Gas Separation
Mechanisms of Gas Separation
Membrane Separation
Types of Membranes
Types of Membrane Separation
Mechanism of Membrane Separation
Technology
Science
This document discusses gas permeation and liquid permeation. It defines permeation as the penetration of a permeate such as liquid, gas, or vapor through a solid material. Gas permeation uses a non-porous membrane to separate a gaseous feed stream into permeate and non-permeate streams based on differences in permeation rates. Liquid permeation occurs when a volatile liquid mixture is applied to one side of a non-porous membrane and the other side contains liquid, with permeation dependent on molecular size and polarity of the liquid. Common applications include hydrogen separation and removal of carbon dioxide or organic solvents from air.
PDMS, or poly(dimethylsiloxane), is an optically clear, inert, non-toxic, and non-flammable material that is elastic at low temperatures and viscoelastic at high temperatures. It is used in flexible electronics and gas/liquid separations due to its flexibility and low cost. Permeability measures the intrinsic permeation rate of a species through a material and is determined by the diffusion coefficient and solubility coefficient. PDMS permeability can be modified by changing the degree of substitution, silicone backbone chain length, structure, and alkyl chain length - with shorter alkyl chains and longer backbones increasing permeability. Further research aims to figure out reaction mechanisms to add more hydrocarbon chain length and decrease PDMS permeability
The document discusses leaching during phase inversion membrane formation and the solution-diffusion model of permeation in polymer membranes. During phase inversion, a fraction of the polymer material leaches out into the solvent, resulting in different membrane morphologies. The solution-diffusion model describes permeation as a three step process where materials dissolve in the membrane, diffuse through it down a concentration gradient, then desorb on the other side. Diffusion through the polymer is the slowest and rate-limiting step.
This document provides an overview of mass transfer concepts and processes. It begins with definitions of mass transfer and examples of mass transfer in nature. It then discusses various separation processes that rely on mass transfer principles, including distillation, gas absorption, drying, and crystallization. Key mass transfer topics covered include molecular diffusion, interphase mass transfer, mass transfer coefficients, and gas-liquid contacting equipment like tray towers and packed towers.
In the Process of generating Nitrogen, Carbon Molecular Sieve (CMS) plays a very vital role. With the help of CMS only Nitrogen is produced. CMS takes up the oxygen, carbon dioxide and other impurities and release the pure nitrogen.
PSA is one of the unique processes in which gases are separated with the help of pressure swing technology is called PSA. In this process when the bed is in desorption mode with the help of release pressure it is been regenerated and then to swing to adsorption mode.
This document discusses membrane separation processes. It defines membranes as thin layers that selectively control the transport of materials between phases. There are two main types of membranes: permeable and semipermeable. Membrane processes are classified based on the size of materials separated and the driving force used. Examples given include reverse osmosis and ultrafiltration in the dairy industry. Key concepts covered include transmembrane pressure, recovery percentage, molecular weight cutoff, and solute rejection coefficient. Advantages of membrane separation include energy savings, low temperature operation, and recovery of both concentrate and permeate.
Distillation is the most important separation technology in the chemical process industry. More than 90% of separations are based on distillation.
Hybrid systems offer an interesting alternative in some difficult separations for distillation with either large number of theoretical trays; large heat loads or both.
Hybrid processes in separation operations are characterized by the combination of two unit operations.
Each unit operation itself is considered to be a separation process, but the combination generates special advantages.
This document discusses gas permeation and liquid permeation. It defines permeation as the penetration of a permeate such as liquid, gas, or vapor through a solid material. Gas permeation uses a non-porous membrane to separate a gaseous feed stream into permeate and non-permeate streams based on differences in permeation rates. Liquid permeation occurs when a volatile liquid mixture is applied to one side of a non-porous membrane and the other side contains liquid, with permeation dependent on molecular size and polarity of the liquid. Common applications include hydrogen separation and removal of carbon dioxide or organic solvents from air.
PDMS, or poly(dimethylsiloxane), is an optically clear, inert, non-toxic, and non-flammable material that is elastic at low temperatures and viscoelastic at high temperatures. It is used in flexible electronics and gas/liquid separations due to its flexibility and low cost. Permeability measures the intrinsic permeation rate of a species through a material and is determined by the diffusion coefficient and solubility coefficient. PDMS permeability can be modified by changing the degree of substitution, silicone backbone chain length, structure, and alkyl chain length - with shorter alkyl chains and longer backbones increasing permeability. Further research aims to figure out reaction mechanisms to add more hydrocarbon chain length and decrease PDMS permeability
The document discusses leaching during phase inversion membrane formation and the solution-diffusion model of permeation in polymer membranes. During phase inversion, a fraction of the polymer material leaches out into the solvent, resulting in different membrane morphologies. The solution-diffusion model describes permeation as a three step process where materials dissolve in the membrane, diffuse through it down a concentration gradient, then desorb on the other side. Diffusion through the polymer is the slowest and rate-limiting step.
This document provides an overview of mass transfer concepts and processes. It begins with definitions of mass transfer and examples of mass transfer in nature. It then discusses various separation processes that rely on mass transfer principles, including distillation, gas absorption, drying, and crystallization. Key mass transfer topics covered include molecular diffusion, interphase mass transfer, mass transfer coefficients, and gas-liquid contacting equipment like tray towers and packed towers.
In the Process of generating Nitrogen, Carbon Molecular Sieve (CMS) plays a very vital role. With the help of CMS only Nitrogen is produced. CMS takes up the oxygen, carbon dioxide and other impurities and release the pure nitrogen.
PSA is one of the unique processes in which gases are separated with the help of pressure swing technology is called PSA. In this process when the bed is in desorption mode with the help of release pressure it is been regenerated and then to swing to adsorption mode.
This document discusses membrane separation processes. It defines membranes as thin layers that selectively control the transport of materials between phases. There are two main types of membranes: permeable and semipermeable. Membrane processes are classified based on the size of materials separated and the driving force used. Examples given include reverse osmosis and ultrafiltration in the dairy industry. Key concepts covered include transmembrane pressure, recovery percentage, molecular weight cutoff, and solute rejection coefficient. Advantages of membrane separation include energy savings, low temperature operation, and recovery of both concentrate and permeate.
Distillation is the most important separation technology in the chemical process industry. More than 90% of separations are based on distillation.
Hybrid systems offer an interesting alternative in some difficult separations for distillation with either large number of theoretical trays; large heat loads or both.
Hybrid processes in separation operations are characterized by the combination of two unit operations.
Each unit operation itself is considered to be a separation process, but the combination generates special advantages.
This document discusses dispersion systems and emulsions in oil refining. It defines dispersion systems as heterogeneous systems containing one substance dispersed in another substance. Dispersion systems consist of a dispersed phase and dispersion medium. Emulsions are mixtures of two or more immiscible liquids where one liquid is dispersed as droplets in another. The document discusses different types of emulsions and dispersion systems based on properties like particle size, phase state, and interaction between phases. It also discusses emulsion formation, stabilization, and breaking emulsions through various demulsification methods.
This document discusses air sampling methods and gas chromatography. It provides an overview of different air sampling techniques for particulate and gaseous pollutants including filtration, impingement, precipitation, absorption and adsorption sampling. It also describes the basic components and process of gas chromatography, including the carrier gas, column, stationary phase, detectors and how it can be used for qualitative analysis of mixtures. Gas chromatography is presented as a technique that separates mixtures based on differential partitioning between a mobile gas phase and a stationary liquid or solid phase.
This document discusses air sampling methods and gas chromatography. It provides an overview of different air sampling techniques for particulate and gaseous pollutants including filtration, impingement, precipitation, absorption, adsorption and condensation. It also describes the basic components and process of gas chromatography, including carrier gases, columns, stationary phases, detectors and how it can be used for qualitative analysis. Gas chromatography is presented as a technique to separate and analyze mixtures using differences in volatility and polarity between components.
Absorption and stripping ppt by sumon sahoosanjibmahata2
This document provides an overview of absorption and stripping mass transfer operations. It defines absorption as removing a solute gas from a mixture of gases by extracting it into a liquid solvent, while stripping is the reverse process of removing a solute gas from a liquid. It compares plate and packed columns, discussing their advantages. It also covers counter-current flow, solvent selection criteria, mass balances, applications like H2S removal and gas purification, and concludes that absorption is the operation of preferentially dissolving one or more gas components into a liquid.
This document discusses air sampling methods and gas chromatography. It begins by describing various air sampling techniques for particulate and gaseous pollutants, including filtration, impingement, precipitation, absorption, adsorption and condensation. It then discusses gas chromatography, explaining the basic components and process. Key aspects covered are the carrier gas, column, stationary phase, detectors and how gas chromatography can be used to qualitatively analyze samples based on retention times and peak detection.
This document provides an overview of membrane technology. It defines membrane technology as processes that use semipermeable membranes to separate molecules and ions on a molecular level. The document then discusses various membrane separation processes like microfiltration, ultrafiltration, nanofiltration and reverse osmosis. It also covers membrane materials, modules, factors affecting performance, fouling, and applications of membrane technology in food processing industries like juice, dairy, fermented beverages and probiotic beverages. Emerging applications of membrane technology in novel food processing techniques and high-pressure processes are also mentioned.
This document discusses various techniques for separating solids, liquids, and gases. It describes processes like gravity separation, sieving, magnetic separation, and chemical leaching to separate contaminants from soils. Filtration, distillation, freeze crystallization, membrane pervaporation, and reverse osmosis are discussed as methods to separate dissolved and undissolved particles from liquids. Finally, techniques for gas separation are covered, including pressure swing adsorption, vacuum swing adsorption, temperature swing adsorption, cryogenic distillation, and membrane gas separation.
A review on affinity chromatography.ppt shadybenjamin ejeh
This document reviews affinity chromatography. It discusses how affinity chromatography uses the reversible binding between a target molecule and ligand attached to a matrix to purify proteins. The document outlines the key components of affinity chromatography systems - the matrix, spacer arm, and ligand. It also describes the principles, stages, applications, advantages and disadvantages of affinity chromatography.
This presentation provides an overview of bubble column reactors. It begins with an introduction that defines a bubble column reactor as a cylindrical vessel with a gas distributor at the bottom used for multiphase contact and reactions. The presentation then covers the theory of bubble column operation, design equations for parameters like superficial gas velocity and gas holdup, applications in chemical processes, and advantages like good heat and mass transfer with low costs and no moving parts.
Gas chromatography is an analytical technique used to separate and analyze volatile compounds. It works by distributing the sample between a stationary phase and a mobile gas phase. Key components of a gas chromatography system include the carrier gas, injector, column, and detector. The column allows separation of compounds based on differences in partitioning between the stationary and mobile phases. Detectors then provide a quantitative measurement of separated components. Common applications of gas chromatography include analysis of pharmaceuticals, foods, flavors, fragrances, and petrochemicals.
This document summarizes membrane separation processes. It describes that membrane separation uses a semi-permeable barrier to allow faster movement of some components over others. The retained part is called retentate and the passing part permeate. Membrane separation is desirable as it saves energy, has a long membrane life, is defect-free, compact and easily operated. The document discusses membrane materials, permeance factors, transport mechanisms including porous and non-porous membranes. It provides examples of industrial applications like dialysis, reverse osmosis, and pervaporation.
The document discusses various methods for controlling gaseous contaminants, including absorption, adsorption, condensation, and incineration. Absorption involves dissolving a gas in a liquid, such as water, through solubility and mass transfer. Adsorption accumulates molecules on surfaces through physical or chemical attraction. Condensation occurs when a gas changes to a liquid due to cooling and condensation nuclei. Incineration uses combustion and high temperatures to convert waste into ash, flue gas, and heat.
Current advancement in different gas liquid operationsSunny Chauhan
CURRENT ADVANCEMENT IN DIFFERENT GAS-LIQUID OPERATIONS,Gas Liquid operation equipment
,Extractive distillation
,Advances in Gas Absorption,High efficiency venturi scrubber
,Advances in Diffusion
,Advances in Stirred Tanks
,Advances in Distillation
,Advances in Venturi Scrubber
Mixing is defined as reducing inhomogeneity to achieve a desired process result, where the inhomogeneity can be of concentration, phase, or temperature. Agitation accomplishes mixing of phases and enhances mass and heat transfer between phases and external surfaces. Basic design factors for mixing include impellers, vessel dimensions, impeller placement, and operating parameters like speed. Mixing occurs through distribution, which transports materials throughout the vessel via bulk currents, and dispersion, which facilitates rapid transfer through the creation of eddies down to the Kolmogorov scale of mixing. The mixing time is considered the time for the concentration to differ from the final concentration by less than 10% after initial segregation.
This document discusses gas chromatography. It begins by defining chromatography and describing different chromatography techniques. It then focuses on gas chromatography, explaining that the mobile phase is a carrier gas and the stationary phase is a liquid or polymer coating inside a column. Key components of a gas chromatograph are described, including the carrier gas, injector, column, temperature control, stationary phases, and detectors. The document discusses how gas chromatography can be used for qualitative analysis of compounds and lists some advantages and disadvantages. It concludes by mentioning gas chromatography-mass spectrometry as a modern approach.
This document discusses the fundamentals of rheology and how rheological tests can help with polymer processing and development. It describes different types of rheometers including capillary, rotational, and extensional rheometers. Capillary rheology provides information about how materials behave when melted and correlates flow parameters to mechanical properties. Capillary rheology can determine optimal processing parameters and investigate issues. The document also discusses how rheological properties relate to molecular weight and processing techniques like extrusion, injection molding, and blow molding that can be simulated using a capillary rheometer.
Null Bangalore | Pentesters Approach to AWS IAMDivyanshu
#Abstract:
- Learn more about the real-world methods for auditing AWS IAM (Identity and Access Management) as a pentester. So let us proceed with a brief discussion of IAM as well as some typical misconfigurations and their potential exploits in order to reinforce the understanding of IAM security best practices.
- Gain actionable insights into AWS IAM policies and roles, using hands on approach.
#Prerequisites:
- Basic understanding of AWS services and architecture
- Familiarity with cloud security concepts
- Experience using the AWS Management Console or AWS CLI.
- For hands on lab create account on [killercoda.com](https://killercoda.com/cloudsecurity-scenario/)
# Scenario Covered:
- Basics of IAM in AWS
- Implementing IAM Policies with Least Privilege to Manage S3 Bucket
- Objective: Create an S3 bucket with least privilege IAM policy and validate access.
- Steps:
- Create S3 bucket.
- Attach least privilege policy to IAM user.
- Validate access.
- Exploiting IAM PassRole Misconfiguration
-Allows a user to pass a specific IAM role to an AWS service (ec2), typically used for service access delegation. Then exploit PassRole Misconfiguration granting unauthorized access to sensitive resources.
- Objective: Demonstrate how a PassRole misconfiguration can grant unauthorized access.
- Steps:
- Allow user to pass IAM role to EC2.
- Exploit misconfiguration for unauthorized access.
- Access sensitive resources.
- Exploiting IAM AssumeRole Misconfiguration with Overly Permissive Role
- An overly permissive IAM role configuration can lead to privilege escalation by creating a role with administrative privileges and allow a user to assume this role.
- Objective: Show how overly permissive IAM roles can lead to privilege escalation.
- Steps:
- Create role with administrative privileges.
- Allow user to assume the role.
- Perform administrative actions.
- Differentiation between PassRole vs AssumeRole
Try at [killercoda.com](https://killercoda.com/cloudsecurity-scenario/)
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This document discusses dispersion systems and emulsions in oil refining. It defines dispersion systems as heterogeneous systems containing one substance dispersed in another substance. Dispersion systems consist of a dispersed phase and dispersion medium. Emulsions are mixtures of two or more immiscible liquids where one liquid is dispersed as droplets in another. The document discusses different types of emulsions and dispersion systems based on properties like particle size, phase state, and interaction between phases. It also discusses emulsion formation, stabilization, and breaking emulsions through various demulsification methods.
This document discusses air sampling methods and gas chromatography. It provides an overview of different air sampling techniques for particulate and gaseous pollutants including filtration, impingement, precipitation, absorption and adsorption sampling. It also describes the basic components and process of gas chromatography, including the carrier gas, column, stationary phase, detectors and how it can be used for qualitative analysis of mixtures. Gas chromatography is presented as a technique that separates mixtures based on differential partitioning between a mobile gas phase and a stationary liquid or solid phase.
This document discusses air sampling methods and gas chromatography. It provides an overview of different air sampling techniques for particulate and gaseous pollutants including filtration, impingement, precipitation, absorption, adsorption and condensation. It also describes the basic components and process of gas chromatography, including carrier gases, columns, stationary phases, detectors and how it can be used for qualitative analysis. Gas chromatography is presented as a technique to separate and analyze mixtures using differences in volatility and polarity between components.
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This document provides an overview of absorption and stripping mass transfer operations. It defines absorption as removing a solute gas from a mixture of gases by extracting it into a liquid solvent, while stripping is the reverse process of removing a solute gas from a liquid. It compares plate and packed columns, discussing their advantages. It also covers counter-current flow, solvent selection criteria, mass balances, applications like H2S removal and gas purification, and concludes that absorption is the operation of preferentially dissolving one or more gas components into a liquid.
This document discusses air sampling methods and gas chromatography. It begins by describing various air sampling techniques for particulate and gaseous pollutants, including filtration, impingement, precipitation, absorption, adsorption and condensation. It then discusses gas chromatography, explaining the basic components and process. Key aspects covered are the carrier gas, column, stationary phase, detectors and how gas chromatography can be used to qualitatively analyze samples based on retention times and peak detection.
This document provides an overview of membrane technology. It defines membrane technology as processes that use semipermeable membranes to separate molecules and ions on a molecular level. The document then discusses various membrane separation processes like microfiltration, ultrafiltration, nanofiltration and reverse osmosis. It also covers membrane materials, modules, factors affecting performance, fouling, and applications of membrane technology in food processing industries like juice, dairy, fermented beverages and probiotic beverages. Emerging applications of membrane technology in novel food processing techniques and high-pressure processes are also mentioned.
This document discusses various techniques for separating solids, liquids, and gases. It describes processes like gravity separation, sieving, magnetic separation, and chemical leaching to separate contaminants from soils. Filtration, distillation, freeze crystallization, membrane pervaporation, and reverse osmosis are discussed as methods to separate dissolved and undissolved particles from liquids. Finally, techniques for gas separation are covered, including pressure swing adsorption, vacuum swing adsorption, temperature swing adsorption, cryogenic distillation, and membrane gas separation.
A review on affinity chromatography.ppt shadybenjamin ejeh
This document reviews affinity chromatography. It discusses how affinity chromatography uses the reversible binding between a target molecule and ligand attached to a matrix to purify proteins. The document outlines the key components of affinity chromatography systems - the matrix, spacer arm, and ligand. It also describes the principles, stages, applications, advantages and disadvantages of affinity chromatography.
This presentation provides an overview of bubble column reactors. It begins with an introduction that defines a bubble column reactor as a cylindrical vessel with a gas distributor at the bottom used for multiphase contact and reactions. The presentation then covers the theory of bubble column operation, design equations for parameters like superficial gas velocity and gas holdup, applications in chemical processes, and advantages like good heat and mass transfer with low costs and no moving parts.
Gas chromatography is an analytical technique used to separate and analyze volatile compounds. It works by distributing the sample between a stationary phase and a mobile gas phase. Key components of a gas chromatography system include the carrier gas, injector, column, and detector. The column allows separation of compounds based on differences in partitioning between the stationary and mobile phases. Detectors then provide a quantitative measurement of separated components. Common applications of gas chromatography include analysis of pharmaceuticals, foods, flavors, fragrances, and petrochemicals.
This document summarizes membrane separation processes. It describes that membrane separation uses a semi-permeable barrier to allow faster movement of some components over others. The retained part is called retentate and the passing part permeate. Membrane separation is desirable as it saves energy, has a long membrane life, is defect-free, compact and easily operated. The document discusses membrane materials, permeance factors, transport mechanisms including porous and non-porous membranes. It provides examples of industrial applications like dialysis, reverse osmosis, and pervaporation.
The document discusses various methods for controlling gaseous contaminants, including absorption, adsorption, condensation, and incineration. Absorption involves dissolving a gas in a liquid, such as water, through solubility and mass transfer. Adsorption accumulates molecules on surfaces through physical or chemical attraction. Condensation occurs when a gas changes to a liquid due to cooling and condensation nuclei. Incineration uses combustion and high temperatures to convert waste into ash, flue gas, and heat.
Current advancement in different gas liquid operationsSunny Chauhan
CURRENT ADVANCEMENT IN DIFFERENT GAS-LIQUID OPERATIONS,Gas Liquid operation equipment
,Extractive distillation
,Advances in Gas Absorption,High efficiency venturi scrubber
,Advances in Diffusion
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,Advances in Venturi Scrubber
Mixing is defined as reducing inhomogeneity to achieve a desired process result, where the inhomogeneity can be of concentration, phase, or temperature. Agitation accomplishes mixing of phases and enhances mass and heat transfer between phases and external surfaces. Basic design factors for mixing include impellers, vessel dimensions, impeller placement, and operating parameters like speed. Mixing occurs through distribution, which transports materials throughout the vessel via bulk currents, and dispersion, which facilitates rapid transfer through the creation of eddies down to the Kolmogorov scale of mixing. The mixing time is considered the time for the concentration to differ from the final concentration by less than 10% after initial segregation.
This document discusses gas chromatography. It begins by defining chromatography and describing different chromatography techniques. It then focuses on gas chromatography, explaining that the mobile phase is a carrier gas and the stationary phase is a liquid or polymer coating inside a column. Key components of a gas chromatograph are described, including the carrier gas, injector, column, temperature control, stationary phases, and detectors. The document discusses how gas chromatography can be used for qualitative analysis of compounds and lists some advantages and disadvantages. It concludes by mentioning gas chromatography-mass spectrometry as a modern approach.
This document discusses the fundamentals of rheology and how rheological tests can help with polymer processing and development. It describes different types of rheometers including capillary, rotational, and extensional rheometers. Capillary rheology provides information about how materials behave when melted and correlates flow parameters to mechanical properties. Capillary rheology can determine optimal processing parameters and investigate issues. The document also discusses how rheological properties relate to molecular weight and processing techniques like extrusion, injection molding, and blow molding that can be simulated using a capillary rheometer.
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#Abstract:
- Learn more about the real-world methods for auditing AWS IAM (Identity and Access Management) as a pentester. So let us proceed with a brief discussion of IAM as well as some typical misconfigurations and their potential exploits in order to reinforce the understanding of IAM security best practices.
- Gain actionable insights into AWS IAM policies and roles, using hands on approach.
#Prerequisites:
- Basic understanding of AWS services and architecture
- Familiarity with cloud security concepts
- Experience using the AWS Management Console or AWS CLI.
- For hands on lab create account on [killercoda.com](https://killercoda.com/cloudsecurity-scenario/)
# Scenario Covered:
- Basics of IAM in AWS
- Implementing IAM Policies with Least Privilege to Manage S3 Bucket
- Objective: Create an S3 bucket with least privilege IAM policy and validate access.
- Steps:
- Create S3 bucket.
- Attach least privilege policy to IAM user.
- Validate access.
- Exploiting IAM PassRole Misconfiguration
-Allows a user to pass a specific IAM role to an AWS service (ec2), typically used for service access delegation. Then exploit PassRole Misconfiguration granting unauthorized access to sensitive resources.
- Objective: Demonstrate how a PassRole misconfiguration can grant unauthorized access.
- Steps:
- Allow user to pass IAM role to EC2.
- Exploit misconfiguration for unauthorized access.
- Access sensitive resources.
- Exploiting IAM AssumeRole Misconfiguration with Overly Permissive Role
- An overly permissive IAM role configuration can lead to privilege escalation by creating a role with administrative privileges and allow a user to assume this role.
- Objective: Show how overly permissive IAM roles can lead to privilege escalation.
- Steps:
- Create role with administrative privileges.
- Allow user to assume the role.
- Perform administrative actions.
- Differentiation between PassRole vs AssumeRole
Try at [killercoda.com](https://killercoda.com/cloudsecurity-scenario/)
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3. INTRODUCTION
Gas separation refers to the process of isolating or
extracting specific gases from a mixture using
various methods and technologies.
Gas separation is crucial across industries for
purifying gases, enhancing air quality, and refining
products.
Membranes play a pivotal role by selectively
allowing specific gases to pass through while
retaining others.
4. TECHNIQUES FOR
GAS SEPARATION
Membrane
Separation
• Utilizes
membranes with
specific pore
sizes or materials
that allow
selective passage
of gases based
on their
molecular size,
shape, or affinity
for the
membrane
material
Adsorption
• Involves the
adherence of
gases onto
surfaces or
adsorbents,
where certain
gases are
preferentially
retained while
others pass
through
Absorption
• Relies on the
solubility of
gases in liquids
or solid
absorbents,
where specific
gases dissolve
more readily
than others,
allowing their
separation
Pressure Swing
Adsorption
• Cycles between
high and low
pressures to
adsorb and
desorb gases
onto adsorbents,
allowing
selective
separation
Cryogenic
Distillation
• Uses low
temperatures to
condense gases
into liquids,
separating
different
components
based on their
boiling points
6. Save Large Amount Of Energy
Long Life Membrane
Defect Free
More Contact
More Easily Operated, Controlled And Maintained
WHY MEMBRANE SEPARATION ?
10. MECHANISMS IN
POROUS MEMBRANES
MACROPOROUS MEMBRANES
ConvectiveFlowMechanism
• Larger pores allow gases to pass without selective separation
• Limited efficiency for gas separation due to pore size
13. MECHANISMS IN
DENSE POLYMER MEMBRANES
Solution-DiffusionMechanism
Permeation Overview
• Gas absorption, diffusion through the polymer matrix, and desorption
• Dependent on chemical structure and nature of the gas
14. PERMEABILITY COEFFICIENT (P)
• Represents the flux of a specific gas through the membrane
• Formula: P = Q⋅δ / A⋅Δp, where Q is the gas permeation rate, δ is membrane thickness, A is
membrane surface area, and Δp is the pressure difference
SELECTIVITY (α)
• Ratio of permeability coefficients of different gases
• Formula: α = Pi / Pj for single gas permeation
RELATIONSHIP BETWEEN P, D, AND S
• P = D × S defines the relationship between permeability, diffusivity, and solubility coefficients
• Diffusivity reflects molecule mobility; solubility increases with molecular weight
KEY PARAMETERS AFFECTING
MEMBRANE PERFORMANCE
15. SORPTION MECHANISMS IN RUBBERY MEMBRANES
Henry’s LawandSolution-Diffusion
• Describes sorption of low molecular weight gases in rubbery polymers.
• Solution-diffusion mechanism akin to penetrant sorption in low molecular weight liquids.
Temperature-DependentSorptionBehavior
• Describes the behavior of rubbery membranes at varying temperatures and gas concentrations.
SORPTION PROCESSES IN GLASSY MEMBRANES
Dual-ModeModelandLangmuir Adsorption
• Differentiates between gas molecules absorbed in the polymer matrix and those adsorbed in microscopic
voids.
• Dual sorption components influence overall sorption behavior.
DIFFERENCES BETWEEN
RUBBERY AND GLASSY
MEMBRANES