pharmacists’ documentation of outcomes. Pharmaceutical care issues (PCI) and patient details were collected both prospectively and retrospectively from three DCVR clinics. The PCI`s were categorized according to a triangularised system consisting of multiple categories. These were ‘checks’, ‘changes’ (‘change in drug therapy process’ and ‘change in drug therapy’), ‘drug therapy problems’ and ‘quality assurance descriptors’ (‘timer perspective’ and ‘degree of change’). A verified medication assessment tool (MAT) for patients with chronic cardiovascular disease was applied to the patients from one of the clinics. The tool was used to quantify PCI`s and pharmacist actions that were centered on implementing or enforcing clinical guideline standards. A database was developed to be used as an assessment tool and to standardize the documentation of achievement of outcomes. Feedback on the audit of the pharmaceutical care delivery and the database was received from the DCVR clinic pharmacist at a focus group meeting.
Natural farming @ Dr. Siddhartha S. Jena.pptxsidjena70
A brief about organic farming/ Natural farming/ Zero budget natural farming/ Subash Palekar Natural farming which keeps us and environment safe and healthy. Next gen Agricultural practices of chemical free farming.
UNDERSTANDING WHAT GREEN WASHING IS!.pdfJulietMogola
Many companies today use green washing to lure the public into thinking they are conserving the environment but in real sense they are doing more harm. There have been such several cases from very big companies here in Kenya and also globally. This ranges from various sectors from manufacturing and goes to consumer products. Educating people on greenwashing will enable people to make better choices based on their analysis and not on what they see on marketing sites.
"Understanding the Carbon Cycle: Processes, Human Impacts, and Strategies for...MMariSelvam4
The carbon cycle is a critical component of Earth's environmental system, governing the movement and transformation of carbon through various reservoirs, including the atmosphere, oceans, soil, and living organisms. This complex cycle involves several key processes such as photosynthesis, respiration, decomposition, and carbon sequestration, each contributing to the regulation of carbon levels on the planet.
Human activities, particularly fossil fuel combustion and deforestation, have significantly altered the natural carbon cycle, leading to increased atmospheric carbon dioxide concentrations and driving climate change. Understanding the intricacies of the carbon cycle is essential for assessing the impacts of these changes and developing effective mitigation strategies.
By studying the carbon cycle, scientists can identify carbon sources and sinks, measure carbon fluxes, and predict future trends. This knowledge is crucial for crafting policies aimed at reducing carbon emissions, enhancing carbon storage, and promoting sustainable practices. The carbon cycle's interplay with climate systems, ecosystems, and human activities underscores its importance in maintaining a stable and healthy planet.
In-depth exploration of the carbon cycle reveals the delicate balance required to sustain life and the urgent need to address anthropogenic influences. Through research, education, and policy, we can work towards restoring equilibrium in the carbon cycle and ensuring a sustainable future for generations to come.
Characterization and the Kinetics of drying at the drying oven and with micro...Open Access Research Paper
The objective of this work is to contribute to valorization de Nephelium lappaceum by the characterization of kinetics of drying of seeds of Nephelium lappaceum. The seeds were dehydrated until a constant mass respectively in a drying oven and a microwawe oven. The temperatures and the powers of drying are respectively: 50, 60 and 70°C and 140, 280 and 420 W. The results show that the curves of drying of seeds of Nephelium lappaceum do not present a phase of constant kinetics. The coefficients of diffusion vary between 2.09.10-8 to 2.98. 10-8m-2/s in the interval of 50°C at 70°C and between 4.83×10-07 at 9.04×10-07 m-8/s for the powers going of 140 W with 420 W the relation between Arrhenius and a value of energy of activation of 16.49 kJ. mol-1 expressed the effect of the temperature on effective diffusivity.
2. INTRODUCTION
• What is alkalinity?
Alkalinity of a water is the measure of its capacity to neutralize acids i.e. to
absorb hydrogen ions without significant change in pH.
• Parameters which causes the alkalinity
Alkalinity is caused by the presence of hydroxide ions, carbonates and
bicarbonates.
At pH <8.3 , only bicarbonates are found to occur , because at lower pH all
carbonates are converted into bicarbonates by the action of CO2 and H2O.
CO2 + H2O + CaCO3 Ca(HCO3)2
3. If its pH falls below 4.5 since the all are converted into carbonic acid.
As far as natural water concern, algae in natural water usually found to be rich
in carbonates.
By the photosynthesis the algae provides CO2 and the carbonates are converted
into the bicarbonates and hence the algae rises the pH of water to above 8.3.
At pH 8.3 or more carbonates as well as bicarbonates both may exist
Hydroxide are however found to exist at much higher values of pH say about 10
to 11.
4. Total alkalinity in water may consist of,
I. Only hydroxide
II. Only carbonates
III. Hydroxide and carbonates
IV. Carbonates and bicarbonates
V. Only bicarbonates
First four possibilities will exist when the pH of water is more than 8.3 and
fifth possibility will exist only when the pH is in between 4.5 to 8.3.
It is assumed that hydroxide and bicarbonate alkalinity cannot be present
together in the same sample , although this may not be 100% true always.
5. Environmental Significance
Alkalinity in water has a little public health significance
Highly alkaline waters are usually not pleasant to taste.
Sometimes chemically treated waters are alkaline so standards are
sometimes established on that chemically treated waters
The principal objection of alkalinity in water is the reactions that occur
between alkalinity and certain cations in waters.The resultant precipitates
can corrode the pipes and other accessories of water distribution system.
6. Measurement of Alkalinity
Alkalinity of a water sample can be measured by titrating the given water
sample with a standard solution of sulphuric acid.
Further adding of sulphuric acid will results in increasing the H+ ions and
reducing its pH value.
The amount of H2SO4 added till the pH of the mixture is reduced to 8.3, as
detected by the use of an indicator dye- phenolphthalein.
This will help in the determining the alkalinity existing in water above pH of
8.3.
Further addition of sulphuric acid , till the pH is reduced to about 4.5 will help in
determining the total alkalinity in the water.
NOTE- No alkalinity can exist below pH 4.5.
7. Alkalinity is measured as CaCO3 (having equivalent weight = 50),its one mole
will weigh 50 gm/l, or 50 mg/ml.
That means 1 ml of alkalinity consumed by the use of 1 ml of N.H2SO4 will
weigh 50 mg and hence,
Alkalinity (as CaCO3) in water sample in mg/l
= [ml of H2SO4 used * N*50]*1000
ml of water sample
8. For highly alkaline waters, the first step is to titrate it by adding the acid to
reduce its pH up to 8.3.
The second step is to titrate it to reduce its pH to an indicated value of about
4.5.
If the initial value of pH is less than 8.3, the second step itself will become the
first step in the method of titration.
The end point of titration is change in the color of water with indicator dyes at
specific pH values.
9. Indicator
Phenolphthalein
If pH is more than 8.3 it turns water to pink.
At pH = 8.3 , it changes the water from pink to colorless.
Phenolphthalein gives us the amount of acid required to reduce the pH of water
upto 8.3.
Methyl-orange
Is used as an indicator , since it changes from red/orange to yellow in orange at
pH 4.6
The alkalinity determined upto pH = 8.3 , by phenolphthalein ; i.e 10x is the
usually called the phenolphthalein alkalinity and represented by P.
The alkalinity determined upto pH = 4.5 ; i.e 10y is called the total alkalinity and
is represented by T.
10. Hydroxide only:
Sample containing only hydroxide when the pH is more than 10.
Titration is completed at the phenolphthalein end point.
In this case the hydroxide alkalinity is equal to P.
Carbonates only:
Samples containing only carbonate alkalinity have a pH of 8.3 or more.
The titration to phenolphthalein end point is equal to the one half of the total
titration.
In this case total alkalinity is twice the phenolphthalein alkalinity i.e T = 2P.
11. Hydroxide and carbonate alkalinities both:
samples containing hydroxide as well as carbonate alkalinity have a high pH
usually above 10.
The titration from the phenolphthalein end point to methyl orange end point
represents one half of the carbonate alkalinity.
Carbonate – bicarbonate alkalinities both:
Samples containing carbonate and bicarbonate alkalinities have a pH > 8.3 and
less than 11.
The titration to the phenolphthalein end point represents one half pf the
carbonate alkalinity.
So the carbonate alkalinity is calculated as equal to 2P and bicarbonate
alkalinity is equal toT – 2P.
12. Bicarbonates only:
• Samples having a pH less than 8.3 will have only bicarbonate alkalinity which is
equal to total alkalinity .
• In this case P = 0 and phenolphthalein will not produce any pink color when
added to the water.
13. APPLICATION OF ALKALINITY DATA
1. Chemical coagulation
2. Water softening
3. Corrosion control
4. Buffer capacity
5. Industrial wastes